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1. 发明授权

US5294665A Water soluble or water dispersible polyisocyanate mixtures and their use in stoving compositions 失效
标题翻译：水溶性或水分散性多异氰酸酯混合物及其在烘烤组合物中的用途
公开(公告)号：US5294665A
公开(公告)日：1994-03-15
申请号：US82224
申请日：1993-06-24
申请人： Josef Pedain , Heino Muller , Dieter Mager , Harald Blum , Holger Casselmann
发明人： Josef Pedain , Heino Muller , Dieter Mager , Harald Blum , Holger Casselmann
IPC分类号： C08G18/83 , C08G18/00 , C08G18/08 , C08G18/10 , C08G18/42 , C08G18/66 , C08G18/70 , C08G18/80 , C09D175/00 , C09D175/06
CPC分类号： C08G18/8061 , C08G18/0823 , C08G18/4277 , C08G18/6659 , C08G18/706 , C08G18/8048
摘要： The present invention relates to a polyisocyanate mixture which has blocked isocyanate groups and an average NCO-functionality, based on reversibly blocked isocyanate groups, of 2.0 to 2.6, and is the reaction product, converted into the salt form by the at least partial neutralization of the incorporated carboxyl groups, ofi) at least one organic diisocyanate having a molecular weight of 168 to 300 withii) at least one monofunctional blocking agent for isocyanate groups,iii) at least one monobasic or dibasic hydroxycarboxylic acid,iv) 1 to 15 wt. %, based on the weight of component i), of at least one dihydric to hexahydric alcohol having a molecular weight of 62 to 182 andv) 50 to 500 wt. %, based on the weight of component i), of at least one diol having a molecular weight of 350 to 950 and containing ester groups.The present invention also relates to the use of this polyisocyanate mixture in combination with water dispersible or water soluble polyhydroxyl compounds for the production of aqueous stoving lacquers.
摘要翻译：本发明涉及具有封端异氰酸酯基团和基于可逆封端异氰酸酯基团的平均NCO官能度为2.0至2.6的多异氰酸酯混合物，并且是反应产物，通过至少部分中和 i）至少一种分子量为168至300的有机二异氰酸酯，ii）至少一种用于异氰酸酯基团的单官能封端剂，iii）至少一种一元或二元羟基羧酸，iv）1至15 重量至少一种分子量为62至182的二羟基至六元醇，v）50至500重量％，基于组分i）的重量％基于组分i）的重量，至少一种分子量为350至950的二醇并含有酯基。本发明还涉及这种多异氰酸酯混合物与水分散性或水溶性多羟基化合物的组合用于生产含水烘烤漆的用途。

2. 发明授权

US5455297A Water-based coating compositions and their use for the production of flexible coatings 失效
标题翻译：水性涂料组合物及其用于生产柔性涂料的用途
公开(公告)号：US5455297A
公开(公告)日：1995-10-03
申请号：US169943
申请日：1993-12-20
申请人： Josef Pedain , Heino Muller , Dieter Mager , Manfred Schonfelder
发明人： Josef Pedain , Heino Muller , Dieter Mager , Manfred Schonfelder
IPC分类号： C08G18/08 , C08G18/70 , C08G18/80 , C09D5/02 , C09D175/00 , C09D175/04 , C08G18/34
CPC分类号： C08G18/0823 , C08G18/706 , C08G18/8048 , C08G18/8077 , Y10T428/31605
摘要： The present invention relates to a heat-crosslinkable water-based coating composition containing as bindera) a water-soluble or water-dispersible polyol component andb) a water-soluble or water-dispersible blocked polyisocyanate which has an average NCO functionality of 2.0 to 2.6 and is based on the reaction product ofb1) a polyisocyanate mixture having an average NCO functionality of 2.5 to 3.5 and containing (i) at least 15% by weight of an organic diisocyanate,b2) a blocking agent for isocyanate groups in an amount of 50 to 80 equivalent-%, based on the isocyanate groups of component b1) andb3) an aliphatic monohydroxymonocarboxylic acid in a quantity of 20 to 50 equivalent-%, based on the isocyanate groups of component b1) and the hydroxyl groups of component b3), wherein the equivalent ratio, based on the isocyanate-reactive groups of blocking agent b2) and the hydroxyl groups of component b3) to the isocyanate groups of component b1) is at least 0.9:1.
摘要翻译：本发明涉及一种热交联性水性涂料组合物，其包含作为粘合剂的a）水溶性或水分散性多元醇组分和b）具有平均NCO官能度为2.0的水溶性或水分散性封端多异氰酸酯基于b1）具有2.5至3.5的平均NCO官能度并且包含（i）至少15重量％的有机二异氰酸酯的聚异氰酸酯混合物的反应产物，b2）用于异氰酸酯基团的封闭剂基于组分b1）的异氰酸酯基团和基于组分b1）的异氰酸酯基团的b3）相对于基团b1）的异氰酸酯基团的量为20至50当量的脂族单羟基单羧酸的量为50至80当量％组分b3），其中基于组分b1）的异氰酸酯基团的封端剂b2）和组分b3）的羟基的异氰酸酯反应性基团的当量比至少为0.9:1。

