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1. 发明授权

US5856045A Lithium ion electrolytic cell and method for fabricating same 失效
标题翻译：锂离子电解槽及其制造方法
公开(公告)号：US5856045A
公开(公告)日：1999-01-05
申请号：US747778
申请日：1996-11-13
申请人： Denis G. Fauteux , Jie Shi , Arthur A. Massucco
发明人： Denis G. Fauteux , Jie Shi , Arthur A. Massucco
IPC分类号： H01M4/13 , H01M4/62 , H01M10/0525
CPC分类号： H01M4/13 , H01M4/621 , H01M10/0525 , H01M4/62 , Y10T29/49115
摘要： The present invention relates to secondary electrolytic cells, and more particularly, to lithium ion electrolytic cells with an inorganic binder and an associated process for fabrication of same. A binder material is mixed with an active material for eventual application onto the surface of a first and/or second electrode. The binder material is soluble with the active material yet insoluble with respect to the associated organic electrolyte.
摘要翻译：本发明涉及二次电解池，特别涉及具有无机粘合剂的锂离子电解槽及其制造方法。将粘合剂材料与活性材料混合以最终施加到第一和/或第二电极的表面上。粘合剂材料可与活性材料溶解，并且相对于相关的有机电解质不溶。

2. 发明授权

US5591544A Current collector device 失效
标题翻译：集电器设备
公开(公告)号：US5591544A
公开(公告)日：1997-01-07
申请号：US399192
申请日：1995-03-06
申请人： Denis G. Fauteux , Arthur A. Massucco , Ronnie D. Wilkins , Jie Shi
发明人： Denis G. Fauteux , Arthur A. Massucco , Ronnie D. Wilkins , Jie Shi
IPC分类号： H01M4/66 , H01M4/64
CPC分类号： H01M4/667 , H01M4/66 , H01M4/661 , Y10T29/49115
摘要： A current collector device for a rechargeable electrolytic cell and method for manufacturing same. The device includes an aluminum current collector having a substantially reduced oxidation layer relative to its native oxide layer, to, in turn, exhibit a relatively low interfacial impedance. A layer of electrode material is applied and adhered to the surface of the aluminum current collector to enable electrochemical activity with the particular ions in an electrolyte within the electrolytic cell. A primer may be applied between the electrode material and the aluminum current collector, wherein the primer serves to substantially preclude re-growth of the oxide layer which would otherwise occur absent such a primer.
摘要翻译：一种用于可再充电电解池的集流装置及其制造方法。该器件包括相对于其天然氧化物层具有显着减小的氧化层的铝集电器，进而显示相对低的界面阻抗。施加电极材料层并将其粘附到铝集电器的表面上，以使电解池中的电解质中的特定离子具有电化学活性。可以在电极材料和铝集电器之间施加底漆，其中底漆用于基本排除氧化层的再生长，否则这种底漆将不会发生。

3. 发明授权

US5588971A Current collector device and method of manufacturing same 失效
标题翻译：集电器件及其制造方法
公开(公告)号：US5588971A
公开(公告)日：1996-12-31
申请号：US325994
申请日：1994-10-19
申请人： Denis G. Fauteux , Arthur A. Massucco , Ronnie D. Wilkins , Jie Shi
发明人： Denis G. Fauteux , Arthur A. Massucco , Ronnie D. Wilkins , Jie Shi
IPC分类号： H01M4/66 , H01M4/04
CPC分类号： H01M4/667 , H01M4/66 , H01M4/661 , Y10T29/49115
摘要： A current collector device for a rechargeable electrolytic cell and method for manufacturing same. The device includes an aluminum current collector having a substantially reduced oxidation layer relative to its native oxide layer, to, in turn, exhibit a relatively low interfacial impedance. A layer of electrode material is applied and adhered to the surface of the aluminum current collector to enable electrochemical activity with the particular ions in an electrolyte within the electrolytic cell. A primer may be applied between the electrode material and the aluminum current collector, wherein the primer serves to substantially preclude re-growth of the oxide layer which would otherwise occur absent such a primer.
摘要翻译：一种用于可再充电电解池的集流装置及其制造方法。该器件包括相对于其天然氧化物层具有显着减小的氧化层的铝集电器，进而显示相对低的界面阻抗。施加电极材料层并将其粘附到铝集电器的表面上，以使电解池中的电解质中的特定离子具有电化学活性。可以在电极材料和铝集电器之间施加底漆，其中底漆用于基本排除氧化层的再生长，否则这种底漆将不会发生。

