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1. 发明授权

US4296187A Integrated carbon/insulator structure and method for fabricating same 失效
标题翻译：集成碳/绝缘体结构及其制造方法
公开(公告)号：US4296187A
公开(公告)日：1981-10-20
申请号：US159266
申请日：1980-06-13
申请人： John E. Barnes , Franz Goebel , William T. McHugh
发明人： John E. Barnes , Franz Goebel , William T. McHugh
IPC分类号： H01M4/06 , H01M4/64 , H01M4/96 , H01M6/14
CPC分类号： H01M6/14 , H01M4/64 , H01M4/96
摘要： A thin, integrated carbon/insulator structure, and a method for fabricating same, for use in a primary electrochemical cell. A quantity of a wet carbon slurry material including a mixture of carbon black, water and/or isopropyl alcohol, and a binder such as finely-divided "Teflon" in suspension, is deposited onto a porous fiberglass substrate and rolled to a prescribed thickness. The rolling operation causes a portion of the slurry material to diffuse into the surface of the porous fiberglass substrate and permanently adhere to and unite with a surface portion of the fiberglass substrate in an integrated, interlocking fashion.The fiberglass substrate having the layer of carbon slurry material integrated therewith is then dried to cause the layer of carbon slurry material to dry and shrink to the form of a layer of carbon plaque having a network of cracks produced therethrough in a random pattern as a result of the shrinkage during drying. The layer of carbon plaque at this stage represents an aggregation of porous carbon globules. The layer of carbon plaque is re-rolled to close cracks at the upper surface of the layer while simultaneously establishing a desired thickness for the layer. After curing the above arrangement to increase adherence of the carbon globules to each other and to the fiberglass substrate, an integrated carbon/insulator structure of a desired size and configuration for use in a primary electrochemical cell can be cut out from the abovedescribed arrangement.
摘要翻译：薄的集成碳/绝缘体结构及其制造方法，用于初级电化学电池。将一定数量的包含炭黑，水和/或异丙醇的混合物的湿碳浆料和悬浮液中细碎的“特氟纶”的粘合剂沉积在多孔玻璃纤维基材上并轧制至规定的厚度。轧制操作导致一部分浆料材料扩散到多孔玻璃纤维基材的表面，并以一体化的互锁方式永久地粘合并与玻璃纤维基材的表面部分结合。然后将具有与其一体化的碳浆料材料层的玻璃纤维基材干燥以使碳浆料材料层干燥并收缩成具有随机图案产生的裂纹网络的碳斑块的形式，结果的干燥期间的收缩。该阶段的碳斑层表示多孔碳球的聚集体。碳层的层被重新卷起以在层的上表面处闭合裂纹，同时为该层确定所需的厚度。在固化上述布置以增加碳球彼此和玻璃纤维基材的粘附性之后，可以从上述布置中切出用于初级电化学电池的所需尺寸和构型的整体碳/绝缘体结构。

