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1. 发明申请

US20090221759A1 Oligomers And Polymers Containing Sulfinate Groups And Method For The Production Thereof 有权
标题翻译：含有亚磺酸盐的低聚物和聚合物及其制备方法
公开(公告)号：US20090221759A1
公开(公告)日：2009-09-03
申请号：US12324320
申请日：2008-11-26
申请人： Thomas Haring , Jochen Kerres , Wei Zhang
发明人： Thomas Haring , Jochen Kerres , Wei Zhang
IPC分类号： C08F126/06 , C08G16/00
CPC分类号： H01M6/181 , C08C19/02 , C08F8/04 , C08J5/2243 , C08J2381/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： The invention relates to novel polymers or oligomers containing at least sulfinate groups (P-(SO2)nX, X=1-(n=1), 2-(n=2) or 3-(n=3) valent metal cation or H+ or ammonium ion NR4+ where R=alkyl, aryl, H), which are obtained by completely or partially reducing polymers or oligomers containing at least SO2Y-groups (Y═F, Cl, Br, I, OR, NR2 (R=alkyl and/or aryl and/or H), N-imidazolyL N-pyrazolyl) by means of suitable reducing agents in a suspension or in a solution formPolymer and polymer(blend)membranes which are obtained by further reacting the received sulfinated polymers, especially by alkylation of the sulfinate groups with mono- di- or oligo functional electrophiles. The invention further relates to methods for producing the sulfinated polymers and for further reacting the sulfinated polymers with electrophiles by S-alkylation.
摘要翻译：本发明涉及至少含有亚磺酸基团（P-（SO 2）n X，X = 1-（n = 1），2-（n = 2）或3-（n = 3）价金属阳离子或通过完全或部分还原含有至少SO 2 Y基团（YF，Cl，Br，I，OR，NR 2（R =烷基和/或烷基）的聚合物或低聚物）获得的H +或铵离子NR4 +，其中R =烷基，芳基，H）或芳基和/或H），N-咪唑并吡唑基），通过合适的还原剂以悬浮液或溶液形式聚合物和聚合物（共混物）膜，其通过进一步使所接收的磺化聚合物反应而获得，特别是通过烷基化的亚硫酸酯基团与单 - 或寡功能亲电试剂。本发明还涉及用于生产硫化聚合物的方法，以及通过S-烷基化进一步使硫化聚合物与亲电体反应。

2. 发明申请

US20080090972A1 Oligomers and Polymers Containing Sulfinate Groups, and Methods for Producing the Same 审中-公开
标题翻译：含有亚磺酸基的低聚物和聚合物及其制备方法
公开(公告)号：US20080090972A1
公开(公告)日：2008-04-17
申请号：US11869530
申请日：2007-10-09
申请人： Jochen Kerres , Thomas Haring
发明人： Jochen Kerres , Thomas Haring
IPC分类号： C08F8/34 , C08G75/00
CPC分类号： B01D67/0093 , B01D71/52 , B01D71/68 , B01D71/80 , B01D71/82 , B01D2323/30 , C08G65/48 , C08G75/23 , C08G2650/02 , C08G2650/20 , C08J5/2256 , C08J5/2287 , C08J2381/06 , C08L81/06 , C08L2312/00 , H01M8/0289 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1044 , H01M8/1072 , H01M2300/0082 , H01M2300/0091 , Y02P70/56 , C08L71/00
摘要： The invention relates to polymers obtained by S-alkylation of sulfinated polymers with alkylation agents, and AB-cross-linked polymers obtained by reacting polymers containing alkylation groups with low-molecular sulfinates, under S-alkylation, or AB-cross-linked polymers obtained by S-alkylation of sulfinated polymers with polymers containing alkylation groups.
摘要翻译：本发明涉及通过磺化聚合物与烷基化试剂的S-烷基化获得的聚合物，以及通过使含有烷基化基团的聚合物与低分子亚硫酸盐在S-烷基化反应获得的AB交联聚合物或获得的AB-交联聚合物通过磺化聚合物与含有烷基化基团的聚合物进行S-烷基化。