4. 发明授权

US5580686A Electrolytic cell and electrolytic process 失效
标题翻译：电解池和电解过程
公开(公告)号：US5580686A
公开(公告)日：1996-12-03
申请号：US542710
申请日：1995-10-13
申请人： Jie Shi , Arthur A. Massucco , Denis G. Fauteux
发明人： Jie Shi , Arthur A. Massucco , Denis G. Fauteux
IPC分类号： H01M4/62 , H01M4/02 , H01M4/66 , H01M10/40
CPC分类号： H01M4/664 , H01M4/66
摘要： An electrolytic cell having an electrolyte, a first and second electrode and a primer comprised of lithium polysilicate and carbon, applied to at least one of the first and second electrodes, wherein the primer is chemically and electrochemically stable and electronically conductive so as to decrease interfacial resistance in the cell to enhance columbic efficiency.
摘要翻译：一种具有电解质，第一和第二电极以及由聚硅酸锂和碳构成的底漆的电解槽，其被施加到第一和第二电极中的至少一个，其中底漆是化学和电化学稳定的并且是电子导电的，以便降低界面细胞中的抗性提高了突变效率。

5. 发明授权

US6030719A Lithium ion electrolytic cell having a controlled electrode surface interface 有权
标题翻译：具有受控电极表面界面的锂离子电解槽
公开(公告)号：US6030719A
公开(公告)日：2000-02-29
申请号：US136986
申请日：1998-08-20
申请人： Denis G. Fauteux , Jie Shi , Kazuko Otani , Eitaro Takahashi , Kenji Okahara
发明人： Denis G. Fauteux , Jie Shi , Kazuko Otani , Eitaro Takahashi , Kenji Okahara
IPC分类号： H01M4/02 , H01M2/02 , H01M4/04 , H01M4/62 , H01M4/66 , H01M6/16 , H01M10/38 , H01M10/40 , H01M10/42 , H01M10/44 , H01M10/52
CPC分类号： H01M4/62 , H01M10/0525 , H01M10/058 , H01M4/0442 , H01M4/66 , H01M4/661 , H01M10/4235 , H01M10/446 , H01M10/52 , H01M2/0275 , H01M2002/0205 , H01M6/168
摘要： The present invention is directed to a lithium ion electrolytic cell having a controlled electrode surface interface, and, an associated electrochemical process. The lithium ion electrolytic cell includes an electrode with a carbonaceous surface and a passivating layer, and, an electrolyte having a solvent. The passivating layer includes lithium, carbon and at least one of an additive or the product of interaction of the additive with the carbonaceous surface. The passivating layer has, as measured by X-ray photoelectron spectroscopy, a relative thickness index within the range of about from 10 to about 90, and a lithium ion content index in the range from about 0.1 to about 0.7.
摘要翻译：本发明涉及具有受控电极表面界面的锂离子电解槽，以及相关联的电化学工艺。锂离子电解槽包括具有碳质表面的电极和钝化层，以及具有溶剂的电解质。钝化层包括锂，碳和添加剂或添加剂与碳质表面的相互作用的产物中的至少一种。通过X射线光电子能谱测定，钝化层的相对厚度指数在约10至约90的范围内，锂离子含量指数在约0.1至约0.7的范围内。

