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1. 发明授权

US5705589A Organosilane and organopolysiloxane free radical initiators and macromonomers and graft copolymers which can be prepared with them 失效
标题翻译：有机硅烷和有机聚硅氧烷自由基引发剂和可与它们一起制备的大分子单体和接枝共聚物
公开(公告)号：US5705589A
公开(公告)日：1998-01-06
申请号：US501750
申请日：1995-07-12
申请人： Jochen Dauth , Bernward Deubzer , Oskar Nuyken , Brigette Voit , Ralf Kollefrath
发明人： Jochen Dauth , Bernward Deubzer , Oskar Nuyken , Brigette Voit , Ralf Kollefrath
IPC分类号： C07F7/18 , C08F4/04 , C08F4/72 , C08F283/12 , C08F290/00 , C08G77/28 , C08G77/388 , C08G77/392 , C08G77/452
CPC分类号： C07F7/184 , C08F283/12 , C08F4/04 , C08G77/388 , C08G77/392
摘要： The organosilanes and organopolysiloxanes containing groups which form free radicals and are soluble in organic solvents, processes for their preparation, macromonomers and graft copolymers from the organosilanes and organopolysiloxanes according to the invention as free radical initiators and organic monomers which can be polymerized by free radicals, a process for the preparation of the macromonomers and graft copolymers and their use.
摘要翻译：含有自由基并且可溶于有机溶剂的基团的有机硅烷和有机聚硅氧烷，其可用于制备本发明的有机硅烷和有机聚硅氧烷的大分子单体和接枝共聚物作为自由基引发剂和可通过自由基聚合的有机单体，一种制备大分子单体和接枝共聚物的方法及其用途。

2. 发明授权

US5548070A Organosilicon compounds having triazene groups 失效
标题翻译：具有三烯基的有机硅化合物
公开(公告)号：US5548070A
公开(公告)日：1996-08-20
申请号：US276926
申请日：1994-07-19
申请人： Jochen Dauth , Bernward Deubzer , Elfriede Mayer , Oskar Nuyken , Brigitte Voit , Ralf Kollefrath
发明人： Jochen Dauth , Bernward Deubzer , Elfriede Mayer , Oskar Nuyken , Brigitte Voit , Ralf Kollefrath
IPC分类号： C07F7/10 , C07F7/08 , C08F283/12 , C08F293/00 , C08F297/00 , C08G77/26 , C08G77/38 , C08G77/388 , C08G77/398 , C07C245/00
CPC分类号： C07F7/0854 , C08G77/26 , C08G77/388 , C08G77/398
摘要： The organosilicon compounds have at least one Si--C-bonded organic radical which contains at least one triazene group. The organosilicon compounds can be employed as heat- and light-unstable free radical initiators for the preparation of homo-, graft co- and block copolymers from olefinically unsaturated compounds and for crosslinking organosilicon compounds and organic compounds which can be polymerized by free radical polymerization.
摘要翻译：有机硅化合物具有至少一个含有至少一个三烯基的Si-C键合的有机基团。有机硅化合物可用作热和光不稳定的自由基引发剂，用于从烯属不饱和化合物制备均聚物，接枝共聚物和嵌段共聚物，并用于交联可通过自由基聚合聚合的有机硅化合物和有机化合物。

