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    • 1. 发明授权
    • Method of making a silicon-containing film
    • 制造含硅膜的方法
    • US08603426B1
    • 2013-12-10
    • US13730432
    • 2012-12-28
    • Klaus KunzeWenzhuo GuoFabio ZürcherMao TakashimaLaila FranciscoJoerg RockenbergerBrent Ridley
    • Klaus KunzeWenzhuo GuoFabio ZürcherMao TakashimaLaila FranciscoJoerg RockenbergerBrent Ridley
    • C01B21/068
    • C01B6/00C01B6/003C01B6/34
    • A method of making hydrogenated Group IVA compounds having reduced metal-based impurities, compositions and inks including such Group IVA compounds, and methods for forming a semiconductor thin film. Thin semiconducting films prepared according to the present invention generally exhibit improved conductivity, film morphology and/or carrier mobility relative to an otherwise identical structure made by an identical process, but without the washing step. In addition, the properties of the present thin film are generally more predictable than those of films produced from similarly prepared (cyclo)silanes that have not been washed according to the present invention. The present invention advantageously provides semiconducting thin film structures having qualities suitable for use in electronics applications, such as display devices or RF ID tags, while enabling high-throughput manufacturing processes that form such thin films in seconds or minutes, rather than hours or days as with conventional photolithographic processes.
    • 制备具有还原的金属基杂质的氢化IVA族化合物的方法,包括这种IVA族化合物的组合物和油墨以及形成半导体薄膜的方法。 根据本发明制备的薄半导体膜通常相对于通过相同方法制备但不具有洗涤步骤的其它相同结构显示改进的导电性,膜形态和/或载流子迁移率。 此外,本发明的薄膜的性质通常比从根据本发明未被洗涤的类似制备的(环)硅烷生产的薄膜的性能更可预测。 本发明有利地提供了具有适合用于电子应用(例如显示装置或RF ID标签)的质量的半导体薄膜结构,同时实现了在几秒或几分钟而不是几小时或几天内形成这种薄膜的高通量制造工艺, 与传统的光刻工艺。
    • 7. 发明申请
    • PRINTING OF CONTACT METAL AND INTERCONNECT METAL VIA SEED PRINTING AND PLATING
    • 通过种子印刷和镀层印刷接触金属和互连金属
    • US20090020829A1
    • 2009-01-22
    • US12175450
    • 2008-07-17
    • Aditi CHANDRAArvind KAMATHJames Montague CLEEVESJoerg ROCKENBERGERMao TakashimaErik SCHER
    • Aditi CHANDRAArvind KAMATHJames Montague CLEEVESJoerg ROCKENBERGERMao TakashimaErik SCHER
    • H01L21/768H01L21/28H01L29/78
    • H01L21/288H01L21/28518H01L21/32051H01L21/32053H01L21/76838H01L21/76873H01L21/76895H01L27/1285H01L27/1292H01L29/458H01L29/78618H01L2924/0002H01L2924/00
    • Methods of forming contacts (and optionally, local interconnects) using an ink comprising a silicide-forming metal, electrical devices such as diodes and/or transistors including such contacts and (optional) local interconnects, and methods for forming such devices are disclosed. The method of forming contacts includes depositing an ink of a silicide-forming metal onto an exposed silicon surface, drying the ink to form a silicide-forming metal precursor, and heating the silicide-forming metal precursor and the silicon surface to form a metal silicide contact. Optionally, the metal precursor ink may be selectively deposited onto a dielectric layer adjacent to the exposed silicon surface to form a metal-containing interconnect. Furthermore, one or more bulk conductive metal(s) may be deposited on remaining metal precursor ink and/or the dielectric layer. Electrical devices, such as diodes and transistors may be made using such printed contact and/or local interconnects. A metal ink may be printed for contacts as well as for local interconnects at the same time, or in the alternative, the printed metal can act as a seed for electroless deposition of other metals if different metals are desired for the contact and the interconnect lines. This approach advantageously reduces the number of processing steps and does not necessarily require any etching.
