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    • 3. 发明授权
    • Water purification methods with in situ generation of metal hydroxide flocculants
    • 水净化方法与原位生成金属氢氧化絮凝剂
    • US06177016B1
    • 2001-01-23
    • US09361765
    • 1999-07-27
    • Jorge MillerLuisa Kling Miller
    • Jorge MillerLuisa Kling Miller
    • C02F170
    • C02F1/5236C02F1/74
    • The present invention is directed to methods for purifying wastewater, including water which may or may not contain fatty acids or oils, by producing in situ a hydrophobic flocculant including a water-insoluble metal hydroxide. In the preferred methods, metallic cations are produced by the gradual dissolution of consumable, similar metal sources, preferably, a fluidized bed of metallic particles. The motion of the particles of the fluidized bed maintains the surfaces thereof clean of oxides and other contaminants in order to facilitate the gradual dissolution thereof. Oxidation of the dissolved cations to form the water-insoluble metal hydroxide is achieved by flowing an oxidizing agent, e.g., air or pure oxygen, through the system. Contaminants are entrapped and removed within the insoluble flocculants, including the water-insoluble metal hydroxide and, optionally, metallic soaps which are formed in the presence of fatty acids. Thus, clean, contaminant-free water may be separated and removed from the insoluble flocculants and entrapped contaminants.
    • 本发明涉及通过原位生产包含水不溶性金属氢氧化物的疏水性絮凝剂来净化废水的方法,包括可含或不含有脂肪酸或油的水。 在优选的方法中,金属阳离子是通过消耗的,类似的金属源,优选金属颗粒的流化床的逐渐溶解产生的。 流化床颗粒的运动使其表面清洁氧化物和其它污染物,以便于其逐渐溶解。 溶解的阳离子氧化形成水不溶性金属氢氧化物是通过使氧化剂(例如空气或纯氧)流过系统来实现的。 污染物在不溶性絮凝剂中被包埋和除去,包括水不溶性金属氢氧化物和任选的在脂肪酸存在下形成的金属皂。 因此,清洁,无污染的水可以从不溶性絮凝剂和夹带的污染物中分离出并除去。
    • 7. 发明授权
    • Method of producing alcohols
    • 醇的生产方法
    • US08227647B2
    • 2012-07-24
    • US12927936
    • 2010-11-30
    • Jorge MillerLuisa Kling Miller
    • Jorge MillerLuisa Kling Miller
    • C07C29/48C07C27/16
    • C07C29/095C07C17/10C07C67/11C07C19/075C07C31/04C07C69/06
    • A method comprising reacting an alkane gas with a halogen gas in a halogenations reactor to form a halogenation reaction product mixture comprising alkane halide and hydrogen halide mixture; mixing the halogenations reaction product mixture with a countercurrent flow of a metal organic salt thereby forming an extractor product mixture of a metal halide, organic salt, and organic acid separating the organic ester and organic acid mixture from the metal halide; oxygenating the metal halide to form a metal oxide and halide containing gasses; separating the metal oxide from the halide containing gasses; mixing the metal oxide with water to form a metal oxide slurry; mixing the metal oxide slurry with a countercurrent flow of the organic ester and organic acid mixture to form a raw product comprising alkanol, a metal organic salt is provided.
    • 一种方法,包括在卤化反应器中使烷烃气体与卤素气体反应以形成卤化反应产物混合物,其包含烷烃卤化物和卤化氢混合物; 将卤化反应产物混合物与金属有机盐的逆流混合,从而形成金属卤化物,有机盐和有机酸的萃取产物混合物,从有机酯和有机酸混合物中分离出金属卤化物; 使金属卤化物氧化以形成金属氧化物和含卤气的气体; 从含卤化物气体中分离金属氧化物; 将金属氧化物与水混合以形成金属氧化物浆料; 将金属氧化物浆料与有机酯和有机酸混合物的逆流混合以形成包含链烷醇,金属有机盐的粗产物。