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1. 发明授权

US07781537B2 Functionalized poly(arylene ether) composition and method 有权
标题翻译：官能化聚（亚芳基醚）组合物和方法
公开(公告)号：US07781537B2
公开(公告)日：2010-08-24
申请号：US11877817
申请日：2007-10-24
申请人： Joop Birsak , Herbert Shin-I Chao , Bryan Duffey , Amy Rene Freshour , Hugo Gerard Edward Ingelbrecht , Qiwei Liu , Michael Joseph O'Brien , Prameela Susarla , Michael Vallance , Kenneth Paul Zarnoch
发明人： Joop Birsak , Herbert Shin-I Chao , Bryan Duffey , Amy Rene Freshour , Hugo Gerard Edward Ingelbrecht , Qiwei Liu , Michael Joseph O'Brien , Prameela Susarla , Michael Vallance , Kenneth Paul Zarnoch
IPC分类号： C08L71/12
CPC分类号： C08G65/485 , C08F220/06 , C08F222/1006 , C08F283/06 , C08F283/08 , C08F290/061 , C08F290/062
摘要： A curable composition includes an olefinically unsaturated monomer and a poly(arylene ether) having two polymerizable groups and an intrinsic viscosity of about 0.05 to about 0.30 deciliters per gram. The composition exhibits an improved combination of high flow during molding and high post-cure stiffness and impact strength. The composition is particularly useful for fabricating plastic-packaged electronic devices.
摘要翻译：可固化组合物包括烯属不饱和单体和具有两个可聚合基团的聚（亚芳基醚），特性粘度为约0.05至约0.30分升/克。该组合物在模塑期间显示出高流动性和高后固化刚度和冲击强度的改进的组合。该组合物特别适用于制造塑料封装的电子器件。

2. 发明授权

US07329708B2 Functionalized poly(arylene ether) composition and method 有权
标题翻译：官能化聚（亚芳基醚）组合物和方法
公开(公告)号：US07329708B2
公开(公告)日：2008-02-12
申请号：US10920744
申请日：2004-08-18
申请人： Joop Birsak , Herbert Shin-I Chao , Bryan Duffey , Amy Rene Freshour , Hugo Gerard Eduard Ingelbrecht , Qiwei Lu , Michael Joseph O'Brien , Prameela Susarla , Michael Vallance , Kenneth Paul Zarnoch
发明人： Joop Birsak , Herbert Shin-I Chao , Bryan Duffey , Amy Rene Freshour , Hugo Gerard Eduard Ingelbrecht , Qiwei Lu , Michael Joseph O'Brien , Prameela Susarla , Michael Vallance , Kenneth Paul Zarnoch
IPC分类号： C08L71/12
CPC分类号： C08G65/485 , C08F220/06 , C08F222/1006 , C08F283/06 , C08F283/08 , C08F290/061 , C08F290/062
摘要： A curable composition includes an olefinically unsaturated monomer and a poly(arylene ether) having two polymerizable groups and an intrinsic viscosity of about 0.05 to about 0.30 deciliters per gram. The composition exhibits an improved combination of high flow during molding and high post-cure stiffness and impact strength. The composition is particularly useful for fabricating plastic-packaged electronic devices.
摘要翻译：可固化组合物包括烯属不饱和单体和具有两个可聚合基团的聚（亚芳基醚），特性粘度为约0.05至约0.30分升/克。该组合物在模塑期间显示出高流动性和高后固化刚度和冲击强度的改进的组合。该组合物特别适用于制造塑料封装的电子器件。

3. 发明授权

US06521703B2 Curable resin composition, method for the preparation thereof, and articles derived thereform 失效
标题翻译：可固化树脂组合物，其制备方法和衍生的制品
公开(公告)号：US06521703B2
公开(公告)日：2003-02-18
申请号：US09765065
申请日：2001-01-17
申请人： Kenneth Paul Zarnoch , Hua Guo , Herbert Shin-I Chao
发明人： Kenneth Paul Zarnoch , Hua Guo , Herbert Shin-I Chao
IPC分类号： C08L6706
CPC分类号： C08K5/06 , C08G63/54 , C08G65/485 , C08L67/06 , C08L71/126 , C08L2666/18 , C08L71/00
摘要： A curable resin composition includes an unsaturated polyester, an alkenyl aromatic compound, and a capped poly(arylene ether). The composition is suitable for low temperature curing and exhibits reduced curing shrinkage and reduced brittleness.
摘要翻译：可固化树脂组合物包括不饱和聚酯，烯基芳族化合物和封端的聚（亚芳基醚）。该组合物适用于低温固化，显示出降低的固化收缩率和降低的脆性。

