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1. 发明授权

US4124693A Recovery, manipulation and storage of bromine 失效
标题翻译：溴的回收，操作和储存
公开(公告)号：US4124693A
公开(公告)日：1978-11-07
申请号：US833132
申请日：1977-09-14
申请人： Joseph A. Shropshire , Daniel J. Eustace
发明人： Joseph A. Shropshire , Daniel J. Eustace
IPC分类号： B01D53/68 , C01B7/09 , C01B7/10 , B01D53/34
CPC分类号： C01B7/096 , B01D53/68
摘要： An improved method of removing bromine from fluid streams comprises contacting the fluid stream with an aqueous solution of certain asymmetrical quaternary ammonium bromides whereby a liquid, water immiscible bromine complex is formed that can be stored, manipulated and readily handled and which complex can be dissociated to liberate molecular bromine.
摘要翻译：从流体流中除去溴的改进方法包括使流体流与某些不对称的季铵溴化物的水溶液接触，由此形成液体，水不混溶的溴络合物，其可以被储存，操纵和容易地处理，并且哪些络合物可以分解成释放分子溴。

2. 发明授权

US4124478A Thin sheet apparatus and a fluid flow device 失效
标题翻译：薄片装置和流体流动装置
公开(公告)号：US4124478A
公开(公告)日：1978-11-07
申请号：US766127
申请日：1977-02-07
申请人： Hsue C. Tsien , Joseph A. Shropshire , Agustin F. Venero
发明人： Hsue C. Tsien , Joseph A. Shropshire , Agustin F. Venero
IPC分类号： C25B9/00 , C25B9/20 , F28F3/08 , H01M8/02 , H01M8/24 , H01M12/02
CPC分类号： H01M8/246 , B01D63/082 , C25B9/20 , F28F3/083 , H01M8/0273 , B01D2313/10 , B01D2313/12 , Y10S366/03
摘要： A thin sheet apparatus is described as having a front and a back and having a central area and a frame area disposed around the central area. The central area is made of a fluid impermeable material having substantially planar surfaces. The frame area contains two sets of supply orifices and drainage orifices which are opposite one another. The frame area also contains a plurality of channels for each orifice which connects the orifice with the central area. The pluralities of channels for the first set of supply orifices and drainage orifices are located on the front of the frame area while the pluralities of channels for the second set of supply orifices and drainage orifices are located on the back. Also described is a fluid flow device which contains a number of stacked groups of elements in which each of the groups contains the above mentioned thin sheet apparatus as well as various plastic sheets having channels connecting the supply orifices and drainage orifices and having membrane separator means for the stacked elements. The fluid flow device is particularly useful as an electrochemical cell in a preferred embodiment in which the central area is made of conductive material and in which the stacked groups of elements contain current collectors at each end.
摘要翻译：薄片装置被描述为具有前部和后部并且具有设置在中心区域周围的中心区域和框架区域。中心区域由具有基本平坦表面的不透液体材料制成。框架区域包含两组彼此相对的供应孔和排水孔。框架区域还包括用于将孔口与中心区域连接的每个孔口的多个通道。第一组供水孔和排水孔的多个通道位于框架区域的前部，而第二组供水孔和排水孔的多个通道位于背面。还描述了一种流体流动装置，其包含多个堆叠的元件组，其中每个组包含上述薄片装置以及具有连接供给孔和排出孔的通道的各种塑料片，并且具有用于堆叠元素。在优选实施例中，流体流动装置特别适用于电化学电池，其中中心区域由导电材料制成，并且其中堆叠的元件组在每个端部都包含集电器。

