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1. 发明授权

US4460790A Substituted 1,11-diaminoundecanes, processes for producing them, and their use 失效
标题翻译：取代的1,11-二氨基十一烷，其制备方法及其用途
公开(公告)号：US4460790A
公开(公告)日：1984-07-17
申请号：US288853
申请日：1981-07-31
申请人： Dieter Reinehr , Josef Pfeifer
发明人： Dieter Reinehr , Josef Pfeifer
IPC分类号： C07D225/00 , C07D225/02 , C07D225/04 , C07D307/52 , C07D333/20 , C08G59/50 , C08G69/26 , C07C87/14 , C07C87/32 , C07C87/34 , C07C87/36
CPC分类号： C07C251/72 , C07D225/00 , C07D225/02 , C07D225/04 , C07D307/52 , C07D333/20 , C08G59/50 , C08G69/26
摘要： There are described novel substituted 1,11-diaminoundecanes, particularly those of the formula ##STR1## [R.sub.1 is alkyl having 1-12 C atoms, R.sub.2 is hydrogen or alkyl having 1-12 C atoms, R.sub.3 is alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, aralkyl having 7 or 8 C atoms, unsubstituted or substituted aryl, pyridyl, furyl or thienyl, R.sub.4 is hydrogen, alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, or unsubstituted or substituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are alkylene having 3-11 C atoms], and processes for prducing them. The compound of the formula I can be used for example for producing polycondensation products, particularly polyamides. They can be used also as curing agents for epoxide resins.
摘要翻译：描述了新的取代的1,11-二氨基十一烷，特别是式（I）的那些：[R1是具有1-12个碳原子的烷基，R2是氢或具有1-12个C原子的烷基，R3是具有1个 -12个C原子，具有4-12个碳原子的环烷基，7或8个C原子的芳烷基，未取代或取代的芳基，吡啶基，呋喃基或噻吩基，R4是氢，具有1-12个碳原子的烷基，具有4-12个碳原子的环烷基原子或未取代或取代的芳基，或R 1和R 2和/或R 3和R 4一起为3-11个碳原子的亚烷基），以及其制备方法。式I化合物可用于制备缩聚产物，特别是聚酰胺。它们也可以用作环氧树脂的固化剂。

2. 发明授权

US4377683A Transparent copolyamide from isophorone diamine and substituted undecane diamine 失效
标题翻译：来自异佛尔酮二胺和取代十一烷二胺的透明共聚酰胺
公开(公告)号：US4377683A
公开(公告)日：1983-03-22
申请号：US272866
申请日：1981-06-12
申请人： Josef Pfeifer , Dieter Reinehr
发明人： Josef Pfeifer , Dieter Reinehr
IPC分类号： C08G69/00 , C08G69/26 , C08G69/28
CPC分类号： C08G69/265 , C08G69/28
摘要： Transparent copolyamides are obtained by reacting a mixture (A) of isophoronediamine and isophthalic acid, terephthalic acid or a mixture of isophthalic acid and terephthalic acid with a mixture (B) of a diamine ##STR1## and terephthalic acid or a mixture of terephthalic acid and isophthalic acid or with a mixture (C) of a diamine ##STR2## and terephthalic acid or isophthalic acid or mixtures thereof, R', R" and R.sub.1 to R.sub.6 being as defined in the patent claim.The reaction can also be carried out with an excess of diamine and with addition of H.sub.3 PO.sub.2 or salts thereof or white phosphorus.The novel copolyamides are distinguished by good thermoplastic processability, low water absorption and good resistance to hydrolysis, and are useful for the production of transparent mouldings.
摘要翻译：透明共聚酰胺通过异佛尔酮二胺和间苯二甲酸的混合物（A），对苯二甲酸或间苯二甲酸和对苯二甲酸的混合物与二胺（II）和对苯二甲酸的混合物（B）反应而获得，或对苯二甲酸和间苯二甲酸的混合物或二胺（III）的混合物（C）和对苯二甲酸或间苯二甲酸或其混合物，R'，R“和R 1至R 6的定义如前所述在专利权利要求中。反应也可以用过量的二胺和加入H 3 PO 2或其盐或白磷进行。新型共聚酰胺的特征在于良好的热塑性加工性，低吸水性和良好的耐水解性，并且可用于生产透明模制品。