4. 发明授权

US06303224B1 Method for attaching a fluoride-based polymer layer to a polyphenylene ether or polystyrene layer, and related articles 失效
标题翻译：用于将氟化物基聚合物层附着到聚苯醚或聚苯乙烯层上的方法及相关物品
公开(公告)号：US06303224B1
公开(公告)日：2001-10-16
申请号：US09089760
申请日：1998-06-03
申请人： John R. Krahn , Herbert Shin-I Chao
发明人： John R. Krahn , Herbert Shin-I Chao
IPC分类号： B32B2708
CPC分类号： B32B27/08 , B32B7/12 , B32B27/285 , B32B2371/00 , B32B2419/06 , C09J151/00 , C09J153/00 , Y10T428/2998 , Y10T428/31504 , Y10T428/3154 , Y10T428/31855 , Y10T428/31931 , Y10T428/31935
摘要： This invention is directed to a tie layer for improving the adhesion of a layer of a fluoride-based polymeric material to a layer of a polyphenylene ether- or polystyrene-based material. The tie layer comprises a copolymer of a styrenic material like high impact polystyrene, and an acrylic material such as poly(methyl methacrylate) (PMMA). The tie layer composition may further include at least one flexibilizing agent which is compatible with one of the materials in the other layers. Exemplary flexibilizing agents are blends or copolymers which comprise rubber and polystyrene, or core-shell impact modifiers, or combinations of these types of materials. The layers can be coextruded or laminated, using conventional techniques.
摘要翻译：本发明涉及一种用于改善氟化物基聚合物材料层与聚苯醚或聚苯乙烯基材料层的粘合性的粘结层。连接层包括苯乙烯类材料如高抗冲聚苯乙烯和丙烯酸材料如聚（甲基丙烯酸甲酯）（PMMA）的共聚物。粘结层组合物还可以包括至少一种与其它层中的材料之一相容的柔性剂。灵活性增强剂的例子是包括橡胶和聚苯乙烯或核 - 壳抗冲击改性剂或这些类型的材料的组合的共混物或共聚物。这些层可以使用常规技术共挤出或层压。

5. 发明授权

US5756196A Composition and method for enhancing the surface adhesion of polyurethane foam to surfaces of thermoplastic blends 失效
公开(公告)号：US5756196A
公开(公告)日：1998-05-26
申请号：US769358
申请日：1996-12-19
申请人： Herbert Shin-I Chao , Geoffrey Henry Riding , David John Swanson
发明人： Herbert Shin-I Chao , Geoffrey Henry Riding , David John Swanson
IPC分类号： B32B7/10 , B32B7/12 , B32B27/08 , B32B27/40 , C08J5/12 , C08K5/17 , C08L25/04 , C08L25/06 , C08L71/00 , C08L71/12 , C09J5/00 , B32B27/00
CPC分类号： C08J5/12 , B32B27/08 , B32B27/40 , B32B7/10 , B32B7/12 , C08K5/17 , C08L25/06 , C08L71/123 , C08J2375/04 , C08L71/12 , Y10T428/249991 , Y10T428/31587 , Y10T428/31938
摘要： A composition and method for promoting improved adhesion between a thermoplastic resinous substrate and polyurethane foam is provided. In one aspect of this invention, the composition comprises a thermoplastic mixture of at least one polyphenylene ether and at least one poly(alkenylaromatic) compound; and at least one primary amine-containing material or secondary amine-containing material.