2. 发明授权

US4377033A Integrated carbon/insulator structure and method for fabricating same 失效
标题翻译：集成碳/绝缘体结构及其制造方法
公开(公告)号：US4377033A
公开(公告)日：1983-03-22
申请号：US251622
申请日：1981-04-06
申请人： John E. Barnes , Franz Goebel , William T. McHugh
发明人： John E. Barnes , Franz Goebel , William T. McHugh
IPC分类号： H01M4/64 , H01M4/96 , H01M6/14
CPC分类号： H01M4/64 , H01M4/96 , H01M6/14 , Y10T29/49108 , Y10T29/49115
摘要： A thin, integrated carbon/insulator structure, and a method for fabricating same, for use in a primary electrochemical cell. A quantity of a wet carbon slurry material including a mixture of carbon black, water and/or isopropyl alcohol, and a binder such as finely-divided "Teflon" in suspension, is deposited onto a porous fiberglass substrate and rolled to a prescribed thickness. The rolling operation causes a portion of the slurry material to diffuse into the surface of the porous fiberglass substrate and permanently adhere to and unite with a surface portion of the fiberglass substrate in an integrated, interlocking fashion. The fiberglass substrate having the layer of carbon slurry material integrated therewith is then dried to cause the layer of carbon slurry material to dry and shrink to the form of a layer of carbon plaque having a network of cracks produced therethrough in a random pattern as a result of the shrinkage during drying. The layer of carbon plaque at this stage represents an aggregation of porous carbon globules. The layer of carbon plaque is re-rolled to close cracks at the upper surface of the layer while simultaneously establishing a desired thickness for the layer. After curing the above arrangement to increase adherence of the carbon globules to each other and to the fiberglass substrate, an integrated carbon/insulator structure of a desired size and configuration for use in a primary electrochemical cell can be cut out from the abovedescribed arrangement.
摘要翻译：薄的集成碳/绝缘体结构及其制造方法，用于初级电化学电池。将一定数量的包含炭黑，水和/或异丙醇的混合物的湿碳浆料和悬浮液中细碎的“特氟纶”的粘合剂沉积在多孔玻璃纤维基材上并轧制至规定的厚度。轧制操作导致一部分浆料材料扩散到多孔玻璃纤维基材的表面，并以一体化的互锁方式永久地粘合并与玻璃纤维基材的表面部分结合。然后将具有与其一体化的碳浆料材料层的玻璃纤维基材干燥以使碳浆料材料层干燥并收缩成具有随机图案产生的裂纹网络的碳斑块的形式，结果的干燥期间的收缩。该阶段的碳斑层表示多孔碳球的聚集体。碳层的层被重新卷起以在层的上表面处闭合裂纹，同时为该层确定所需的厚度。在固化上述布置以增加碳球彼此和玻璃纤维基材的粘附性之后，可以从上述布置中切出用于初级电化学电池的所需尺寸和构型的整体碳/绝缘体结构。

3. 发明授权

US4615956A Method of treating lithium cells to reduce start-up delay time 失效
标题翻译：处理锂电池以减少启动延迟时间的方法
公开(公告)号：US4615956A
公开(公告)日：1986-10-07
申请号：US804561
申请日：1985-12-04
申请人： Franz Goebel , William T. McHugh
发明人： Franz Goebel , William T. McHugh
IPC分类号： H01M6/50 , H01M10/36 , H01M6/14
CPC分类号： H01M6/50
摘要： An electrochemical cell of the type having a lithium anode and a cathode current collector wetted by an electrolyte solution of thionyl chloride and lithium tetrachloroaluminate is treated before storage by applying a reverse current sufficient to deposit lithium on the surface of the anode.
摘要翻译：通过施加足以在阳极表面上沉积锂的反向电流，在储存之前处理具有由锂亚锡和四氯铝酸锂的电解液润湿的锂阳极和阴极集电器的电化学电池。

4. 发明授权

US4668592A Electrochemical cell having porous metal coupling members 失效
标题翻译：具有多孔金属耦合构件的电化学电池
公开(公告)号：US4668592A
公开(公告)日：1987-05-26
申请号：US743182
申请日：1985-06-10
申请人： Peter B. Harris , Franz Goebel , Gerard H. Boyle , William T. McHugh
发明人： Peter B. Harris , Franz Goebel , Gerard H. Boyle , William T. McHugh
IPC分类号： H01M2/26 , H01M6/14 , H01M10/04 , H01M6/32
CPC分类号： H01M10/0413 , H01M2/266 , H01M6/14
摘要： An electrochemical cell has a generally cylindrical battery stack comprised of disc-shaped components including alternating first polarity electrodes and second polarity electrodes. Adjacent first polarity electrodes are coupled by ring-shaped coupling members. The coupling members are made of porous metal which allows the passage of a liquid cell component from a central well into the battery stack.
摘要翻译：电化学电池具有由包括交替的第一极性电极和第二极性电极的盘形部件组成的大致圆柱形的电池堆叠。相邻的第一极性电极通过环形耦合构件耦合。联接构件由多孔金属制成，允许液体单元元件从中心孔通入电池组。

