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    • 1. 发明授权
    • Toners and developers containing bis(ammonium) tetrahalomanganate salts
as charge-control agents
    • 含有双(铵)四卤代锰酸盐的调色剂和显影剂作为电荷控制剂
    • US5582946A
    • 1996-12-10
    • US350592
    • 1994-12-07
    • John C. WilsonDinesh Tyagi
    • John C. WilsonDinesh Tyagi
    • G03G9/097
    • G03G9/09741G03G9/0975G03G9/09783
    • New electrostatographic toners and developers are provided containing charge-control agents comprising bis(ammonium) tetrahalomanganate salts having the structure: ##STR1## wherein R, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto-, or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto-, or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; or wherein any two or more of R, R.sup.1, R.sup.2, or R.sup.3 can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, andX, which can be the same or different, is selected from fluorine, chlorine, Bromine or iodine.
    • 提供了新的静电色调剂和显影剂,其含有电荷控制剂,其包含具有以下结构的双(铵)四卤代高锰酸盐:其中R,R 1,R 2和R 3相同或不同并且独立地选自氢; 具有1至24个碳原子的未取代的烷基; 具有1至24个碳原子的取代的烷基被一个或多个羟基,羧基,烷氧基,烷氧基,酰氧基,硝基,氰基,酮基或卤代基取代; 具有3至7个碳原子的环烷基; 具有6至14个碳原子的未取代的芳基; 被一个或多个羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基取代的具有6至14个碳原子的取代芳基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基团; 或其中R,R 1,R 2或R 3中的任何两个或更多个可以彼此互连以形成5至14元饱和或不饱和的环系,并且可以相同或不同的X选自氟, 氯,溴或碘。
    • 2. 发明授权
    • Bis(quaternary phosphonium) tetrahalomanganate salts as charge-control
agents
    • 双(季鏻)四卤代马来酸盐作为电荷控制剂
    • US5512407A
    • 1996-04-30
    • US350790
    • 1994-12-07
    • John C. WilsonDinesh Tyagi
    • John C. WilsonDinesh Tyagi
    • G03G9/097
    • G03G9/09766G03G9/09741G03G9/0975G03G9/09783
    • New electrostatographic toners and developers are provided containing charge-control agents comprising bis(quaternary phosphonium) tetrahalomanganate salts having the structure: ##STR1## wherein R is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; phenyl or substituted phenyl;R.sup.1, R.sup.2 and R.sup.3, which can be the same or different, are independently selected from hydrogen; an alkyl group having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy-; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-groups; andX, which can be the same or different, is independently selected from fluorine, chlorine, bromine or iodine.
    • 提供了新的静电彩色调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的双(季鏻)四卤代高锰酸盐:其中R选自未取代的具有1至24个碳原子的烷基; 具有1至24个碳原子的取代的烷基被一个或多个羟基,羧基,烷氧基 - ,烷酰氧基 - ,酰氧基 - ,硝基 - ,氰基 - ,酮基或卤代基取代; 具有3至7个碳原子的环烷基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基团; 苯基或取代的苯基; R 1,R 2和R 3可以相同或不同,独立地选自氢; 具有1至24个碳原子的烷基; 羟基 - 羧基 烷氧基 碳烷氧基 酰氧基 - 氨基 - 硝基 氰基 酮基 或卤代基团; 和X可以相同或不同,独立地选自氟,氯,溴或碘。
    • 4. 发明授权
    • Toners and developers containing ammonium tetrahaloferrate salts as
charge-control agents
    • 含有四卤代钒酸盐作为电荷控制剂的调色剂和显影剂
    • US5464719A
    • 1995-11-07
    • US350598
    • 1994-12-07
    • John C. WilsonDinesh Tyagi
    • John C. WilsonDinesh Tyagi
    • G03G9/083G03G9/097
    • G03G9/09783G03G9/09741G03G9/0975G03G9/09758
    • New electrostatographic toners and developers are provided containing charge-control agents comprising ammonium tetrahaloferrate salts having the structure: ##STR1## wherein R, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; or wherein any two or more of R, R.sup.1, R.sup.2, or R.sup.3 can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, andX, which can be the same or different, is selected from fluorine, chlorine, bromine or iodine.
