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1. 发明授权

US06395904B1 Binuclear non-heme iron catalysts 失效
标题翻译：双核非血红素铁催化剂
公开(公告)号：US06395904B1
公开(公告)日：2002-05-28
申请号：US09486547
申请日：2000-06-06
申请人： John P. Caradonna , Subhasish Mukerjee , Adonis Stassinopoulos
发明人： John P. Caradonna , Subhasish Mukerjee , Adonis Stassinopoulos
IPC分类号： C07F1500
CPC分类号： C07F15/025 , C07C29/48 , C07C235/50 , C07C315/02 , C07C2602/28 , C07D301/02 , C07C35/205
摘要： The subject invention provides a binuclear metal complex having structure (I) wherein M1, and M2 are independently selected from the group consisting of Fe, Co, Mn and Ru; wherein m and n are independently +2 or +3; wherein R1, R2, R3, R4, R5 and R6 are independently a linear C1-C6 alkyl, C5-C6 cycloalkyl, phenyl, etc.; wherein (i) R1 and R2, (ii) R3 and R4, or (iii) R5 and R6 independently and optionally are linked covalently and together with the respective adjoining C atom comprise a spirocyclic ring; wherein i, j and k are integers such that 2≦i+j+k≦4; wherein p is 1 or 2, and q is 0, 1 or 2 such that m+n−4=p×q; wherein (i) R1 or R2 and R3 or R4, (ii) R3 or R4 and R4 or R5, or (iii) R1 or R2 and R5 or R6 independently and optionally are linked covalently and together with the respective adjoining C atoms comprise a fused ring; wherein Ar is 1,2-phenylene, 1,2- or 2,3-naphthylene, etc., wherein said Ar is optionally substitued by C1-C6 alkyl or alkoxy; wherein L is N-methylimidazole, N-ethylimidazole, etc.; and wherein X is fluorine, chlorine, bromine, etc. Also provided are methods of oxidation of alkanes, arenes, and sulfides using the binuclear metal complex as a catalyst and a method of preparing said complex.
摘要翻译：本发明提供具有结构（I）的双核金属络合物，其中M1和M2独立地选自Fe，Co，Mn和Ru; 其中m和n独立地是+2或+3; 其中R1，R2，R3，R4，R5和R6独立地为直链C1-C6烷基，C5-C6环烷基，苯基等; 其中（i）R 1和R 2，（ⅱ）R 3和R 4，或（ⅲ）R 5和R 6独立地且任选被共价连接并与相邻的C原子一起包含一个螺环; 其中i，j和k是整数，使得2 <= i + j + k <= 4; 其中p为1或2，q为0,1或2，使得m + n-4 = pxq; 其中（i）R 1或R 2和R 3或R 4，（ⅱ）R 3或R 4和R 4或R 5，或（ⅲ）R 1或R 2和R 5或R 6独立且任选地与相邻的C原子共价连接并连接稠环; 其中Ar为1,2-亚苯基，1,2-或2,3-亚萘基等，其中所述Ar任选被C 1 -C 6烷基或烷氧基取代; 其中L是N-甲基咪唑，N-乙基咪唑等; 并且其中X是氟，氯，溴等。还提供了使用双核金属络合物作为催化剂的烷烃，芳烃和硫化物的氧化方法和制备所述络合物的方法。

