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1. 发明申请

US20100022676A1 PHOTOCURABLE COMPOSITIONS COMPRISING A PHOTOINITIATOR OF THE PHENYLGLYOXYLATE TYPE 审中-公开
标题翻译：含有苯甲酸酯类型的光敏剂的可光性组合物
公开(公告)号：US20100022676A1
公开(公告)日：2010-01-28
申请号：US12442779
申请日：2007-09-24
申请人： Jonathan Rogers , Johannes Benkhoff , Karin Powell , Tunja Jung , Kurt Dietliker , Pascal Hayoz , Jean-Luc Birbaum , Thomas Vogel , Rinaldo Hüsler
发明人： Jonathan Rogers , Johannes Benkhoff , Karin Powell , Tunja Jung , Kurt Dietliker , Pascal Hayoz , Jean-Luc Birbaum , Thomas Vogel , Rinaldo Hüsler
IPC分类号： C08F2/46 , C08J7/18 , C07C69/67
CPC分类号： G03F7/031 , C07C59/90 , C07C69/738 , C07C2601/10 , C07C2601/14 , C08F2/50 , G03F7/0045 , G03F7/038
摘要： The invention provides a uv-curable colored composition, comprising (a) at least one selected ethylenically unsaturated photopolymerizable compound; (b) at least one selected curing agent; and (c) at least one selected colorant.
摘要翻译：本发明提供了一种紫外线固化着色组合物，其包含（a）至少一种选择的烯属不饱和光聚合化合物; （b）至少一种选择的固化剂; 和（c）至少一种选择的着色剂。

2. 发明授权

US07723399B2 N-substituted imides as polymerization initiators 有权
标题翻译： N-取代酰亚胺作为聚合引发剂
公开(公告)号：US07723399B2
公开(公告)日：2010-05-25
申请号：US11666887
申请日：2005-10-31
申请人： Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
发明人： Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
IPC分类号： C08F299/00 , C07D221/04 , C07D209/56 , C07D209/48
CPC分类号： C07D207/404 , B33Y70/00 , C07D207/46 , C07D209/48 , C07D221/14 , C08F4/00
摘要： The invention relates to novel N-substituted imides and polymerizable compositions comprising these N-substituted imides. The invention further relates to the use of N-substituted imides as polymerization initiators. The imides are compounds of the formula (I) and (II) wherein n is 1 or 2; m is 1 or 2; R1 and R2 are each, independently of one another, hydrogen, C1-C18alkyl, C1-C-18alkenyl C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxycarbonyl; or R1 and R2 together with the adjacent —CO—N—CO— group may form a monocyclic, bicyclic or polycyclic ring, said ring having up to 50 non hydrogen atoms and wherein said ring may contain the structural element (formula III) more than once; R3 if n is 1, is C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, OR10 or SR11, NR12R13; wherein R3 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene R4 and R5, correspond to R1 and R2; R6 if n is 1, is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, NR14R15; wherein R6 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene; R7 is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxy-carbonyl; or R7 and R14 or R7 and R15 form together with the N-atom attached to R7 a 5-6 membered ring, optionally interrupted by —NH—, —N(C1-C8alkyl)-, —O— and/or S-atoms.
摘要翻译：本发明涉及新型的N-取代的酰亚胺和包含这些N-取代的酰亚胺的可聚合组合物。本发明还涉及N-取代的酰亚胺作为聚合引发剂的用途。酰亚胺是式（I）和（II）的化合物，其中n为1或2; m为1或2; R 1和R 2各自独立地为氢，C 1 -C 18烷基，C 1 -C 18烯基C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，其各自可被卤素，C 1 -C 4 - 烷基，羟基，C 1 -C 1-6烷氧基，羰基，C 1 -C 6烷氧基羰基; 或R 1和R 2与相邻的-CO-N-CO-基团一起可以形成单环，双环或多环，所述环具有至多50个非氢原子，并且其中所述环可含有结构单元（式III）一旦; 如果n为1，R 3为C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，OR 10或SR 11，NR 12 R 13; 其中如果n为2，R 3为C 2 -C 12亚烷基，C 6 -C 14亚芳基，亚二甲苯基R4和R 5对应于R 1和R 2; 如果n为1，R 6为氢，C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，NR 14 R 15; 其中如果n为2，R 6为C 2 -C 12亚烷基，C 6 -C 14亚芳基，亚二甲苯基; R 7是氢，C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，其各自可被卤素，C 1 -C 4 - 烷基，羟基，C 1 -C 6烷氧基，羰基，C 1 -C 6烷氧基 - 羰基取代; 或R 7和R 14或R 7和R 15与连接至R 7的N-原子一起形成5-6元环，任选被-NH-，-N（C 1 -C 8烷基） - ， - 和 - 或S-原子。

