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1. 发明授权

US6028219A Process for the nitration of diphenylethers 失效
标题翻译：硝基二苯醚的工艺
公开(公告)号：US6028219A
公开(公告)日：2000-02-22
申请号：US901545
申请日：1997-07-28
申请人： John Heathcote Atherton , Stephen Martin Brown , James Peter Muxworthy , Martin Lennon
发明人： John Heathcote Atherton , Stephen Martin Brown , James Peter Muxworthy , Martin Lennon
IPC分类号： C07B43/02 , C07C201/08 , C07C205/38 , C07C205/59 , C07C205/60 , C07C303/40 , C07C311/51 , C07C205/06
CPC分类号： C07C201/08 , C07C303/40
摘要： A process for the preparation of a compound of general formula I: ##STR1## wherein: R.sup.1 is hydrogen or C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 alkenyl or C.sub.2 -C.sub.6 alkynyl, any of which may optionally be substituted with one or more substituents selected from halogen and OH; or COOR.sup.4, COR.sup.6, CONR.sup.4 R.sup.5 or CONHSO.sub.2 R.sup.4 ;R.sup.4 and R.sup.5 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl optionally substituted with one or more halogen atoms;R.sup.6 is a halogen atom or a group R.sup.4 ;R.sup.2 is hydrogen or halo;R.sup.3 is C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl or C.sub.2 -C.sub.4 alkynyl, any of which may optionally be substituted with one or more halogen atoms; or halo;the process comprising reacting a compound of general formula II: ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are as defined for general formula I; with a nitrating agent comprising nitric acid or a mixture of nitric and sulphuric acids in the presence of an organic solvent and in the presence of acetic anhydride, characterized in that the molar ratio of acetic anhydride to compound of general formula II is from about 1:1 to 3:1.
摘要翻译：一种制备通式I化合物的方法：其中：R 1是氢或C 1 -C 6烷基，C 2 -C 6烯基或C 2 -C 6炔基，其中任何一个可以被一个或多个选自卤素和哦; 或COOR4，COR6，CONR4R5或CONHSO2R4; R 4和R 5各自独立地为氢或任选被一个或多个卤素原子取代的C 1 -C 4烷基; R6是卤素原子或基团R4; R2是氢或卤素; R 3是C 1 -C 4烷基，C 2 -C 4烯基或C 2 -C 4炔基，其中任何一个可以任选被一个或多个卤素原子取代; 或卤素; 所述方法包括使通式II的化合物：其中R 1，R 2和R 3如通式I所定义; 与硝酸和硝酸和硫酸的混合物在有机溶剂的存在下和在乙酸酐存在下的硝化剂，其特征在于乙酸酐与通式II的化合物的摩尔比为约1： 1到3：1。

2. 发明授权

US5952531A Nitration process 失效
标题翻译：硝化过程
公开(公告)号：US5952531A
公开(公告)日：1999-09-14
申请号：US960924
申请日：1997-10-30
申请人： Ian Jeffrey Grassham Priestley , James Peter Muxworthy , John Heathcote Atherton , Martin Lennon , Stephen Martin Brown
发明人： Ian Jeffrey Grassham Priestley , James Peter Muxworthy , John Heathcote Atherton , Martin Lennon , Stephen Martin Brown
IPC分类号： C07B43/02 , C07C201/08 , C07C205/38 , C07C205/59 , C07C231/12 , C07C235/44 , C07C303/40 , C07C311/51 , C07C43/00 , C07C29/00 , C07C205/00
CPC分类号： C07C303/40 , C07B43/02 , C07C201/08
摘要： A process for the nitration of an aromatic or heteroaromatic compound with a nitrating agent comprising nitric acid or a mixture of nitric and sulphuric acids, characterised in that nitration is performed in a solvent comprising at least 50% v/v of a C.sub.1 -C.sub.6 alkyl ester of a C.sub.1 -C.sub.4 carboxylic acid. The process is of particular use for the nitration of diphenyl ethers to give compounds which are useful as herbicides or as intermediates in the synthesis of herbicides.
摘要翻译：一种用包含硝酸或硝酸和硫酸的混合物的硝化剂硝化芳族或杂芳族化合物的方法，其特征在于，在包含至少50％v / v的C 1 -C 6烷基的溶剂中进行硝化酯的C 1 -C 4羧酸。该方法特别用于二苯醚的硝化，得到可用作除草剂的化合物或作为除草剂合成中的中间体。

