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    • 7. 发明申请
    • POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS
    • 可聚合光敏剂和辐射可固化组合物
    • US20110224324A1
    • 2011-09-15
    • US13129413
    • 2009-12-01
    • Johan LoccufierLuc Van MaeleJaymes Van LuppenRoland Claes
    • Johan LoccufierLuc Van MaeleJaymes Van LuppenRoland Claes
    • C08F2/46C07C69/587C07C69/602C07C69/734
    • C07D335/16C07C69/54C07C233/20C07C235/08C07C323/12C07C2601/14C07C2602/42C07D209/86C07D295/108G03F7/027G03F7/031
    • A polymerizable photoinitiator is represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w=1 to (p−z) and z=0 to (p−w); L represents an optionally substituted (p+y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation.
    • 可聚合的光引发剂由式(I)表示:其中R 1,R 2和R 3独立地选自氢,任选取代的烷基和任选取代的芳基,或者R 1和R 3表示必要的原子以形成 五至八元环; p,w,y和z都是整数,y代表值1到6; p表示w和z的和; p代表1到6的值; w = 1〜(p-z),z = 0〜(p-w) L表示含有1至14个碳原子的任选取代的(p + y)价连接基团; A表示选自丙烯酸酯基,甲基丙烯酸酯基,苯乙烯基,丙烯酰胺基,甲基丙烯酰胺基,马来酸酯基,富马酸酯基,衣康酸酯基,乙烯基醚基中的自由基聚合性基团 烯丙基醚基,烯丙基酯基和乙烯基酯基; 并且X表示光引发部分,其包含至少一个能够在暴露于光化辐射时引发自由基聚合反应的基团。
    • 9. 发明授权
    • Polymerizable photoinitiators and radiation curable compositions
    • 可聚合光引发剂和可辐射固化组合物
    • US08492452B2
    • 2013-07-23
    • US13129413
    • 2009-12-01
    • Johan LoccufierLuc Van MaeleJaymes Van LuppenRoland Claes
    • Johan LoccufierLuc Van MaeleJaymes Van LuppenRoland Claes
    • C08F2/50C08J3/28
    • C07D335/16C07C69/54C07C233/20C07C235/08C07C323/12C07C2601/14C07C2602/42C07D209/86C07D295/108G03F7/027G03F7/031
    • A polymerizable photoinitiator is represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w=1 to (p−z) and z=0 to (p−w); L represents an optionally substituted (p+y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation.
    • 可聚合的光引发剂由式(I)表示:其中R 1,R 2和R 3独立地选自氢,任选取代的烷基和任选取代的芳基,或者R 1和R 3表示必要的原子以形成 五至八元环; p,w,y和z都是整数,y代表值1到6; p表示w和z的和; p代表1到6的值; w = 1〜(p-z),z = 0〜(p-w) L表示含有1至14个碳原子的任选取代的(p + y)价连接基团; A表示选自丙烯酸酯基,甲基丙烯酸酯基,苯乙烯基,丙烯酰胺基,甲基丙烯酰胺基,马来酸酯基,富马酸酯基,衣康酸酯基,乙烯基醚基中的自由基聚合性基团 烯丙基醚基,烯丙基酯基和乙烯基酯基; 并且X表示光引发部分,其包含至少一个能够在暴露于光化辐射时引发自由基聚合反应的基团。