3. 发明申请

US20080132600A1 N-Substituted Imides As Polymerization Initiators 有权
公开(公告)号：US20080132600A1
公开(公告)日：2008-06-05
申请号：US11666887
申请日：2005-10-31
申请人： Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
发明人： Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
IPC分类号： C08L79/08 , C07D209/48 , C07D221/06 , C07D207/46 , C07D209/56
CPC分类号： C07D207/404 , B33Y70/00 , C07D207/46 , C07D209/48 , C07D221/14 , C08F4/00
摘要： The invention relates to novel N-substituted imides and polymerizable compositions comprising these N-substituted imides. The invention further relates to the use of N-substituted imides as polymerization initiators. The imides are compounds of the formula (I) and (II) wherein n is 1 or 2; m is 1 or 2; R1 and R2 are each, independently of one another, hydrogen, C1-C18alkyl, C1-C18alkenyl C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxycarbonyl; or R1 and R2 together with the adjacent —CO—N—CO— group may form a monocyclic, bicyclic or polycyclic ring, said ring having up to 50 non hydrogen atoms and wherein said ring may contain the structural element (formula III) more than once; R3 if n is 1, is C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, OR10 or SR11, NR12R13; wherein R3 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene R4 and R5, correspond to R1 and R2; R6 if n is 1, is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, NR14R15; wherein R6 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene; R7 is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxy-carbonyl; or R7 and R14 or R7 and R15 form together with the N-atom attached to R7 a 5-6 membered ring, optionally interrupted by —NH—, —N(C1-C8alkyl)-, —O- and/or S-atoms.

4. 发明授权

US08637585B2 Silsesquioxane photoinitiators 有权
标题翻译：倍半硅氧烷光引发剂
公开(公告)号：US08637585B2
公开(公告)日：2014-01-28
申请号：US13130796
申请日：2009-11-24
申请人： Markus Frey , Christophe Frossard , Katia Studer , Karin Powell , Jean-Luc Birbaum , Martin Müller
发明人： Markus Frey , Christophe Frossard , Katia Studer , Karin Powell , Jean-Luc Birbaum , Martin Müller
IPC分类号： C08F2/50 , C08J3/28 , C08F283/12 , C08F283/00
CPC分类号： C07F7/21 , B33Y70/00
摘要： Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1′) wherein n is 2m; m is an integer of 2 to 30; the sum of n′+a is an integer 4-60; n′ is an even-numbered integer; a is an even- or uneven-numbered integer; and for example different A C1-C12alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C1-C3alkylene, preferably propylene; R1 and R2 for example are a photoactive moiety Q, or C2-20alkyl; Q is for example a group of formula (4); Z2 is for example C1-C6alkylene which is unsubstituted or substituted by one or more OR6; and R6, R12, R13 and R14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.
摘要翻译：光引发剂化合物，其包含与多面体低聚倍半硅氧烷结合的光活性部分和胺官能团，该光引发剂由式（1）或（1'）表示，其中n为2m; m为2〜30的整数， n'+ a的和为4-60的整数; n'是偶数整数; a是偶数或不均匀的整数; 例如不同的A C1-C12烷基或光活性部分Q1或式（2）的基团; E例如是直接键合，L是直链或支链C1-C3亚烷基，优选丙烯; R1和R2例如是光活性部分Q或C2-20烷基; Q例如是式（4）的一组; Z2为例如未被取代或被一个或多个OR 6取代的C 1 -C 6亚烷基; R 6，R 12，R 13和R 14例如为氢; 特别适用于低迁移性光引发剂。