3. 发明授权

US5902897A Polyamines and their use in coating compositions 失效
标题翻译：多胺及其在涂料组合物中的用途
公开(公告)号：US5902897A
公开(公告)日：1999-05-11
申请号：US684355
申请日：1996-07-19
申请人： Christian Wamprecht , Theodor Engbert , Holger Casselmann , Josef Pedain , Jurgen Meixner
发明人： Christian Wamprecht , Theodor Engbert , Holger Casselmann , Josef Pedain , Jurgen Meixner
IPC分类号： C07C211/13 , C08G18/40 , C08G18/46 , C08G18/64 , C08G18/80 , C08G73/02 , C08L79/02 , C09D175/00 , C09D175/04 , C09D179/02 , C07C229/26
CPC分类号： C08G18/6415 , C08G18/4669 , C08G73/02 , C08G73/028 , C08L79/02 , C09D179/02
摘要： The present invention relates to polyamines which are prepared by reactinga) unsaturated oligoesters having an average of 2 to 4 double bonds per molecule andb) optionally other unsaturated compounds suitable as Michael addition acceptors and having an average of 1 to 4 double bonds per molecule withc) (cyclo)aliphatic diamines having two primary amino groups andd) optionally other amino-functional compounds suitable as Michael addition donors.The present invention also relates to the use of these polyamines as a binder component in lacquers and coating compositions, particularly as reactants for blocked polyisocyanates in one-component stoving lacquers.
摘要翻译：本发明涉及多胺，其通过使a）每分子平均具有2至4个双键的不饱和低聚酯和b）任选的适合作为迈克尔加成受体并且每分子平均具有1至4个双键的其它不饱和化合物与c）具有两个伯氨基的（环）脂族二胺和d）任选的其它适用作迈克尔加成供体的氨基官能化合物。本发明还涉及这些多胺作为粘合剂组分在漆和涂料组合物中的用途，特别是作为单组分烘烤漆中封端多异氰酸酯的反应物。

4. 发明授权

US5705593A Diphenylmethane diisocyanate based polyisocyanates containing allophanate groups and having blocked isocyanate groups 失效
标题翻译：含有脲基甲酸酯基并具有封端异氰酸酯基团的二苯基甲烷二异氰酸酯基聚异氰酸酯
公开(公告)号：US5705593A
公开(公告)日：1998-01-06
申请号：US709801
申请日：1996-09-10
申请人： Lutz Schmalstieg , Josef Pedain , Theodor Engbert , Holger Casselmann , Frank Kobelka
发明人： Lutz Schmalstieg , Josef Pedain , Theodor Engbert , Holger Casselmann , Frank Kobelka
IPC分类号： C07C275/60 , C08G18/78 , C08G18/80 , C09D175/00 , C09D175/04 , C07C273/18
CPC分类号： C08G18/7837 , C07C275/60 , C08G18/8093
摘要： The present invention relates to polyisocyanates prepared from diphenylmethane diisocyanate wherein at least 95% of the isocyanate groups are blocked with diethyl malonate and wherein the polyisocyanates have, based on solids, A) a content of unblocked and blocked isocyanate groups (calculated as NCO) of 9% to 13%, B) a content of allophanate groups (calculated as C.sub.2 HN.sub.2 O.sub.3, molecular weight 101) of 3% to 9% and C) a calculated average functionality of 2.0 to 2.5. The present invention also relates to a process for the production of these polyisocyanates and to their use as crosslinking agents for organic polyhydroxyl compounds in polyurethane stoving lacquers.
摘要翻译：本发明涉及由二苯基甲烷二异氰酸酯制备的多异氰酸酯，其中至少95％的异氰酸酯基团用丙二酸二乙酯封闭，其中多异氰酸酯基于固体A具有未封端和封闭的异氰酸酯基团的含量（以NCO计算） 9％〜13％，B）脲基甲酸酯基（含量为C2HN2O3，分子量101）含量为3％〜9％，C）计算出的平均官能度为2.0〜2.5。本发明还涉及一种生产这些多异氰酸酯的方法，以及它们在聚氨酯烘烤漆中用作有机多羟基化合物的交联剂的用途。

