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1. 发明授权

US5777182A Cobalt-catalyzed process for preparing 1,3-propanidiol 失效
标题翻译：用于制备1,3-丙二醇的钴催化方法
公开(公告)号：US5777182A
公开(公告)日：1998-07-07
申请号：US703295
申请日：1996-08-26
申请人： Joseph Broun Powell , Lynn Henry Slaugh , Thomas Clayton Forschner , Jiang-Jen Lin , Terry Blane Thomason , Paul Richard Weider , Thomas Carl Semple , Juan Pedro Arhancet , Howard Lam-Ho Fong , Stephen Blake Mullin , Kevin Dale Allen , David Cleve Eubanks , David William Johnson
发明人： Joseph Broun Powell , Lynn Henry Slaugh , Thomas Clayton Forschner , Jiang-Jen Lin , Terry Blane Thomason , Paul Richard Weider , Thomas Carl Semple , Juan Pedro Arhancet , Howard Lam-Ho Fong , Stephen Blake Mullin , Kevin Dale Allen , David Cleve Eubanks , David William Johnson
IPC分类号： C07C29/141 , C07C45/58 , C07C45/80 , C07C27/04
CPC分类号： C07C45/58 , C07C29/141 , C07C45/80
摘要： 1,3-propanediol is prepared in a process which involves hydroformylating ethylene oxide: (a) in an essentially non-water-miscible solvent in the presence of a non-ligated cobalt catalyst and a catalyst promoter at a temperature within the range of about 50.degree. to about 100.degree. C. and a pressure within the range of about 500 to about 5000 psig, to produce an intermediate product mixture comprising less than about 15 wt % 3-hydroxypropanal; (b) adding an aqueous liquid and extracting at a temperature less than about 100.degree. C. the 3-hydroxypropanal to provide an aqueous phase comprising 3-hydroxypropanal in greater concentration than the concentration of 3-hydroxypropanal in said intermediate product mixture, and an organic phase comprising the cobalt catalyst; (c) separating the aqueous phase from the organic phase; (d) hydrogenating the 3-hydroxypropanal to provide a hydrogenation product mixture comprising 1,3-propanediol; and (e) recovering 1,3-propanediol from said hydrogenation product mixture. The process enables the production of 1,3-propanediol in high yields and selectivity without the use of a phosphine ligand-modified cobalt catalyst.
摘要翻译： 1,3-丙二醇的制备方法包括在环氧乙烷中加氢甲酰化：（a）在非连接的钴催化剂和催化剂助催化剂存在下，在基本上与水不混溶的溶剂中，温度范围为约 50℃至约100℃，压力范围为约500至约5000psig，以产生包含小于约15重量％的3-羟基丙醛的中间产物混合物; （b）加入水性液体并在低于约100℃的温度下提取3-羟基丙醛，以提供比所述中间产物混合物中3-羟基丙醛浓度更高浓度的3-羟基丙醛的水相，以及包含钴催化剂的有机相; （c）将水相与有机相分离; （d）氢化3-羟基丙醛以提供包含1,3-丙二醇的氢化产物混合物; 和（e）从所述氢化产物混合物中回收1,3-丙二醇。该方法能够以高产率和选择性生产1,3-丙二醇，而不需要使用膦配体改性的钴催化剂。

2. 发明授权

US5981808A Cobalt-catalyzed process for preparing 1, 3-propanediol from etylene oxide 失效
标题翻译：用于由乙烯氧化物制备1,3-丙二醇的钴催化方法
公开(公告)号：US5981808A
公开(公告)日：1999-11-09
申请号：US892831
申请日：1997-07-15
申请人： Joseph Broun Powell , Lynn Henry Slaugh , David Cleve Eubanks , Stephan Blake Mullin , Terry Blain Thomason , Paul Richard Weider , Thomas Carl Semple
发明人： Joseph Broun Powell , Lynn Henry Slaugh , David Cleve Eubanks , Stephan Blake Mullin , Terry Blain Thomason , Paul Richard Weider , Thomas Carl Semple
IPC分类号： C07C29/141 , C07C45/58 , C07C27/00
CPC分类号： C07C29/141 , C07C45/58
摘要： 1,3-Propanediol is prepared in a process which involves reacting ethylene oxide with carbon monoxide and hydrogen in an essentially non-water-miscible solvent in the presence of a non-phosphine-ligated cobalt catalyst and a catalyst promoter to produce an intermediate product mixture containing 3-hydroxypropanal in an amount less than 15 wt %; extracting the 3-hydroxypropanal from the intermediate product mixture into an aqueous liquid at a temperature less than about 100.degree. C. and separating the aqueous phase containing 3-hydroxypropanal from the organic phase containing cobalt catalyst; hydrogenating the 3-hydroxypropanal in the aqueous phase to 1,3-propanediol; and recovering the 1,3-propanediol.The process enables the production of 1,3-propanediol in high yield and selectivity without the use of a phosphine ligand-modified cobalt catalyst.
摘要翻译：在一种方法中制备1,3-丙二醇，该方法包括在非磷化氢连接的钴催化剂和催化剂促进剂的存在下，将环氧乙烷与一氧化碳和氢气在基本上不与水相混溶的溶剂中反应以产生中间产物含有小于15重量％的3-羟基丙醛的混合物; 在低于约100℃的温度下将中间产物混合物中的3-羟基丙醛萃取到含水液体中，并从含钴催化剂的有机相中分离出含有3-羟基丙醛的水相; 将水相中的3-羟基丙醛氢化为1,3-丙二醇; 并回收1,3-丙二醇。该方法能够以高产率和选择性生产1,3-丙二醇，而不需要使用膦配位体改性的钴催化剂。