3. 发明授权

US4472318A 1,10-Substituted 10-amino-deca-3,7-diene-nitriles and process for their preparation 失效
标题翻译： 1,10-取代的10-氨基 - 十烯-3,7-二烯 - 腈及其制备方法
公开(公告)号：US4472318A
公开(公告)日：1984-09-18
申请号：US461045
申请日：1983-01-26
申请人： Dieter Reinehr , Josef Pfeifer
发明人： Dieter Reinehr , Josef Pfeifer
IPC分类号： C08G69/00 , C07C67/00 , C07C253/00 , C07C255/30 , C07C255/31 , C07C255/42 , C08G69/26 , C07C121/45 , C07C121/48 , C07C121/78
CPC分类号： C07C255/00 , C08G69/26
摘要： Novel 10-amino-deca-3,7-diene-nitriles of the formula ##STR1## are described, in which R.sub.1 is C.sub.1-12 -alkyl, R.sub.2 is H or C.sub.1-12 -alkyl, R.sub.3 is C.sub.1-12 -alkyl, cycloalkyl having 4-12 ring C atoms, C.sub.7-8 -aralkyl, substituted or unsubstituted aryl or, if R.sub.4 =H, --Ch.dbd.CH--alkyl or --C(alkyl).dbd.CH--alkyl each having 1-4 C atoms in the alkyl groups, and R.sub.4 =H, C.sub.1-12 -alkyl, cycloalkyl having 4-12 ring C atoms, C.sub.7-8 -aralkyl or substituted or unsubstituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are C.sub.3-11 -alkylene. The compounds (I) can be reduced in a manner known per se to give the corresponding 1,11-diamino-undeca-3,7-dienes. The latter are valuable intermediates and are suitable especially for the preparation of transparent crosslinkable polyamides.
摘要翻译：描述了式（I）的新的10-氨基 - 癸-3,7-二烯 - 腈，其中R 1是C 1-12 - 烷基，R 2是H或C 1-12 - 烷基，R 3是C1- 具有4-12个环C原子的环烷基，C7-8-芳烷基，取代或未取代的芳基，或如果R4 = H，-Ch = CH-烷基或-C（烷基）= CH-烷基，各自具有1- 4个C原子，R4 = H，C1-12烷基，具有4-12个环C原子的环烷基，C7-8-芳烷基或取代或未取代的芳基，或R1和R2和/或R3和R4一起是C3-11-亚烷基。化合物（I）可以以本身已知的方式还原，得到相应的1,11-二氨基 - 十一碳-3,7-二烯。后者是有价值的中间体，并且特别适于制备透明的可交联聚酰胺。

4. 发明授权

US4277621A Substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal derivatives and processes for their preparation 失效
标题翻译：取代的11-氨基 - 十一烷-4,8-二烯酸和11-氨基 - 十一烷醛衍生物及其制备方法
公开(公告)号：US4277621A
公开(公告)日：1981-07-07
申请号：US83140
申请日：1979-10-09
申请人： Dieter Reinehr , Josef Pfeifer
发明人： Dieter Reinehr , Josef Pfeifer
IPC分类号： C08G59/00 , C07C67/00 , C07C209/00 , C07C209/40 , C07C209/42 , C07C209/52 , C07C209/62 , C07C211/09 , C07C211/17 , C07C211/25 , C07C211/27 , C07C211/29 , C07C239/00 , C07C241/00 , C07C251/04 , C07C251/16 , C07C251/34 , C07C251/52 , C07C251/78 , C07C251/80 , C07C251/82 , C07C281/06 , C07C281/08 , C07D225/00 , C07D225/02 , C07D225/04 , C07D307/52 , C07D333/06 , C07D333/20 , C08G59/50 , C08G69/26 , C07C109/14 , C07C109/16 , C07C131/00
CPC分类号： C07C251/72 , C07D225/00 , C07D225/02 , C07D225/04 , C07D307/52 , C07D333/20 , C08G59/50 , C08G69/26
摘要： Novel substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal aldehyde-derivatives of the formulae Ia ##STR1## in which R.sub.1 to R.sub.6, Y and m are as defined in patent claim 1, and processes for their preparation are described. The compounds of the formulae Ia and Ib can be catalytically hydrogenated to novel 1,11-diaminoundecanes, which, in turn, can be used, for example, for the preparation of polycondensation products, in particular transparent polyamides, or as curing agents for epoxide resins.
摘要翻译：（Ia）或Ib（VI）的新型取代的11-氨基 - 十一碳-4,8-二烯酸和11-氨基 - 十一醛醛衍生物，其中R 1至R 6，Y 和m如专利权利要求1中所定义，并描述了其制备方法。式Ia和Ib的化合物可以催化氢化成新的1,11-二氨基十一烷，其又可用于例如缩聚产物，特别是透明聚酰胺的制备，或作为环氧化物的固化剂树脂。