6. 发明授权

US06855776B2 Amino-terminated polybutadienes 有权
标题翻译：氨基封端的聚丁二烯
公开(公告)号：US06855776B2
公开(公告)日：2005-02-15
申请号：US10300435
申请日：2002-11-20
申请人： Herbert Shin-I Chao , John Schmidhauser , Alain Robert Drexler , Nan Tian
发明人： Herbert Shin-I Chao , John Schmidhauser , Alain Robert Drexler , Nan Tian
IPC分类号： C08C19/00 , C08G18/62 , C08G18/69 , C08L15/00 , C08F8/30
CPC分类号： C08G18/6208 , C08C19/00 , C08G18/696 , C08G2190/00 , C08L15/00 , Y10S525/911
摘要： Improved amine-terminated polybutadienes (ATPBs) having one or two terminal groups of the formula —CHRNH2 wherein R is C1-C20 alkyl, are prepared by aminating a secondary hydroxyl-terminated polybutadiene having no ether groups. The ATPBs may be hydrogenated or partially hydrogenated, either prior to or after the animation, to saturate or partially saturate the polymers. Preferred ATPBs are of the formula H2NCHR-(polybutadiene)-CHRNH2 wherein R is C1-C20 alkyl. Polyureas, polyurethanes, crosslinked epoxies, polyamides, and other derivatives with improved properties can be prepared from the ATPBs. The resultant derivatives are useful in liquid binders for braking systems, electric potting compositions, coatings, adhesives, sealants, and water proofing membranes, for example.
摘要翻译：通过胺化不具有醚基的仲羟基封端的聚丁二烯来制备具有一个或两个式-CHRNH 2末端基团的胺封端的聚丁二烯（ATPB），其中R是C1-C20烷基。在动画之前或之后，ATPB可以被氢化或部分氢化，使聚合物饱和或部分饱和。优选的ATPB具有式H2NCHR-（聚丁二烯）-CHRNH 2，其中R是C 1 -C 20烷基。可以从ATPB制备具有改进性能的聚脲，聚氨酯，交联环氧树脂，聚酰胺和其它衍生物。所得到的衍生物可用于例如制动系统，电灌封组合物，涂料，粘合剂，密封剂和防水膜的液体粘合剂中。

7. 发明授权

US5688837A Method of improving adhesion of polyurethane foam to polycarbonate and articles made thereby 失效
标题翻译：改善聚氨酯泡沫与聚碳酸酯粘合性的方法及其制成的制品
公开(公告)号：US5688837A
公开(公告)日：1997-11-18
申请号：US533051
申请日：1995-09-25
申请人： Herbert Shin-I Chao , Carol Lynn Fasoldt , Abbas Mohamad Safieddine , Christian Lietzau
发明人： Herbert Shin-I Chao , Carol Lynn Fasoldt , Abbas Mohamad Safieddine , Christian Lietzau
IPC分类号： A61K47/48 , C07K16/30 , C08J5/12 , C08G18/00
CPC分类号： C08J5/12 , A61K47/48638 , C07K16/3069 , A61K2039/505 , C08J2369/00 , C08J2375/04 , Y10T428/31507 , Y10T428/31551 , Y10T428/31554
摘要： A method improves the adhesion of polyurethane foam to polycarbonate by providing reactive groups on the polycarbonate surface. The adhesion is further improved by utilizing a polyurethane mix with an isocyanate index greater than 82. Articles comprising polycarbonate and polyurethane foam adhered to the polycarbonate by the method of the instant invention, such as automobile dashboards, are also provided.
摘要翻译：一种方法通过在聚碳酸酯表面上提供反应性基团来改善聚氨酯泡沫与聚碳酸酯的粘合性。通过使用异氰酸酯指数大于82的聚氨酯混合物，进一步提高了粘合性。本发明还提供了通过本发明的方法粘附到聚碳酸酯上的聚碳酸酯和聚氨酯泡沫的制品，例如汽车仪表板。