    • 提供了新的静电调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的四卤代钒酸盐:其中R,R 1,R 2和R 3相同或不同并且独立地选自氢; 具有1至24个碳原子的未取代的烷基; 被一个或多个羟基,羧基,烷氧基,烷氧基,酰氧基,硝基,氰基,酮基或卤代基取代的碳原子数1〜24的取代烷基。 具有3至7个碳原子的环烷基; 具有6至14个碳原子的未取代的芳基; 被一个或多个羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基取代的具有6至14个碳原子的取代的芳基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基团; 或其中R,R 1,R 2或R 3中的任何两个或更多个可以彼此互连以形成5至14元饱和或不饱和的环系,并且可以相同或不同的X选自氟, 氯,溴或碘。
    • 5. 发明授权
    • Quaternary phosphonium tetrahaloferrate salts as charge-control agents
for toners
    • 四卤代四氢鏻盐作为调色剂的电荷控制剂
    • US5459006A
    • 1995-10-17
    • US350564
    • 1994-12-07
    • John C. WilsonDinesh Tyagi
    • John C. WilsonDinesh Tyagi
    • A62D101/24G03G9/097
    • G03G9/09741A62D2101/24
    • New electrostatographic toners and developers are provided containing charge-control agents comprising quaternary phosphonium tetrahaloferrate salts having the structure: ##STR1## wherein R is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; phenyl or substituted phenyl;R.sup.1, R.sup.2 and R.sup.3, which can be the same or different, are independently selected from hydrogen; an alkyl group having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy-; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-groups; andX, which can be the same or different, is independently selected from fluorine, chlorine, bromine or iodine.
    • 提供了新的静电调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的四卤代钒酸盐:其中R选自未取代的具有1至24个碳原子的烷基; 具有1至24个碳原子的取代的烷基被一个或多个羟基,羧基,烷氧基 - ,烷酰氧基 - ,酰氧基 - ,硝基 - ,氰基 - ,酮基或卤代基取代; 具有3至7个碳原子的环烷基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基团; 苯基或取代的苯基; R 1,R 2和R 3可以相同或不同,独立地选自氢; 具有1至24个碳原子的烷基; 羟基 - 羧基 烷氧基 碳烷氧基 酰氧基 - 氨基 - 硝基 氰基 酮基 或卤代基团; 和X可以相同或不同,独立地选自氟,氯,溴或碘。
    • 8. 发明授权
    • Toners and developers containing ammonium trihalozincates as
charge-control agents
    • 含有三卤代三甲酸铵的调色剂和显影剂作为电荷控制剂
    • US5604069A
    • 1997-02-18
    • US350772
    • 1994-12-07
    • John C. WilsonDinesh Tyagi
    • John C. WilsonDinesh Tyagi
    • G03G9/097G03G9/08
    • G03G9/09741G03G9/09783
    • New electrostatographic toners and developers are provided containing charge-control agents comprising ammonium trihalozincate salts having the structure: ##STR1## wherein R, R.sup.1, R.sup.2 and R.sup.3 are the same or different and are independently selected from hydrogen; an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an unsubstituted aryl group having from 6 to 14 carbon atoms; a substituted aryl group having from 6 to 14 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; or wherein any two or more of R, R.sup.1, R.sup.2, or R.sup.3 can be interconnected to one another to form a 5 to 14 membered saturated or unsaturated ring system, andX, which can be the same or different, is selected from fluorine, chlorine, bromine or iodine.
    • 提供了新的静电彩色调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的三卤代酸铵盐:其中R,R 1,R 2和R 3相同或不同并且独立地选自氢; 具有1至24个碳原子的未取代的烷基; 被一个或多个羟基,羧基,烷氧基,烷氧基,酰氧基,硝基,氰基,酮基或卤代基取代的碳原子数1〜24的取代烷基。 具有3至7个碳原子的环烷基; 具有6至14个碳原子的未取代的芳基; 被一个或多个羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基取代的具有6至14个碳原子的取代的芳基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基团; 或其中R,R 1,R 2或R 3中的任何两个或更多个可以彼此互连以形成5至14元饱和或不饱和的环系,并且可以相同或不同的X选自氟, 氯,溴或碘。
    • 9. 发明授权
    • Toners and developers containing quaternary phosphonium
3,5-Di-tertiary-alkyl-4-hydroxybenzenesulfonates as charge-control
agents
    • 含有3,5-二叔烷基-4-羟基苯磺酸季鏻作为电荷控制剂的调色剂和显影剂
    • US5508140A
    • 1996-04-16
    • US361068
    • 1994-12-21
    • John C. WilsonDinesh Tyagi
    • John C. WilsonDinesh Tyagi
    • G03G9/097G03G9/00
    • G03G9/0975G03G9/09741
    • New electrostatographic toners and developers are provided containing charge-control agents comprising quaternary phosphonium salts having the structure: ##STR1## wherein R.sup.1 and R.sup.2 are tertiary-alkyl containing from 4 to 8 carbon atoms; R.sup.3 is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group may be unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; phenyl or substituted phenyl; andR.sup.4, R.sup.5 and R.sup.6, which can be the same or different, are independently selected from hydrogen; an alkyl group having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy-; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-groups.