3. 发明申请

US20090032437A1 Catalytic Distillation Process for Primary Haloalkanes 失效
标题翻译：主要卤代烷烃的催化蒸馏工艺
公开(公告)号：US20090032437A1
公开(公告)日：2009-02-05
申请号：US11887195
申请日：2006-03-24
申请人： Howard Lam-Ho Fong , Brendan Dermot Murray , Thomas Carl Semple
发明人： Howard Lam-Ho Fong , Brendan Dermot Murray , Thomas Carl Semple
IPC分类号： C10G65/02 , C07C19/075
CPC分类号： C07C17/23 , A61K8/20 , A61Q17/04 , C07C17/10 , C07C17/358 , C07C17/383 , C07C41/16 , C11D1/72 , C11D11/0082 , Y02P20/127 , C07C19/075 , C07C43/04
摘要： A process for making primary haloalkanes by catalytic distillation of internal haloalkanes which comprises a) introducing an internal haloalkane feed into a catalytic distillation column; b) isomerizing at least a portion of the internal haloalkane feed in the presence of an internal haloalkane isomerization catalyst at a temperature at or above the boiling point of the internal haloalkanes and below the temperature and pressure at which hydrogen halide is formed to form primary haloalkanes; and removing the primary haloalkanes from the catalytic distillation column.
摘要翻译：通过内部卤代烷烃的催化蒸馏制备主要卤代烷烃的方法，其包括：a）将内部卤代烷烃进料引入催化蒸馏塔; b）在内部卤代烷烃异构化催化剂的存在下，在内部卤代烷烃的沸点或高于内部卤代烷的沸点的温度和低于形成卤化氢的温度和压力下形成主要的卤代烷烃，异构化内部卤代烷烃进料的至少一部分 ; 并从催化蒸馏塔中除去主卤代烷烃。

4. 发明授权

US08115039B2 Catalytic distillation process for primary haloalkanes 失效
标题翻译：主要卤代烷烃的催化蒸馏方法
公开(公告)号：US08115039B2
公开(公告)日：2012-02-14
申请号：US11887195
申请日：2006-03-24
申请人： Howard Lam-Ho Fong , Brendan Dermot Murray , Thomas Carl Semple
发明人： Howard Lam-Ho Fong , Brendan Dermot Murray , Thomas Carl Semple
IPC分类号： C07C21/00
CPC分类号： C07C17/23 , A61K8/20 , A61Q17/04 , C07C17/10 , C07C17/358 , C07C17/383 , C07C41/16 , C11D1/72 , C11D11/0082 , Y02P20/127 , C07C19/075 , C07C43/04
摘要： A process for making primary haloalkanes by catalytic distillation of internal haloalkanes which comprises a) introducing an internal haloalkane feed into a catalytic distillation column; b) isomerizing at least a portion of the internal haloalkane feed in the presence of an internal haloalkane isomerization catalyst at a temperature at or above the boiling point of the internal haloalkanes and below the temperature and pressure at which hydrogen halide is formed to form primary haloalkanes; and removing the primary haloalkanes from the catalytic distillation column.
摘要翻译：通过内部卤代烷烃的催化蒸馏制备主要卤代烷烃的方法，其包括：a）将内部卤代烷烃进料引入催化蒸馏塔; b）在内部卤代烷烃异构化催化剂的存在下，在内部卤代烷烃的沸点或高于内部卤代烷的沸点的温度和低于形成卤化氢的温度和压力下形成主要的卤代烷烃，异构化内部卤代烷烃进料的至少一部分 ; 并从催化蒸馏塔中除去主卤代烷烃。

