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    • 5. 发明授权
    • Method for producing an asymmetric support membrane by physical gelation and the membranes obtained thereby
    • 通过物理凝胶化制备不对称支持膜的方法和由此获得的膜
    • US06486240B1
    • 2002-11-26
    • US09428994
    • 1999-10-28
    • Jong Ok WonYong Soo KangHyun Chae ParkUn Young KimSeong Hyun Yoo
    • Jong Ok WonYong Soo KangHyun Chae ParkUn Young KimSeong Hyun Yoo
    • C08K534
    • B01D67/0011B01D67/0016B01D69/10B01D71/64B01D71/68B01D2325/022B01D2325/026Y10T428/24998
    • An asymmetric support membrane can be prepared by using a phase separation method. The method includes immersing a polymer solvent solution into water. The polymer solution is made by dissolving 15 to 35% by weight of the polymer into a solvent that lets the polymer solution become a gel at a temperature of 0 to 50° C. The solution is then allowed to gel and brought into a final membrane form in water for phase separation and formation of the asymmetric support membrane. The polymer may be poly(vinyl chloride), polyethersulfone, polyetherimide and polyamic(methylester). The solvent is &ggr;-butyrolactone alone as a major solvent or is a mixed solvent with N-methyl-2-pyrrolidone as a cosolvent. The asymmetric support membrane is a porous support membrane of a sponge form having open pores that are connected to one another with a narrow pore size distribution. Thus, the asymmetric support membrane has an improved permeance and mechanical strength. Further, because it has a narrow pore size distribution, a coating process can be optimized with a material having high selectivity. Therefore, the composite membranes having improved selectivity can be easily produced by the present invention.
    • 可以通过使用相分离方法制备不对称支撑膜。 该方法包括将聚合物溶剂溶液浸入水中。 聚合物溶液通过将15-35%(重量)的聚合物溶解在溶剂中,使聚合物溶液在0至50℃的温度下变成凝胶。然后将溶液凝胶化并进入最后的膜 在水中形成相分离和形成不对称支撑膜。 聚合物可以是聚(氯乙烯),聚醚砜,聚醚酰亚胺和聚酰胺(甲酯)。 溶剂是单独的γ-丁内酯作为主要溶剂,或者是与N-甲基-2-吡咯烷酮作为助溶剂的混合溶剂。 不对称支撑膜是海绵形式的多孔支撑膜,其具有彼此连接并具有窄孔径分布的开口孔。 因此,不对称支撑膜具有改善的渗透性和机械强度。 此外,由于其具有窄的孔径分布,因此可以用具有高选择性的材料来优化涂布工艺。 因此,通过本发明可以容易地制备具有提高的选择性的复合膜。