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1. 发明授权

US5348687A M41S materials having nonlinear optical properties 失效
标题翻译：具有非线性光学特性的M41S材料
公开(公告)号：US5348687A
公开(公告)日：1994-09-20
申请号：US157549
申请日：1993-11-26
申请人： Jeffrey S. Beck , Guenter H. Kuehl , David H. Olson , John L. Schlenker , Galen D. Stucky , James C. Vartuli
发明人： Jeffrey S. Beck , Guenter H. Kuehl , David H. Olson , John L. Schlenker , Galen D. Stucky , James C. Vartuli
IPC分类号： G02F1/355 , G02B1/02 , H01L31/0264 , H01L31/0344
CPC分类号： B82Y20/00 , G02F1/3556
摘要： A material exhibiting third order nonlinear optic properties includes quantum size clusters of semiconducting guest material incorporated into the pores of M41S material in an arrangement to provide nonlinear optic properties.A material exhibiting second order nonlinear optic properties includes an organic guest material incorporated into the pores of M41S material so that a non-centrosymmetric structure is formed which will provide second harmonic generation when subjected to electromagnetic radiation of a selected frequency.
摘要翻译：显示三阶非线性光学特性的材料包括结合到M41S材料的孔中的半导体客体材料的量子尺寸簇，以提供非线性光学性质。显示二阶非线性光学性质的材料包括并入M41S材料的孔中的有机载体材料，使得形成非对称中心对称结构，当经受选定频率的电磁辐射时，其将提供二次谐波产生。

2. 发明授权

US5364797A Sensor device containing mesoporous crystalline material 失效
标题翻译：含有介孔结晶材料的传感器装置
公开(公告)号：US5364797A
公开(公告)日：1994-11-15
申请号：US64280
申请日：1993-05-20
申请人： David H. Olson , Galen D. Stucky , James C. Vartuli
发明人： David H. Olson , Galen D. Stucky , James C. Vartuli
IPC分类号： G01N21/77 , G01N27/333 , G01N31/22 , G01N33/00 , G01N33/487 , G01N33/543 , B01J29/00 , C12Q1/00 , G01N21/00 , G01N27/00 , G01N31/00 , G01N33/20 , G01N33/53
CPC分类号： G01N33/54373 , G01N21/648 , G01N21/7703 , G01N31/221 , G01N31/223 , G01N2021/7786 , Y10T436/15 , Y10T436/16 , Y10T436/17 , Y10T436/18 , Y10T436/19 , Y10T436/20 , Y10T436/21
摘要： A sensor device includes ultra-large pore crystalline material M41S as a selective detecting element, and a measuring element for quantifying physical, chemical or biological events which occur within the crystalline material. The crystalline material may also contain an additional selective detecting component within its pores.
摘要翻译：传感器装置包括作为选择性检测元件的超大孔结晶材料M41S和用于量化在结晶材料内发生的物理，化学或生物事件的测量元件。结晶材料还可以在其孔内含有另外的选择性检测组分。

3. 发明授权

US4773987A Shape-selective conversion of organic feedstock using clathrate group tectosilicates 失效
标题翻译：有机原料的形态选择性转化使用包合物组织硅酸盐
公开(公告)号：US4773987A
公开(公告)日：1988-09-27
申请号：US36825
申请日：1987-04-10
申请人： William E. Garwood , John L. Schlenker , James C. Vartuli
发明人： William E. Garwood , John L. Schlenker , James C. Vartuli
IPC分类号： B01J29/40 , B01J29/70 , B01J29/80 , C10G45/64 , C10G65/12 , C10G47/02
CPC分类号： B01J29/80 , C10G45/64 , C10G65/12 , B01J29/40 , B01J29/70
摘要： This invention relates to an efficient process for shape-selective conversion of organic feedstock with a catalyst comprising a Clathrate Group tectosilicate such as ZSM-39 and a highly siliceous, shape selective zeolite such as ZSM-5. In one embodiment, a stabilized, dewaxed lube stock is prepared by catalytically dewaxing a hydrocrackate.
摘要翻译：本发明涉及一种用含有诸如ZSM-39的包合物组合硅酸盐催化剂和高度硅质的形状选择性沸石如ZSM-5的催化剂对有机原料进行形态选择性转化的有效方法。在一个实施方案中，通过催化脱蜡加氢裂化剂制备稳定的脱蜡润滑剂原料。

