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    • 5. 发明授权
    • Photographic recording material
    • 摄影记录材料
    • US5674668A
    • 1997-10-07
    • US704461
    • 1996-08-26
    • Jorg HagemannGunter HellingBeate Weber
    • Jorg HagemannGunter HellingBeate Weber
    • G03C7/00G03C1/005G03C1/815G03C7/388
    • G03C7/3885G03C1/005G03C1/8155Y10S430/132
    • A color photographic recording material having at least one silver halide emulsion layer, which material contains in at least one of its layers a combination of at least one UV absorber of the formula I and at least one low molecular weight or polymeric oil formula containing acid groups, for example of the formula T--�R.sup.21 --(Q.sup.1).sub.p !.sub.q --X.sup.21 --OH (II), exhibits improved absorption for UV light. ##STR1## In the formula I: R.sup.1 and R.sup.3 mean H, halogen, hydroxy, mercapto, alkyl, aryl, alkoxy, aryloxy, acyloxy, alkylthio, arylthio, --NR.sup.5 --R.sup.6, alkoxycarbonyl, carbamoyl or sulphamoyl; R.sup.2 means H, hydroxy, halogen or alkyl; R.sup.4 means alkyl, alkoxy, alkylthio, aryloxy, arylthio or a residue of the formula ##STR2## R.sup.5 means H, alkyl or aryl; R.sup.6 means H, alkyl, aryl, acyl, alkoxycarbonyl, carbamoyl, sulphamoyl or sulphonyl; m, n and o mean 1, 2, 3 or 4, wherein two or more residues R.sup.1, R.sup.2 and R.sup.3 are identical or different; in the formula II: X.sup.21 means ##STR3## T means H or a segment of a polymer skeleton; Q.sup.1 and Q.sup.2 mean --O-- or --NR.sup.22 --; R.sup.21 means alkylene or arylene; R.sup.22 means H, alkyl or aryl; p, q and r mean 0 or 1.
    • 一种具有至少一个卤化银乳剂层的彩色照相记录材料,该材料在其至少一层中含有至少一种式I的UV吸收剂与至少一种含有酸基团的低分子量或聚合物油配方的组合 ,例如式T- [R21-(Q1)p] q-X21-OH(Ⅱ)表现出改进的UV光吸收。 (I)在式I中,R 1和R 3表示H,卤素,羟基,巯基,烷基,芳基,烷氧基,芳氧基,酰氧基,烷硫基,芳硫基,-NR5-R6,烷氧基羰基,氨基甲酰基或氨磺酰基。 R2表示H,羟基,卤素或烷基; R 4表示烷基,烷氧基,烷硫基,芳氧基,芳硫基或式烷基,芳基,酰基,烷氧基羰基,氨基甲酰基,氨磺酰基或磺酰基的残基; m,n和o表示1,2,3或4,其中两个或多个残基R1,R2和R3相同或不同; 在公式II中:X21表示骨架; Q1和Q2表示-O-或-NR22-; R21表示亚烷基或亚芳基; R22表示H,烷基或芳基; p,q和r表示0或1。
    • 6. 发明授权
    • Colour photographic silver halide material
    • 彩色照相卤化银材料
    • US5935773A
    • 1999-08-10
    • US639970
    • 1996-04-29
    • Jorg HagemannGunter Helling
    • Jorg HagemannGunter Helling
    • G03C7/392G03C1/46
    • G03C7/39268G03C7/39208G03C7/39296
    • A colour photographic silver halide material with a support, at last one silver halide emulsion layer containing at least one yellow coupler and at least one silver halide emulsion layer containing a cyan coupler applied thereon, in which material the silver halide emulsion layer, of which there is at least one, containing at least one yellow coupler and/or the silver halide emulsion layer, of which there is at least one, containing at least one cyan coupler contains a compound of the formula (I) ##STR1## in which R.sub.1, R.sub.2, R.sub.3 mean alkyl, alkenyl or acyl andn means 6, 7 or 8,is distinguished by improved stability of the image dyes produced by processing.
