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    • 6. 发明申请
    • Olefin Oligomerization
    • 烯烃低聚
    • US20060199987A1
    • 2006-09-07
    • US11342000
    • 2006-01-27
    • Keith KuechlerStephen BrownAn VerberckmoesMarc PuttemansSteven Silverberg
    • Keith KuechlerStephen BrownAn VerberckmoesMarc PuttemansSteven Silverberg
    • C07C2/02
    • C10G50/00C07C2/12C07C11/02
    • A process for producing a hydrocarbon composition that comprises contacting a feed stream, that comprises at least one C3 to C8 olefin, and an olefinic recycle stream, that comprises a first olefinic recycle stream and no more than 10 wt % of C10+ non-normal olefins, with a molecular sieve catalyst in a reaction zone under olefin oligomerization conditions producing an oligomerization effluent stream; separating the oligomerization effluent stream to produce a first olefinic stream, that has a weight ratio of C4−/(C5-C8) molecules from about 0.8 to about 1.2 times the weight ratio of C4−/(C5-C8) molecules found in the oligomerization effluent stream, and a first hydrocarbon product stream, that comprises at least 1 wt % and no more than 30 wt % of C9 non-normal olefin; and splitting the first olefinic stream to produce the first olefinic recycle stream and a first purge stream.
    • 一种用于生产烃组合物的方法,其包括将包含至少一种C 3 -C 30至C 8 O 12烯烃的进料流与烯烃再循环料流接触,所述烯烃再循环料流包含第一 烯烃再循环料流和不超过10重量%的C 10 N +非正常烯烃,在烯烃低聚条件下在反应区中分子筛催化剂产生低聚流出物流; 分离低聚流出物流以产生第一烯烃流,其具有C 4 - /(C 5 -C 8) - 重量比的重量比, 分子在低聚流出物中发现的C 4 - /(C 5 -C 8 N)重量比的约0.8至约1.2倍 流和第一烃产物流,其包含至少1重量%且不超过30重量%的C 9不正规烯烃; 和分裂第一烯烃流以产生第一烯烃再循环流和第一吹扫流。