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1. 发明授权

US07223897B2 Process for the production of olefins 失效
标题翻译：烯烃生产工艺
公开(公告)号：US07223897B2
公开(公告)日：2007-05-29
申请号：US11256194
申请日：2005-10-24
申请人： John William Couves , David Charles Griffiths , Brian Edward Messenger , Ian Allan Beattie Reid
发明人： John William Couves , David Charles Griffiths , Brian Edward Messenger , Ian Allan Beattie Reid
IPC分类号： C07C4/02 , C07C4/06
CPC分类号： B01J23/626 , B01J23/56 , B01J23/62 , C07C5/48 , C07C2521/02 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/44 , C07C11/02
摘要： A process for the production of an olefin from a hydrocarbon by autothermal cracking, which process comprises: partially combusting the hydrocarbon and an oxygen-containing gas in the presence of a catalyst, wherein the stoichiometric ratio of hydrocarbon to oxygen is 5 to 16 times the stoichiometric ratio of hydrocarbon to oxygen required for complete combustion of the hydrocarbon to carbon dioxide and water, characterised in that the catalyst comprises palladium and at least one further metal being a Group IIIA, Group IVA, VA, a transition metal or a lanthanide.
摘要翻译：一种通过自热裂解从烃生产烯烃的方法，该方法包括：在催化剂存在下部分燃烧烃和含氧气体，其中烃与氧气的化学计量比为5至16倍烃完全燃烧到二氧化碳和水所需的烃与氧的化学计量比，其特征在于催化剂包括钯和至少一种另外的金属，其为IIIA族，IVA族，VA族，过渡金属或镧系元素。

2. 发明授权

US07169962B2 Process for the production of olefins 失效
标题翻译：烯烃生产工艺
公开(公告)号：US07169962B2
公开(公告)日：2007-01-30
申请号：US10332800
申请日：2001-07-04
申请人： David Charles Griffiths , Ian Raymond Little , Brian Edward Messenger , Ian Allan Beattie Reid
发明人： David Charles Griffiths , Ian Raymond Little , Brian Edward Messenger , Ian Allan Beattie Reid
IPC分类号： C07C4/02 , C07C5/333
CPC分类号： C07C5/48 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C10G2400/20 , C10G2400/22 , Y02P30/40 , C07C11/02
摘要： Process for the production of an olefin comprising partially combusting in a reaction zone a mixture of a hydrocarbon and an oxygen-containing gas in the presence of a catalyst which is capable of supporting combustion beyond the fuel rich limit of flammability to produce the olefin. The superficial feed velocity of the mixture is at least 250 cm s−1 at standard temperature and operating pressure, with the proviso that where the catalyst is an unsupported catalyst, the superficial feed velocity of the mixture is at least 300 cm s−1 at standard temperature and operating pressure. The process is carried out at a pressure of at least 1.3 bara and the reaction zone is not externally heated.
摘要翻译：一种生产烯烃的方法，包括在催化剂存在下在反应区域中部分地燃烧烃和含氧气体的混合物，所述催化剂能够支持燃料超过燃料的燃烧极限以产生烯烃。在标准温度和操作压力下，混合物的表面进料速度至少为250cm 3，条件是当催化剂为无载体催化剂时，混合物的表面进料速度为在标准温度和操作压力下至少为300cm 3。该方法在至少1.3巴的压力下进行，并且反应区不进行外部加热。

3. 发明授权

US07164053B2 Process for the production of olefins 失效
标题翻译：烯烃生产工艺
公开(公告)号：US07164053B2
公开(公告)日：2007-01-16
申请号：US10221752
申请日：2001-02-22
申请人： Gavin Thomas Binmore , David Charles Griffiths , Brian Edward Messenger , Ian Allan Beattie Reid
发明人： Gavin Thomas Binmore , David Charles Griffiths , Brian Edward Messenger , Ian Allan Beattie Reid
IPC分类号： C07C5/327
CPC分类号： C07C5/48 , C07C2521/02 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/36 , C07C2523/46 , C07C2523/50 , C07C2523/52 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C11/02
摘要： Process for the production of an olefin from a hydrocarbon, which process comprises contacting the hydrocarbon and a molecular oxygen-containing gas with a catalyst under auto-thermal conditions sufficient to produce the olefin. The catalyst comprises a component (a) and a component (b), wherein component (a) is at least one metal selected from Group IIIA, Group IVA, Group VA and the transition metals and component (b) is at least one transition metal. The catalyst does not comprise either palladium or platinum.
摘要翻译：用于从烃生产烯烃的方法，该方法包括在足以产生烯烃的自动热条件下使烃和含分子氧的气体与催化剂接触。催化剂包含组分（a）和组分（b），其中组分（a）是选自IIIA族，IVA族，VA族和过渡金属中的至少一种金属，组分（b）是至少一种过渡金属。催化剂不包括钯或铂。