3. 发明授权

US5998562A Permanent organosilicon compounds, their preparation and use 失效
标题翻译：永久性有机硅化合物，其制备和用途
公开(公告)号：US5998562A
公开(公告)日：1999-12-07
申请号：US888934
申请日：1997-07-07
申请人： Guenter Mahr , Jochen Dauth , Bernward Deubzer , Monika Ott , Petra Gratzl , Hans Lautenschlager
发明人： Guenter Mahr , Jochen Dauth , Bernward Deubzer , Monika Ott , Petra Gratzl , Hans Lautenschlager
IPC分类号： C14C11/00 , C07F7/10 , C07F7/18 , C08G77/10 , C08G77/26 , C08G77/388 , C08G77/54 , D06M15/643 , C08G77/08
CPC分类号： C08G77/388 , C08G77/54 , Y10S8/01
摘要： The present invention relates to triazine-containing organosilicon compounds having units of the formulaA.sub.a R.sub.b X.sub.c SiO.sub.(4-a-b-c)/2 (I),whereR is identical or different and denotes a hydrogen atom or a monovalent substituted or unsubstituted hydrocarbon radical, having 1 to 26 carbon atoms, preferably 1 to 18 per radical,X is identical or different and is a halogen atom, a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical, having 1 to 18 carbon atoms, preferably 1 to 8 per radical and which may be substituted by an ether oxygen atom,a is 0 or 1, preferably 0.01-0.5b is 0, 1, 2 or 3, preferably 0.5-3.0c is 0, 1, 2 or 3, preferably 0.0-2.0 and the sum a+b+c.ltoreq.4, preferably 0.1-3.5, andA is a radical of the formula ##STR1## where R.sup.2 is an unbranched or branched, optionally substituted alkylene radical, having 1 to 18, preferably 1 to 12, carbon atoms,Y is identical or different and denotes a hydrogen atom or an unbranched or branched alkyl radical, having 1 to 12, preferably 1 to 8, carbon atoms or denotes a radical of the formula --OR.sup.1, where R.sup.1 has the meaning given above, andZ is identical or different and denotes X, --NR.sub.2, --(O)CR or --SR, where X and R have the meanings given above with the proviso that at least one radical A containing at least one halogen atom, preferably a chlorine atom, is present per polymer molecule.
摘要翻译：本发明涉及具有式AaRbXcSiO（4-abc）/ 2（I）单元的含三嗪的有机硅化合物，其中R相同或不同，表示氢原子或一价取代或未取代的烃基，其具有1至 26个碳原子，优选1至18个基团，X相同或不同，为卤素原子，氯原子或式-OR1基团，其中R1表示具有1至18个碳原子的烷基，优选1 至8个，并且可被醚氧原子取代，a为0或1，优选为0.01-0.5b为0,1,2或3，优选0.5-3.0c为0,1,2或3，优选为总和a + b + c 4，优选0.1-3.5，A是下式的基团，其中R 2是无支链或支链的任选取代的亚烷基，其具有1至18，优选1至 12，碳原子，Y相同或不同，表示氢原子或无支链或支链烷基，具有1至12个，优选为1〜8个碳原子，或表示式-OR1的基团，其中R1具有上述含义，Z相同或不同，表示X，-NR2， - （O）CR或-SR，其中X和 R具有上述含义，条件是每个聚合物分子存在至少一个含有至少一个卤素原子，优选氯原子的基团A.