5. 发明申请

US20090270655A1 Conversion of Alkylhalides Into Alcohol Alkoxylates 审中-公开
标题翻译：烷基卤转化为醇烷氧基化物
公开(公告)号：US20090270655A1
公开(公告)日：2009-10-29
申请号：US11887194
申请日：2006-03-24
申请人： Howard Lam-Ho Fong , Thomas Howard Johnson , Thomas Carl Semple
发明人： Howard Lam-Ho Fong , Thomas Howard Johnson , Thomas Carl Semple
IPC分类号： C07C41/01
CPC分类号： A61Q17/04 , A61K8/39 , C07C41/16 , C11D1/72 , C11D11/04 , C07C43/15 , C07C43/11
摘要： A process for converting alkyl halides to alkyl alcohol alkoxylates is described. This is a direct alkoxylation because the alkyl alcohol alkoxylates are made without going through an alkyl alcohol intermediate. The process comprises direct alkoxylation coupling of alkyl halides with a nucleophilic material in the presence of a homogeneous catalyst system to produce alkyl alcohol alkoxylates, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds. A process for converting alkanes (paraffins) to alkyl alcohol alkoxylates is also described. This method comprises a) halogenation of at least one alkane to produce at least one alkyl halide; and b) direct alkoxylation coupling of at least a portion of the alkyl halide with a nucleophilic material in the presence of a homogeneous catalyst system to produce alkyl alcohol alkoxylates, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds.
摘要翻译：描述了将烷基卤转化为烷基醇烷氧基化物的方法。这是直接烷氧基化，因为烷基醇烷氧基化物不经过烷基醇中间体而制备。该方法包括在均相催化剂体系存在下烷基卤与亲核材料的直接烷氧基化偶合以产生烷基醇烷氧基化物，其中均相催化剂体系包含至少一种具有形成金属 - 卤素键的能力的金属或金属化合物。还描述了将烷烃（链烷烃）转化成烷基醇烷氧基化物的方法。该方法包括a）至少一种烷烃的卤化以产生至少一种烷基卤; 和b）在均相催化剂体系存在下，烷基卤化物与亲核材料的至少一部分直接烷氧基化偶联以产生烷基醇烷氧基化物，其中均相催化剂体系包含至少一种具有能力的金属或金属化合物以形成金属 - 卤素键。

6. 发明申请

US20090054274A1 Formation of Heteroatom Containing Derivatives of Paraffins 审中-公开
标题翻译：含有衍生物的杂原子的形成
公开(公告)号：US20090054274A1
公开(公告)日：2009-02-26
申请号：US11887169
申请日：2006-03-24
申请人： Howard Lam-Ho Fong , Thomas Howard Johnson , Thomas Carl Semple
发明人： Howard Lam-Ho Fong , Thomas Howard Johnson , Thomas Carl Semple
IPC分类号： E21B43/25 , C07C17/23 , C07C43/10
CPC分类号： C07C41/16 , C07C17/23 , C07C17/38 , C07C19/075 , C07C43/11 , C07C43/15
摘要： A process by which alkyl halides may be reacted (coupled) with nucleophilic materials in the presence of a homogeneous catalyst system. The process comprises reacting (coupling) alkyl halides with a nucleophilic material in the presence of a homogeneous catalyst system to produce derivatives of alkyl halides, wherein the homogeneous catalyst system comprises at least one metal or metal compound which has the ability to form metal-halogen bonds.
摘要翻译：在均相催化剂体系存在下，烷基卤化物可与亲核材料反应（偶联）的方法。该方法包括在均相催化剂体系的存在下使烷基卤与亲核材料反应（偶合）以产生烷基卤化物的衍生物，其中均相催化剂体系包含至少一种具有形成金属卤素的能力的金属或金属化合物债券。

7. 发明申请

US20120181025A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A VERY HIGH SALINITY, HIGH TEMPERATURE FORMATION 有权
标题翻译：来自非常高的盐度，高温形成的增强烃的回收方法和组合
公开(公告)号：US20120181025A1
公开(公告)日：2012-07-19
申请号：US13264172
申请日：2010-04-14
申请人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： E21B43/00
CPC分类号： C09K8/584
摘要： A method of treating a very high salinity high temperature hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of a hydrocarbon containing formation having a brine salinity of above about 13 wt % and a temperature of above about 7° C., wherein the composition comprises a C15-18 internal olefin sulfonate; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译：描述了处理非常高盐度的高温含烃地层的方法。该方法包括（a）向至少一部分具有高于约13重量％的盐水盐度和高于约7℃的温度的含烃地层提供烃回收组合物，其中所述组合物包含C15-18 内烯烃磺酸盐; 和（b）允许组合物与含烃地层中的烃相互作用。