5. 发明授权

US4658066A 1,10-substituted 1,11-diamino-undeca-3,7-dienes and processes for their preparation 失效
标题翻译： 1,10-取代的1,11-二氨基 - 十一碳-3,7-二烯及其制备方法
公开(公告)号：US4658066A
公开(公告)日：1987-04-14
申请号：US763321
申请日：1985-08-07
申请人： Dieter Reinehr , Josef Pfeifer
发明人： Dieter Reinehr , Josef Pfeifer
IPC分类号： C08G69/00 , C07C67/00 , C07C209/00 , C07C209/40 , C07C209/44 , C07C211/22 , C07C253/00 , C07C255/30 , C08G69/26 , C07C55/28 , C07C57/34
CPC分类号： C07C255/00 , C08G69/26
摘要： Novel diamines of the formula ##STR1## are described, in which R.sub.1 is C.sub.1-12 -alkyl, R.sub.2 is H or C.sub.1-12 -alkyl, R.sub.3 is C.sub.1-12 -alkyl, cycloalkyl having 4-12 ring C atoms, C.sub.7-8 -aralkyl, substituted or unsubstituted aryl or, if R.sub.4 =H, is also --CH.dbd.CH--alkyl or --C(alkyl).dbd.CH-- alkyl each having 1-4 C atoms in the alkyl groups, and R.sub.4 is H, C.sub.1-12 -alkyl, cycloalkyl having 4-12 ring C atoms, C.sub.7-8 -aralkyl or substituted or unsubstituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are C.sub.3-11 -alkylene. The diamines (I) are valuable intermediates and are suitable especially for the preparation of transparent crosslinkable polyamides.
摘要翻译：描述了式（I）的新型二胺，其中R 1是C 1-12 - 烷基，R 2是H或C 1-12 - 烷基，R 3是C 1-12 - 烷基，具有4-12个环C原子的环烷基，C7-8-芳烷基，取代或未取代的芳基，或者如果R4 = H，也是-CH = CH-烷基或-C（烷基）=在烷基中具有1-4个C原子的CH-烷基，R4 是H，C 1-12 - 烷基，具有4-12个环C原子的环烷基，C7-8-芳烷基或取代或未取代的芳基，或R1和R2和/或R3和R4一起是C3-11 - 亚烷基。二胺（I）是有价值的中间体，特别适用于制备透明的可交联聚酰胺。

6. 发明授权

US4355177A Substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal derivatives and processes for their preparation 失效
标题翻译：取代的11-氨基 - 十一烷-4,8-二烯酸和11-氨基 - 十一烷醛衍生物及其制备方法
公开(公告)号：US4355177A
公开(公告)日：1982-10-19
申请号：US230081
申请日：1981-01-30
申请人： Dieter Reinehr , Josef Pfeifer
发明人： Dieter Reinehr , Josef Pfeifer
IPC分类号： C08G59/00 , C07C67/00 , C07C209/00 , C07C209/40 , C07C209/42 , C07C209/52 , C07C209/62 , C07C211/09 , C07C211/17 , C07C211/25 , C07C211/27 , C07C211/29 , C07C239/00 , C07C241/00 , C07C251/04 , C07C251/16 , C07C251/34 , C07C251/52 , C07C251/78 , C07C251/80 , C07C251/82 , C07C281/06 , C07C281/08 , C07D225/00 , C07D225/02 , C07D225/04 , C07D307/52 , C07D333/06 , C07D333/20 , C08G59/50 , C08G69/26 , C07C109/16 , C07C119/08 , C07C119/10 , C07C133/02
CPC分类号： C07C251/72 , C07D225/00 , C07D225/02 , C07D225/04 , C07D307/52 , C07D333/20 , C08G59/50 , C08G69/26
摘要： Novel substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal aldehyde-derivatives of the formulae Ia ##STR1## in which R.sub.1 to R.sub.6, Y and m are as defined in patent claim 1, and processes for their preparation are described. The compounds of the formulae Ia and Ib can be catalytically hydrogenated to novel 1,11-diaminoundecanes, which, in turn, can be used, for example, for the preparation of polycondensation products, in particular transparent polyamides, or as curing agents for epoxide resins.
摘要翻译：式Ia（Ia）或Ib（Ib）+ TR 的新型取代的11-氨基 - 十一烷-4,8-二烯酸和11-氨基 - 十一醛醛衍生物，其中R 1至R 6 ，Y和m如专利权利要求1中所定义，并描述了其制备方法。式Ia和Ib的化合物可以催化氢化成新的1,11-二氨基十一烷，其又可用于例如缩聚产物，特别是透明聚酰胺的制备，或作为环氧化物的固化剂树脂。