5. 发明授权

US4284691A Electrochemical cell 失效
标题翻译：电化学电池
公开(公告)号：US4284691A
公开(公告)日：1981-08-18
申请号：US159271
申请日：1980-06-13
申请人： Franz Goebel , William T. McHugh
发明人： Franz Goebel , William T. McHugh
IPC分类号： H01M4/64 , H01M6/12 , H01M6/14 , H01M6/46 , H01M2/26
CPC分类号： H01M4/64 , H01M6/12 , H01M6/14 , H01M6/46
摘要： A high-rate, low-temperature, primary electrochemical cell. The cell in accordance with the invention includes an elongated cylindrical metal housing within which a vertical array of battery stack components is disposed and exposed to a cathodelectrolyte solution. Each of the battery stack components has an opening therein through which an elongated metal rod located centrally within the housing passes and serves as an electrical terminal for the cell.The components of the battery stack include a plurality of thin, flat, circular, lithium anode discs secured to the metal rod, and a plurality of carbon current collector cathode/insulator structures arranged in the array in alternation with the lithium anode discs. Each of the carbon current collector cathode/insulator structures includes a generally circular, thin, metal current collector spaced from the metal rod by way of the opening therein and having a size and shape so as to generally conform to the interior configuration of the housing and make direct physical contact with an interior wall of the housing. First and second circular, flat, thin, porous carbon layers are disposed on opposite sides of the metal current collector and spaced from the metal rod by way of the openings therein. First and second circular, flat, porous fiberglass insulators integrated with the first and second porous carbon layers, respectively, are in direct physical contact with adjacent ones of the lithium anode discs and separate the porous carbon layers from the adjacent lithium anode discs.
摘要翻译：高速率，低温，初级电化学电池。根据本发明的电池包括细长的圆柱形金属外壳，其中电池堆组件的垂直阵列布置在其中并暴露于阴极电解液。每个电池堆组件具有开口，通过该开口，位于壳体中心的细长金属杆通过该开口，并且用作电池的电端子。电池堆的组件包括固定到金属棒的多个薄的平坦的圆形锂阳极盘，以及与锂阳极盘交替排列成阵列的多个碳集电极阴极/绝缘体结构。每个碳电集流体阴极/绝缘体结构包括大致圆形，薄的金属集流体，其通过其中的开口与金属棒间隔开，并具有尺寸和形状，以便大致符合壳体的内部结构，与外壳的内墙直接接触。第一和第二圆形，扁平，薄的多孔碳层设置在金属集流体的相对侧上，并通过其中的开口与金属棒间隔开。与第一和第二多孔碳层分别集成的第一和第二圆形，平坦，多孔的玻璃纤维绝缘体与相邻的锂阳极盘直接物理接触，并将多孔碳层与相邻的锂阳极盘分开。

6. 发明授权

US5227267A Disc electrode and busbar for an electrochemical battery 失效
标题翻译：盘式电极和母线用于电化学电池
公开(公告)号：US5227267A
公开(公告)日：1993-07-13
申请号：US607807
申请日：1990-11-01
申请人： Franz Goebel , David C. Batson , William T. McHugh
发明人： Franz Goebel , David C. Batson , William T. McHugh
IPC分类号： H01M2/26 , H01M4/70 , H01M4/74 , H01M6/14 , H01M10/04
CPC分类号： H01M10/0413 , H01M2/266 , H01M4/70 , H01M4/74 , H01M6/14
摘要： A high discharge rate electrochemical battery structure is disclosed as having a perforated disc electrode stack comprising pluralities of disc electrodes respectively connected to a pair of busbars. Each disc electrode has a tab with two fins which are bent at 90 degrees to the disc electrode. Each fin is inserted between two parts of the corresponding busbar and welded thereto. The design of the busbars and disc electrodes provides for redundancy of electrical contact, high thermal and electrical conductivity and improved resistance to mechanical shock.
摘要翻译：公开了一种高放电率电化学电池结构，其具有包括分别连接到一对母线的多个盘状电极的多孔盘电极堆叠。每个圆盘电极具有带有两个翅片的凸片，其与盘形电极成90度弯曲。每个翅片插入相应母线的两个部分并焊接到其上。母线和圆盘电极的设计提供了电接触的冗余性，高导热性和导电性，并提高了对机械冲击的抵抗力。