8. 发明申请

US20110021389A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY 有权
标题翻译：增强烃回收方法与组合
公开(公告)号：US20110021389A1
公开(公告)日：2011-01-27
申请号：US12866245
申请日：2009-02-06
申请人： Kirk Herbert Raney , Thomas Carl Semple
发明人： Kirk Herbert Raney , Thomas Carl Semple
IPC分类号： C09K8/58
CPC分类号： C09K8/584
摘要： A method of treating a hydrocarbon containing formation, comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the hydrocarbon recovery composition comprises a propoxylated composition which comprises (1) a glycerol sulfonate of a propoxylated primary alcohol having a branched aliphatic group with an average carbon number from 10 to 24 and having an average number of branches per aliphatic group of from 0.7 to 2.5 and having at least 0.5, preferably from 3 to 12, moles of propylene oxide per mole of primary alcohol and (2) polypropylene glycol; provided that the primary alcohol is propoxylated by contacting the alcohol with propylene oxide in the presence of a catalytically effective amount of one or more of the phosphate salts of lanthanum series elements or the rare earth elements, preferably a carbonate salt thereof, wherein the propoxylated composition comprising the propoxylated alcohol and from 1 to 30 wt % of polypropylene glycol is produced; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译：一种处理含烃地层的方法，包括（a）向所述含烃地层的至少一部分提供烃回收组合物，其中所述烃回收组合物包含丙氧基化组合物，其包含（1）丙氧基化初级的甘油磺酸盐具有平均碳数为10至24并且每个脂族基团的平均分支数为0.7至2.5并且每摩尔初级粒子具有至少0.5，优选3至12摩尔环氧丙烷的支链脂族基团的醇的醇，醇和（2）聚丙二醇; 条件是通过在催化有效量的一种或多种镧系元素的磷酸盐或稀土元素，优选其碳酸盐的存在下，使醇与环氧丙烷接触，将伯醇丙氧基化，其中丙氧基化组合物包括丙氧基化醇和1至30wt％的聚丙二醇; 和（b）允许组合物与含烃地层中的烃相互作用。

9. 发明授权

US06451937B1 Selective, catalytic, thermal functionalization of primary C-H hydrocarbon bonds 失效
标题翻译：主要C-H烃键的选择性，催化，热官能化
公开(公告)号：US06451937B1
公开(公告)日：2002-09-17
申请号：US09516897
申请日：2000-03-01
申请人： John F. Hartwig , Thomas Carl Semple , Huiyuan Chen
发明人： John F. Hartwig , Thomas Carl Semple , Huiyuan Chen
IPC分类号： C08F444
CPC分类号： C07F5/027 , B01J23/464 , B01J31/1608 , B01J31/2291 , B01J31/2295 , B01J2531/822 , B01J2531/827 , C07F5/025
摘要： A process for the catalytic coupling of aliphatic or alkyl branched alicyclic hydrocarbons with a functionalizing reagent under thermal conditions to selectively functionalize the hydrocarbon at its primary C—H site.
摘要翻译：脂肪族或烷基支链脂环烃与官能化试剂在热条件下催化偶合以在其初级C-H位点选择性官能化烃的方法。

10. 发明授权

US08759261B2 Method and composition for enhanced hydrocarbons recovery 有权
标题翻译：增强烃回收的方法和组成
公开(公告)号：US08759261B2
公开(公告)日：2014-06-24
申请号：US12366558
申请日：2009-02-05
申请人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
发明人： Julian Richard Barnes , Kirk Herbert Raney , Thomas Carl Semple , Paul Gregory Shpakoff , Johan Paul Smit , Jasper Roelf Smit
IPC分类号： C09K8/584 , B23G1/06 , E21B43/22
CPC分类号： C09K8/584
摘要： The present invention provides a method of treating a hydrocarbon containing formation comprising (a) providing a hydrocarbon recovery composition to at least a portion of the hydrocarbon containing formation, wherein the composition comprises one or more internal olefin sulfonates having 17 or more carbon atoms, (b) adding water and/or brine from the hydrocarbon formation to the composition, (c) adding a solubilizer which comprises an ethoxylated alcohol wherein the alcohol before ethoxylation had an average molecular weight of at least about 220 and (d) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation. The solubilizer may comprise less than about 0.1 wt %, preferably from about 0.02 to about 0.05 wt %, of the total composition and it may have from about 5 to about 9 moles of ethylene oxide per mole of alcohol.
摘要翻译：本发明提供了一种处理含烃地层的方法，包括（a）向含烃地层的至少一部分提供烃回收组合物，其中所述组合物包含一种或多种具有17个或更多个碳原子的内烯烃磺酸盐（ b）从组合物中加入水和/或盐水，（c）加入包含乙氧基化醇的增溶剂，其中乙氧基化前的醇的平均分子量至少约为220，（d）使组合物与含烃地层中的烃相互作用。增溶剂可以占总组合物的小于约0.1重量％，优选约0.02至约0.05重量％，并且每摩尔醇可具有约5至约9摩尔环氧乙烷。

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