7. 发明授权

US4297480A Transparent polyamide from branched chain C.sub.11 diamine 失效
标题翻译：来自支链C11二胺的透明聚酰胺
公开(公告)号：US4297480A
公开(公告)日：1981-10-27
申请号：US83142
申请日：1979-10-09
申请人： Josef Pfeifer , Dieter Reinehr
发明人： Josef Pfeifer , Dieter Reinehr
IPC分类号： C08G69/00 , C08G69/26
CPC分类号： C08G69/26
摘要： There are described transparent polyamides, and processes for producing them, which polyamides consist of recurring structural elements of the formula I ##STR1## or of recurring structural elements of the formula II ##STR2## [carbonyl groups in the structural elements (II) bound in the 1,3- and/or 1,4-position to the benzene nucleus, R.sub.1 =C.sub.1-12 -alkyl, R.sub.2 =H, C.sub.1-12 -alkyl, R.sub.3 =C.sub.1-12 -alkyl, C.sub.4-12 -cycloalkyl, C.sub.7-8 -aralkyl, unsubstituted or substituted aryl, R.sub.4 =H, C.sub.1-12 -alkyl, C.sub.4-12 -cycloalkyl, C.sub.7-8 -aralkyl, or unsubstituted or substituted aryl, or R.sub.3 /R.sub.4 together=C.sub.3-11 -alkylene, R.sub.5 /R.sub.6 independently of one another=hydrogen or methyl, and R.sub.7 /R.sub.8 together=C.sub.3-11 -alkylene]. The polyamides according to the invention are suitable for producing transparent moulded articles of the widest variety, and are distinguished in particular by low water absorption, high stability to hydrolysis, and/or good dimensional stability under the action of moisture or humidity.
摘要翻译：描述了透明聚酰胺及其制备方法，该聚酰胺由式I的重复结构元素组成或式II的重复结构元素（II）结构元素（II）中的羰基与1,3-环中的1,3-和/或1,4-位结合，R1 = C1-12烷基，R2 = H，C1-12 - 烷基，R3 = C 1-12烷基，C 4-12 - 环烷基，C 7-8 - 芳烷基，未取代或取代的芳基，R 4 = H，C 1-12 - 烷基，C 4-12 - 环烷基，C7-8-芳烷基或未取代或取代的芳基，或R 3 / R 4一起= C 3-11 - 亚烷基，R 5 / R 6彼此独立地为氢或甲基，并且R 7 / R 8一起为C 3-10亚烷基。根据本发明的聚酰胺适用于生产最广泛品种的透明模塑制品，特别是在水分或湿度作用下，具有低吸水率，高水解稳定性和/或良好的尺寸稳定性。

8. 发明授权

US4487947A Substituted 1,11-diaminoundecanes, processes for producing them, and their use 失效
标题翻译：取代的1,11-二氨基十一烷，其制备方法及其用途
公开(公告)号：US4487947A
公开(公告)日：1984-12-11
申请号：US421208
申请日：1982-09-22
申请人： Dieter Reinehr , Josef Pfeifer
发明人： Dieter Reinehr , Josef Pfeifer
IPC分类号： C07D225/00 , C07D225/02 , C07D225/04 , C07D307/52 , C07D333/20 , C08G59/50 , C08G69/26 , C07D307/06 , C07D307/04
CPC分类号： C07C251/72 , C07D225/00 , C07D225/02 , C07D225/04 , C07D307/52 , C07D333/20 , C08G59/50 , C08G69/26
摘要： There are described novel substituted 1,11-diaminoundecanes, particularly those of the formula ##STR1## [R.sub.1 is alkyl having 1-12 C atoms, R.sub.2 is hydrogen or alkyl having 1-12 C atoms, R.sub.3 is alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, aralkyl having 7 or 8 C atoms, unsubstituted or substituted aryl, pyridyl, furyl or thienyl, R.sub.4 is hydrogen, alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, or unsubstituted or substituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are alkylene having 3-11 C atoms], and processes for producing them. The compound of the formula I can be used for example for producing polycondensation products, particularly polyamides. They can be used also as curing agents for epoxide resins.
摘要翻译：描述了新的取代的1,11-二氨基十一烷，特别是式（I）的那些：[R1是具有1-12个碳原子的烷基，R2是氢或具有1-12个C原子的烷基，R3是具有1个 -12个C原子，具有4-12个碳原子的环烷基，7或8个C原子的芳烷基，未取代或取代的芳基，吡啶基，呋喃基或噻吩基，R4是氢，具有1-12个碳原子的烷基，具有4-12个碳原子的环烷基原子或未取代或取代的芳基，或R 1和R 2和/或R 3和R 4一起是具有3-11个碳原子的亚烷基）和其制备方法。式I化合物可用于制备缩聚产物，特别是聚酰胺。它们也可以用作环氧树脂的固化剂。

