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1. 发明授权

US06727371B2 Method for converting an organic compound with a hydroperoxide 有权
标题翻译：用氢过氧化物转化有机化合物的方法
公开(公告)号：US06727371B2
公开(公告)日：2004-04-27
申请号：US10240278
申请日：2002-09-30
申请人： Ulrich Müller , Joaquim Henrique Teles , Norbert Rieber , Andreas Walch , Peter Bassler , Alwin Rehfinger , Anne Wenzel , Wolfgang Harder
发明人： Ulrich Müller , Joaquim Henrique Teles , Norbert Rieber , Andreas Walch , Peter Bassler , Alwin Rehfinger , Anne Wenzel , Wolfgang Harder
IPC分类号： C07D30112
CPC分类号： B01J8/02 , B01J8/0285 , B01J29/90 , B01J2208/021 , B01J2219/00033 , B01J2219/00051 , C07D301/00
摘要： In a continuous process for reacting an organic compound with hydroperoxide in the presence of a catalyst, the reaction is carried out in a reactor assembly comprising at least two reactors connected in parallel.
摘要翻译：在催化剂存在下使有机化合物与氢过氧化物反应的连续方法中，反应在包含至少两个平行连接的反应器的反应器组件中进行。

2. 发明授权

US06673950B1 Method for reacting an organic compound with a hydroperoxide 有权
标题翻译：使有机化合物与氢过氧化物反应的方法
公开(公告)号：US06673950B1
公开(公告)日：2004-01-06
申请号：US10030183
申请日：2002-02-01
申请人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Norbert Rieber , Anne Wenzel , Andreas Walch , Wolfgang Harder
发明人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Norbert Rieber , Anne Wenzel , Andreas Walch , Wolfgang Harder
IPC分类号： C07D30119
CPC分类号： C07D301/12
摘要： In a process for reacting an organic compound with a hydroperoxide using at least one heterogeneous catalyst, both the pH and the temperate of the reaction medium are changed during the reaction
摘要翻译：在使用至少一种非均相催化剂使有机化合物与氢过氧化物反应的方法中，反应介质的pH和温度在反应期间都改变

3. 发明授权

US06518441B2 Method for oxidizing an organic compound containing at least one C-C double bond 有权
标题翻译：氧化含有至少一个C-C双键的有机化合物的方法
公开(公告)号：US06518441B2
公开(公告)日：2003-02-11
申请号：US09424847
申请日：1999-12-06
申请人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Martin Fischer , Stefan Quaiser , Wolfgang Harder , Karsten Eller , Peter Bassler , Anne Wenzel , Gerd Kaibel , Achim Stammer , Jochem Henkelmann , Arnd Böttcher , Joaquim Henrique Teles , Michael Schulz , Gert Treiber
发明人： Georg Heinrich Grosch , Ulrich Müller , Andreas Walch , Norbert Rieber , Martin Fischer , Stefan Quaiser , Wolfgang Harder , Karsten Eller , Peter Bassler , Anne Wenzel , Gerd Kaibel , Achim Stammer , Jochem Henkelmann , Arnd Böttcher , Joaquim Henrique Teles , Michael Schulz , Gert Treiber
IPC分类号： C07D30112
CPC分类号： C07D301/19 , B01J29/90 , B01J38/14 , C07B41/00 , C07D301/12 , Y02P20/584
摘要： A process for oxidizing an organic compound having at least one C—C double bond or a mixture of two or more thereof comprises the following steps: (I) preparing a hydroperoxide, (II) reacting an organic compound having at least one C—C double bond or a mixture of two or more thereof with the hydroperoxide prepared in step (I) in the presence of a zeolite catalyst, (III) regenerating the at least partially deactivated zeolite catalyst used in step (II), and (IV) conducting the reaction of step (II) using a zeolite catalyst containing the catalyst regenerated in step (III).
摘要翻译：氧化具有至少一个CC双键的有机化合物或其两种或多种的混合物的方法包括以下步骤：（I）制备氢过氧化物，（II）使具有至少一个CC双键的有机化合物或在沸石催化剂存在下，在步骤（I）中制备的氢过氧化物的两种或更多种的混合物与再生步骤（II）中使用的至少部分失活的沸石催化剂的（III）反应，和（Ⅳ）进行步骤（II）使用含有在步骤（III）中再生的催化剂的沸石催化剂。

