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    • 3. 发明授权
    • Rotating cylinder-throwing power electrode
    • 旋转投掷电极
    • US5275711A
    • 1994-01-04
    • US901049
    • 1992-06-19
    • Joseph A. AbysIgor V. KadijaJoseph J. Maisano, Jr.
    • Joseph A. AbysIgor V. KadijaJoseph J. Maisano, Jr.
    • C25D21/12G01G9/00G01N5/00G01N27/26G01N27/42
    • G01N27/426Y10S204/07
    • This invention pertains to an apparatus and method for measuring throwing power of electroplating solutions. The apparatus is easy to use and gives reproducible measurements. The apparatus emulates the performance of a conventional Haring Blum cell. The major disadvantage of the standard Haring Blum cell is its limited aility to vary the solution mass transport, thus limiting its applicability to very low current density applications. Furthermore, even under low-mass transport conditions, non-uniform solution distribution is experienced leading to erroneous interpretation. This invention permits the study of throwing power of electroplating solutions under a whole variety of solution agitation. The invention embodies an instrument for and a method of measuring the throwing power of electrolytes. The instrument is in a form of an elongated cylindrical body adapted for rotation about its longitudinal axis and includes a fixed conductive anode element and at least two cathode elements, at least one of which is variably spaced from the anode element. Preferably, one cathode element is fixed relative to the anode element a first predetermined distance and another cathode element is spaced from the anode element a second variable distance which is a multiple of the first distance. The instrument also includes means for providing current to the anode element and equi-potentially to each of the cathode elements. The measuring includes providing each of the cathode elements with a pre-weighed removable metal foil, rotating the instrument which the anode and cathode elements are completely submerged in an electrolyte, applying current to the anode and the cathode elements, removing the metal foils from the cathode elements and weighing the metal foils with the deposit thereon to compare the weight of deposited metal at different cathode element positions.
    • 本发明涉及用于测量电镀溶液的投射功率的装置和方法。 该设备易于使用,并提供可重复的测量。 该装置模拟常规Haring Blum电池的性能。 标准Haring Blum电池的主要缺点是其有限的能力来改变溶液质量传输,从而将其适用性限制在非常低的电流密度应用中。 此外,即使在低质量运输条件下,也会导致不均匀的溶液分布,导致错误的解释。 本发明允许在各种溶液搅拌下研究电镀溶液的抛光力。 本发明体现了测量电解质投掷功率的仪器和方法。 该仪器是细长的圆柱形主体的形式,其适于围绕其纵向轴线旋转并且包括固定的导电阳极元件和至少两个阴极元件,其中至少一个阴极元件与阳极元件可变地间隔开。 优选地,一个阴极元件相对于阳极元件固定第一预定距离,而另一个阴极元件与阳极元件间隔开第二可变距离,该第二可变距离是第一距离的倍数。 仪器还包括用于向阳极元件提供电流并且等同地潜在于每个阴极元件的装置。 测量包括为每个阴极元件提供预先称重的可拆卸金属箔,将阳极和阴极元件完全浸没在电解质中的仪器旋转,向阳极和阴极元件施加电流,从金属箔中除去金属箔 阴极元件并对其上沉积的金属箔进行称重,以比较不同阴极元件位置处沉积的金属的重量。
    • 6. 发明授权
    • Hydrodynamically modulated hull cell
    • 水动力调制船体细胞
    • US5413692A
    • 1995-05-09
    • US40711
    • 1993-03-31
    • Joseph A. AbysIgor V. Kadija
    • Joseph A. AbysIgor V. Kadija
    • C25D21/12C25D5/04G01N27/26G01N27/30G01N27/42
    • G01N27/42C25D5/04Y10S204/07
    • Electrodeposition in surface finishing as well as in electroforming can be performed in a broad range of hydrodynamic conditions. In some instances, such as barrel plating, the liquid is barely moving relative to the work piece, while in jet plating the solution moves up to several meters per second relative to the piece to be plated. In such a wide range of hydrodynamic conditions, the selection of appropriate quality control (QC) methods for each particular operation is very critical. The QC method has to resemble the manufacturing operation in terms of the hydrodynamic conditions otherwise the quality control and the functional test for the bath performance have no meaning. Available Hull Cell systems have a limited capability in varying the liquid velocity. At best a relative velocity of up to 20 or perhaps 30 cm/sec can be achieved with uneven distribution.The invention provides, in electroplating QC methods for manufacturing, better similarity and relevance between a Hull Cell QC test and a particular plating operation. The invention is a simple and yet functional instrument which can be used to identify the performance of the plating bath prior to manufacturing operation under similar hydrodynamic conditions. The instrument is a rotating cylinder with a flexible Cu test panel attached to its surface. Like a Hull Cell, a range of current density can be simultaneously applied. Unlike a Hull Cell, the rotating speed of the cylinder and hence the solution agitation is practically unlimited. The operator can identify the operating window for the particular process and apply them to the production line. The instrument has also demonstrated usefulness in developing proprietary electroplating chemistries.