4. 发明授权

US6068929A Radiation-curing or heat-curing organosiloxane compositions containing (methyl) styrene groups 失效
标题翻译：含有（甲基）苯乙烯基团的辐射固化或热固化有机硅氧烷组合物
公开(公告)号：US6068929A
公开(公告)日：2000-05-30
申请号：US72211
申请日：1998-05-04
申请人： Jochen Dauth , Josef Wolferseder , Bernward Deubzer
发明人： Jochen Dauth , Josef Wolferseder , Bernward Deubzer
IPC分类号： C08F299/08 , C08F290/14 , C08G77/38 , C08G77/46 , C08G77/50 , C08L83/07 , C09D155/00 , C09D183/07 , C09D183/12 , C09D183/14 , C08F283/12 , B32B27/00
CPC分类号： C09D183/12 , C08G77/46 , C08G77/50 , C09D183/14
摘要： Novel organosiloxane compositions which contain (methyl)styrene groups and can be prepared on the basis ofA) oligomeric or polymeric organosilicon compounds comprising at least one unit of the formulaGR.sub.c SiO.sub.(4-c-1)/2 (I)or at least one unit of the formula (I) and at least one unit of the formulaO.sub.(4-c-1)/2) R.sub.c Si--G.sup.1 --R.sub.c SiO.sub.(4-c-1)/2(II)B) monomeric alkenyloxy compounds, maleates, fumarates, maleimides, (meth)acrylates, (methyl)styrenes, acrylamides, itaconic esters and/or oligomeric or polymeric organosilicon compounds containing on average more than one alkenyloxy, maleate, fumarate, maleimide or (meth)acrylate group, where R are identical or different hydrocarbon radicals which may be halogenated or unhalogenated or a radical of the formula--R.sup.1 --[OCH.sub.2 CH.sub.2 ].sub.o --[OCH(CH.sub.3)CH.sub.2 ].sub.p --[O(CH.sub.2).sub.4 ].sub.q --OR.sup.2,whereR.sup.1 is a linear or branched alkylene radical,R.sup.2 is a hydrogen atom, an alkyl radical or a radical of the formula --CO--R.sup.3, where R.sup.3 is an alkyl radical,G is a radical of the formula (IV) --R.sup.4 -(phenyl) which is substituted by [--Y.sub.(5-d) ] and (--R.sup.5.sub.d), with the proviso that at least one radical R.sup.5 is present andG.sup.1 is a radical of the formula (V) --(phenyl)-(R.sup.4).sub.d -- which is substituted by [--Y.sub.4-d ], whereR.sup.4 is a linear or branched, substituted or unsubstituted alkylene radical,R.sup.5 is a vinyl radical or isopropenyl radical,Y can be identical or different and each Y is a hydrogen atom or is as defined for R, or is a radical of the formula --OR.sup.6, whereR.sup.6 is a C.sub.1-8 alkyl radical optionally interrupted by an ether oxygen atom, andc is 0, 1 or 2, on average from 0.0 to 2.0,d is 1, 2 or 3,o is 0 or an integer from 1 to 100,p is 0 or an integer from 1 to 100, andq is 0 or an integer from 1 to 100, with the proviso that the sum o+p+q is >0.
摘要翻译：含有（甲基）苯乙烯基团的新型有机硅氧烷组合物并且可以基于A）包含至少一种式GRcO（4-c-1）/ 2（I）单元的低聚或聚合有机硅化合物或至少一个单元（4-c-1）/ 2）RcSi-G1-RcSiO（4-c-1）/ 2（II）B）单体链烯氧基化合物，马来酸酯，富马酸酯的至少一个单元，马来酰亚胺，（甲基）丙烯酸酯，（甲基）苯乙烯，丙烯酰胺，衣康酸酯和/或低聚或聚合的有机硅化合物，其平均含有多于一个烯氧基，马来酸酯，富马酸酯，马来酰亚胺或（甲基）丙烯酸酯基团，其中R相同或可以被卤化或未卤化的不同烃基或式-R1- [OCH2CH2] o- [OCH（CH3）CH2]对 - [O（CH2）4] q-OR2的基团，其中R1是直链或支链亚烷基，R2是氢原子，烷基或式-CO-R3的基团，其中R3是烷基，G是式（IV）-R4-（苯基） h被[-Y（5-d）]和（-R5d）取代，条件是存在至少一个基团R 5，并且G 1是式（Ⅴ） - （苯基） - （R 4）d - 被[-Y4-d]取代，其中R4是直链或支链的取代或未取代的亚烷基，R5是乙烯基或异丙烯基，Y可以相同或不同，并且每个Y是氢原子或是如R所定义，或者是式-OR 6的基团，其中R 6是任选被醚氧原子中断的C 1-8烷基，c是0,1或2，平均为0.0至2.0，d为 1,2或3，o为0或1〜100的整数，p为0或1〜100的整数，q为0或1〜100的整数，条件是+ o + p + q是> 0。