7. 发明授权

US4315060A Metal substrate for an electrochemical cell 失效
标题翻译：用于电化学电池的金属基底
公开(公告)号：US4315060A
公开(公告)日：1982-02-09
申请号：US159267
申请日：1980-06-13
申请人： Franz Goebel , William T. McHugh
发明人： Franz Goebel , William T. McHugh
IPC分类号： H01M2/22 , H01M2/26 , H01M4/70 , H01M6/14 , H01M6/46 , H01M6/00
CPC分类号： H01M6/46 , H01M4/70
摘要： A metal current collector substrate adapted to be inserted into an elongated cylindrical housing of a primary electrochemical cell. The metal current collector substrate is employed together with porous carbon and fiberglass separator elements to form a carbon current collector electrode/separator assembly for use in the electrochemical cell.The metal current collector substrate in accordance with the invention comprises a thin, circular, metal disc (e.g., of nickel) having a plurality of curved notches around its periphery. The notches are equally-spaced about the periphery of the disc (e.g., at 45.degree. intervals) and define a plurality of deflective, resilient arcuate portions intermediate to the notches. Prior to insertion into the housing of the cell, the disc is flat and has a diameter greater than the internal diameter of the housing. The disc is inserted into the housing by pushing the disc longitudinally into the housing whereupon the arcuate portions are deflected upwardly by physical contact with the interior wall of the housing. This deflection causes the arcuate portions to move toward each other and in turn to cause the disc to generally conform to the interior cross section of the housing. The arcuate portions following the deflection thereof are at acute angles with respect to the interior wall of the housing and make direct physical contact with the wall of the housing. In addition, due to the adjacency of the notches in the disc to the wall of the housing, a plurality of passageways are established between the disc and the interior wall of the housing.
摘要翻译：金属集电器基板，适于插入主电化学电池的细长圆柱形外壳中。金属集流体基板与多孔碳和玻璃纤维分离器元件一起使用以形成用于电化学电池的碳集电极电极/分离器组件。根据本发明的金属集电器基板包括薄的圆形金属盘（例如镍），其周围具有多个弯曲的凹口。凹口围绕圆周的周边等间隔（例如，以45°间隔），并且在凹口之间限定多个弯曲的，有弹性的弧形部分。在插入电池壳体之前，该盘是扁平的并且具有大于壳体内径的直径。通过将盘纵向推入壳体而将盘插入壳体中，由此弓形部分通过与壳体的内壁物理接触而向上偏转。这种偏转导致弓形部分朝向彼此移动，并且继而导致盘基本上符合壳体的内部横截面。其偏转之后的弓形部分相对于壳体的内壁呈锐角，并与壳体的壁直接物理接触。此外，由于盘中的凹口与壳体的壁相邻，在盘和壳体的内壁之间建立了多个通道。