4. 发明授权

US5264203A Synthetic mesoporous crystalline materials 失效
标题翻译：合成介孔结晶材料
公开(公告)号：US5264203A
公开(公告)日：1993-11-23
申请号：US735224
申请日：1991-07-24
申请人： Jeffrey S. Beck , Charles T. Kresge , Michael E. Leonowicz , Wieslaw J. Roth , James C. Vartuli
发明人： Jeffrey S. Beck , Charles T. Kresge , Michael E. Leonowicz , Wieslaw J. Roth , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , C01B33/34
CPC分类号： B01J29/04 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J29/0308 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： This invention relates to a new synthetic composition of ultra-large pore crystalline material, e.g., [metallo]silicoaluminophosphate, having a composition, expressed on an anhydrous basis as follows:M.sub.n/q (W.sub.a X.sub.b Y.sub.c Z.sub.d O.sub.h)wherein M is one or more ions; n is the charge of the composition excluding M expressed as oxides; q is the weighted molar average valence of M; n/q is the number of moles or mole fraction of M; W is one or more divalent elements; X is one or more trivalent elements; Y is one or more tetravalent elements; Z is one or more pentavalent elements; a, b, c, and d are mole fractions of W, X, Y, and Z, respectively; (a+b+c+d)=1; a .gtoreq. 0; b, c, and d are each>0; and h is a number of from 1 to 2.5. The crystalline material is prepared by i) crystallizing a reaction mixture comprising sources of W, X, Z and an organic directing agent; ii) contacting the product of i) with a reaction mixture comprising sources of Y and organic directing agent; and iii) maintaining the mixture of ii) under conditions sufficient to form said composition of matter. The composition is suited to use for catalytic conversion of organic compounds.
摘要翻译：本发明涉及具有如下无水基础的组成的[金属]硅铝磷酸盐的超大孔结晶材料的新合成组合物：Mn / q（WaXbYcZdOh）其中M是一个或多个离子; n是不含M表示为氧化物的组成的电荷; q是M的加权摩尔平均化合价; n / q是M的摩尔数或摩尔分数; W是一个或多个二价元素; X是一个或多个三价元素; Y是一种或多种四价元素; Z是一种或多种五价元素; a，b，c和d分别为W，X，Y和Z的摩尔分数; （a + b + c + d）= 1; a> / = 0; b，c和d各自> 0; h为1〜2.5的数。晶体材料通过i）使含有W，X，Z和有机导向剂的反应混合物结晶来制备; ii）使i）的产物与包含Y和有机导向剂的反应混合物接触; 和iii）保持ii）的混合物在足以形成所述组合物的条件下。该组合物适用于有机化合物的催化转化。

5. 发明授权

US5246689A Synthetic porous crystalline material its synthesis and use 失效
标题翻译：合成多孔结晶材料的合成与应用
公开(公告)号：US5246689A
公开(公告)日：1993-09-21
申请号：US735240
申请日：1991-07-24
申请人： Jeffrey S. Beck , William S. Borghard , Charles T. Kresge , Michael E. Leonowicz , Wieslaw J. Roth , James C. Vartuli
发明人： Jeffrey S. Beck , William S. Borghard , Charles T. Kresge , Michael E. Leonowicz , Wieslaw J. Roth , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： C10G11/05 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： This invention relates to a composition of matter, e.g., silicoaluminate or metalloaluminosilicate, comprising an inorganic, porous crystalline phase material exhibiting, after calcination, an X-ray diffraction pattern with at least one peak at a d-spacing greater than 1.8 nm and having a benzene adsorption capacity of greater than 15 grams benzene per 100 grams of said material at 6.7 kPa (50 torr) and 25.degree. C. wherein said crystalline phase has a composition expressed as follows:M.sub.n/q (W.sub.a X.sub.b Y.sub.c O.sub.h)wherein M is one or more ions; n is the charge of the composition excluding M expressed as oxides; q is the weighted molar average valence of M; n/q is the number of moles or mole fraction of M; W is one or more divalent elements; X is one or more trivalent elements; Y is one or more tetravalent elements; a, b, and c are mole fractions of W, X, and Y, respectively; h is a number of from 1 to 2.5; (a+b+c)=1; and a, b, and c, are each >0.
摘要翻译：本发明涉及一种物质的组合物，例如硅铝酸盐或金属铝硅酸盐，其包含无机多孔结晶相材料，其在煅烧后表现出具有至少一个d值大于1.8nm的峰的X射线衍射图，并且具有在6.7kPa（50托）和25℃下每100克所述材料苯吸附量大于15克苯。其中所述结晶相的组成如下表示：Mn / q（WaXbYcOh）其中M是一个或更多离子 n是不含M表示为氧化物的组成的电荷; q是M的加权摩尔平均化合价; n / q是M的摩尔数或摩尔分数; W是一个或多个二价元素; X是一个或多个三价元素; Y是一种或多种四价元素; a，b和c分别是W，X和Y的摩尔分数; h是从1到2.5的数字; （a + b + c）= 1; 和a，b和c分别为> 0。