4. 发明授权

US07291760B2 Process for the production of olefins 失效
标题翻译：烯烃生产工艺
公开(公告)号：US07291760B2
公开(公告)日：2007-11-06
申请号：US11602206
申请日：2006-11-21
申请人： David Charles Griffiths , Ian Raymond Little , Brian Edward Messenger , Ian Allan Beattie Reid
发明人： David Charles Griffiths , Ian Raymond Little , Brian Edward Messenger , Ian Allan Beattie Reid
IPC分类号： C07C4/02 , C07C5/333
CPC分类号： C07C5/48 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C10G2400/20 , C10G2400/22 , Y02P30/40 , C07C11/02
摘要： A process for the production of an olefin comprising partially combusting in a reaction zone a mixture of a hydrocarbon and an oxygen-containing gas in the presence of a catalyst which is capable of supporting combustion beyond the fuel rich limit of flammability to produce the olefin, wherein the superficial feed velocity of said mixture is at least 250 cm s?-1? at standard temperature and operating pressure with the proviso that where the catalyst is an unsupported catalyst, the superficial feed velocity of said mixture is at least 300 cm s−1 at standard temperature and operating pressure.
摘要翻译：一种生产烯烃的方法，包括在催化剂存在下在反应区域中部分地燃烧烃和含氧气体的混合物，所述催化剂能够支持超出燃料的燃烧极限以产生烯烃，其中所述混合物的表面进料速度为至少250cm 3 / 在标准温度和操作压力下，条件是当催化剂是无载体催化剂时，在标准温度和操作压力下，所述混合物的表面进料速度为至少300cm -1。

5. 发明授权

US07135603B2 Process for the production of olefins 失效
标题翻译：烯烃生产工艺
公开(公告)号：US07135603B2
公开(公告)日：2006-11-14
申请号：US10332776
申请日：2001-06-26
申请人： Brian Edward Messenger
发明人： Brian Edward Messenger
IPC分类号： C07C4/06
CPC分类号： C07C5/48 , C07C2523/08 , C07C2523/14 , C07C2523/28 , C07C2523/30 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/62 , C07C2523/72 , C07C2523/89 , C10G2400/20 , C10G2400/22 , C07C11/02
摘要： Process for the production of olefins such as ethylene from a hydrocarbon such as ethane. The process involves passing a mixture of the hydrocarbon and an oxagen-containing gas through a catalyst zone which is capable of supporting combustion beyond the fuel rich limit of flammability to produce the olefin. The catalyst zone comprises at least a first catalyst bed and a second catalyst bed. The second catalyst bed is located downstream of the first catalyst bed, is of a different composition to the first catalyst bed and comprises at least one metal selected from the group consisting of Mo, W, and groups IB, IIB, IIIB, IVB, VB, VIIB and VIII of the Periodic Table. Suitably, the first catalyst bed comprises platinum and the second catalyst bed comprises tin- or copper-promoted nickel, cobalt or iridium catalyst or a copper-only catalyst.
摘要翻译：从烃如乙烷生产烯烃如乙烯的方法。该方法包括使烃和含氧化物的气体的混合物通过催化剂区，该催化剂区能够支持超过燃料的燃烧极限的燃烧以产生烯烃。催化剂区包括至少第一催化剂床和第二催化剂床。第二催化剂床位于第一催化剂床的下游，与第一催化剂床的组成不同，并且包含选自Mo，W和IB，IIB，IIIB，IVB，VB中的至少一种金属，周期表VIIB和VIII。合适地，第一催化剂床包含铂，第二催化剂床包括锡或铜促进的镍，钴或铱催化剂或仅含铜催化剂。

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