2. 发明授权

US07781123B2 Method and apparatus for forming electrode interconnect contacts for a solid-oxide fuel cell stack 有权
标题翻译：用于形成固体氧化物燃料电池堆的电极互连触点的方法和装置
公开(公告)号：US07781123B2
公开(公告)日：2010-08-24
申请号：US11145647
申请日：2005-06-06
申请人： Joseph M. Keller , Karl J. Haltiner, Jr. , Subhasish Mukerjee , Diane M. England , Gary F. Reisdorf , Steven L. Cooper , Willem Vilders, III
发明人： Joseph M. Keller , Karl J. Haltiner, Jr. , Subhasish Mukerjee , Diane M. England , Gary F. Reisdorf , Steven L. Cooper , Willem Vilders, III
IPC分类号： H01M8/12 , H01M8/02 , H01M4/86 , C04B35/64
CPC分类号： H01M8/0245 , H01M4/8621 , H01M4/8885 , H01M8/0232 , H01M8/0236 , H01M8/0297 , H01M8/1213 , H01M8/1246 , H01M8/2425 , H01M8/2457 , Y02E60/525 , Y02P70/56
摘要： An electrical interconnect for a solid-oxide fuel cell stack assembly, including a novel sintering paste and an improved manufacturing process for an anode and cathode electrical contacts is disclosed. On the anode side, the paste contains a metallic oxide such as NiO, and an amount of sacrificial pore-forming particles, such as carbon particles or polymer spheres, which are vaporized during sintering of the paste, resulting in a very porous connection having good electrical conductivity and good adhesion. A preferred level of pore-former in the paste is about 40 volume percent. On the cathode side, the paste contains a noble metal such as for example, gold, platinum, palladium or rhodium, and an amount of the sacrificial pore-forming particles. The paste may be applied to the surfaces in a grid pattern or, because the resulting contact is porous after sintering, it may be applied as a continuous layer.
摘要翻译：公开了一种用于固体氧化物燃料电池堆组件的电互连，其包括新颖的烧结膏和用于阳极和阴极电触点的改进的制造工艺。在阳极侧，糊状物含有NiO等金属氧化物，以及在糊料烧结过程中蒸发的诸如碳颗粒或聚合物球的牺牲性成孔颗粒的量，导致非常多孔的连接具有良好的导电性好，附着力好。浆料中成孔剂的优选含量为约40体积％。在阴极侧，糊状物含有贵金属，例如金，铂，钯或铑，以及一定量的牺牲性成孔颗粒。糊状物可以以网格图案施加到表面，或者由于所得接触在烧结之后是多孔的，所以可以作为连续层施加。

3. 发明授权

US07601450B2 Hybrid interconnect for a solid-oxide fuel cell stack 失效
标题翻译：用于固体氧化物燃料电池堆的混合互连
公开(公告)号：US07601450B2
公开(公告)日：2009-10-13
申请号：US11087904
申请日：2005-03-23
申请人： Diane M. England , Lane Wilson , Subhasish Mukerjee , Catherine Vavonese
发明人： Diane M. England , Lane Wilson , Subhasish Mukerjee , Catherine Vavonese
IPC分类号： H01M2/02
CPC分类号： H01M8/0208 , H01M8/021 , H01M8/0223 , H01M8/0247 , H01M8/0297 , H01M8/2425 , H01M8/2465 , H01M2008/1293 , Y10T428/24273
摘要： An electrical interconnect for a fuel cell assembly comprising a peripheral frame formed of one or more materials having a coefficient of thermal expansion similar to that of adjacent elements to which the interconnect must be bonded and a central portion formed of a corrosion-resistant material for conducting electric current between adjacent fuel cells. Preferably, the central portion is attached to the peripheral frame via a brazed corrugated lap joint for relieving thermal expansion differences between the frame and the central portion. Preferably, the joint includes an interlayer of a ductile material, for example, a nickel, copper, silver or gold layer, which helps to relieve thermal stress between the frame and the central portion.
摘要翻译：一种用于燃料电池组件的电互连件，包括由一种或多种材料形成的外围框架，所述外围框架的热膨胀系数类似于要连接互连件的相邻元件的热膨胀系数;以及由用于导电的耐腐蚀材料形成的中心部分相邻燃料电池之间的电流。优选地，中心部分通过钎焊的波纹搭接接头附接到周边框架，用于减轻框架和中心部分之间的热膨胀差异。优选地，接头包括延性材料的中间层，例如镍，铜，银或金层，其有助于缓解框架和中心部分之间的热应力。

