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    • 6. 发明授权
    • Process for the hydroformylation of sulfur-containing thermally cracked
petroleum residue and novel products thereof
    • 含硫热裂解石油残渣加氢甲酰化的方法及其新产物
    • US5030774A
    • 1991-07-09
    • US461137
    • 1990-01-04
    • Alexis A. OswaldRam N. BhatiaEdmund J. MozeleskiAlexandr P. GlivickyBarry G. BrueggemanJohn R. HootonCharles M. SmithChang S. Hsu
    • Alexis A. OswaldRam N. BhatiaEdmund J. MozeleskiAlexandr P. GlivickyBarry G. BrueggemanJohn R. HootonCharles M. SmithChang S. Hsu
    • C07C29/16C07C45/50
    • C07C29/16C07C45/50
    • A catalytic process for the hydroformylation of olefinic, sulfur containing thermally cracked petroleum streams to produce aldehydes and/or alcohols is disclosed. The catalysts are homogeneous transition metal carbonyl complexes. Especially preferred catalysts for low and medium pressure hydroformylation are cobalt and rhodium carbonyl hydride complexes in which some of the carbonyl ligands have been replaced by trivalent phosphorus ligands. In a preferred high pressure hydroformylation, the sulfur-containing naphtha and gas oil distillate feeds are proudced from vacuum residue by high temperature thermal cracking. Such feeds contain more than 20% olefins with 1-n-olefins as the single major types. These olefin components are hydroformylated in the presence of a cobalt cabonyl complex to produce a novel type of semilinear aldehyde and/or alcohol product containing an average of less than one alkyl branch per molecule. The alcohols are converted to dialkyl phthalates and other esters having a unique balance of plasticizer properties. They are also useful for producing novel surfactants, particularly ethoxylated derivatives.For the preparation of products containing minimal concentrations of sulfur compounds, narrow distillate fractions of thermally cracked residua are preferred. In the C.sub.6 to C.sub.11 carbon range, single carbon fractions of sharply reduced aromatic hydrocarbon and thiophenic sulfur content can be obtained. These fractions of increased linear olefin content can be advantageously used as hydroformylation feeds in the derivation of low sulfur containing alcohols and related products of increased linearity.
    • 公开了一种用于烯烃,含硫热裂解石油气流加氢甲酰化以产生醛和/或醇的催化方法。 催化剂是均匀的过渡金属羰基络合物。 用于低和中压加氢甲酰化的特别优选的催化剂是钴和铑羰基氢化物络合物,其中一些羰基配体已被三价磷配体取代。 在优选的高压加氢甲酰化中,含硫石脑油和粗柴油馏出物通过高温热裂解从真空残渣中骄傲。 这样的进料含有超过20%的烯烃,其中1-正烯烃作为单一主要类型。 这些烯烃组分在钴内酰胺基配合物的存在下被加氢甲酰化,以产生每分子平均含有小于一个烷基支链的新型的半线性醛和/或醇产物。 醇被转化为邻苯二甲酸二烷基酯和具有独特平衡的增塑剂性质的其它酯。 它们也可用于生产新型表面活性剂,特别是乙氧基化衍生物。 对于含有最少浓度的硫化合物的产品的制备,优选热裂化残渣的窄馏分馏分。 在C6至C11碳范围内,可以获得芳香烃锐减的单碳馏分和噻吩硫含量。 增加的线性烯烃含量的这些馏分可以有利地用作促进含低级含硫醇和增加线性的相关产物的加氢甲酰化进料。
    • 7. 发明授权
    • Apparatus for mechanically extracting fish roe
    • 用于机械提取鱼籽的设备
    • US4332057A
    • 1982-06-01
    • US161372
    • 1980-06-20
    • Charles M. Smith
    • Charles M. Smith
    • A22C25/00
    • A22C25/00
    • An apparatus for mechanically extracting fish roe utilized in conjunction with a continuous operation to butcher and clean fish, especially salmon. After head removal, each fish traverses along a V-shaped trough, tail first and belly up, through side compressing (but resilient) rollers, vertically disposed, forcing the roe sack out of the fish body through the opening provided by the head removal. The trough has a lower opening strategically located relative to the rollers to allow the fish roe to drop by gravity to a collecting receptacle.