9. 发明授权

US4484004A Substituted 1,11-diaminoundecanes, processes for producing them and their use 失效
标题翻译：取代的1,11-二氨基十一烷，其制备方法及其用途
公开(公告)号：US4484004A
公开(公告)日：1984-11-20
申请号：US421209
申请日：1982-09-22
申请人： Dieter Reinehr , Josef Pfeifer
发明人： Dieter Reinehr , Josef Pfeifer
IPC分类号： C07D225/00 , C07D225/02 , C07D225/04 , C07D307/52 , C07D333/20 , C08G59/50 , C08G69/26 , C07C87/02 , C07C87/00
CPC分类号： C07C251/72 , C07D225/00 , C07D225/02 , C07D225/04 , C07D307/52 , C07D333/20 , C08G59/50 , C08G69/26
摘要： There are described novel substituted 1,11-diaminoundecanes, particularly those of the formula ##STR1## [R.sub.1 is alkyl having 1-12 C atoms, R.sub.2 is hydrogen or alkyl having 1-12 C atoms, R.sub.3 is alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, aralkyl having 7 or 8 C atoms, unsubstituted or substituted aryl, pyridyl, furyl or thienyl, R.sub.4 is hydrogen, alkyl having 1-12 C atoms, cycloalkyl having 4-12 C atoms, or unsubstituted or substituted aryl, or R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 together are alkylene having 3-11 C atoms], and processes for producing them. The compound of the formula I can be used for example for producing polycondensation products, particularly polyamides. They can be used also as curing agents for epoxide resins.
摘要翻译：描述了新的取代的1,11-二氨基十一烷，特别是式（I）的那些：[R1是具有1-12个碳原子的烷基，R2是氢或具有1-12个C原子的烷基，R3是具有1个 -12个C原子，具有4-12个C原子的环烷基，7或8个C原子的芳烷基，未取代或取代的芳基，吡啶基，呋喃基或噻吩基，R4是氢，具有1-12个碳原子的烷基，具有4-12个碳原子的环烷基原子或未取代或取代的芳基，或R 1和R 2和/或R 3和R 4一起是具有3-11个碳原子的亚烷基）和其制备方法。式I化合物可用于制备缩聚产物，特别是聚酰胺。它们也可以用作环氧树脂的固化剂。

10. 发明授权

US4465823A Ethylenically unsaturated crosslinkable transparent polyamide 失效
标题翻译：乙烯不饱和可交联透明聚酰胺
公开(公告)号：US4465823A
公开(公告)日：1984-08-14
申请号：US461050
申请日：1983-01-26
申请人： Joseph Berger , Josef Pfeifer , Dieter Reinehr
发明人： Joseph Berger , Josef Pfeifer , Dieter Reinehr
IPC分类号： C08G69/00 , C08G69/26 , C08G75/04
CPC分类号： C07C255/00 , C08G69/26 , C08G75/045
摘要： Novel crosslinkable transparent polyamides are described which are obtained by the condensation of diamines of the formula ##STR1## with aromatic and/or aliphatic dicarboxylic acids or amide-forming derivatives thereof, preferably in the presence of an inorganic or organic phosphorus compound as an accelerator. In the formula, R.sub.1 to R.sub.4 are defined as in patent claim 1. The novel polyamides are suitable for the production of solvent-resistant coatings on various substrates, for the production of images under the action of light, in particular when mixed with polythiols and photoinitiators or photosensitizers, or for the production of transparent mouldings.
摘要翻译：描述了通过将式（II）＆lt; IMAGE＆gt;的二胺与芳族和/或脂族二羧酸或其酰胺形成衍生物缩合获得的新型可交联的透明聚酰胺，优选在无机或有机磷化合物作为促进剂。在该式中，R1至R4如专利权利要求1中所定义。新型聚酰胺适用于生产各种基材上的耐溶剂涂层，用于在光作用下生产图像，特别是当与多硫醇和光引发剂或光敏剂，或用于生产透明模制品。

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