3. 发明申请

US20100151352A1 Composites and Composite Membranes 审中-公开
标题翻译：复合材料和复合膜
公开(公告)号：US20100151352A1
公开(公告)日：2010-06-17
申请号：US12636323
申请日：2009-12-11
申请人： Thomas Haring , Vladimir Linkov , Jochen Kerres , Andreas Ullrich , Chy-Ming Tang , Martin Hein , Wei Zhang
发明人： Thomas Haring , Vladimir Linkov , Jochen Kerres , Andreas Ullrich , Chy-Ming Tang , Martin Hein , Wei Zhang
IPC分类号： H01M8/10 , C25C7/04 , B01D61/42 , C08J5/22 , B05D3/02 , B01D61/36 , C02F1/44 , B01D61/02 , B01D53/22 , H01M6/18
CPC分类号： B01D67/0093 , B01D67/0006 , B01D67/0011 , B01D69/12 , B01D69/141 , B01D71/00 , B01D71/52 , B01D71/62 , B01D71/82 , B01D2323/30 , B01D2325/14 , C08J5/2275 , C08J2379/06 , C25B13/08 , H01B1/122 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1081 , H01M8/1088 , H01M10/05 , H01M10/0565 , Y02P70/56
摘要： The invention relates to the following types of composite membranes; composites or composite membranes obtained by adding a metal salt, e.g. from ZrOCl2, to a solvent, especially DMSO, for dissolving one or more polymers in an organic solvent or in aqueous systems, in addition to the subsequent precipitation in the matrix of the thus produced composite-membrane by post-treatment thereof in an acid or in a salt solution, especially phosphoric acid. The invention also relates to composites or composite membranes obtained by subsequent ion exchange of finished polymer membranes with a suitable salt cation, especially ZrO2+, wherein the polymer membrane is, optionally, swollen with an organic solvent or a mixture of organic solvent with water prior to the ion exchange and the subsequent precipitation of a low soluble salt, e.g. from Zr3(PO4)4, in the membrane by post-treatment thereof in an acid or in a salt solution, especially phosphoric acid. The invention further relates to composites or composite membranes obtained by adding nano-scaled Zr3(PO4)4 powder to a polymer solution, composites and composite membranes obtained according to the above-mentioned methods, wherein additional heteropoly acids are also incorporated into the polymer or membrane morphology, in addition to methods for producing said inventive polymers and membranes.
摘要翻译：本发明涉及以下类型的复合膜; 复合材料或复合膜，通过加入金属盐，从ZrOCl 2到溶剂，特别是DMSO中，用于将一种或多种聚合物溶解在有机溶剂或水性体系中，以及随后通过在酸中后处理由此制备的复合膜的基质中的沉淀，或在盐溶液中，特别是磷酸。本发明还涉及通过随后使用合适的盐阳离子，特别是ZrO 2 +离子交换成品聚合物膜而获得的复合材料或复合膜，其中聚合物膜任选地在有机溶剂或有机溶剂与水的混合物之前在水中溶胀离子交换和随后的低溶解盐沉淀，例如通过在酸或盐溶液，特别是磷酸中后处理，从Zr3（PO4）4中除去。本发明还涉及通过将纳米级Zr 3（PO 4）4粉末加入到根据上述方法获得的聚合物溶液，复合材料和复合膜中而获得的复合材料或复合膜，其中另外的杂多酸也被引入聚合物或膜形态，以及用于制备所述本发明聚合物和膜的方法。