3. 发明授权

US07772376B2 Manufacturing process 失效
标题翻译：制造过程
公开(公告)号：US07772376B2
公开(公告)日：2010-08-10
申请号：US11632839
申请日：2005-07-18
申请人： David Martin Payne , Douglas John Edwin Spencer , John Heathcote Atherton , Zachary Richard Meadows
发明人： David Martin Payne , Douglas John Edwin Spencer , John Heathcote Atherton , Zachary Richard Meadows
IPC分类号： C09B41/00
CPC分类号： C09B41/006 , B01F5/0413 , B01F5/0602 , B01F5/102 , B01F7/16 , B01J19/0086 , B01J19/2435 , B01J2219/00006 , B01J2219/0011 , B01J2219/00164 , C09B41/007 , Y10T137/0329 , Y10T137/2509
摘要： A process for the preparation of a desired chemical compound in a continuous reactor in which a part of the product stream exits the reactor and part of the product stream is recycled around the reactor in order to reduce the amount of buffer that would otherwise be required.
摘要翻译：在连续反应器中制备所需化学化合物的方法，其中产物流的一部分离开反应器和部分产物流在反应器周围循环，以便减少否则将需要的缓冲液的量。

4. 发明申请

US20090118478A1 Manufacturing Process 失效
标题翻译：制造工艺
公开(公告)号：US20090118478A1
公开(公告)日：2009-05-07
申请号：US11632839
申请日：2005-07-18
申请人： David Martin Payne , Douglas John Edwin Spencer , John Heathcote Atherton , Zachary Richard Meadows
发明人： David Martin Payne , Douglas John Edwin Spencer , John Heathcote Atherton , Zachary Richard Meadows
IPC分类号： C07C245/00
CPC分类号： C09B41/006 , B01F5/0413 , B01F5/0602 , B01F5/102 , B01F7/16 , B01J19/0086 , B01J19/2435 , B01J2219/00006 , B01J2219/0011 , B01J2219/00164 , C09B41/007 , Y10T137/0329 , Y10T137/2509
摘要： A process for the preparation of a desired chemical compound in a continuous reactor in which a part of the product stream exits the reactor and part of the product stream is recycled around the reactor in order to reduce the amount of buffer that would otherwise be required.
摘要翻译：在连续反应器中制备所需化学化合物的方法，其中产物流的一部分离开反应器和部分产物流在反应器周围循环，以便减少否则将需要的缓冲液的量。

5. 发明授权

US5679843A Process for the production of N-phosphonomethylalycine and salts thereof 失效
标题翻译：制备N-膦酰基甲基黄嘌呤及其盐的方法
公开(公告)号：US5679843A
公开(公告)日：1997-10-21
申请号：US556319
申请日：1995-11-13
申请人： Ian Hodgkinson , John Heathcote Atherton
发明人： Ian Hodgkinson , John Heathcote Atherton
IPC分类号： C07F9/38
CPC分类号： C07F9/3813
摘要： A process whereby N-phosphonomethylglycine (glyphosate) or its salts is manufactured by: 1) forming N-phosphonomethylglycinonitrile by reacting aminomethylphosphonic acid, an alkali metal cyanide and formaldehyde in aqueous solution at a pH in the range from 10 to 13 (and preferably from 11 to 11.5) whilst adding mineral acid at a rate sufficient to maintain the pH within the desired range, and thereafter 2) hydrolysing the N-phosphonomethylglycinonitrile product of Stage (1) to form a salt of N-phosphonomethylglycine and optionally 3) neutralising the salt of N-phosphonomethylglycine to form N-phosphonomethylglycine
摘要翻译：通过以下方法制造N-膦酰基甲基甘氨酸（草甘膦）或其盐的方法：1）通过使氨基甲基膦酸，碱金属氰化物和甲醛在水溶液中在10至13（优选从 11至11.5），同时以足以将pH保持在所需范围内的速率加入无机酸，然后2）水解阶段（1）的N-膦酰基甲基甘氨腈产物以形成N-膦酰基甲基甘氨酸的盐，并任选地3）中和 N-膦酰基甲基甘氨酸盐形成N-膦酰基甲基甘氨酸

6. 发明授权

US07138548B2 Process for the preparation of aryl hydrazone and aryl hydrazine 失效
标题翻译：芳基腙和芳基肼的制备方法
公开(公告)号：US07138548B2
公开(公告)日：2006-11-21
申请号：US10493503
申请日：2002-10-02
申请人： Andrew John Blacker , David Dodman , David Anthony Jackson , Jan Michael Fielden , John Heathcote Atherton
发明人： Andrew John Blacker , David Dodman , David Anthony Jackson , Jan Michael Fielden , John Heathcote Atherton
IPC分类号： C07C249/16 , C07C241/02
CPC分类号： C07C249/16 , C07C251/86
摘要： A process for the preparation of a compound of formula (I): wherein Ar represents an optionally substituted aromatic carbocycle or heterocycle, and R1 and R2 independently represent hydrogen, C1-10 alkyl, C(O)C1-10 alkyl or optionally substituted aryl provided that R1 and R2 are not both hydrogen which process comprises reacting together a compound of formula (II): Ar—X (II) wherein Ar is as defined in relation to formula (I) and X represents a leaving group with a a compound of formula (III) wherein R1 and R2 are as defined in relation to formula (I) under aqueous conditions in the presence of a Pd (II) salt, a ligand and a Group I or Group II metal hydroxide base at a pH greater than 7. Compounds of formula (I) may be hydrolysed to the corresponding hydrazine.
摘要翻译：制备式（I）化合物的方法：其中Ar表示任选取代的芳族碳环或杂环，R 1和R 2独立地表示氢，C C（O）C 1-10烷基或任选取代的芳基，条件是R 1和R 2可以相同或不同，（II）的化合物反应：式中，式（II）所示的化合物与式（II）化合物反应：＆lt;线内公式描述=“In-Line Formula”end =“lead”→Ar-X 其中Ar如关于式（I）所定义，X表示具有式（III）化合物的离去基团，其中R