8. 发明授权

US5158843A Small particle thin electrochemical electrode and method 失效
标题翻译：小粒子薄电化学电极及方法
公开(公告)号：US5158843A
公开(公告)日：1992-10-27
申请号：US548455
申请日：1990-07-02
申请人： David C. Batson , Franz Goebel , Peter B. Harris , Peter F. Morello
发明人： David C. Batson , Franz Goebel , Peter B. Harris , Peter F. Morello
IPC分类号： H01M4/04 , H01M4/96 , H01M6/14
CPC分类号： H01M4/0419 , H01M4/04 , H01M4/0402 , H01M4/0404 , H01M4/0471 , H01M4/96 , H01M6/14
摘要： An electrochemical cell electrode such as the cathode element for a high energy density battery cell and its fabrication sequence are disclosed. Material such as finely-divided carbon particles is dispersed over the electrode surface during an ultrasonic energy assisted wet spraying process which produces very thin electrodes that are also low in fabrication cost and increased in uniformity and energy density capability. Fine particle material deposition on both a metal foil electrode and on an insulating member that is later joined to a metal foil electrode are contemplated.
摘要翻译：公开了一种电化学电池电极，例如用于高能量密度电池单元的阴极元件及其制造顺序。在超声波能量辅助湿式喷涂工艺中，诸如细碎碳颗粒的材料分散在电极表面上，其产生制造成本低且均匀性和能量密度能力增加的非常薄的电极。考虑在金属箔电极和后面与金属箔电极接合的绝缘构件上沉积细粒子。

9. 发明授权

US4765798A Method of adding electrolyte to electrochemical cells 失效
标题翻译：向电化学电池中添加电解质的方法
公开(公告)号：US4765798A
公开(公告)日：1988-08-23
申请号：US110751
申请日：1987-10-20
申请人： David C. Batson , Ronald E. Barth , Franz Goebel , Peter B. Harris
发明人： David C. Batson , Ronald E. Barth , Franz Goebel , Peter B. Harris
IPC分类号： H01M2/36 , H01M6/14 , H01M6/00 , H01M10/50
CPC分类号： H01M6/14 , H01M2/361 , Y10T29/49108 , Y10T29/49115
摘要： A liquid electrolyte solution is added to porous components of an electrochemical cell prior to assembly. The electrolyte solution is frozen and all the components are assembled into a sealed cell. The electrolyte solution is then allowed to melt.
摘要翻译：在组装之前，将电解质溶液加入到电化学电池的多孔组分中。将电解液冷冻并将所有组分组装成密封的电池。然后使电解质溶液熔化。

10. 发明授权

US4565753A Electrochemical cell having wound electrode structures 失效
标题翻译：具有缠绕电极结构的电化学电池
公开(公告)号：US4565753A
公开(公告)日：1986-01-21
申请号：US719833
申请日：1985-04-03
申请人： Franz Goebel , David C. Batson , Timothy B. Haskins
发明人： Franz Goebel , David C. Batson , Timothy B. Haskins
IPC分类号： H01M10/04 , H01M4/02 , H01M4/04 , H01M6/10 , H01M6/14 , H01M6/16
CPC分类号： H01M6/14 , H01M6/10
摘要： A type of electrochemical cell has two electrode structure elements wound in a coil and inserted in a sealed can. The electrode structures are separated by a porous insulating sheet. One electrode structure has a metal substrate carrying a plurality of holes. The metal substrate supports layers of an electrode material such as porous carbon. Both edges and one end of the substrate is kept free of the material. The bare end of the substrate is on the outside of the coil. The substrate and porous insulating sheets are wider than the other electrode structures, so that when the coil is inserted in the can, the substrate and the porous insulating sheet makes contact with the top and bottom internal surfaces of the can.
摘要翻译：一种电化学电池具有缠绕在线圈中并插入密封罐中的两个电极结构元件。电极结构被多孔绝缘片隔开。一个电极结构具有承载多个孔的金属基板。金属基板支撑多孔碳等电极材料层。衬底的两个边缘和一个端部保持没有材料。基板的裸露端在线圈的外侧。基板和多孔绝缘片比其他电极结构宽，使得当线圈插入罐中时，基板和多孔绝缘片与罐的顶部和底部内表面接触。

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