4. 发明申请

US20060172084A1 Composites and composite membranes 有权
公开(公告)号：US20060172084A1
公开(公告)日：2006-08-03
申请号：US11348870
申请日：2006-02-06
申请人： Jochen Kerres , Thomas Haring , Rima Haring
发明人： Jochen Kerres , Thomas Haring , Rima Haring
IPC分类号： B05D3/00 , H01B1/14 , B32B3/26
CPC分类号： B01D67/0041 , B01D69/141 , B01D71/00 , B01D71/024 , B01D71/62 , B01D71/68 , B01D2325/18 , B01D2325/26 , B01J21/16 , B01J31/10 , B01J31/1633 , B01J35/065 , C08J5/2275 , C08J2383/02 , H01M8/0289 , H01M8/1023 , H01M8/103 , H01M8/1032 , H01M8/1051 , H01M8/1081 , Y02E60/523 , Y02P70/56 , Y10T428/249953 , Y10T428/249969
摘要： The invention relates to a composite or a composite membrane consisting of an ionomer and of an inorganic optionally functionalized phyllosilicate. The isomer can be: (a) a cation exchange polymer; (b) an anion exchange polymer; (c) a polymer containing both anion exchanger groupings as well as cation exchanger groupings on the polymer chain; or (d) a blend consisting of (a) and (b), whereby the mixture ratio can range from 100% (a) to 100% (b). The blend can be ionically and even covalently cross-linked. The inorganic constituents can be selected from the group consisting of phyllosilicates or tectosilicates.

5. 发明授权

US08742021B2 Ionomers with ionic groups in the side chain 失效
标题翻译：在侧链中具有离子基团的离聚物
公开(公告)号：US08742021B2
公开(公告)日：2014-06-03
申请号：US13330614
申请日：2011-12-19
申请人： Thomas Haring , Jochen Kerres , Martin Hein
发明人： Thomas Haring , Jochen Kerres , Martin Hein
IPC分类号： C08L27/04 , C08L9/00 , C08L39/04 , C08F8/40 , B01J39/18
CPC分类号： B01J39/185 , B01D67/0006 , B01D67/0093 , B01D71/68 , B01D71/82 , B01D2325/16 , B01J39/19 , C08G65/48 , C08G75/0286 , C08J5/2231 , C08J5/2256 , C08J2365/02 , C08J2381/06 , H01M8/0289 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , H01M2300/0082 , Y02E60/523 , Y02P70/56
摘要： Ionomers and ionomer membranes, consisting of a non-fluorinated or partly fluorinated non-, partly or fully-aromatic main chain and a non- or partly-fluorinated side chain with ionic groups or their non-ionic precursors, have a positive impact on the proton conductivity of the ionomers. Various processes produce these polymeric proton conductors.
摘要翻译：由非氟化或部分氟化的非部分或完全芳族主链和具有离子基团或其非离子前体的非或部分氟化的侧链组成的离聚物和离子交联聚合物膜对离聚物的质子电导率。各种方法产生这些聚合物质子导体。

6. 发明授权

US08030414B2 Oligomers and polymers containing sulfinate groups and method for the production thereof 有权
标题翻译：含有亚磺酸盐基团的低聚物和聚合物及其制备方法
公开(公告)号：US08030414B2
公开(公告)日：2011-10-04
申请号：US12324320
申请日：2008-11-26
申请人： Thomas Haring , Jochen Kerres , Wei Zhang
发明人： Thomas Haring , Jochen Kerres , Wei Zhang
IPC分类号： C08F8/00 , C08F14/00 , C08F114/00 , C08F214/00
CPC分类号： H01M6/181 , C08C19/02 , C08F8/04 , C08J5/2243 , C08J2381/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： The invention relates to novel polymers or oligomers containing at least sulfinate groups (P—(SO2)nX, X=1-(n=1), 2-(n=2) or 3-(n=3) valent metal cation or H+ or ammonium ion NR4+ where R=alkyl, aryl, H), which are obtained by completely or partially reducing polymers or oligomers containing at least SO2Y-groups (Y═F, Cl, Br, I, OR, NR2 (R=alkyl and/or aryl and/or H), N-imidazolyl, N-pyrazolyl) by means of suitable reducing agents in a suspension or in a solution form.Polymer and polymer(blend)membranes which are obtained by further reacting the received sulfinated polymers, especially by alkylation of the sulfinate groups with mono- di- or oligo functional electrophiles. The invention further relates to methods for producing the sulfinated polymers and for further reacting the sulfinated polymers with electrophiles by S-alkylation.
摘要翻译：本发明涉及至少含有亚磺酸基团（P-（SO 2）n X，X = 1-（n = 1），2-（n = 2）或3-（n = 3）价金属阳离子或 H +或铵离子NR4 +，其中R =烷基，芳基，H），其通过完全或部分还原含有至少SO 2 Y基团（Y = F，Cl，Br，I，OR，NR 2（R = 和/或芳基和/或H），N-咪唑基，N-吡唑基），通过合适的还原剂以悬浮液或溶液形式存在。聚合物和聚合物（共混物）膜，其通过进一步使所接收的磺化聚合物反应而获得，特别是通过亚硫酸酯基团与单 - 或寡功能亲电体的烷基化。本发明还涉及用于生产硫化聚合物的方法，以及通过S-烷基化进一步使硫化聚合物与亲电体反应。