    • 具有载体的彩色照相卤化银材料,最后含有至少一种黄色成色剂的卤化银乳剂层和至少一种含有青色成色剂的卤化银乳剂层,其中存在卤化银乳剂层,其中存在卤化银乳剂层 至少一个,含有至少一个黄色成色剂和/或卤化银乳剂层,其中至少有一个含有至少一个含有式(I)的化合物的青色成色剂,其中R1,R2,R3 平均烷基,烯基或酰基,n表示6,7或8,其特征在于通过加工产生的图像染料的改进的稳定性。
    • 7. 发明授权
    • Photographic recording material
    • 摄影记录材料
    • US5340709A
    • 1994-08-23
    • US28815
    • 1993-03-10
    • Jorg HagemannGunter Helling
    • Jorg HagemannGunter Helling
    • G03C7/38G03C7/30G03C7/392G03C1/34
    • G03C7/39232G03C7/301
    • Compounds of Formula I are suitable as light stabilizers for the image dyes produced by chromogenic development from pyrazoloazole couplers ##STR1## In Formula I, R.sup.1 represents H, a group that can be split off under alkaline conditions, alkyl or aryl;R.sup.2 represents --OH, alkyl, aryl, alkoxy or ##STR2## R.sup.3, R.sup.4, R.sup.5 and R.sup.6 represent H, --OH, --COOH, --SO.sub.3 H, --SO.sub.2 H, alkyl, aryl, alkoxy, sulphonyl, sulphamoyl, acylamino or ##STR3## at least one of the groups R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 being a group of the formula ##STR4## A represents alkylene with 1-6 C atoms; n represents 0 or 1,R.sup.7 represents H or alkyl, optionally substituted alkyl,R.sup.8 represents optionally substituted alkyl, cycloalkyl or aryl with 4-20 C atoms;R.sup.1 and R.sup.3 can form a 5- or 6-membered ring, in which case R.sup.2 =--OH or alkoy;R.sup.2 and R.sup.4 can form a 5- or 6-membered carbocyclic ring.
    • 式I的化合物适合作为由吡唑并咪唑成色剂显色发生产生的图像染料的光稳定剂,可以在碱性条件下分离烷基或芳基; R2代表-OH,烷基,芳基,烷氧基或R3,R4,R5和R6表示H,-OH,-COOH,-SO3H,-SO2H,烷基,芳基,烷氧基,磺酰基,氨磺酰基,酰基氨基或 R 2,R 3,R 4,R 5和R 6中的至少一个是下式的基团:A表示具有1-6个C原子的亚烷基; n表示0或1,R7表示H或烷基,任选取代的烷基,R8表示任选取代的烷基,环烷基或具有4-20个C原子的芳基; R1和R3可以形成5-或6-元环,在这种情况下R2 = -OH或烷基; R2和R4可以形成5-或6-元碳环。
    • 8. 发明授权
    • Photographic recording material containing a light-protective agent
    • 含有防晒剂的摄影记录材料
    • US5310643A
    • 1994-05-10
    • US967819
    • 1992-10-28
    • Gunter HellingJorg Hagemann
    • Gunter HellingJorg Hagemann
    • C07D213/34C08G18/10G03C7/32G03C7/388G03C7/392G03C7/396G03C1/34G03C7/38
    • G03C7/396C08G18/10G03C7/3882
    • Compounds corresponding to Formula I are suitable as light stabilizers for the image dyes produced from colour couplers by chromogenic development. They are also suitable as oil formers for the colour couplers. In a colour photographic recording material, they are preferably used in combination with a pyrazoloazole coupler and associated with a light-sensitive silver halide emulsion layer. ##STR1## In Formula I, R.sup.1 denotes H, a group which can be split off under alkaline conditions, alkyl or aryl;R.sup.2 denotes OH, alkyl, aryl, alkoxy or ##STR2## R.sup.3, R.sup.4, R.sup.5 and R.sup.6 denote H, OH, COOH, SO.sub.3 H, SO.sub.2 H, alkyl, aryl, alkoxy, sulphonyl, sulphamoyl, acylamino or ##STR3## and at least one of the groups R.sup.2, R.sup.3, R.sup.4 R.sup.5 and R.sup.6 is a group of the formula ##STR4## A denotes an alkylene group having 1-6 carbon atoms, n stands for 0 or 1,R.sup.7 denotes H or an optionally substituted alkyl group,R.sup.8 denotes the group of a polymer produced by polycondensation, in particular a polyester, polyether, polycarbonate, polyurethane or polyester polyurethane,R.sup.1 and R.sup.3 may form a 5-membered or 6-membered ring, in which case R.sup.2 =OH or alkoxy, andR.sup.2 and R.sup.4 may form a 5-membered or 6-membered carbocyclic ring.