4. 发明申请

US20080032172A1 Conductive coating for solid oxide fuel cell 审中-公开
标题翻译：固体氧化物燃料电池导电涂层
公开(公告)号：US20080032172A1
公开(公告)日：2008-02-07
申请号：US11499583
申请日：2006-08-04
申请人： Subhasish Mukerjee , Karl J. Haltiner , Kerry Duane Meinhardt , Jin Yong Kim , Eric Mast , Vincent Lee Sprenkle
发明人： Subhasish Mukerjee , Karl J. Haltiner , Kerry Duane Meinhardt , Jin Yong Kim , Eric Mast , Vincent Lee Sprenkle
IPC分类号： H01M8/12 , H01M8/24
CPC分类号： H01M8/0228 , H01M8/0204 , H01M8/021 , H01M8/0223 , H01M2008/1293 , Y02P70/56
摘要： A solid oxide fuel cell stack that contains a plurality of fuel cells, each of which includes an anode and a cathode disposed on opposite sides of a solid electrolyte, and an electrically conductive interconnect disposed between the anode and cathode. The interconnect includes a substrate and a first surface in electrical contact with the anode and a second surface in electrical contact with the cathode, wherein at least a portion of at least one of the surfaces includes cobalt.
摘要翻译：一种固体氧化物燃料电池堆，其包含多个燃料电池，每个燃料电池包括设置在固体电解质的相对侧上的阳极和阴极以及设置在阳极和阴极之间的导电互连。互连包括基底和与阳极电接触的第一表面和与阴极电接触的第二表面，其中至少一个表面的至少一部分包括钴。

5. 发明授权

US07306872B2 Modular fuel cell cassette for forming a solid-oxide fuel cell stack 有权
标题翻译：用于形成固体氧化物燃料电池堆的模块化燃料电池盒
公开(公告)号：US07306872B2
公开(公告)日：2007-12-11
申请号：US11027095
申请日：2004-12-30
申请人： Karl J. Haltiner, Jr. , Subhasish Mukerjee , Lawrence A. Chick , Kerry D. Meinhardt , Dean M. Paxton , Vincent L. Sprenkle , K. Scott Weil , John E. Deibler , Paul E. George, II , Kurtis P. Recknagle
发明人： Karl J. Haltiner, Jr. , Subhasish Mukerjee , Lawrence A. Chick , Kerry D. Meinhardt , Dean M. Paxton , Vincent L. Sprenkle , K. Scott Weil , John E. Deibler , Paul E. George, II , Kurtis P. Recknagle
IPC分类号： H01M2/00 , H01M2/08
CPC分类号： H01M8/2425 , H01M8/0232 , H01M8/0247 , H01M8/0282 , H01M8/247 , H01M8/2483 , H01M2008/1293
摘要： A modular fuel cell cassette for use in assembling a fuel cell stack comprising a metal separator plate and a metal cell-mounting plate joined at their edges to form a hollow cassette. A fuel cell subassembly is attached to the mounting plate and extends through an opening in the mounting plate. The plates include openings to form chimney manifolds for supply and exhaust of fuel gas to the anode and air to the cathode. A conductive interconnect element extends from the fuel cell subassembly to make contact with the next cassette in a stack. The anode openings in the mounting plate and separator plate are separated by spacer rings such that the cassette is incompressible. A fuel cell stack comprises a plurality of cassettes, the mounting plate of one cassette being attached to, and insulated from, the separator plate of the next-adjacent cassette by a dielectric seal surrounding the interconnect.
摘要翻译：一种用于组装燃料电池堆的模块化燃料电池盒，包括金属隔板和在其边缘连接以形成中空盒的金属电池安装板。燃料电池子组件附接到安装板并延伸穿过安装板中的开口。这些板包括用于形成烟囱歧管的开口，用于将燃料气体供给和排出到阳极和空气到阴极。导电互连元件从燃料电池子组件延伸以与堆叠中的下一个盒体接触。安装板和隔离板中的阳极开口由间隔环分开，使得盒不可压缩。燃料电池堆包括多个盒，一个盒的安装板通过围绕互连的电介质密封件附接到下一相邻盒的隔板并与之隔绝。