7. 发明申请

US20090221787A1 Production Of Monomer, Oligomer And Polymer Phosphonic Acid Esters And Phosphonic And Sulphonic Acids By A Nucleophile Aromatic Substitution 审中-公开
标题翻译：通过亲核取代芳基取代单体，低聚物和聚合物膦酸酯和膦酸和磺酸的生产
公开(公告)号：US20090221787A1
公开(公告)日：2009-09-03
申请号：US11995187
申请日：2006-07-10
申请人： Thomas Haring , Jochen Kerres , Martin Hein , Frank Schonberger
发明人： Thomas Haring , Jochen Kerres , Martin Hein , Frank Schonberger
IPC分类号： C08G75/00 , C07C315/00 , C07F9/02 , C08G73/24
CPC分类号： B01D71/52 , B01D71/66 , B01D71/68 , C07C303/02 , C07C317/22 , C07F9/3834 , C07F9/404 , C08F8/36 , C08F8/40 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M2300/0082 , Y02P70/56
摘要： The invention relates to producing monomer, oligomer and polymer non-fluorinated, partially fluorinated or perfluorinated sulphonic acids by reacting halogenated, low-molecular weight, oligomer or macromolecular arenes with (hydrogen) sulphites, dithionites, sulphides or other reducing sulfur salts, possibly by oxidising sulphur-containing arene intermediates which are formed at a sulphur oxidation degree less than +6 by means of appropriate oxidation agents with formation of corresponding sulphonate functional groups (sulphonic acid, sulfohalogenide, sulphonamide and sulphonic acid ester groups). The invention also relates to a method for producing monomer, oligomer or polymer non-halogenated, partially halogenated or perhalogenated phosphonic acid esters and the derivatives thereof (for example, a free phosphonic acid or a phosphonic acid salt) by a nucleophile aromatic substitution (Michaelis-Becker-reaktion, complete or partial substitution of halogenide functional groups by phosphate functional groups (phosphonic acid esters, phosphonic acid amides, phosphonic acids, phosphonic acid salts, phosphonic acid halogenides). Said invention also relates to a method for producing polymer or ionomer non-halogenated, partially halogenated or perhalogenated containing (CF2)xPO(OR)2— or (CF2)xSO2Me- or (CF2)xSO3Me- side chains, (wherein x=1-20, R=any organic radical, Me=any monovalent cation). A method for carrying out a nucleophile polycondensation of said functionalised (i.e. sulphonated, sulphonated or phosphonated) monomers into oligomers or polymers is also disclosed.
摘要翻译：本发明涉及通过卤代，低分子量，低聚物或大分子芳烃与（氢）亚硫酸盐，连二亚硫酸盐，硫化物或其它还原硫盐反应制备单体，低聚物和聚合物非氟化的，部分氟化的或全氟化的磺酸，可能通过通过形成相应的磺酸盐官能团（磺酸，磺基卤化物，磺酰胺和磺酸酯基团）的合适的氧化剂，氧化含硫芳烃中间体，它们以小于+6的硫氧化度形成。本发明还涉及通过亲核试剂芳香取代产生单体，低聚物或聚合物非卤代，部分卤化或全卤代膦酸酯及其衍生物（例如游离膦酸或膦酸盐）的方法（Michaelis - 磷酸酯官能团（膦酸酯，膦酸酰胺，膦酸，膦酸盐，膦酸卤化物）完全或部分取代卤化物官能团的方法本发明还涉及聚合物或离聚物的制备方法（CF 2）x SO 2 Me-或（CF 2）x SO 3 Me侧链，（其中x = 1-20，R =任何有机基团，Me =任何还公开了将所述官能化（即磺化，磺化或膦酸化）单体进行亲核物缩聚成低聚物或聚合物的方法。