5. 发明授权

US6043362A Hydrophilic permanent organosilicon compounds 失效
标题翻译：亲水性永久性有机硅化合物
公开(公告)号：US6043362A
公开(公告)日：2000-03-28
申请号：US888557
申请日：1997-07-07
申请人： Jochen Dauth , Guenter Mahr , Bernward Deubzer , Petra Gratzl , Hans-Juergen Lautenschlager
发明人： Jochen Dauth , Guenter Mahr , Bernward Deubzer , Petra Gratzl , Hans-Juergen Lautenschlager
IPC分类号： C07F7/10 , C07F7/18 , C08G77/10 , C08G77/26 , C08G77/388 , C08G77/46 , D06M13/02 , D06M13/148 , D06M13/322 , D06M13/35 , D06M13/355 , D06M13/358 , D06M13/364 , D06M13/50 , D06M13/51 , D06M13/513 , C07D47/00
CPC分类号： C08G77/388 , C08G77/26 , C08G77/46
摘要： The invention relates to oxyalkylene-group-containing organosilicon compounds having units of the formula ##STR1## where R is identical or different, and denotes a monovalent halogenated or nonhalogenated hydrocarbon radical, X is identical or different and is a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical which can be substituted by an ether oxygen atom,a is 0 or 1,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3 and the total a+b+c.ltoreq.4 andA is a radical of the formula ##STR2## where R.sup.2 signifies an unbranched or branched substituted or unsubstituted divalent hydrocarbon radical, which may or may not contain ether, amine, sulfide, ester, amide, carbonate, urea and urethane groups, B is identical or different, and denotes X, --NR.sub.2.sup.1, --O--C(.dbd.O)--R.sup.1, --SR.sup.1 or a radical of the formula--NR.sup.3 R.sup.2 [O--CH(CH.sub.3)--CH.sub.2 ].sub.d [OCH.sub.2 CH.sub.2 ].sub.e [O(CH.sub.2).sub.4 ].sub.f OR.sup.4 (III),where X, R.sup.1 and R.sup.2 have the meanings given for these above, R.sup.3 is identical or different and is a hydrogen atom or has the meaning of R, R.sup.4 has the meaning of R.sup.3 or signifies a radical of the formula--C(.dbd.O)--R, --R.sup.2 NR.sub.2.sup.3, --NR.sup.3 R.sup.2 --, --R.sup.2 NR.sub.2.sup.3 H.sup.+ X.sup.-,d, e and f are an integer from 0 to 200, with the proviso that the sum d+e+f.gtoreq.1 and B contains at least one radical of the formula (III) per polymer molecule.
摘要翻译：本发明涉及具有下式的单元的含氧化烯基的有机硅化合物，其中R相同或不同，表示一价卤代或非卤代烃基，X相同或不同，为氯原子或式 - OR1，其中R1表示可被醚氧原子取代的烷基，a为0或1，b为0,1,2或3，c为0,1,2或3，总计a + b + C 4和A是下式的基团，其中R 2表示无支链或支链的取代或未取代的二价烃基，其可以含有或不含有醚，胺，硫醚，酯，酰胺，碳酸酯，脲和氨基甲酸酯基团， B表示相同或不同的表示X，-NR 21，-OC（= O）-R 1，-SR 1或-NR 3 R 2基团的基团[O-CH（CH 3）-CH 2] d [OCH 2 CH 2] CH 2）4] fOR 4（III），其中X，R 1和R 2具有上述含义，R 3相同或不同，为氢原子或具有R的含义，R 4具有平均或表示式-C（= O）-R，-R2NR23，-NR3R2-，-R2NR23H + X，D，e和f的基团为0至200的整数，条件是总和d + e + f> / = 1，B包含每个聚合物分子中至少一个式（III）的基团。