4. 发明授权

US06479680B1 Method for reacting an organic compound with a hydroperoxide 有权
标题翻译：使有机化合物与氢过氧化物反应的方法
公开(公告)号：US06479680B1
公开(公告)日：2002-11-12
申请号：US09762290
申请日：2001-02-07
申请人： Peter Bassler , Wolfgang Harder , Peter Resch , Norbert Rieber , Wilhelm Ruppel , Joaquim Henrique Teles , Andreas Walch , Anne Wenzel , Peter Zehner
发明人： Peter Bassler , Wolfgang Harder , Peter Resch , Norbert Rieber , Wilhelm Ruppel , Joaquim Henrique Teles , Andreas Walch , Anne Wenzel , Peter Zehner
IPC分类号： C07D30112
CPC分类号： C07D301/12 , C07B33/00
摘要： A process for the reaction of an organic compound with a hydroperoxide comprises at least the steps (i) to (iii) below: (i) reaction of the hydroperoxide with the organic compound to give a mixture comprising the reacted organic compound and unreacted hydroperoxide, (ii) separation of the unreacted hydroperoxide from the mixture resulting from step (i), (iii) reaction of the hydroperoxide separated off in step (ii) with the organic compound.
摘要翻译：有机化合物与氢过氧化物反应的方法至少包括以下步骤（i）至（iii）：（i）氢过氧化物与有机化合物的反应，得到包含反应的有机化合物和未反应的氢过氧化物的混合物，（ii）从步骤（i），（iii）中得到的混合物中分离未反应的氢过氧化物，（iii）步骤（ii）中分离出的氢过氧化物与有机化合物的反应。

5. 发明授权

US06958304B2 Method for regenerating a zeolite catalyst 失效
标题翻译：再生沸石催化剂的方法
公开(公告)号：US06958304B2
公开(公告)日：2005-10-25
申请号：US10380070
申请日：2001-09-11
申请人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Anne Wenzel , Norbert Rieber , Ulrich Müller , Peter Rudolf
发明人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Anne Wenzel , Norbert Rieber , Ulrich Müller , Peter Rudolf
IPC分类号： B01J29/89 , B01J29/90 , B01J38/14 , B01J38/04 , B01J20/34 , B01J29/04 , C07D301/12
CPC分类号： B01J29/90 , B01J29/89 , B01J38/14
摘要： A process for the regeneration of a zeolite catalyst which comprises treating the catalyst thermally in the presence of a gas stream at temperatures above 120° C., the weight-based residence time of the gas stream over the catalyst during the thermal treatment being greater than 2 hours.
摘要翻译：一种沸石催化剂再生方法，其包括在温度高于120℃的气流存在下热处理催化剂，在热处理过程中气流在催化剂上的重量停留时间大于 2小时。

6. 发明授权

US06756503B2 Method for the production of propylene oxide 有权
标题翻译：生产环氧丙烷的方法
公开(公告)号：US06756503B2
公开(公告)日：2004-06-29
申请号：US10312862
申请日：2003-01-02
申请人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Anne Wenzel , Norbert Rieber , Peter Rudolf
发明人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Anne Wenzel , Norbert Rieber , Peter Rudolf
IPC分类号： C07D30112
CPC分类号： C07D301/12 , Y02P20/582
摘要： A process for the preparation of propylene oxide in which (i) propene is reacted with hydrogen peroxide in the presence of methanol to give propylene oxide, giving a mixture (Gi) comprising propylene oxide, methanol, water and unreacted hydrogen peroxide, (ii) a mixture (Gii) comprising methanol, water and hydrogen peroxide is separated off from the mixture (Gi), giving a mixture (Ga) comprising propylene oxide, and (iii) water is separated off from the mixture (Gii), giving a mixture (Giii) comprising methanol and methyl formate.
摘要翻译：一种制备环氧丙烷的方法，其中（i）丙烯在甲醇存在下与过氧化氢反应得到环氧丙烷，得到包含环氧丙烷，甲醇，水和未反应的过氧化氢的混合物（Gi），（ii）从混合物（Gi）中分离出包含甲醇，水和过氧化氢的混合物（Gii），得到包含环氧丙烷的混合物（Ga），和（iii）从混合物（Gii）中分离出水，得到混合物（Giii），其包含甲醇和甲酸甲酯。

7. 发明授权

US06790969B2 Method for regenerating a zeolite catalyst 有权
标题翻译：再生沸石催化剂的方法
公开(公告)号：US06790969B2
公开(公告)日：2004-09-14
申请号：US10363407
申请日：2003-03-04
申请人： Ulrich Müller , Joaquim Henrique Teles , Anne Wenzel , Wolfgang Harder , Peter Rudolf , Alwin Rehfinger , Peter Ba&bgr;ler , Norbert Rieber
发明人： Ulrich Müller , Joaquim Henrique Teles , Anne Wenzel , Wolfgang Harder , Peter Rudolf , Alwin Rehfinger , Peter Ba&bgr;ler , Norbert Rieber
IPC分类号： C07D30112
CPC分类号： C07D301/12 , B01J29/89 , B01J29/90 , Y02P20/584
摘要： A process for regenerating a zeolite catalyst comprises thermal treatment of the catalyst at above 120° C. in the presence of a gas stream comprising hydrogen.
摘要翻译：用于再沸沸石催化剂的方法包括在包含氢的气流的存在下，在120℃以上热处理催化剂。

