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    • 2. 发明申请
    • Pigment preparation based on an azo pigment
    • 基于偶氮颜料的颜料制剂
    • US20090305156A1
    • 2009-12-10
    • US11919662
    • 2006-04-20
    • Joachim WeberPatrick HoetzelKarl-Heinz SchweikartFrank Alfter
    • Joachim WeberPatrick HoetzelKarl-Heinz SchweikartFrank Alfter
    • G03G9/09C09B27/00C09D11/02G02C7/10
    • G02B5/223C09B67/0022C09B67/0046C09B67/0086
    • The invention relates to a pigment preparation which contains the mono-azo pigment of formula (1) and 0.1 to 40% by weight, preferably 0.5 to 25% by weight, in particular 1.0 to 17.5% by weight, of a pigment dispersant, in relation to the weight of the mono-azo pigment of formula (I), which is composed of disazo compounds, at least 30% by weight of the disazo compounds forming an asymmetrical disazo compound of formula Y-X-A-X-Z (II), in which A stands for biphenylene, 3,3′-dichlorobiphenylene, 3,3′-dimethoxybiphenylene, 3,3′-dimethylbiphenylene or 2,2′-dichloro-3,3′-dimethoxybiphenylene; X stands for a —NH—CO—CH(COCH3)-N═N—, —N═N—CH(COCH3)-CO—NH— or —N═N— group; Y stands for substituted or unsubstituted phenyl, pyrazolin-5-on-4-yl, 1-phenyl-pyrazolin-5-on-4-yl, 2-hydroxynaphth-1-yl or 2-hydroxy-3-(phenylaminocarbonyl)naphth-1-yl, the substituents being C1-C4-alkyl, C1-C4-alkoxy, nitro, halogen or C1-C4-alkoxycarbonyl and having the meaning of Y, and the compounds being further substituted with a sulphonic acid group present as an ammonium salt.
    • 本发明涉及一种颜料制剂,其包含式(1)的单偶氮颜料和0.1至40重量%,优选0.5至25重量%,特别是1.0至17.5重量%的颜料分散剂, 相对于由双偶氮化合物组成的式(I)单偶氮颜料的重量,至少30重量%的形成式YXAXZ(II)的不对称双偶氮化合物的双偶氮化合物,其中A代表 亚联苯基,3,3'-二氯联苯,3,3'-二甲氧基联苯,3,3'-二甲基联苯或2,2'-二氯-3,3'-二甲氧基联苯; X代表-NH-CO-CH(COCH 3)-N-N-,-N-N-CH(COCH 3)-CO-NH-或-N-N-基; Y代表取代或未取代的苯基,吡唑啉-5-酮,1-苯基 - 吡唑啉-5-酮,2-羟基萘-1-基或2-羟基-3-(苯基氨基羰基)萘 取代基是C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,硝基,卤素或C 1 -C 4 - 烷氧基羰基并且具有Y的含义,并且该化合物进一步被存在的磺酸基团取代 铵盐。
    • 3. 发明授权
    • Pigment preparation based on an azo pigment
    • 基于偶氮颜料的颜料制剂
    • US07855041B2
    • 2010-12-21
    • US11919662
    • 2006-04-20
    • Joachim WeberPatrick HoetzelKarl-Heinz SchweikartFrank Alfter
    • Joachim WeberPatrick HoetzelKarl-Heinz SchweikartFrank Alfter
    • G03G9/09C09B27/00C09D11/02G02C7/10
    • G02B5/223C09B67/0022C09B67/0046C09B67/0086