6. 发明授权

US07270906B2 Solid-oxide fuel cell module for a fuel cell stack 失效
标题翻译：用于燃料电池堆的固体氧化物燃料电池模块
公开(公告)号：US07270906B2
公开(公告)日：2007-09-18
申请号：US10178809
申请日：2002-06-24
申请人： Karl J. Haltiner, Jr. , Haskell Simpkins , Subhasish Mukerjee
发明人： Karl J. Haltiner, Jr. , Haskell Simpkins , Subhasish Mukerjee
IPC分类号： H01M2/00 , H01M2/02 , H01M2/14
CPC分类号： H01M8/2425 , H01M8/0247 , H01M8/0273 , H01M8/242 , H01M8/2483
摘要： A fuel cell module having four sheet metal parts stamped from flat stock. The parts do not require any forming operations such as folding or dishing. Each part may have a different thickness to suit its function. The first part is a cell mounting frame for receiving and supporting a PEN fuel cell element. The second part is a cathode spacer, the thickness of the spacer determining the height of the cathode air flow field. The third part is an anode spacer, the thickness of spacer determining the height of the anode fuel flow field. The fourth part is a separator plate for separating the anode gas flow in one cell from the cathode air flow in an adjacent cell in a fuel cell stack. The four plates are joined by welding or brazing and may be assembled in any order or combination which suits the assembly process. Any desired number of modules may be stacked together to form a fuel cell stack.
摘要翻译：一种燃料电池组件，具有由扁平材料冲压的四个金属片。这些部件不需要任何成形操作，例如折叠或凹陷。每个部件可能具有不同的厚度以适应其功能。第一部分是用于接收和支撑PEN燃料电池元件的电池安装框架。第二部分是阴极间隔件，间隔物的厚度确定阴极气流场的高度。第三部分是阳极间隔物，间隔物的厚度决定阳极燃料流场的高度。第四部分是用于将一个电池中的阳极气体流与燃料电池堆中相邻电池中的阴极空气流分离的隔板。四个板通过焊接或钎焊连接，并且可以以适合组装过程的任何顺序或组合进行组装。可以将任何所需数量的模块堆叠在一起以形成燃料电池堆。

7. 发明申请

US20060147767A1 Trapping method and system for energy conversion devices 审中-公开
公开(公告)号：US20060147767A1
公开(公告)日：2006-07-06
申请号：US11371571
申请日：2006-03-09
申请人： Malcolm Grieve , Jeffrey Weissman , Subhasish Mukerjee
发明人： Malcolm Grieve , Jeffrey Weissman , Subhasish Mukerjee
IPC分类号： H01M8/06 , B01J19/00 , B01D24/48 , B01D29/60
CPC分类号： H01M8/0662 , H01M8/0612 , Y10T137/2519
摘要： A trap for an energy conversion device comprises a trapping system comprising a filter element and a trap element, and fluidly coupled to a reforming system. The trapping system is monitored by a combination of devices including an on-board diagnostic system, a temperature sensor, and a pressure differential sensor, which can individually or in combination determine when to regenerate the trapping system. The method for trapping sulfur and particulate matter using the trapping system comprises dispensing fuel into the energy conversion device. The fuel is processed in a reformer system to produce a reformate. The reformate is introduced into the trapping system and filtered to remove particulate matter and sulfur.

8. 发明申请

US20060024541A1 Solid-oxide fuel cell system having an upstream reformate combustor 有权
标题翻译：具有上游重整燃烧器的固体氧化物燃料电池系统
公开(公告)号：US20060024541A1
公开(公告)日：2006-02-02
申请号：US10909577
申请日：2004-08-02
申请人： Amanda Weiss , Subhasish Mukerjee , Karl Haltiner , Gregory Alexander
发明人： Amanda Weiss , Subhasish Mukerjee , Karl Haltiner , Gregory Alexander
IPC分类号： H01M8/04 , H01M8/06 , H01M8/12
CPC分类号： H01M8/0618 , C01B3/386 , C01B2203/0261 , C01B2203/066 , C01B2203/1288 , C01B2203/1604 , H01M8/04022 , H01M8/04134 , H01M2008/1293
摘要： A solid-oxide fuel cell system wherein a reformate combustor is disposed in the reformate flow path between a hydrocarbon reformer and a fuel cell stack. At system start-up, reformate is partially burned within the combustor by admitting combustion air, and the partially-burned reformate is passed through the anode chambers of the stack to warm the anodes. In addition, reformate is passed through a cathode-air heat exchanger to warm combustion air entering the cathode chambers of the stack. The combustor may continue to be supplied with a low level of air during steady-state operation of the SOFC, thereby providing a moist environment within the anode chambers to prevent coking of the anodes and providing additional heat to the reformate. The combustor decouples the reformer from the stack thermodynamically, permitting the reformer and the stack each to run in its own optimal temperature range.
摘要翻译：一种固体氧化物燃料电池系统，其中重整燃烧器设置在烃重整器和燃料电池堆之间的重整产品流路中。在系统启动时，通过加入燃烧空气在燃烧室内部分燃烧重整产物，部分燃烧的重整产物通过堆叠的阳极室，以加热阳极。此外，重整产物通过阴极 - 空气热交换器以加热进入堆叠的阴极室的燃烧空气。在SOFC的稳态操作期间，燃烧器可以继续供应低水平的空气，从而在阳极室内提供潮湿环境，以防止阳极焦化并向重整产品提供额外的热量。燃烧器使热重分离器与热堆动力学解耦，允许重整器和堆叠各自运行在其最佳温度范围内。