    • 对应于式I的化合物适合作为通过显色发展由成色剂产生的图像染料的光稳定剂。 它们也适用于成色剂的成油器。 在彩色照相记录材料中,它们优选与吡唑并唑成色剂组合使用并与感光卤化银乳剂层相关联。 (I)式I中,R 1表示H,可在碱性条件下分解的基团,烷基或芳基; R2表示OH,烷基,芳基,烷氧基或O3H,SO2H,烷基,芳基,烷氧基,磺酰基,氨磺酰基,酰基氨基或氨基,R2,R3,R4 R5和R6中的至少一个是式 A表示具有1-6个碳原子的亚烷基,n表示0或1,R7表示H或任选取代的烷基,R8表示通过缩聚制备的聚合物的基团,特别是聚酯,聚醚, 聚碳酸酯,聚氨酯或聚酯聚氨酯,R1和R3可以形成5元或6元环,在这种情况下R2 = OH或烷氧基,R2和R4可以形成5元或6元碳环。
    • 9. 发明授权
    • Color photographic recording material containing combination of phenolic
light stabilizers with novel polycyclic phenols as color stabilizers
for the magenta pyrazoloazol type azomethine dyes
    • 包含酚类光稳定剂与新型多环酚的组合的彩色照相记录材料作为品红色吡唑并唑型偶氮甲碱染料的颜色稳定剂
    • US5436125A
    • 1995-07-25
    • US281623
    • 1994-07-28
    • Jorg HagemannBeate Weber
    • Jorg HagemannBeate Weber
    • G03C7/30G03C7/392
    • G03C7/3008
    • In a color photographic recording material, the light stability of a dye image produced from a magenta coupler and stabilized with a compound of the formula I may be further improved by additionally using a compound of one of the formulae II and III. ##STR1## In the formulae I, II and III, R.sup.1, R.sup.21, R.sup.25, R.sup.31, R.sup.34 mean H, alkyl, aryl, acyl;R.sup.2, R.sup.22, R.sup.32 mean --OR.sup.1 alkyl, aryl, dialkylamino, acylamino, sulphonamido, acyl, sulphonyl;R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.23, R.sup.24, R.sup.33 mean H, halogen or a residue as R.sup.2 ;m, n, q mean 0, 1, 2 or 3;o means 0, 1 or 2;p means a positive integer;A means alkylene, --O--, --S--, --NR.sup.25 --, --SO.sub.2 ;B means alkylene, --O--, --S--, --NR.sup.34 --, --SO.sub.2 --;wherein two adjacent residues --OR.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 may together complete a 5- to 8-membered ring, two adjacent residues --OR.sup.21, R.sup.23, R.sup.22 or --OR.sup.21, R.sup.24, R.sup.22, or --OR.sup.31, R.sup.33 or R.sup.32, R.sup.33 may together complete a 5- or 6-membered ring, wherein R.sup.22 or R.sup.32 are not identical to --OR.sup.21 or --OR.sup.31 respectively, if R.sup.21 or R.sup.31 is H, and wherein two residues R.sup.31 are not simultaneously H.
    • 在彩色照相记录材料中,通过另外使用式II和III之一的化合物,可以进一步提高由品红成色剂产生并用式I化合物稳定化的染料影像的光稳定性。 (III)在式I,II和III中,R 1,R 21,R 25,R 31,R 34表示H,烷基,芳基,酰基; R2,R22,R32表示-OR1烷基,芳基,二烷基氨基,酰氨基,磺酰氨基,酰基,磺酰基; R 3,R 4,R 5,R 6,R 23,R 24,R 33表示H,卤素或残基作为R 2; m,n,q表示0,1,2或3; o表示0,1或2; p表示正整数; A表示亚烷基,-O - , - S - , - NR 25 - , - SO 2; B表示亚烷基,-O - , - S - , - NR 34 - , - SO 2 - ; 其中两个相邻的残基-OR1,R2,R3,R4,R5,R6可以一起完成5-至8-元环,两个相邻的残基-OR 21,R 23,R 22或-OR 21,R 24,R 22或-OR 31,R 33 或R32,R33可以一起完成5-或6-元环,其中如果R 21或R 31为H,R 22或R 32分别不与-OR 21或-OR 31相同,并且其中两个残基R31不同时为H.