    • 公开了使用包含硅化物形成金属的油墨形成触点(和任选的局部互连)的方法,诸如二极管和/或包括这种触点的晶体管的电气器件,(可选的)局部互连)以及用于形成这种器件的方法。 形成接触的方法包括将硅化物形成金属的油墨沉积到暴露的硅表面上,干燥油墨以形成形成硅化物的金属前体,以及加热形成硅化物的金属前体和硅表面以形成金属硅化物 联系。 任选地,可以将金属前体油墨选择性地沉积到与暴露的硅表面相邻的电介质层上,以形成含金属互连。 此外,一个或多个体导电金属可以沉积在剩余的金属前体油墨和/或介电层上。 可以使用这种印刷的接触和/或局部互连来制造电子器件,例如二极管和晶体管。 金属墨水可以同时印刷以用于接触以及局部互连,或者替代地,如果需要用于接触和互连线的不同金属,印刷金属可以用作其它金属的无电沉积的种子 。 这种方法有利地减少了处理步骤的数量,并且不一定需要任何蚀刻。
    • 8. 发明授权
    • Methods of making metal silicide contacts, interconnects, and/or seed layers
    • 制造金属硅化物接触,互连和/或种子层的方法
    • US08158518B2
    • 2012-04-17
    • US12175450
    • 2008-07-17
    • Aditi ChandraArvind KamathJames Montague CleevesJoerg RockenbergerMao TakashimaErik Scher
    • Aditi ChandraArvind KamathJames Montague CleevesJoerg RockenbergerMao TakashimaErik Scher
    • H01L21/44
    • H01L21/288H01L21/28518H01L21/32051H01L21/32053H01L21/76838H01L21/76873H01L21/76895H01L27/1285H01L27/1292H01L29/458H01L29/78618H01L2924/0002H01L2924/00
    • Methods of forming contacts (and optionally, local interconnects) using an ink comprising a silicide-forming metal, electrical devices such as diodes and/or transistors including such contacts and (optional) local interconnects, and methods for forming such devices are disclosed. The method of forming contacts includes depositing an ink of a silicide-forming metal onto an exposed silicon surface, drying the ink to form a silicide-forming metal precursor, and heating the silicide-forming metal precursor and the silicon surface to form a metal silicide contact. Optionally, the metal precursor ink may be selectively deposited onto a dielectric layer adjacent to the exposed silicon surface to form a metal-containing interconnect. Furthermore, one or more bulk conductive metal(s) may be deposited on remaining metal precursor ink and/or the dielectric layer. Electrical devices, such as diodes and transistors may be made using such printed contact and/or local interconnects. A metal ink may be printed for contacts as well as for local interconnects at the same time, or in the alternative, the printed metal can act as a seed for electroless deposition of other metals if different metals are desired for the contact and the interconnect lines. This approach advantageously reduces the number of processing steps and does not necessarily require any etching.
    • 公开了使用包含硅化物形成金属的油墨形成触点(和任选的局部互连)的方法,诸如二极管和/或包括这种触点的晶体管的电气器件,(可选的)局部互连)以及用于形成这种器件的方法。 形成接触的方法包括将硅化物形成金属的油墨沉积到暴露的硅表面上,干燥油墨以形成形成硅化物的金属前体,以及加热形成硅化物的金属前体和硅表面以形成金属硅化物 联系。 任选地,可以将金属前体油墨选择性地沉积到与暴露的硅表面相邻的电介质层上,以形成含金属互连。 此外,一个或多个体导电金属可以沉积在剩余的金属前体油墨和/或介电层上。 可以使用这种印刷的接触和/或局部互连来制造电子器件,例如二极管和晶体管。 金属墨水可以同时印刷以用于接触以及局部互连,或者替代地,如果需要用于接触和互连线的不同金属,印刷金属可以用作其它金属的无电沉积的种子 。 这种方法有利地减少了处理步骤的数量,并且不一定需要任何蚀刻。