    • The invention relates to a pigment preparation which contains the monoazo pigment of the formula (I) and 0.1% to 40%, preferably 0.5% to 25%, in particular 1.0% to 17.5% of a pigment dispersant, in relation to the weight of the monoazo pigment of the formula (I), which is composed of disazo compounds at least 30% of the diazo compounds forming an asymmetric disazo compound of the formula (II) Y-X-A-X-Z  (II), in which A is biphenylene, 3,3′-dichlorobiphenylene, 3,3′-dimethoxybiphenylene, 3,3′-dimethylbiphenylene or 2,2′-dichloro-3,3′-dimethoxybiphenylene; X is a group —NH—CO—CH(COCH3)—N═N—, —N═N—CH(COCH3)—CO—NH—or —N═N—; Y is substituted or unsubstituted phenyl, pyrazolin-5-on-4-yl, 1-phenyl-Pyrazolin -5-on-4-Lyl, 2-hydroxynaphth-1-yl or 2-hydroxy-3-(phenylamino-carbonyl) naphth-1-yl, the substituents being C1-C4 alkyl, C1-C4 alkoxy, nitro, halogen or C1-C4 alkoxycarbonyl, and have the meaning of Y, and the compounds being further substituted with a sulfonic acid group present as an ammonium salt. Y stands for substituted or unsubstituted phenyl, pyrazolin-5-on-4-yl, 1-phenyl-pyrazolin-5-on-4-yl, 2-hydroxynaphth-1-yl or 2-hydroxy-3-(phenylaminocarbonyl)naphth-1-yl, the substituents being C1-C4-alkyl, C1-C4-alkoxy, nitro, halogen or C1-C4-alkoxycarbonyl and having the meaning of Y, and the compounds being further substituted with a sulphonic acid group present as an ammonium salt.
    • 本发明涉及一种颜料制剂,其含有式(I)的单偶氮颜料和0.1%至40%,优选0.5%至25%,特别是1.0%至17.5%的颜料分散剂,相对于 式(I)的单偶氮颜料由双偶氮化合物组成,至少30%的重氮化合物形成式(II)YXAXZ(II)的不对称双偶氮化合物,其中A为联苯,3,3' 二氯联苯,3,3'-二甲氧基联苯,3,3'-二甲基联苯或2,2'-二氯-3,3'-二甲氧基联苯; X是基团-NH-CO-CH(COCH 3)-N = N-,-N = N-CH(COCH 3)-CO-NH-或-N = N- Y是取代或未取代的苯基,吡唑啉-5-酮,1-苯基 - 吡唑啉-5-酮-4-基,2-羟基萘-1-基或2-羟基-3-(苯基氨基 - 羰基) 萘-1-基,取代基为C 1 -C 4烷基,C 1 -C 4烷氧基,硝基,卤素或C 1 -C 4烷氧基羰基,并且具有Y的含义,并且化合物进一步被作为铵存在的磺酸基取代 盐。 Y代表取代或未取代的苯基,吡唑啉-5-酮,1-苯基 - 吡唑啉-5-酮,2-羟基萘-1-基或2-羟基-3-(苯基氨基羰基)萘 取代基是C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,硝基,卤素或C 1 -C 4 - 烷氧基羰基并且具有Y的含义,并且该化合物进一步被存在的磺酸基团取代 铵盐。
    • 10. 发明授权
    • Isoindoline pigments based on aminoquinoxalinediones
    • 基于氨基喹喔啉的异吲哚啉颜料
    • US5716446A
    • 1998-02-10
    • US643593
    • 1996-05-06
    • Frank AlfterRudiger JungGustav Kapaun
    • Frank AlfterRudiger JungGustav Kapaun
    • C09B55/00C09B57/04C09B67/20C09D7/12C09D11/00
    • C09B57/04