6. 发明授权

US5853917A Electrolytic cell having a controlled electrode surface interface 失效
标题翻译：具有受控电极表面界面的电解槽
公开(公告)号：US5853917A
公开(公告)日：1998-12-29
申请号：US812021
申请日：1997-03-06
申请人： Denis G. Fauteux , Jie Shi
发明人： Denis G. Fauteux , Jie Shi
IPC分类号： H01M2/02 , H01M4/62 , H01M4/66 , H01M6/16 , H01M10/0525 , H01M10/058 , H01M10/42 , H01M10/44 , H01M10/52 , H01M6/14
CPC分类号： H01M10/0525 , H01M10/058 , H01M4/0442 , H01M4/62 , H01M4/66 , H01M4/661 , H01M10/4235 , H01M10/446 , H01M10/52 , H01M2/0275 , H01M2002/0205 , H01M6/168
摘要： The present invention is directed to an electrolytic cell having a controlled electrode surface interface, and, an associated manufacturing and chemical process. The electrolytic cell includes an electrode with a carbon surface, and, an electrolyte having a solvent. An additive, associated with at least one of the electrolyte or first and second electrodes, reacts with the carbon surface to form a passivating layer so as to block chemical interaction between the carbon surface and the solvent. Furthermore, the additive will not result in gas formation upon its decomposition.
摘要翻译：本发明涉及具有受控电极表面界面的电解池，以及相关的制造和化学过程。电解槽包括具有碳表面的电极和具有溶剂的电解质。与电解质或第一和第二电极中的至少一个相关联的添加剂与碳表面反应以形成钝化层，以阻止碳表面和溶剂之间的化学相互作用。此外，添加剂在分解时不会导致气体形成。

7. 发明授权

US5503946A Particulate interface for electrolytic cells and electrolytic process 失效
标题翻译：电解槽细胞界面和电解过程
公开(公告)号：US5503946A
公开(公告)日：1996-04-02
申请号：US314878
申请日：1994-09-29
申请人： Denis G. Fauteux , Jie Shi , Richard Gary
发明人： Denis G. Fauteux , Jie Shi , Richard Gary
IPC分类号： H01M4/13 , H01M10/05 , H01M10/052 , H01M10/0565 , H01M4/62
CPC分类号： H01M10/052 , H01M10/05 , H01M10/0565 , H01M4/0452 , H01M4/13 , Y10T29/49115
摘要： An electrolytic cell and electrolytic process wherein the cell includes a metal anode, such as a lithium anode, a cathode and an electrolyte. The surface of the anode is treated with a substantially non-continuous electronically conductive particulate coating, wherein the particulate may consist of carbon. This non-continuously applied particulate coating not only provokes the formation of a stable passivating layer (toward suppression of dendritic growth), but it also serves to lower and substantially sustain interfacial resistance at the surface of the anode during the life of the cell.
摘要翻译：一种电解池和电解方法，其中电池包括金属阳极，例如锂阳极，阴极和电解质。阳极的表面用基本不连续的电子导电颗粒涂层处理，其中颗粒可以由碳组成。这种非连续施加的颗粒涂层不仅引起形成稳定的钝化层（朝向抑制树枝状生长），而且还用于在电池寿命期间降低并基本上维持阳极表面的界面电阻。

8. 发明授权

US5434021A Secondary electrolytic cell and electrolytic process 失效
标题翻译：二次电解池和电解过程
公开(公告)号：US5434021A
公开(公告)日：1995-07-18
申请号：US290017
申请日：1994-08-12
申请人： Denis G. Fauteux , Martin Van Buren , Jie Shi , Mehmet Rona
发明人： Denis G. Fauteux , Martin Van Buren , Jie Shi , Mehmet Rona
IPC分类号： H01M4/62 , H01M4/13 , H01M10/00 , H01M10/05 , H01M10/12 , H01M4/60
CPC分类号： H01M10/05 , H01M4/13
摘要： An electrolytic cell and electrolytic process wherein the cell includes a metal anode (such as a lithium anode), a cathode and an electrolyte. A surface layer which is applied to the metal anode enables transfer of ions from the metal anode to the electrolyte and thus allows the ions to pass back into contact with the metal anode. The surface layer is also electronically conductive so that the ions will be uniformally attracted back onto the metal anode during electrodeposition to, in turn, substantially suppress dendrite growth and, in turn, substantially increase the cycle life of the cell.
摘要翻译：一种电解槽和电解工艺，其中电池包括金属阳极（例如锂阳极），阴极和电解质。施加到金属阳极的表面层能够将离子从金属阳极转移到电解质，从而允许离子返回与金属阳极接触。表面层也是电子导电的，使得在电沉积期间离子将均匀地吸引回到金属阳极上，从而基本上抑制枝晶生长，并且进而显着增加电池的循环寿命。