5. 发明授权

US06248415B1 Aqueous polyurethane dispersions having improved water and solvent resistance 失效
标题翻译：具有改善的耐水和耐溶剂性的水性聚氨酯分散体
公开(公告)号：US06248415B1
公开(公告)日：2001-06-19
申请号：US09118657
申请日：1998-07-17
申请人： Josef Pedain , Eberhard Arning , Dieter Mager , Lutz Schmalstieg , Ronald-Karl Jerg
发明人： Josef Pedain , Eberhard Arning , Dieter Mager , Lutz Schmalstieg , Ronald-Karl Jerg
IPC分类号： C08J300
CPC分类号： C08G18/6659 , C08G18/0823 , C08G18/7837 , Y10T428/16 , Y10T428/167 , Y10T428/31551 , Y10T428/31591 , Y10T428/31989
摘要： The present invention relates to aqueous polyurethane dispersions prepared from a polyisocyanate component and one or more isocyanate-reactive compounds wherein at least 5% by weight of polyisocyanate component is a diisocyanate corresponding to formula (I) wherein R is a difunctional, C4 to C18, aliphatic, cycloaliphatic or aromatic hydrocarbon residue obtained by removing the NCO groups from an organic diisocyanate and R′ is a monofunctional, C1 to C18 hydrocarbon radical, which may contain ether oxygen atoms. The present invention also relates to the use of these PUR dispersions for coating any substrates, preferably wood substrates, such as parquet flooring.
摘要翻译：本发明涉及由多异氰酸酯组分和一种或多种异氰酸酯反应性化合物制备的水性聚氨酯分散体，其中至少5重量％的多异氰酸酯组分是对应于式（I）的二异氰酸酯，其中R是双官能的，C 4至C 18的脂族，通过从有机二异氰酸酯除去NCO基团而获得的脂环族或芳族烃残基，R'是可以含有醚氧原子的单官能的C1-C18烃基。本发明还涉及这些PUR分散体用于涂覆任何基材，优选木质基材，例如镶木地板。

6. 发明授权

US5882544A Polycyclic iminooxadiazinediones from (cyclo)aliphatic 1,4-diisocyanates 失效
标题翻译：（环）脂族1,4-二异氰酸酯的多环亚氨基恶二嗪二酸酯
公开(公告)号：US5882544A
公开(公告)日：1999-03-16
申请号：US989066
申请日：1997-12-11
申请人： Frank Richter , Dieter Mager , Josef Pedain
发明人： Frank Richter , Dieter Mager , Josef Pedain
IPC分类号： C07D498/04 , C08G18/00 , C08G18/79 , C08G101/00 , C09D175/04 , C09K3/12 , A61K31/535 , C07D267/14 , C07D273/04
CPC分类号： C07D498/04 , C08G18/79 , C08G2101/00 , C08G2150/20
摘要： The present invention relates to polycyclic iminooxadiazinediones A corresponding to formula I ##STR1## The present invention also relates to mixtures of these polycyclic iminooxadiazinediones with other isocyanate derivatives and to their use for the production of optionally foamed polyurethane plastics, for the production of paints and coatings and for the production or formulation of active ingredients, pharmaceutical products, etc.
摘要翻译：本发明涉及对应于式I的多环亚氨基恶二嗪二酮A（I）本发明还涉及这些多环亚氨基恶二嗪二酸与其它异氰酸酯衍生物的混合物及其用于生产任选发泡聚氨酯塑料的用途，用于生产油漆和涂料以及生产或配制活性成分，药品等。