5. 发明申请

US20120142793A1 SILSESQUIOXANE PHOTOINITIATORS 有权
标题翻译： SILSESQUIOXANE照相机
公开(公告)号：US20120142793A1
公开(公告)日：2012-06-07
申请号：US13130796
申请日：2009-11-24
申请人： Markus Frey , Christophe Frossard , Katia Studer , Karin Powell , Jean-Luc Birbaum , Martin Müller
发明人： Markus Frey , Christophe Frossard , Katia Studer , Karin Powell , Jean-Luc Birbaum , Martin Müller
IPC分类号： C08F2/46 , C08G77/38 , C08J9/00 , C09D137/00 , C09D11/10 , C09J137/00 , C08G77/388 , C08F224/00
CPC分类号： C07F7/21 , B33Y70/00
摘要： Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1′) wherein n is 2m; m is an integer of 2 to 30; the sum of n′+a is an integer 4-60; n′ is an even-numbered integer; a is an even- or uneven-numbered integer; and for example different A C1-C12alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C1-C3alkylene, preferably propylene; R1 and R2 for example are a photoactive moiety Q, or C2-20alkyl; Q is for example a group of formula (4); Z2 is for example C1-C6alkylene which is unsubstituted or substituted by one or more OR6; and R6, R12, R13 and R14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.
摘要翻译：光引发剂化合物，其包含与多面体低聚倍半硅氧烷结合的光活性部分和胺官能团，该光引发剂由式（1）或（1'）表示，其中n为2m; m为2〜30的整数， n'+ a的和为4-60的整数; n'是偶数整数; a是偶数或不均匀的整数; 例如不同的A C1-C12烷基或光活性部分Q1或式（2）的基团; E例如是直接键合，L是直链或支链C1-C3亚烷基，优选丙烯; R1和R2例如是光活性部分Q或C2-20烷基; Q例如是式（4）的一组; Z2为例如未被取代或被一个或多个OR 6取代的C 1 -C 6亚烷基; R 6，R 12，R 13和R 14例如为氢; 特别适用于低迁移性光引发剂。

6. 发明授权

US07727702B2 Method of coloring a coating composition 失效
标题翻译：着色涂料组合物的方法
公开(公告)号：US07727702B2
公开(公告)日：2010-06-01
申请号：US11547153
申请日：2005-03-29
申请人： Johannes Benkhoff , Karin Powell
发明人： Johannes Benkhoff , Karin Powell
IPC分类号： G03F7/00 , G03F7/004 , G03F7/20
CPC分类号： G03F7/105 , B41M5/30 , B41M5/323 , B41M5/327 , B41M2205/04 , C09D5/032 , C09D7/41 , C09D11/50 , G03C1/732 , Y10S430/106 , Y10S430/146
摘要： A method is provided for irreversibly coloring a coating composition containing a color former comprising the steps of a) providing a coating composition that contains an UV curable resin, a thermosetting resin or an alkyd resin with the proviso that the coating composition contains no developer nor any additive which may function as developer; b) mixing the coating composition with the color former whereby no color is formed; c) applying the colorless composition obtained in step b) to a substrate; d) in case of a thermosetting resin curing the resin between 100 and 300° C., preferably between 100 and 150° C., whereby no color is formed, in case of alkyd resin drying of the resin at room temperature, whereby no color is formed; e) exposure to UV or high energy radiation below 400 nm whereby the color is formed.
摘要翻译：提供了一种用于不可逆地着色含有着色剂的涂料组合物的方法，包括以下步骤：a）提供含有UV可固化树脂，热固性树脂或醇酸树脂的涂料组合物，条件是涂料组合物不含显影剂，也不含任何可用作显影剂的添加剂; b）将涂料组合物与成色剂混合，不形成颜色; c）将步骤b）中得到的无色组合物加到基材上; d）在热固性树脂固化树脂100至300℃之间，优选在100至150℃之间的情况下，在室温下树脂的醇酸树脂干燥的情况下，不会形成颜色，因此没有颜色形成了; e）暴露于低于400nm的UV或高能量辐射，从而形成颜色。