8. 发明申请

US20070185305A1 Oligomers and polymers containing sulfinate groups and method for the production thereof 审中-公开
标题翻译：含有亚磺酸盐基团的低聚物和聚合物及其制备方法
公开(公告)号：US20070185305A1
公开(公告)日：2007-08-09
申请号：US11602481
申请日：2006-11-20
申请人： Thomas Haring , Jochen Kerres , Wei Zhang
发明人： Thomas Haring , Jochen Kerres , Wei Zhang
IPC分类号： C08G75/00
CPC分类号： H01M6/181 , C08C19/02 , C08F8/04 , C08J5/2243 , C08J2381/00 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1072 , Y02P70/56
摘要： The invention relates to novel polymers or oligomers containing at least sulfonite groups (P—(SO2)nX, X=1−(n=1), 2−(n=2) or 3−(n=3) valent metal cation or H+ or ammonium ion NR4+ where R=alkyl, aryl, H), which are obtained by completely or partially reducing polymers or oligomers containing at least SO2Y-groups (Y═F, Cl, Br, I, OR, NR2 (R=alkyl and/or aryl and/or H), N-imidazolyl, N-pyrazolyl) by means of suitable reducing agents in a suspension or in a solution form. The invention also relates to polymers and polymer(blend) membranes which are obtained by further reacting the obtained sulfinated polymers, especially by alkylation of the sulfinate groups with mono- di- or oligo functional electrophiles. The invention further relates to methods for producing the sulfinated polymers and for further reacting the sulfinated polymers with electrophiles by S-alkylation.
摘要翻译：本发明涉及至少含有亚磺酸基团的新型聚合物或低聚物（X-1-（n = 1），2-（ n = 2）或3-（n = 3）价金属阳离子或H +或铵离子NR 4 +，其中R =烷基，芳基，H），其通过完全或部分还原含有至少SO 2 Y基（YF，Cl，Br，I，OR，NR 2）的聚合物或低聚物而获得（R =烷基和/或芳基和/或H），N-咪唑基，N-吡唑基），通过合适的还原剂以悬浮液或溶液形式。本发明还涉及聚合物和聚合物（共混物）膜，其通过进一步使得到的硫化聚合物反应而获得，特别是通过亚磺酸基团与单 - 或寡官能亲电体的烷基化。本发明还涉及用于生产硫化聚合物的方法，以及通过S-烷基化进一步使硫化聚合物与亲电体反应。

9. 发明授权

US07049020B2 Composites and composite membranes 有权
公开(公告)号：US07049020B2
公开(公告)日：2006-05-23
申请号：US09984564
申请日：2001-10-30
申请人： Jochen Kerres , Thomas Haring , Rima Haring
发明人： Jochen Kerres , Thomas Haring , Rima Haring
IPC分类号： H01M8/10 , H01M10/40 , C25B13/00 , C25B7/04 , B01D61/42 , B01D61/44
CPC分类号： B01D67/0041 , B01D69/141 , B01D71/00 , B01D71/024 , B01D71/62 , B01D71/68 , B01D2325/18 , B01D2325/26 , B01J21/16 , B01J31/10 , B01J31/1633 , B01J35/065 , C08J5/2275 , C08J2383/02 , H01M8/0289 , H01M8/1023 , H01M8/103 , H01M8/1032 , H01M8/1051 , H01M8/1081 , Y02E60/523 , Y02P70/56 , Y10T428/249953 , Y10T428/249969
摘要： The invention relates to a composite or a composite membrane consisting of an ionomer and of an inorganic optionally functionalized phyllosilicate. The isomer can be: (a) a cation exchange polymer; (b) an anion exchange polymer; (c) a polymer containing both anion exchanger groupings as well as cation exchanger groupings on the polymer chain; or (d) a blend consisting of (a) and (b), whereby the mixture ratio can range from 100% (a) to 100% (b). The blend can be ionically and even covalently cross-linked. The inorganic constituents can be selected from the group consisting of phyllosilicates or tectosilicates.