7. 发明授权

US5216107A Binder compositions for stoving lacquers and a process for the production of coatings therefrom 失效
标题翻译：用于生产漆膜的粘合剂组合物及其生产涂料的方法
公开(公告)号：US5216107A
公开(公告)日：1993-06-01
申请号：US727735
申请日：1991-07-10
申请人： Josef Pedain , Friedrich Schrader , Dieter Mager , Hans-Heribert Burgdorfer
发明人： Josef Pedain , Friedrich Schrader , Dieter Mager , Hans-Heribert Burgdorfer
IPC分类号： B05D3/02 , B05D7/24 , C08G18/32 , C08G18/36 , C08G18/48 , C08G18/65 , C08G18/66 , C08G18/78 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04
CPC分类号： C08G18/6547 , C08G18/3215 , C08G18/36 , C08G18/798 , C08G18/8061
摘要： The present invention relates to a binder composition containinga) 20 to 70% by weight of oligomerization products of 1,6-diisocyanatohexane, the oligomerization products having isocyanate groups at least partially blocked with blocking agents for isocyanate groups and containing at least 50% by weight, based on the weight of the oligomerization products, of blocked uretdione diisocyanates corresponding to formula (I) ##STR1## wherein R represents the residue formed by removal of the active hydrogen atom from a monofunctional blocking agent, andb) 30 to 80% by weight of a polyol component containing a mixture ofb1) 100 parts by weight of an alkoxylation product of bisphenol A corresponding to formula (II) ##STR2## wherein R' is hydrogen or a methyl group and n is a whole or fractional number from 1 to 2,b2) 20 to 200 parts by weight castor oil andb3) 0 to 40 parts by weight of other organic polyhydroxyl compounds.The present invention also relates to a process for the production of coatings by coating heat-resistant substrates with a heat-curing coating composition containing the binder compositions of the present invention and subsequently curing the coatings at 90.degree. to 220.degree. C.
摘要翻译：本发明涉及一种粘合剂组合物，其含有a）20〜70重量％的1,6-二异氰酸根合己烷的低聚产物，所述低聚产物具有至少部分被异氰酸酯基团的封闭剂部分封端的异氰酸酯基团并且含有至少50％对应于式（I）的封端的脲二酮二异氰酸酯的重量（重量），其中R表示通过从单官能封端剂除去活性氢原子形成的残基，和b）30 至80重量％的含有b1）100重量份对应于式（II）的双酚A的烷氧基化产物的多元醇组分（II）其中R'是氢或甲基，n是 1〜2的整数或分数，b2）20〜200重量份蓖麻油和b3）0〜40重量份的其他有机多羟基化合物。本发明还涉及通过用含有本发明的粘合剂组合物的热固化涂料组合物涂覆耐热基材并随后在90℃至220℃固化涂层来生产涂料的方法。

8. 发明授权

US5135987A Modified copolymers, a process for their production, binders containing the modified copolymers and their use in coating compositions and sealing compounds 失效
标题翻译：改性共聚物，其制备方法，含有改性共聚物的粘合剂及其在涂料组合物和密封化合物中的用途
公开(公告)号：US5135987A
公开(公告)日：1992-08-04
申请号：US648537
申请日：1991-02-22
申请人： Christian Wamprecht , Harald Blum , Josef Pedain , Peter Hohlein
发明人： Christian Wamprecht , Harald Blum , Josef Pedain , Peter Hohlein
IPC分类号： C08F8/00 , C08F8/30
CPC分类号： C08F8/30 , C08F8/00
摘要： Binders for moisture-hardening coating or sealing compositions contain modified copolymers having a weight average molecular weight of from 1,500 to 75,000 determined by gel permeation chromatography of olefinically unsaturated compounds containing chemically incorporated moieties which are addition-reactive to amino wherein the modified copolymers contain both(i) intramolecular carboxylic anhydride moieties and(ii) olefinically unsaturated (meth)acrylate moieties in chemically bound form as the moieties which are addition-reactive to amino, with the anhydride equivalent weight being in the range from 392 to 9,800 and the (meth)acrylate equivalent weight in the range from 284 to 7,100.
摘要翻译：用于湿润硬化涂层或密封组合物的粘合剂含有通过凝胶渗透色谱法测定的重均分子量为1,500至75,000的改性共聚物，其含有与氨基加成反应的化学引入部分的烯属不饱和化合物，其中改性共聚物含有（ i）分子内羧酸酐部分和（ii）具有化学结合形式的烯属不饱和（甲基）丙烯酸酯部分作为与氨基加成反应的部分，酸酐当量为392-9,800，和（甲基）丙烯酸酯当量在284至7100的范围内。