3. 发明授权

US4125680A Bipolar carbon-plastic electrode structure-containing multicell electrochemical device and method of making same 失效
标题翻译：双极碳 - 塑料电极结构的多电化学电化学装置及其制备方法
公开(公告)号：US4125680A
公开(公告)日：1978-11-14
申请号：US825605
申请日：1977-08-18
申请人： Joseph A. Shropshire , Hsue C. Tsien
发明人： Joseph A. Shropshire , Hsue C. Tsien
IPC分类号： H01M6/48
CPC分类号： H01M6/48
摘要： A novel multicell electrochemical device having a plurality of bipolar carbon-plastic electrode structures and a novel method of making the device are described. A plurality of bipolar carbon-plastic electrode structures are formed by first molding thin conductive carbon-plastic sheets from heated mixtures of specified carbon and plastic, and then establishing frames of dielectric plastic material around the sheets and sealing the frames to the sheets so as to render the resulting structures liquid impermeable. A plurality of electrochemical cell elements in addition to the electrode structures, e.g. separators, spacers and the like, are also formed with dielectric plastic frames. The frames of both the electrode structures and the additional elements have projections on at least one surface. The electrode structures and the additional elements are stacked to form a group of items in an electrochemically functional arrangement. The arrangement is such that the projection of each frame contacts a frame surface of the next item in the stack. The items in the stack are joined to one another, e.g. by heat welding or ultrasonic welding, at these areas of contact so as to form a multicell electrochemical device capable of holding liquid therein.
摘要翻译：描述了一种具有多个双极碳 - 塑料电极结构的新型多电化学电化学装置和制造该装置的新颖方法。通过首先从特定碳和塑料的加热混合物成型薄导电碳塑料片，然后在片材周围建立介电塑料材料框架并将框架密封到片材上来形成多个双极碳 - 塑料电极结构，以便使所得到的结构液体不可渗透。除了电极结构之外的多个电化学电池元件，例如，分隔件，间隔件等也由电介质塑料框架形成。电极结构和附加元件的框架在至少一个表面上具有突起。电极结构和附加元件被堆叠以形成一组以电化学功能布置的物品。该布置使得每个框架的突起接触堆叠中的下一个物品的框架表面。堆叠中的项目彼此连接，例如。通过热焊接或超声波焊接，在这些接触区域形成能够保持液体的多电化学电化学装置。

4. 发明授权

US4052539A Electrochemical cell with a grahite intercalation compound cathode 失效
标题翻译：电化学细胞与GRAHITE INTERCALATION COMPAT CATHODE
公开(公告)号：US4052539A
公开(公告)日：1977-10-04
申请号：US760156
申请日：1977-01-17
申请人： Joseph A. Shropshire , Gerald H. Newman
发明人： Joseph A. Shropshire , Gerald H. Newman
IPC分类号： H01M4/58 , H01M4/587 , H01M10/052 , H01M10/054 , H01M10/0568 , H01M10/0569 , H01M10/36 , H01M6/14
CPC分类号： H01M4/58 , H01M10/052 , H01M10/0568 , H01M4/587 , H01M10/054 , H01M10/0569
摘要： A battery is disclosed having a nonaqueous electrolyte, an alkali metal anode and a cathode comprising a compound of grahite formed by reacting graphite with ClF.sub.3 and a Lewis acid fluoride of an element selected from B, Si, Ge, Sn, Pb, P, As, Sb, Bi, Ti, Zr, Hf, V, Nb and Ta.

5. 发明授权

US4286027A Shunt current protection for circulating electrolyte in monopolar battery systems (Bat-81) 失效
标题翻译：单极电池系统中电解液分流电流保护（Bat-81）
公开(公告)号：US4286027A
公开(公告)日：1981-08-25
申请号：US144679
申请日：1980-04-28
申请人： Joseph A. Shropshire , Patrick G. Grimes
发明人： Joseph A. Shropshire , Patrick G. Grimes
IPC分类号： H01M2/40 , H01M8/04 , H01M8/18 , H01M8/24
CPC分类号： H01M2/40 , H01M8/04276
摘要： Monopolar battery performance may be enhanced by circulating the electrolyte. A circulating electrolyte configuration for this type of system, however, gives rise to undesirable shunt current effects when used in series arrays. A protective current is applied to reduce or eliminate the shunt currents. The application of the protective current in aqueous monopolar battery systems will result in a REDOX reaction couple, wherein water is electrically consumed at the protective current anode and electrically replaced at the protective current cathode.
摘要翻译：通过循环电解液可以提高单极电池性能。然而，对于这种类型的系统的循环电解质构造在串联阵列中使用时会产生不期望的分流电流效应。施加保护电流以减少或消除分流电流。保护电流在水性单极电池系统中的应用将导致REDOX反应对，其中水在保护电流阳极处被电消耗并且在保护电流阴极处被电替换。