7. 发明授权

US4036868A Nitrogen-containing compounds and use thereof 失效
标题翻译：含氮化合物及其用途
公开(公告)号：US4036868A
公开(公告)日：1977-07-19
申请号：US542048
申请日：1975-01-17
申请人： John Heathcote Atherton
发明人： John Heathcote Atherton
IPC分类号： C08G77/388 , C07F7/10 , C07F7/18
CPC分类号： C08G77/388
摘要： Nitrogen-containing organopolysiloxanes consisting of 0.18 to 14 mole percent of units of the formula (I): OSi(R).C.sub.d H.sub.2d CH.sub.2 N(R.sup.iv).Si(R)O, 0 to 0.1 mole percent of units of the formula (II): OSi(R)NHCH.sub.2 C(R'")=CH.sub.2 ; and 0 to 50 mole percent of units of the formula (III): OSi(R)C.sub.d H.sub.2d CH.sub.2 NH(R.sup.iv), the remaining units being R.sub.3 SiO.sub.1/2 or R.sub.e H.sub.f SiO.sub.4-e-f)/2, where R is a monovalent hydrocarbon group, R'" is hydrogen or methyl, R.sup.iv is hydrogen or alkyl having up to 6 carbon atoms, d is 2 or 3, e is 1 or 2, f is 0 or 1 and e + f is 2; and to organopolysiloxanes having the average general formula: ##STR1## WHERE R' is hydrogen, monovalent hydrocarbon or polyoxyalkylene of the formula (C.sub.n H.sub.2n O).sub.c R" wherein n is 2 or 3, R.sup.iv is hydrogen or alkyl having up to 6 carbon atoms, c is an integer of 1 to 30 and R" is hydrogen or monovalent hydrocarbon, r is a number from 0.1 to 5.0, s is a number from 1 to 4.99, t is a number from 0 to 500 and d is 2 or 3.
摘要翻译：由0.18至14摩尔％的式（I）单元组成的含氮有机聚硅氧烷：OSi（R）.CdH2dCH2N（Riv）.Si（O），0至0.1摩尔％的式（II）单元： OSi（NH）CH 2 C（R“'）= CH 2; 和0至50摩尔％的式（III）的单元：OSi（R）CdH2dCH2NH（Riv），其余单元为R3SiO1 / 2或ReHfSiO4-ef）/ 2，其中R为单价烃基，R“ '是氢或甲基，Riv是氢或具有至多6个碳原子的烷基，d是2或3，e是1或2，f是0或1，e + f是2; 和具有以下平均通式的有机聚硅氧烷：其中R'为氢，式（CnH2nO）cR“的一价烃或聚氧化烯，其中n为2或3，Riv为氢或具有至多6个碳原子的烷基， c为1〜30的整数，R“为氢或一价烃，r为0.1〜5.0的数，s为1〜4.99的数，t为0〜500的数，d为2或3 。

8. 发明授权

US4036807A Fluorine-containing organosilicon compounds 失效
标题翻译：含氟有机硅化合物
公开(公告)号：US4036807A
公开(公告)日：1977-07-19
申请号：US509026
申请日：1974-09-24
申请人： John Heathcote Atherton
发明人： John Heathcote Atherton
IPC分类号： C03C17/30 , C03C25/40 , C07F7/08 , C07F7/12 , C08K9/06
CPC分类号： C07F7/12 , C03C17/30 , C03C25/40 , C07F7/0856 , C08K9/06
摘要： Silanes and siloxanes having at least one group of the general formula ##STR1## WHERE R is a divalent group, R' is a monovalent hydrocarbon group, X is a hydrolyzable group, n is 8, 10 or 12, a is 0 or 1, m is 2, 3 or 4, b is 0, 1 or 2, c is 0, 1, 2 or 3 and b + c is not greater than 3, and uses thereof e.g. in surface treatment of glass fibres.
摘要翻译：具有至少一个通式为“R”是二价基团的硅烷和硅氧烷，R'是一价烃基，X是可水解基团，n是8,10或12，a是0或1， m为2,3或4，b为0,1或2，c为0,1,2或3，b + c为3以下，例如玻璃纤维的表面处理。

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