    • 一种用于机械提取鱼卵的设备,连同连续操作一起进行屠宰和清洁鱼类,特别是鲑鱼。 在头部移除后,每条鱼通过垂直设置的侧压缩(但是弹性的)滚子沿着V形槽,尾巴首先和腹部向上穿过,通过头部移除提供的开口迫使獐鹿袋离开鱼体。 槽具有相对于辊的策略性位置的下开口,以允许鱼卵通过重力下降到收集容器。
    • 9. 发明申请
    • AUTOMATED SYSTEM AND METHOD FOR DELIVERY OF MESSAGES AND PROCESSING OF MESSAGE RESPONSES
    • 自动化系统和方法,用于传递消息和处理消息响应
    • US20110289170A1
    • 2011-11-24
    • US13165539
    • 2011-06-21
    • Charles M. SmithHarold D. St. Clair
    • Charles M. SmithHarold D. St. Clair
    • G06F15/16
    • G06Q10/107H04L51/063H04L51/066H04L51/24H04L51/36
    • An automated system for delivery of messages to multiple recipients, and for processing of responses to the messages, includes a message client, message server, and a system database. A message is created using a universal message form. The message content can be translated into multiple formats and sent to one or more different recipients using one or more different types of messaging devices, including pagers, e-mail readers, telephones, cellular telephones, personal computers, fax machines, and voice mail systems. A recipient profile manager allows each recipient to select the messaging devices to be used for message delivery as well as preferred messaging schedules, priorities, and message security. Receipt of the messages by the recipients is verified, response requirements collected and consolidated from multiple sources and presented to the message originator in a structured format.
    • 用于将消息传递到多个接收者以及处理对消息的响应的自动化系统包括消息客户端,消息服务器和系统数据库。 使用通用消息表单创建消息。 消息内容可以被翻译成多种格式,并且使用一种或多种不同类型的消息传送设备(包括寻呼机,电子邮件阅读器,电话,蜂窝电话,个人计算机,传真机和语音邮件系统)被发送到一个或多个不同的接收者 。 收件人简档管理器允许每个收件人选择要用于消息传递的消息传递设备以及首选消息传递计划,优先级和消息安全性。 对收件人收到的邮件进行验证,从多个来源收集和合并响应要求,并以结构化格式呈现给邮件发起者。
    • 10. 发明授权
    • Automated system and method for delivery of messages and processing of message responses
    • 用于传送消息和处理消息响应的自动系统和方法
    • US07966373B1
    • 2011-06-21
    • US10155836
    • 2002-05-24
    • Charles M. SmithHarold D. St. Clair
    • Charles M. SmithHarold D. St. Clair
    • G06F15/16
    • G06Q10/107H04L51/063H04L51/066H04L51/24H04L51/36
    • An automated system for delivery of messages to multiple recipients, and for processing of responses to the messages, includes a message client, message server, and system database. A message is created using a universal message form. The message content can be translated into multiple formats and sent to one or more different recipients using one or more different types of messaging devices, including pagers, telephones, fax machines, and e-mail readers. A recipient profile manager allows each recipient to select the messaging devices to be used for message delivery as well as preferred messaging schedules, priorities, and message security. Receipt of the messages by the recipients is verified, response requirements collected and consolidated from multiple sources and presented to the message originator in a structured format.
    • 用于将消息传递到多个收件人以及处理对消息的响应的自动化系统包括消息客户端,消息服务器和系统数据库。 使用通用消息表单创建消息。 消息内容可以被翻译成多种格式,并使用一种或多种不同类型的消息传送设备(包括寻呼机,电话,传真机和电子邮件阅读器)发送到一个或多个不同的接收者。 收件人简档管理器允许每个收件人选择要用于消息传递的消息传递设备以及首选消息传递计划,优先级和消息安全性。 对收件人收到的邮件进行验证,从多个来源收集和合并响应要求,并以结构化格式呈现给邮件发起者。