6. 发明授权

US3990915A Primary cell for electric batteries 失效
标题翻译：电池一次电池
公开(公告)号：US3990915A
公开(公告)日：1976-11-09
申请号：US602142
申请日：1975-08-05
申请人： Gerald H. Newman , Joseph A. Shropshire
发明人： Gerald H. Newman , Joseph A. Shropshire
IPC分类号： H01M4/36 , H01M4/58 , H01M6/16 , H01M6/00
CPC分类号： H01M4/5835 , H01M4/36 , H01M6/16
摘要： In an electrochemical cell utilizing an alkali metal anode and a non-aqueous electrolyte there is provided a novel cathode formed by reacting a crystaline form of carbon, such as graphite, with an interhalogen fluoride in the presence of hydrogen fluoride. The preferred interhalogen fluoride is ClF.sub.3.
摘要翻译：在利用碱金属阳极和非水电解质的电化学电池中，提供了在氟化氢存在下使诸如石墨的碳结晶形式与氟化氢反应形成的新型阴极。优选的氟化氟化物是ClF 3。

7. 发明授权

US4164068A Method of making bipolar carbon-plastic electrode structure-containing multicell electrochemical device 失效
标题翻译：制备双极碳 - 塑料电极结构的多电极电化学装置的方法
公开(公告)号：US4164068A
公开(公告)日：1979-08-14
申请号：US862174
申请日：1977-12-19
申请人： Joseph A. Shropshire , Hsue C. Tsien
发明人： Joseph A. Shropshire , Hsue C. Tsien
IPC分类号： H01M6/48 , H01M10/04
CPC分类号： H01M6/48 , H01M10/0418 , Y10T29/49108 , Y10T29/4911 , Y10T29/49114
摘要： A novel multicell electrochemical device having a plurality of bipolar carbon-plastic electrode structures and a novel method of making the device are described. A plurality of bipolar carbon-plastic electrode structures are formed by first molding thin conductive carbon-plastic sheets from heated mixtures of specified carbon and plastic, and then establishing frames of dielectric plastic material around the sheets and sealing the frames to the sheets so as to render the resulting structures liquid impermeable. A plurality of electrochemical cell elements in addition to the electrode structures, e.g. separators, spacers and the like, are also formed with dielectric plastic frames. The frames of both the electrode structures and the additional elements have projections on at least one surface. The electrode structures and the additional elements are stacked to form a group of items in an electrochemically functional arrangement. The arrangement is such that the projection of each frame contacts a frame surface of the next item in the stack. The items in the stack are joined to one another, e.g. by heat welding or ultrasonic welding, at these areas of contact so as to form a multicell electrochemical device capable of holding liquid therein.
摘要翻译：描述了一种具有多个双极碳 - 塑料电极结构的新型多电化学电化学装置和制造该装置的新颖方法。通过首先从特定碳和塑料的加热混合物成型薄导电碳塑料片，然后在片材周围建立介电塑料材料框架并将框架密封到片材上来形成多个双极碳 - 塑料电极结构，以便使所得到的结构液体不可渗透。除了电极结构之外的多个电化学电池元件，例如，分隔件，间隔件等也由电介质塑料框架形成。电极结构和附加元件的框架在至少一个表面上具有突起。电极结构和附加元件被堆叠以形成一组以电化学功能布置的物品。该布置使得每个框架的突起接触堆叠中的下一个物品的框架表面。堆叠中的项目彼此连接，例如。通过热焊接或超声波焊接，在这些接触区域形成能够保持液体的多电化学电化学装置。

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