6. 发明授权

US5969077A Polysiloxanes containing heterocyclic functions, their preparation and use 失效
标题翻译：含有杂环官能团的聚硅氧烷，其制备和用途
公开(公告)号：US5969077A
公开(公告)日：1999-10-19
申请号：US163526
申请日：1998-09-30
申请人： Robert Schrock , Jochen Dauth , Bernward Deubzer
发明人： Robert Schrock , Jochen Dauth , Bernward Deubzer
IPC分类号： C08G77/388 , C08G77/54 , D06M15/643 , C08G77/12
CPC分类号： C08G77/54 , C08G77/388 , D06M15/6436
摘要： Organosiloxane compounds bearing nitrogen-containing heterocycles, in which the heterocycles are bonded to a silicon atom via divalent radicals containing a unit of the general formula (I) ##STR1## in which E is one of the radicals --O--, --S--, --NR.sup.1 -- or --N.dbd., where R and R.sup.1 are each a C.sub.1 - to C.sub.20 -hydrocarbon radical which is optionally substituted by halogen, amine, ammonium or mercapto groups and may optionally be interrupted by groups chosen from --C(O)--, --C(O)--O--, --C(O)--NR.sup.3 --, --NR.sup.3 --, --O--, --S--, and--N.dbd. is a constituent of a heterocycle,can be used for the treatment of textile fibers, textile sheet materials and leather and as stabilizers in synthetic polymers.
摘要翻译：带有含氮杂环的有机硅氧烷化合物，其中杂环通过含有通式（I）的单元的二价基团键合到硅原子上，其中E是基团-O - ， - S-，-NR1- 或-N =，其中R和R 1各自为任选被卤素，胺，铵或巯基取代的C 1 -C 20烃基，并且可以任选地被选自-C（O） - ， - C （O）-O - ， - C（O）-NR 3 - ， - NR 3 - ， - O - ， - S-和-N =是杂环的成分，可用于纺织纤维，织物片材和皮革以及合成聚合物中的稳定剂。

7. 发明授权

US5840951A Organosilicon compounds containing amino groups, their preparation and their use 失效
标题翻译：含有氨基的有机硅化合物，其制备及其用途
公开(公告)号：US5840951A
公开(公告)日：1998-11-24
申请号：US888405
申请日：1997-07-07
申请人： Thomas Hierstetter , Jochen Dauth , Joerg Pfister , Bernward Deubzer
发明人： Thomas Hierstetter , Jochen Dauth , Joerg Pfister , Bernward Deubzer
IPC分类号： C08G77/388 , C08G77/54 , C07F7/10
CPC分类号： C08G77/54
摘要： Organosilicon compounds containing amino groups, their preparation and their use Organosilicon compounds containing amino groups and comprising a) siloxane units of the formula R.sub.a Si(OR.sup.1).sub.b O.sub.(4-a-b)/2 (I) and b) at least one unit per molecule selected from the group consisting of units of the formulae AR.sub.C SiO.sub.(4-c-1)/2 (II), O.sub.(4-c-1)/2 R.sub.C Si--A.sup.1 --R.sub.C SiO.sub.(4-c-1)/2 (III) or ##STR1## where R is an identical or different hydrocarbon radical which has from 1 to 18 carbon atoms, optionally substituted by halogen atoms, alkoxy groups or hydroxy groups where the hydrocarbon radical is optionally interrupted by oxygen atoms, R.sup.1 is an identical or different alkyl radical which is optionally interrupted by oxygen atoms, a is 0, 1, 2 or 3 and b is 0, 1, 2 or 3, with the proviso that the sum a+b is not greater than 3, and c is 0, 1 or 2, A is a radical of the formula --R.sup.2 R.sup.3.sub.z N(--CR.sup.4.sub.2 --R.sup.5).sub.(2-z) (V), A.sup.1 is a radical of the formula ##STR2## and A.sup.2 is a radical of the formula ##STR3## where z is 0 or 1, R.sup.2 is an identical or different alkylene radical having from 2 to 8 carbon atoms, or a radical of the formula ##STR4## R.sup.3 is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, R.sup.4 is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, R.sup.5 is a radical of the formulae --CR.sup.6 .dbd.CR.sup.6.sub.2, --C.tbd.CR.sup.6, where R.sup.6 is identical or different and is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, with the proviso that the organosilicon compound containing amino groups has at least one siloxane unit of formula (II) per molecule and at least one unit selected from the group consisting of units of formulae (III) and (IV) per molecule.
摘要翻译：含有氨基的有机硅化合物及其制备及其用途含有氨基的有机硅化合物，包含a）式RaSi（OR1）bO（4-ab）/ 2（I））的硅氧烷单元，b）每分子选择至少一个单元由式ARCSiO（4-c-1）/ 2（II），O（4-c-1）/ 2RCSi-A1-RCSiO（4-c-1）/ 2（III）或（IV）其中R是具有1至18个碳原子的相同或不同的烃基，任选地被卤素原子，烷氧基或羟基取代，其中烃基任选被氧原子中断，R 1是相同的或任选被氧原子间隔的不同烷基，a是0,1,2或3，b是0,1,2或3，条件是和a + b不大于3，c是 0,1或2，A是式-R 2 R 3 z N（-CR 42 -R 5）（2-z）（V）的基团，A 1是下式的基团（VI），并且A 2是式（VII）其中z为0或1， R2是具有2至8个碳原子的相同或不同的亚烷基，或者式III的基团是氢原子或具有1至8个碳原子的烷基，R4是氢原子或烷基具有1至8个碳原子的基团，R 5是下式的基团-CR 6 = CR 62，-C 3 CON CR 6，其中R 6相同或不同，并且是氢原子或具有1至8个碳原子的烷基，含有氨基的有机硅化合物每分子具有至少一个式（II）的硅氧烷单元和至少一个选自每个分子式（III）和（IV）的单元的单元的单元。