9. 发明授权

US5604056A Electrolytic cell and process for treating an alkali metal electrode 失效
标题翻译：电解槽及碱金属电极处理工艺
公开(公告)号：US5604056A
公开(公告)日：1997-02-18
申请号：US438242
申请日：1995-05-09
申请人： Denis G. Fauteux , Martin Van Buren , Jie Shi
发明人： Denis G. Fauteux , Martin Van Buren , Jie Shi
IPC分类号： H01M2/16 , H01M4/13 , H01M4/62 , H01M10/05 , H01M10/0567 , H01M4/60
CPC分类号： H01M10/0567 , H01M10/05 , H01M4/13 , H01M4/62
摘要： An electrolytic cell and process for treating an alkali metal electrode, wherein an additive is applied to the electrode so as to result in a predominately additive interface between the electrode and an electrolyte. The additive interface is ionically conductive yet non-ionic. In addition, the additive interface is substantially inert when in contact with the electrode, while being substantially insoluble in the electrolyte.
摘要翻译：一种电解池和碱金属电极处理方法，其中向电极施加添加剂以便在电极和电解质之间形成主要的添加界面。添加剂界面是离子导电的而非离子的。此外，当与电极接触时，添加剂界面基本上是惰性的，而基本上不溶于电解质。

10. 发明授权

US5547778A Cavitand electrolytic cell and electrolytic process 失效
标题翻译： Cavitand电解槽和电解过程
公开(公告)号：US5547778A
公开(公告)日：1996-08-20
申请号：US502109
申请日：1995-07-13
申请人： Denis G. Fauteux , Martin Van Buren , Jie Shi
发明人： Denis G. Fauteux , Martin Van Buren , Jie Shi
IPC分类号： H01M4/40 , H01M4/38 , H01M10/05 , H01M10/0567 , H01M10/24 , H01M2/38
CPC分类号： H01M10/0567 , H01M10/05 , H01M4/02 , H01M4/381 , H01M10/24
摘要： An electrolytic cell, such as a rechargeable lithium battery, having cavitands associated with a metal ion source-electrode and an electrolyte. The cavitands, which are anchored to the electrode by a polymer leash, are capable of releasably attracting particular ions, such as lithium ions, which are migrating from the electrolyte, toward the surface of the electrode during electrodeposition. The polymer leash serves to continuously maintain the cavitands at a predetermined distance away from the surface of the electrode, regardless of surface area fluctuations, typically caused during deposition and dissolution of the particular ions. Accordingly, the cavitands facilitate substantially uniform electrodeposition of the particular ions, which, in turn, substantially suppresses and/or controls the formation and growth of a passive film or layer, on the electrode surface, which may otherwise promote the formation of dendrites.
摘要翻译：具有与金属离子源电极和电解质相关联的空穴的诸如可再充电锂电池的电解池。通过聚合物皮带锚定到电极的空穴能够在电沉积期间释放地吸引从电解质迁移到电极表面的特定离子，例如锂离子。聚合物带用于将空穴连续地保持在离电极表面预定距离处，而不管通常在特定离子的沉积和溶解期间引起的表面积波动。因此，空穴促进了特定离子的基本上均匀的电沉积，其进而基本上抑制和/或控制在电极表面上的钝化膜或层的形成和生长，否则可能促进枝晶的形成。

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