    • 提供了新的静电调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的季鏻盐:其中R 1和R 2为含有4至8个碳原子的叔烷基; R3选自未取代的具有1至24个碳原子的烷基; 具有1至24个碳原子的取代的烷基被一个或多个羟基,羧基,烷氧基 - ,烷酰氧基 - ,酰氧基 - ,硝基 - ,氰基 - ,酮基或卤代基取代; 具有3至7个碳原子的环烷基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子的芳烷基和在芳基中具有6至14个碳原子的芳烷基,其中芳基可以是未被取代的或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基团; 苯基或取代的苯基; 和可以相同或不同的R 4,R 5和R 6独立地选自氢; 具有1至24个碳原子的烷基; 羟基 - 羧基 烷氧基 碳烷氧基 酰氧基 - 氨基 - 硝基 氰基 酮基 或卤代基团。
    • 10. 发明授权
    • Quaternary phosphonium trihalozincate salts as charge-control agents for
toners and developers
    • 季铵盐三卤代盐作为调色剂和显影剂的电荷控制剂
    • US5561020A
    • 1996-10-01
    • US350775
    • 1994-12-07
    • John C. WilsonDinesh Tyagi
    • John C. WilsonDinesh Tyagi
    • G03G9/097
    • G03G9/09775G03G9/09741G03G9/0975G03G9/09783
    • New electrostatographic toners and developers are provided containing charge-control agents comprising quaternary phosphonium trihalozincate salts having the structure: ##STR1## wherein R is selected from an unsubstituted alkyl group having from 1 to 24 carbon atoms; a substituted alkyl group having from 1 to 24 carbon atoms substituted with one or more hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, nitro-, cyano-, keto- or halo-groups; a cycloalkyl group having from 3 to 7 carbon atoms; an alkaryl group having from 1 to 20 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group; an aralkyl group having from 1 to 4 carbon atoms in the alkyl group and 6 to 14 carbon atoms in the aryl group wherein the aryl group is unsubstituted or substituted with one or more alkyl-, hydroxy-, carboxy-, alkoxy-, carboalkoxy-, acyloxy-, amino-, nitro-, cyano-, keto- or halo-groups; phenyl or substituted phenyl;R.sup.1, R.sup.2 and R.sup.3, which can be the same or different, are independently selected from hydrogen; an alkyl group having from 1 to 24 carbon atoms; hydroxy-; carboxy-; alkoxy-; carboalkoxy-; acyloxy-; amino-; nitro-; cyano-; keto-; or halo-groups; andX, which can be the same or different, is independently selected from fluorine, chlorine, bromine or iodine.
    • 提供了新的静电调色剂和显影剂,其含有电荷控制剂,其包含具有以下结构的季铵鏻三卤代酸盐:其中R选自未取代的具有1至24个碳原子的烷基; 被一个或多个羟基,羧基,烷氧基,烷氧基,酰氧基,硝基,氰基,酮基或卤代基取代的碳原子数1〜24的取代烷基。 具有3至7个碳原子的环烷基; 烷基中具有1至20个碳原子并且芳基中具有6至14个碳原子的烷芳基; 在烷基中具有1至4个碳原子且在芳基中具有6至14个碳原子的芳烷基,其中芳基未被取代或被一个或多个烷基,羟基,羧基,烷氧基 - ,烷氧基 - ,酰氧基 - ,氨基 - ,硝基 - ,氰基 - ,酮基或卤代基; 苯基或取代的苯基; R 1,R 2和R 3可以相同或不同,独立地选自氢; 具有1至24个碳原子的烷基; 羟基 - 羧基 烷氧基 碳烷氧基 酰氧基 - 氨基 - 硝基 氰基 酮基 或卤代基团; 和X可以相同或不同,独立地选自氟,氯,溴或碘。