7. 发明申请

US20090162307A1 Photolatent Systems 有权
标题翻译：照相系统
公开(公告)号：US20090162307A1
公开(公告)日：2009-06-25
申请号：US12084335
申请日：2006-10-30
申请人： Katharina Fritzsche , Walter Fischer , Johannes Benkhoff , Karin Powell , Dirk Simon
发明人： Katharina Fritzsche , Walter Fischer , Johannes Benkhoff , Karin Powell , Dirk Simon
IPC分类号： A61K8/35 , C07C49/258 , C07D249/06 , A61Q5/06 , C11D1/72 , A61K8/34 , A61Q5/02 , C08K5/05 , C08K5/06 , C09K3/00 , A61Q5/12 , A61Q15/00
CPC分类号： C07C49/84 , C07C49/825 , C07C49/83 , C07D209/48 , C07D249/20 , C08K5/134
摘要： The instant invention relates to new photolatent compounds of the formula I wherein R1 and R2 are each independently of the other C1-C10alkyl or C3-C8cycloalkyl, R3 is hydrogen or C1-C4alkyl, and wherein the photochemically cleaved group R4OH is selected from the group consisting of fragrances, UV absorbers, anti-microbials, anti-fogging agents and clarifiers; with the proviso that, when R1 and R2 are tert-butyl and R3 is hydrogen, R4 is not methyl or phenyl.
摘要翻译：本发明涉及新的式I化合物，其中R 1和R 2各自独立地为C 1 -C 10烷基或C 3 -C 8环烷基，R 3为氢或C 1 -C 4烷基，并且其中光化学裂解基团R 4 OH选自由香料，紫外线吸收剂，抗微生物剂，防雾剂和澄清剂组成; 条件是当R 1和R 2是叔丁基且R 3是氢时，R 4不是甲基或苯基。

8. 发明授权

US07820865B2 Photolatent systems 有权
标题翻译：照相系统
公开(公告)号：US07820865B2
公开(公告)日：2010-10-26
申请号：US12084335
申请日：2006-10-30
申请人： Katharina Fritzsche , Walter Fischer , Johannes Benkhoff , Karin Powell , Dirk Simon
发明人： Katharina Fritzsche , Walter Fischer , Johannes Benkhoff , Karin Powell , Dirk Simon
IPC分类号： C07C49/00 , A61K8/18 , A61Q5/02
CPC分类号： C07C49/84 , C07C49/825 , C07C49/83 , C07D209/48 , C07D249/20 , C08K5/134
摘要： The instant invention relates to new photolatent compounds of the formula I wherein R1 and R2 are each independently of the other C1-C10alkyl or C3-C8cycloalkyl, R3 is hydrogen or C1-C4alkyl, and wherein the photochemically cleaved group R4OH is selected from the group consisting of fragrances, UV absorbers, anti-microbials, anti-fogging agents and clarifiers; with the proviso that, when R1 and R2 are tert-butyl and R3 is hydrogen, R4 is not methyl or phenyl.
摘要翻译：本发明涉及新的式I化合物，其中R 1和R 2各自独立地为C 1 -C 10烷基或C 3 -C 8环烷基，R 3为氢或C 1 -C 4烷基，并且其中光化学裂解基团R 4 OH选自由香料，紫外线吸收剂，抗微生物剂，防雾剂和澄清剂组成; 条件是当R 1和R 2是叔丁基且R 3是氢时，R 4不是甲基或苯基。