    • 电沉积在表面处理以及电铸中可以在宽范围的流体动力学条件下进行。 在一些情况下,例如桶形电镀,液体相对于工件几乎不移动,而在喷射电镀中,溶液相对于被镀件移动到每秒几米。 在如此广泛的流体力学条件下,为每个特定操作选择适当的质量控制(QC)方法是非常关键的。 QC方法与流体动力学条件相似,不同于质量控制和浴液性能的功能试验无意义。 可用的Hull Cell系统在改变液体速度方面具有有限的能力。 最多可达到20或30厘米/秒的相对速度,不均匀分布。 本发明在电镀QC制造方法中提供了Hull Cell QC测试和特定电镀操作之间更好的相似性和相关性。 本发明是一种简单且功能齐全的仪器,可用于在类似的流体动力学条件下制造操作之前识别电镀液的性能。 仪器是一个旋转圆柱体,其表面附着有一个柔性的Cu测试面板。 像Hull Cell一样,可以同时应用电流密度范围。 与船体单元不同,缸体的转速以及溶液搅拌实际上是无限制的。 操作人员可以识别特定过程的操作窗口并将其应用于生产线。 该仪器在开发专有电镀化学物质方面也表现出有用性。
    • 7. 发明授权
    • Hydrodynamically modulated hull cell
    • 水动力调整的HELL细胞
    • US5228976A
    • 1993-07-20
    • US550266
    • 1990-07-09
    • Joseph A. AbysIgor V. Kadija
    • Joseph A. AbysIgor V. Kadija
    • C25D21/12C25D5/04G01N27/26G01N27/30G01N27/42
    • G01N27/42C25D5/04Y10S204/07
    • The invention provides, in electroplating quality control methods for manufacturing, better similarity and relevance between a Hull Cell quality control test and a particular plating operation. The invention is a simple and yet functional instrument which can be used to identify the performance of the plating bath prior to manufacturing operation under similar hydrodynamic conditions. The instrument is a rotating cylinder with a flexible Cu test panel attached to its surface. Like a Hull Cell, a range of current density can be simultaneously applied. Unlike a Hull Cell, the rotating speed of the cylinder and hence the solution agitation is practically unlimited. The operator can identify the operating window for the particular process and apply them to the production line. The instrument has also demonstrated usefulness in developing proprietary electroplating chemistries.
    • 电沉积在表面处理以及电铸中可以在宽范围的流体动力学条件下进行。 在一些情况下,例如桶形电镀,液体相对于工件几乎不移动,而在喷射电镀中,溶液相对于被镀件移动到每秒几米。 在如此广泛的流体力学条件下,为每个特定操作选择适当的质量控制(QC)方法是非常关键的。 QC方法与流体动力学条件相似,不同于质量控制和浴液性能的功能试验无意义。 可用的Hull Cell系统在改变液体速度方面具有有限的能力。 最多可达到20或30厘米/秒的相对速度,不均匀分布。 本发明在用于制造的电镀QC方法中提供了Hull Cell QC测试和特定电镀操作之间更好的相似性和相关性。 本发明是一种简单且功能齐全的仪器,可用于在类似的流体动力学条件下制造操作之前识别电镀液的性能。 仪器是一个旋转圆柱体,其表面附着有一个柔性的Cu测试面板。 像Hull Cell一样,可以同时应用电流密度范围。 与船体单元不同,缸体的转速以及溶液搅拌实际上是无限制的。 操作人员可以识别特定过程的操作窗口并将其应用于生产线。 该仪器在开发专有电镀化学物质方面也表现出有用性。