6. 发明授权

US5145816A Method for functionalizing synthetic mesoporous crystalline material 失效
标题翻译：功能合成多孔结晶材料的方法
公开(公告)号：US5145816A
公开(公告)日：1992-09-08
申请号：US718056
申请日：1991-06-20
申请人： Jeffrey S. Beck , David C. Calabro , Sharon B. McCullen , Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
发明人： Jeffrey S. Beck , David C. Calabro , Sharon B. McCullen , Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
IPC分类号： B01J20/10 , B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/06 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C01B39/04 , C01B39/06 , C01B39/48 , C10G11/05 , C10G47/16
CPC分类号： B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J20/3078 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/045 , B01J29/40 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/12 , B01J2229/14 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/40 , B01J2229/42
摘要： A method is described for modifying an ultra-large pore crystalline material by contacting with a treatment composition M'X'Y'.sub.n wherein M' is an element of Groups IIA, IVA, VA, VIA, VIIA, IB, IIB, IVB, VB or VIB; X' is halide, hydride, alkoxide of C.sub.1-6', or acetate; Y' is X or phosphine, sulfide, carbonyl or cyano; and N=1-5. The contacted crystalline material becomes functionalized. The functionalized material is also described and can be used as a sorbent or catalyst component.
摘要翻译：描述了通过与处理组合物M'X'Y'n接触来改性超大孔结晶材料的方法，其中M'是IIA，IVA，VA，VIA，VIIA，IB，IIB，IVB，IVB族的元素， VB或VIB; X'是卤化物，氢化物，C1-6'的醇盐或乙酸盐; Y'是X或膦，硫化物，羰基或氰基; N = 1-5。接触的结晶材料变得官能化。还描述了官能化材料并且可以用作吸附剂或催化剂组分。

7. 发明授权

US5304363A Porous materials 失效
标题翻译：多孔材料
公开(公告)号：US5304363A
公开(公告)日：1994-04-19
申请号：US907941
申请日：1992-07-02
申请人： Jeffrey S. Beck , Charles T. Kresge , Sharon B. McCullen , Wieslaw J. Roth , James C. Vartuli
发明人： Jeffrey S. Beck , Charles T. Kresge , Sharon B. McCullen , Wieslaw J. Roth , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , C01B33/26
CPC分类号： C10G47/16 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/3078 , B01J29/0308 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： There is provided a porous material. A process for preparing this material involves adding an amphiphilic compound to the reaction mixture for preparing a crystalline oxide. The amphiphilic compound may be a quaternary ammonium cationic surfactant. These surfactants may be in the form of lamellar liquid crystals, and may function as templates for the formation of the present mesoporous oxide materials.
摘要翻译：提供多孔材料。制备该材料的方法包括向反应混合物中加入两亲性化合物以制备结晶氧化物。两亲性化合物可以是季铵阳离子表面活性剂。这些表面活性剂可以是层状液晶的形式，并且可以用作形成本中介氧化物材料的模板。

8. 发明授权

US5334368A Synthesis of mesoporous oxide 失效
标题翻译：中孔氧化物的合成
公开(公告)号：US5334368A
公开(公告)日：1994-08-02
申请号：US995215
申请日：1992-12-22
申请人： Jeffrey S. Beck , Kirk D. Schmitt , James C. Vartuli
发明人： Jeffrey S. Beck , Kirk D. Schmitt , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , C01B33/26
CPC分类号： B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/10 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： There is provided a method for synthesizing a new synthetic composition of ultra-large pore crystalline material which can be used as a sorbent or catalyst component for conversion of organic and inorganic compounds. The crystalline material product of this method exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C. This material may have a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units and a hexagonal arrangement of uniformly sized pores with a maximum perpendicular cross section of at least about 13 Angstrom units. The reaction mixture for preparing this material is prepared by forming a solution containing a source of an oxide, followed by adding a gelling reagent to this solution to form a gel.
摘要翻译：提供了一种用于合成可用作有机和无机化合物转化的吸附剂或催化剂组分的超大孔结晶材料的新合成组合物的方法。该方法的结晶材料产品表现出异常大的吸附能力，其在50托和25℃下苯吸附能力大于约15克苯/ 100克。该材料可具有六角形电子衍射图，其可以用大于约18埃单位的d100值和具有至少约13埃单位的最大垂直截面的均匀尺寸孔的六边形排列。用于制备该材料的反应混合物通过形成含有氧化物源的溶液，然后向该溶液中加入胶凝剂形成凝胶来制备。