9. 发明申请

US20070207925A1 Method of Coloring a Coating Composition 失效
标题翻译：涂料组合物着色方法
公开(公告)号：US20070207925A1
公开(公告)日：2007-09-06
申请号：US11547153
申请日：2005-03-29
申请人： Johannes Benkhoff , Karin Powell
发明人： Johannes Benkhoff , Karin Powell
IPC分类号： B41M5/24
CPC分类号： G03F7/105 , B41M5/30 , B41M5/323 , B41M5/327 , B41M2205/04 , C09D5/032 , C09D7/41 , C09D11/50 , G03C1/732 , Y10S430/106 , Y10S430/146
摘要： A method is provided for irreversibly coloring a coating composition containing a color former comprising the steps of a) providing a coating composition that contains an UV curable resin, a thermosetting resin or an alkyd resin with the proviso that the coating composition contains no developer nor any additive which may function as developer; b) mixing the coating composition with the color former whereby no color is formed; c) applying the colorless composition obtained in step b) to a substrate; d) in case of a thermosetting resin curing the resin between 100 and 300° C., preferably between 100 and 150 ° C., whereby no color is formed, in case of alkyd resin drying of the resin at room temperature, whereby no color is formed; e) exposure to UV or high energy radiation below 400 nm whereby the color is formed.
摘要翻译：提供了一种用于不可逆地着色含有着色剂的涂料组合物的方法，包括以下步骤：a）提供含有UV可固化树脂，热固性树脂或醇酸树脂的涂料组合物，条件是涂料组合物不含显影剂，也不含任何可用作显影剂的添加剂; b）将涂料组合物与成色剂混合，不形成颜色; c）将步骤b）中得到的无色组合物加到基材上; d）在热固性树脂固化树脂100至300℃之间，优选在100至150℃之间的情况下，在室温下树脂的醇酸树脂干燥的情况下，不会形成颜色，因此没有颜色形成了; e）暴露于低于400nm的UV或高能量辐射，从而形成颜色。

10. 发明授权

US08426484B2 Liquid photoinitiator blend 有权
标题翻译：液体光引发剂混合物
公开(公告)号：US08426484B2
公开(公告)日：2013-04-23
申请号：US13144294
申请日：2010-01-04
申请人： Steffen Onclin , Svetozar Lucic , Karin Powell , Wolfgang Peter , Frank Oliver Heinrich Pirrung , Clemens Auschra
发明人： Steffen Onclin , Svetozar Lucic , Karin Powell , Wolfgang Peter , Frank Oliver Heinrich Pirrung , Clemens Auschra
IPC分类号： A61L2/08 , B41M7/00 , B29C71/04 , C08F2/46 , C08J3/28 , H05B6/68 , C08G61/04
CPC分类号： C08F2/50 , G03F7/0048 , G03F7/028 , G03F7/029 , G03F7/031
摘要： The present invention relates to a homogenous liquid blend comprising a photoinitiator and an alkoxylate surfactant for incorporation into aqueous based and solvent based radiation curable systems. In particular the invention relates to a homogenous liquid blend which is liquid at room temperature comprising at least 30% by weight with regard to the whole blend of a solid photoinitiator of the radical type and 1-70% by weight of at least one alkoxylated liquid surface active agent and optionally an organic diluent.
摘要翻译：本发明涉及包含光引发剂和烷氧基化物表面活性剂的均匀液体共混物，其用于掺入含水基和溶剂型可辐射固化体系中。特别地，本发明涉及在室温下为液体的均匀液体共混物，其包含至少30重量％，相对于自由基型固体光引发剂和1-70重量％的至少一种烷氧基化液体的全部共混物表面活性剂和任选的有机稀释剂。

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