10. 发明申请

US20060231484A1 Composites and composite membranes 审中-公开
标题翻译：复合材料和复合膜
公开(公告)号：US20060231484A1
公开(公告)日：2006-10-19
申请号：US10929648
申请日：2004-08-30
申请人： Thomas Haring , Vladimir Linkov , Jochen Kerres , Andreas Ullrich , Chy-Ming Tang , Martin Hein , Wei Zhang
发明人： Thomas Haring , Vladimir Linkov , Jochen Kerres , Andreas Ullrich , Chy-Ming Tang , Martin Hein , Wei Zhang
IPC分类号： B01D71/06
CPC分类号： B01D67/0093 , B01D67/0006 , B01D67/0011 , B01D69/12 , B01D69/141 , B01D71/00 , B01D71/52 , B01D71/62 , B01D71/82 , B01D2323/30 , B01D2325/14 , C08J5/2275 , C08J2379/06 , C25B13/08 , H01B1/122 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1048 , H01M8/1051 , H01M8/1081 , H01M8/1088 , H01M10/05 , H01M10/0565 , Y02P70/56
摘要： The invention relates to the following types of composite membranes; composites or composite membranes obtained by adding a metal salt, e.g. from ZrOCl2, to a solvent, especially DMSO, for dissolving one or more polymers in an organic solvent or in aqueous systems, in addition to the subsequent precipitation in the matrix of the thus produced composite-membrane by post-treatment thereof in an acid or in a salt solution, especially phosphoric acid. The invention also relates to composites or composite membranes obtained by subsequent ion exchange of finished polymer membranes with a suitable salt cation, especially ZrO2+, wherein the polymer membrane is, optionally, swollen with an organic solvent or a mixture of organic solvent with water prior to the ion exchange and the subsequent precipitation of a low soluble salt, e.g. from Zr3 (PO4)4, in the membrane by post-treatment thereof in an acid or in a salt solution, especially phosphoric acid. The invention further relates to composites or composite membranes obtained by adding nano-scaled Zr3(PO4)4 powder to a polymer solution, composites and composite membranes obtained according to the above-mentioned methods, wherein additional heteropoly acids are also incorporated into the polymer or membrane morphology, in addition to methods for producing said inventive polymers and membranes.
摘要翻译：本发明涉及以下类型的复合膜; 复合材料或复合膜，通过加入金属盐，从一种溶剂，特别是DMSO中，将一种或多种聚合物溶解在有机溶剂或水性体系中，除了随后通过如此制备的复合膜的基质沉淀，由在酸或盐溶液，特别是磷酸中进行后处理。本发明还涉及通过随后使用合适的盐阳离子离子交换完成的聚合物膜而获得的复合材料或复合膜，特别是ZrO 2 O + 在离子交换之前用有机溶剂或有机溶剂与水的混合物溶胀，随后沉淀低可溶性盐，例如通过在酸或盐溶液中，特别是磷酸中后处理，从Zr 3（PO 4）4 S 4 。本发明还涉及通过将纳米级Zr 3（PO 4）4 N 4）粉末添加到聚合物溶液中获得的复合材料或复合膜，复合材料以及根据上述方法获得的复合膜，其中除了制备所述本发明聚合物和膜的方法之外，还将其它杂多酸掺入聚合物或膜形态中。

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