8. 发明授权

US09045615B2 Metal carboxylate additives for thermoplastics 有权
标题翻译：用于热塑性塑料的金属羧酸盐添加剂
公开(公告)号：US09045615B2
公开(公告)日：2015-06-02
申请号：US13216398
申请日：2011-08-24
申请人： Jeremy Roland Austin , Herbert Shin-I Chao
发明人： Jeremy Roland Austin , Herbert Shin-I Chao
IPC分类号： C08K5/098 , C08L23/12 , C08L23/04 , C08L23/02 , C08K5/00
CPC分类号： C08K5/0091 , C08K5/098 , C08L23/04 , C08L23/02
摘要： A thermoplastic composition includes a polyolefin having a polymeric backbone and, associated therewith, one or more ionic compounds having a central metal element and one or more carboxylic acid functional moieties. The thermoplastic composition may be, for example, polyethylene or polypropylene. A method of improving the mechanical properties of thermoplastics includes adding, to a thermoplastic composition having a polymeric backbone, an additive including one or more ionic compounds having a central metal element and one or more carboxylic acid functional moieties, wherein the additive is added to the thermoplastic composition at conditions suitable to associate the one or more ionic compounds to the polymeric backbone. The ionic compounds may be, for example, zinc cinnamate, zinc hydrocinnamate, zinc naphthoate, zinc naphthalene acetate, isophthalic acid zinc salt, and phthalic acid zinc salt, and their equivalents substituting calcium or magnesium instead of zinc as the central metal element, and mixtures thereof.
摘要翻译：热塑性组合物包括具有聚合物主链的聚烯烃，并且与其相关联，具有一种或多种具有中心金属元素和一个或多个羧酸官能部分的离子化合物。热塑性组合物可以是例如聚乙烯或聚丙烯。改进热塑性塑料的机械性能的方法包括向具有聚合物主链的热塑性组合物中加入包含一种或多种具有中心金属元素和一种或多种羧酸官能部分的离子化合物的添加剂，其中将添加剂加入到热塑性组合物在适于将一种或多种离子化合物与聚合物骨架缔合的条件下进行。离子性化合物可以是例如肉桂酸锌，氢化肉桂酸锌，萘甲酸锌，萘乙酸锌，间苯二甲酸锌盐和邻苯二甲酸锌盐，它们的取代为钙或镁而不是锌作为中心金属元素的当量，以及其混合物。

9. 发明授权

US06469124B2 Functionalized polyphenylene ether resins and curable compositions comprising them 有权
公开(公告)号：US06469124B2
公开(公告)日：2002-10-22
申请号：US09683352
申请日：2001-12-18
申请人： Adrianus J.F.M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
发明人： Adrianus J.F.M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
IPC分类号： C08G6300
CPC分类号： C08G65/485 , C08L71/02 , C08L2666/02
摘要： The invention relates to a polyphenylene ether resin containing residual aliphatic unsaturation as well as composites, blends, and articles made from the polyphenylene ether resin containing residual aliphatic unsaturation. Also included are reaction products between the polyphenylene ether resin containing residual aliphatic unsaturation and other resins and unsaturated resin formulations, e.g., thermosetting polyesters, acrylics, bismaleiimides, silicones, and allylics, and thermoplastics such as polyolefins, styrenics, rubbers, etc.

10. 发明授权

US06306963B1 Thermosetting resins and laminates 失效
标题翻译：热固性树脂和层压板
公开(公告)号：US06306963B1
公开(公告)日：2001-10-23
申请号：US09657648
申请日：2000-09-07
申请人： Scott A. Lane , Timothy W. Austill , Donald C. Rollen , Herbert Shin-I Chao , Kenneth P. Zarnoch , Hua Guo , David Parrillo , David Peter Reis , Narsi Devanathan , Benny David
发明人： Scott A. Lane , Timothy W. Austill , Donald C. Rollen , Herbert Shin-I Chao , Kenneth P. Zarnoch , Hua Guo , David Parrillo , David Peter Reis , Narsi Devanathan , Benny David
IPC分类号： C08G6391
CPC分类号： C08F290/067 , C08F290/061 , C08L71/126 , H05K1/0353 , C08L2666/04
摘要： Thermosetting polymers and the electrical laminates made therefrom are disclosed. The laminate comprises a cross-linked product of: a) one or more ethylenically unsaturated aromatic monomers, with fire retardation being optionally contributed by one halogenated monomer, b) a vinyl-terminated polybutadiene or butadiene-styrene copolymer containing either a urethane or an ester group, and c) a chemically modified polyphenylene ether resin, preferably low molecular weight chemically modified polyphenylene ether resin. It has been discovered that an unexpected combination of thermal, electrical, and mechanical properties are obtained from the composition recited herein. Therefore, the composition is ideally suited as a matrix polymer for electrical substrate applications.
摘要翻译：公开了热固性聚合物和由其制成的电层压材料。层压体包含交联产物：a）一种或多种烯键式不饱和芳族单体，其阻燃作用由一种卤化单体任选地提供，b）乙烯基封端的聚丁二烯或含有氨基甲酸酯或酯的丁二烯 - 苯乙烯共聚物并且c）化学改性的聚苯醚树脂，优选低分子化学改性的聚苯醚树脂。已经发现，从本文所述的组合物获得热，电和机械性能的意想不到的组合。因此，该组合物理想地适用于电气基底应用的基质聚合物。

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