9. 发明申请

US20050153190A1 Fuel cell stack having foil interconnects and laminated spacers 审中-公开
标题翻译：具有箔互连和层压间隔物的燃料电池堆
公开(公告)号：US20050153190A1
公开(公告)日：2005-07-14
申请号：US10993856
申请日：2004-11-19
申请人： Diane England , Sean Kelly , Subhasish Mukerjee
发明人： Diane England , Sean Kelly , Subhasish Mukerjee
IPC分类号： F16J15/10 , H01M8/02 , H01M8/24 , H01M2/00 , H01M2/02 , H01M2/08
CPC分类号： H01M8/0208 , F16J15/102 , H01M8/021 , H01M8/0273 , H01M8/2425 , H01M8/2432 , H01M8/2484
摘要： Interconnects and perimeter spacers for a fuel cell stack are provided as flexible elements which can conform to non-planarities in a stack's electrolyte elements and thereby avoid inducing torsional stresses in the electrolyte elements. The interconnects are foil elements about 0.005 inches thick, formed of a superalloy such as Hastelloy, Haynes 230, or a stainless steel. The perimeter spacers comprise a plurality of laminate thin spacer elements, each thin spacer element being a laminate of superalloy and a “soft” material such as copper, nickel, or mica. The spacer elements can slide past one another; thus the perimeter spacers can be physically thick, to form the gas flow spaces within the stack, while also being torsionally flexible.
摘要翻译：提供了用于燃料电池堆的互连和周边间隔物作为柔性元件，其可以符合堆叠电解质元件中的非平面性，从而避免在电解质元件中引起扭转应力。这些互连件是约0.005英寸厚的箔元件，由诸如Hastelloy，Haynes 230或不锈钢的超级合金形成。周边间隔件包括多个层压薄的间隔元件，每个薄间隔元件是超合金和诸如铜，镍或云母的“软”材料的层压体。间隔元件可以彼此滑过; 因此周边间隔物可以物理上较厚，以在堆叠内形成气流空间，同时也具有挠性。

10. 发明授权

US07833674B2 Method for improving robustness of solid oxide fuel cell stacks 有权
标题翻译：改善固体氧化物燃料电池堆稳定性的方法
公开(公告)号：US07833674B2
公开(公告)日：2010-11-16
申请号：US12564324
申请日：2009-09-22
申请人： Subhasish Mukerjee , Karl J. Haltiner, Jr.
发明人： Subhasish Mukerjee , Karl J. Haltiner, Jr.
IPC分类号： H01M8/10 , H01M4/82
CPC分类号： H01M4/8892 , H01M4/8878 , H01M8/124 , H01M8/2404 , H01M8/2425 , H01M2004/8684 , H01M2008/1293 , Y02P70/56 , Y10T29/49115
摘要： A method for forming a solid oxide fuel cell stack from a plurality of individual solid oxide fuel cells, wherein the anodes of the solid oxide fuel cells are infiltrated by one or more materials for making the anodes less sensitive to sulfur poisoning and/or less subject to carbon degradation and/or for improving the electrochemical performance of the stack, the method comprising the steps of oxidizing the anodes of the individual solid oxide fuel cells before forming a stack, building a solid oxide fuel cell stack with all of the anodes in an oxidized state, reducing all of the anodes, and then infiltrating all of the anodes with at least one of the materials.
摘要翻译：一种从多个单独的固体氧化物燃料电池形成固体氧化物燃料电池堆的方法，其中固体氧化物燃料电池的阳极被一种或多种材料渗透，以使得阳极对硫中毒不太敏感和/或较少的主体碳降解和/或改善堆的电化学性能，该方法包括以下步骤：在形成堆叠之前氧化各固体氧化物燃料电池的阳极，与所有阳极建立固体氧化物燃料电池堆氧化态，还原所有阳极，然后用至少一种材料渗透所有的阳极。

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