8. 发明授权

US06712942B2 Working up a mixture comprising alkene and oxygen 有权
标题翻译：处理包含烯烃和氧气的混合物
公开(公告)号：US06712942B2
公开(公告)日：2004-03-30
申请号：US10169102
申请日：2002-07-12
申请人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Norbert Rieber , Werner Hefner , Anne Wenzel , Peter Rudolf
发明人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Norbert Rieber , Werner Hefner , Anne Wenzel , Peter Rudolf
IPC分类号： B01D3140
CPC分类号： C07D301/12 , Y02P20/582
摘要： A mixture (M1) comprising an alkene and oxygen is worked up by a process in which (i) oxygen is removed from the mixture (M1) by a nondistillative method to give a mixture (M2) and (ii) the alkene is separated off from the mixture (M2) by distillation.
摘要翻译：包括烯烃和氧气的混合物（M1）通过以下方法处理：其中（i）通过非填充方法从混合物（M1）中除去氧气，得到混合物（M2）和（ii）将烯烃分离从混合物（M2）通过蒸馏。

9. 发明授权

US06849162B2 Method for the production of propylene oxide 有权
标题翻译：生产环氧丙烷的方法
公开(公告)号：US06849162B2
公开(公告)日：2005-02-01
申请号：US10312884
申请日：2001-07-05
申请人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Anne Wenzel , Norbert Rieber , Peter Rudolf
发明人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Anne Wenzel , Norbert Rieber , Peter Rudolf
IPC分类号： C07D301/12 , C07D301/32 , B01D3/34 , C07C27/28
CPC分类号： C07D301/32 , C07D301/12 , Y10S203/22 , Y10S203/24
摘要： A process for the preparation of propylene oxide in the presence of methanol, in which propylene oxide is separated from a mixture propylene oxide and methanol, and the resultant methanol containing mixture is worked up, including seperating methanol from a mixture comprising methanol and methyl formate during the work-up.
摘要翻译：在甲醇存在下制备环氧丙烷的方法，其中环氧丙烷与环氧丙烷和甲醇的混合物分离，并且所得到的含甲醇的混合物被处理，包括从包含甲醇和甲酸甲酯的混合物中分离甲醇，上班。

10. 发明授权

US06881853B2 Method for producing propylene oxide 有权
标题翻译：生产环氧丙烷的方法
公开(公告)号：US06881853B2
公开(公告)日：2005-04-19
申请号：US10484204
申请日：2002-07-18
申请人： Joaquim Henrique Teles , Alwin Rehfinger , Anne Berg , Peter Rudolf , Norbert Rieber , Peter Bassler
发明人： Joaquim Henrique Teles , Alwin Rehfinger , Anne Berg , Peter Rudolf , Norbert Rieber , Peter Bassler
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/582
摘要： A process for preparing propylene oxide comprises at least the following steps: (a) propene is reacted with a hydroperoxide in a solvent in the presence of a zeolite catalyst to give a mixture (M0), where the mixture (M0) comprises propylene oxide, solvent, unreacted propene, unreacted hydroperoxide and oxygen, (b) the propylene oxide is separated from the mixture (M0) so as to give a mixture (M1) which comprises unreacted propene and oxygen, (c) the mixture (M1) is brought into contact with a liquid medium comprising at least a solvent to give the mixtures (M2) and (M3), where the mixture (M3) comprises part of the unreacted propene and oxygen and the mixture (M2) comprises solvent and residual propene, and the mixture (M3) which has been separated off and comprises unreacted propene and oxygen has a ratio of oxygen to propene such that the mixture (M3) is not ignitable, and the mixture (M2) is fed to at least one reaction of propene with hydroperoxide.
摘要翻译：制备环氧丙烷的方法至少包括以下步骤：（a）在沸石催化剂存在下，使丙烯与溶剂中的氢过氧化物反应得到混合物（M 0），其中混合物（M 0）包含丙烯氧化物，溶剂，未反应的丙烯，未反应的氢过氧化物和氧气，（b）将环氧丙烷与混合物（M 0）分离，得到包含未反应的丙烯和氧的混合物（M 1），（c）混合物 M 1）与包含至少一种溶剂的液体介质接触以得到混合物（M 2）和（M 3），其中混合物（M 3）包含部分未反应的丙烯和氧气以及混合物（M 2）包括溶剂和残余丙烯，并且已经分离并包含未反应的丙烯和氧的混合物（M 3）具有氧与丙烯的比例，使得混合物（M 3）不可燃，并且混合物（M 2）进料至丙烯与氢过氧化物的至少一个反应。

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