8. 发明授权

US5627296A Phosphorus-containing organosilicon compounds 失效
标题翻译：含磷有机硅化合物
公开(公告)号：US5627296A
公开(公告)日：1997-05-06
申请号：US559269
申请日：1995-11-15
申请人： Jochen Dauth , Hans Mayer , Bernward Deubzer , Petra Gratzl
发明人： Jochen Dauth , Hans Mayer , Bernward Deubzer , Petra Gratzl
IPC分类号： C07F9/30 , C07F9/38 , C07F9/48 , C07F19/00 , C08G77/395 , C08G77/48 , C07F7/08
CPC分类号： C08G77/395 , C07F9/301 , C07F9/3821 , C07F9/4816 , C08G77/48
摘要： The present invention provides novel phosphorus-containing organosilicon compounds which can be prepared in a simple manner using readily obtainable starting materials, which are hydrophilic to water-soluble and whose hydrophilicity or water-solubility can be specifically controlled by modification of the phosphorus-containing organosilicon compounds.
摘要翻译：本发明提供新颖的含磷有机硅化合物，其可以使用容易获得的起始原料以简单的方式制备，其亲水性为水溶性，并且其亲水性或水溶性可以通过改性含磷有机硅化合物。

9. 发明授权

US5593787A Organosilicon compounds containing (meth) acryloxy groups, their preparation and their use 失效
标题翻译：含有（甲基）丙烯酰氧基的有机硅化合物，其制备及其应用
公开(公告)号：US5593787A
公开(公告)日：1997-01-14
申请号：US548127
申请日：1995-10-25
申请人： Jochen Dauth , Christian Herzig , Bernward Deubzer , Thomas Hierstetter , Petra Gratzl
发明人： Jochen Dauth , Christian Herzig , Bernward Deubzer , Thomas Hierstetter , Petra Gratzl
IPC分类号： B01J31/22 , C07B61/00 , C07F7/08 , C07F7/18 , C08F30/08 , C08G77/14 , C08G77/20 , C08G77/22 , C08G77/38 , C08L83/07 , C09D137/00 , C09D143/04 , C09D183/06 , C09D183/07 , B32B9/04
CPC分类号： C08G77/38 , C08G77/20 , C09D183/06 , Y10T428/31663
摘要： The present invention relates to organosilicon compounds containing (meth)acryloxy groups which can be prepared in a simple manner with high selectivity using readily accessible starting substances. The organopolysiloxanes containing (meth)acryloxy groups rapidly crosslink in the presence of a photoinitiator and light. The compounds of the present invention may be employed in the production of coatings.
摘要翻译：本发明涉及含有（甲基）丙烯酰氧基的有机硅化合物，其可以使用容易获得的起始物质以高选择性以简单的方式制备。含有（甲基）丙烯酰氧基的有机聚硅氧烷在光引发剂和光的存在下迅速交联。本发明的化合物可用于制备涂料。