9. 发明授权

US4990583A Copolymers containing isocyanate and acid anhydride groups, a process for their preparation and their use as a binder components 失效
标题翻译：含有异氰酸酯和酸酐基团的共聚物，其制备方法及其作为粘合剂组分的用途
公开(公告)号：US4990583A
公开(公告)日：1991-02-05
申请号：US305744
申请日：1989-02-03
申请人： Christian Wamprecht , Josef Pedain , Harald Blum
发明人： Christian Wamprecht , Josef Pedain , Harald Blum
IPC分类号： C09K3/10 , C08F220/36 , C08F222/04 , C08F246/00 , C08G18/62 , C08G18/72 , C09D133/06 , C09D175/04
CPC分类号： C08G18/728 , C08F220/36 , C08F222/04 , C08F246/00 , C09D133/064
摘要： Copolymers useful in binders for two-component coating compounds or sealing compounds are copolymers having a weight average molecular weight, determined by the gel permeation chromatography method, of from 1500 to 75,000 of olefinically unsaturated compounds containing chemically incorporated moieties capable of undergoing an addition reaction with hydroxyls wherein the copolymers contain, as hydroxyl reactive groups, both(i) from 0.3 to 7.0% by weight of free isocyanate groups and(ii) from 1 to 25% by weight of acid anhydride groups, calculated as C.sub.4 H.sub.2 O.sub.3,in a chemically bound form.
摘要翻译：用于双组分涂料化合物或密封化合物的粘合剂中的共聚物是具有通过凝胶渗透色谱法测定的重均分子量为1500至75,000的含有化学引入的部分的烯属不饱和化合物的共聚物，其能够经历与羟基，其中共聚物含有（i）0.3至7.0重量％的游离异氰酸酯基团和（ii）按化学键合计算为1至25重量％的以C 4 H 2 O 3计算的酸酐基团，作为羟基反应性基团形成。

10. 发明授权

US5710209A Aqueous binders for coating compositions based on polyester polyurethanes 失效
标题翻译：用于基于聚酯聚氨酯的涂料组合物的水性粘合剂
公开(公告)号：US5710209A
公开(公告)日：1998-01-20
申请号：US602539
申请日：1996-02-20
申请人： Harald Blum , Josef Pedain
发明人： Harald Blum , Josef Pedain
IPC分类号： C08G18/00 , C08G18/08 , C08G18/42 , C08G18/66 , C08G18/73 , C08G18/75 , C09D5/00 , C09D175/06 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C09D175/06 , C08G18/0819 , C08G18/4288 , C08G18/6659 , C08G18/751
摘要： An aqueous dispersion of a polyester polyurethane which contains as essential building component 1-methyl-2,4- and/or -2,6-diisocyanatocyclohexane and its use as the binder for one- or two-component coating compositions, optionally in combination with cross-linking agent resins selected from optionally blocked polyisocyanates and/or aminoplast resins.
摘要翻译：聚酯聚氨酯的水性分散体，其含有作为必要的构建成分1-甲基-2,4-和/或-2,6-二异氰酸基环己烷及其作为单组分或双组分涂料组合物的粘合剂的用途，任选地与选自任选封闭的聚异氰酸酯和/或氨基塑料树脂的交联剂树脂。

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