    • Novel isoindoline pigments of the formula (I): ##STR1## in which R.sup.1 is --CN; R.sup.2 is --CN or a saturated or unsaturated, aromatic or non-aromatic, 5- to 7-membered heterocyclic ring system which can be modified by fusion or bridging with other heterocyclic or isocyclic ring systems, the heteroatoms being N, O and/or S; or a group --CO--NR.sup.6 R.sup.7, in which R.sup.6 and R.sup.7 are identical or different and are hydrogen or C.sub.1 -C.sub.4 -alkyl; or a group --CO--NR.sup.6 R.sup.8, in which R.sup.8 is a saturated or unsaturated, aromatic or non-aromatic, 5- to 7-membered isocyclic or heterocyclic ring which is unsubstituted or substituted by one to 5 of the following radicals: C.sub.1 -C.sub.4 -alkyl, halogen, trifluoromethyl, C.sub.1 -C.sub.4 -alkoxy, carbomethoxy, carbethoxy, carboxamide, carboxamide substituted by a C.sub.1 -C.sub.4 -alkyl or phenyl group, nitro, C.sub.1 -C.sub.4 -acylamino or hydroxyl, and which can be modified by fusion or bridging with other heterocyclic or isocyclic ring systems, the heteroatoms being N, O and/or S; or in which R.sup.1 and R.sup.2 together are a saturated or unsaturated, aromatic or non-aromatic, 5- to 7-membered heterocyclic ring which is unsubstituted or substituted by one to 5 of the following radicals: C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, halogen, trifluoromethyl, carbomethoxy, carbethoxy, carboxamide, carboxamide substituted by a C.sub.1 -C.sub.4 -alkyl or phenyl group, C.sub.1 -C.sub.4 -acylamino or hydroxyl, and which can be modified by fusion or bridging with other heterocyclic or isocyclic ring systems, the heteroatoms being N, O and/or S; the radicals R.sup.3 and R.sup.4 are identical or different and are defined as follows: R.sup.3 is hydrogen, C.sub.1 -C.sub.4 -alkyl, phenyl, C.sub.1 -C.sub.4 -alkoxy, halogen or C.sub.1 -C.sub.4 -acylamino; R.sup.4 is hydrogen, C.sub.1 -C.sub.4 -alkyl, halogen, trifluoromethyl, methoxy, ethoxy or nitro; m is a number from 1 to 4; n is a number from 1 to 3; and R.sup.5 is hydrogen or C.sub.1 -C.sub.4 -alkyl.
    • 式(I)的新型异吲哚啉颜料:其中R 1是-CN; R 2是-CN或饱和或不饱和的芳族或非芳族的5至7元杂环体系,其可以通过与其它杂环或环状环体系的融合或桥接进行修饰,杂原子是N,O和/或 S; 或基团-CO-NR 6 R 7,其中R 6和R 7相同或不同,为氢或C 1 -C 4 - 烷基; 或基团-CO-NR 6 R 8,其中R 8是饱和或不饱和的芳族或非芳族的5至7元环或未被取代或被1至5个以下基团取代的环或杂环:C 1 -C 4 - 烷基,卤素,三氟甲基,C 1 -C 4 - 烷氧基,甲酯基,乙酯基,甲酰胺,被C 1 -C 4 - 烷基或苯基取代的甲酰胺,硝基,C 1 -C 4酰基氨基或羟基, 与其他杂环或环状环系桥连,杂原子为N,O和/或S; 或其中R 1和R 2一起是饱和或不饱和的芳族或非芳族的5至7元杂环,其未被取代或被1至5个以下基团取代:C 1 -C 4烷基,C 1 -C 4 - 烷氧基,卤素,三氟甲基,甲酯基,乙酯基,甲酰胺,被C 1 -C 4 - 烷基或苯基取代的甲酰胺,C 1 -C 4 - 酰基氨基或羟基,并且可以通过与其它杂环或环状环系 ,杂原子为N,O和/或S; 基团R 3和R 4相同或不同,定义如下:R 3是氢,C 1 -C 4 - 烷基,苯基,C 1 -C 4 - 烷氧基,卤素或C 1 -C 4酰氨基; R4是氢,C1-C4-烷基,卤素,三氟甲基,甲氧基,乙氧基或硝基; m是从1到4的数字; n是从1到3的数字; 并且R 5是氢或C 1 -C 4 - 烷基。