10. 发明授权

US5523436A Catalysts for hydrosilylation reactions 失效
标题翻译：催化剂用于氢化硅烷化反应
公开(公告)号：US5523436A
公开(公告)日：1996-06-04
申请号：US165136
申请日：1993-12-10
申请人： Jochen Dauth , Udo Peetz , Bernward Deubzer
发明人： Jochen Dauth , Udo Peetz , Bernward Deubzer
IPC分类号： B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07B61/00 , C07C245/22 , C07C245/24 , C07C255/65 , C07F7/04 , C07F7/10 , C07F7/18 , C07F15/00 , C08G81/00 , C08K5/56 , C08L83/04 , C08L83/05 , C08L83/07 , C07F7/08
CPC分类号： C07F15/0013 , B01J31/1608 , B01J31/181 , C07C245/22 , C07C245/24 , C07C255/65 , C07F15/0006 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/0086 , C07F15/0093 , C08L83/04 , B01J2231/323 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , C07C2101/18 , C08G77/08 , C08G77/12 , C08G77/20
摘要： Novel catalysts of the general formulaMX.sub.a Y.sub.b,in whichM is Pt, Pd, Rh, Ru, Os or Ir,X is a triazene, tetrazene, tetrazadiene or pentazadiene ligand,Y is a ligand selected from Cl, Br, I, NH.sub.3, P(C.sub.2 H.sub.5).sub.3, P(C.sub.6 H.sub.5).sub.3, H, CO, 1,5-cyclooctadiene, pyridine, bipyridine, acetate, acetylacetonate, phenylnitrile, ethylenediamine, acetonitrile, 2,5-norbornadiene, nitrate, nitrite, H.sub.2 O, benzene, diphenylphosphinoethane and 1,3-divinyl-1,1,3,3-tetramethyldisiloxane,a is 1, 2, 3 or 4 andb is 0 or an integer from 1 to 6, are described.The catalysts promote the addition of Si-bonded hydrogen onto an aliphatic multiple bond, in which the catalysts are activated by heating at temperatures of 50.degree. to 250.degree. C., by irradiation with light, by addition of Bronsted acids and/or by addition of acid-forming agents.The catalysts are used in addition crosslinking organopolysiloxane compositions and for the reaction of organosilicon compounds containing Si-bonded hydrogen atoms with organic compounds containing aliphatic multiple bonds.
摘要翻译：通式为MXaYb的新型催化剂，其中M为Pt，Pd，Rh，Ru，Os或Ir，X为三氮烯，四唑，四唑或戊二烯配体，Y为选自Cl，Br，I，NH 3， P（C 2 H 5）3，P（C 6 H 5）3，H，CO，1,5-环辛二烯，吡啶，联吡啶，乙酸乙酯，苯基腈，乙二胺，乙腈，2,5-降冰片二烯，硝酸盐，亚硝酸盐，二苯基膦基乙烷和1,3-二乙烯基-1,1,3,3-四甲基二硅氧烷，a为1,2,3或4，b为0或1〜6的整数。催化剂促进将Si键合的氢添加到脂肪族多重键上，其中催化剂通过在50℃至250℃的温度下加热，通过光照射，通过加入布朗斯台德酸和/或通过加成来活化的成酸剂。催化剂用于另外交联的有机聚硅氧烷组合物，并且用于使含有Si键合的氢原子的有机硅化合物与含有脂肪族多键的有机化合物的反应。

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