9. 发明授权

US5220101A Sorption separation over modified synthetic mesoporous crystalline material 失效
标题翻译：改性合成介孔结晶材料的吸附分离
公开(公告)号：US5220101A
公开(公告)日：1993-06-15
申请号：US918322
申请日：1992-07-22
申请人： Jeffrey S. Beck , David C. Calabro , Sharon B. McCullen , Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
发明人： Jeffrey S. Beck , David C. Calabro , Sharon B. McCullen , Bruce P. Pelrine , Kirk D. Schmitt , James C. Vartuli
IPC分类号： B01D53/86 , B01J20/02 , B01J29/03 , B01J29/04 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , C10G47/16
CPC分类号： C10G47/16 , B01D53/8628 , B01J20/041 , B01J20/06 , B01J20/08 , B01J20/103 , B01J20/12 , B01J20/18 , B01J20/3078 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/40 , B01J29/70 , B01J29/82 , B01J29/83 , B01J29/85 , C01B37/00 , C01B37/02 , C01B37/08 , C01B39/00 , C10G11/05 , B01J2229/12 , B01J2229/14 , B01J2229/26 , B01J2229/32 , B01J2229/34 , B01J2229/36 , B01J2229/40 , B01J2229/42
摘要： A process is provided for separating at least one component from a mixture of components which comprises contacting the mixture with a composition comprising a functionalized inorganic, porous, non-layered crystalline phase having uniformly sized pores of at least about 13, e.g., at least about 15, Angstrom Units in diameter.
摘要翻译：提供了用于从组分混合物中分离至少一种组分的方法，其包括使混合物与包含官能化无机，多孔，非层状结晶相的组合物接触，该组合物具有至少约13，例如至少约 15，直径单位。

10. 发明授权

US5143707A Selective catalytic reduction (SCR) of nitrogen oxides 失效
标题翻译：氮氧化物的选择性催化还原（SCR）
公开(公告)号：US5143707A
公开(公告)日：1992-09-01
申请号：US735232
申请日：1991-07-24
申请人： Jeffrey S. Beck , Richard F. Socha , David S. Shihabi , James C. Vartuli
发明人： Jeffrey S. Beck , Richard F. Socha , David S. Shihabi , James C. Vartuli
IPC分类号： B01D53/94 , B01J29/04
CPC分类号： B01J29/04 , B01D53/9418 , B01D2251/2062 , B01D2255/207 , B01D2255/20723
摘要： Emissions of nitrogen oxides (NO.sub.X) to the atmosphere are reduced by treatment of gases containing nitrogen oxides with a reducing agent such as ammonia in the presence of a catalyst containing a mesoporous crystalline catalyst. The mesoporous crystalline catalyst comprises an inorganic, non-layered, porous, crystalline phase aluminosilicate material which exhibits a benzene adsorption capacity of greater than about 15 grams benzene per 100 grams at 50 torr and 25.degree. C. In its preferred catalytic form, the crystalline material has a uniform, hexagonal arrangement of pores with diameters of at least about 13 .ANG. and exhibiting, after calcination, an X-ray diffraction pattern with at least on d-spacing greater than about 18 .ANG. and a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG. which corresponds to at least one peak in the X-ray diffraction pattern.
摘要翻译：在含有介孔结晶催化剂的催化剂存在下，通过用还原剂如氨处理含氮氧化物的气体，可以减少氮氧化物（NO x）向大气中的排放。介孔结晶催化剂包括无机，非层状，多孔，结晶相的硅铝酸盐材料，其在50乇和25℃下表现出大于约15克苯/ 100克的苯吸附能力。在其优选的催化剂形式中，材料具有均匀的六边形排列的直径至少约为13的孔，并且在煅烧之后表现出至少在d-间距大于约18的X射线衍射图和六角形电子衍射图，其可以是用对应于X射线衍射图中的至少一个峰的大于约18的d100值进行索引。

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