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    • 10. 发明授权
    • Water-based release coating containing fluorochemical
    • 含氟化合物的水性防粘涂层
    • US07411020B2
    • 2008-08-12
    • US11027606
    • 2004-12-28
    • James G. CarlsonJohn C. ClarkJames P. DiZioDavid J. KinningRamesh C. KumarChetan P. Jariwala
    • James G. CarlsonJohn C. ClarkJames P. DiZioDavid J. KinningRamesh C. KumarChetan P. Jariwala
    • C09D133/00B32B33/00
    • C09D133/02Y10S525/902Y10T428/14
    • In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.
    • 一方面,本发明提供了一种水性防粘涂料组合物,其包含以下混合物:A.从0.1至约5wt%的氟(甲基)丙烯酸酯(共)聚合物或含有至少一个氟化基团的含氟氨基甲酸酯化合物 具有式 - (CF 2)n CF 3,其中n为1至3的整数; B.约5至约99.9重量%的包含a的反应产物的共聚物。 约40至约70重量%的(甲基)丙烯酸烷基酯,其中烷基含有16至22个碳原子,b。 约3至约20重量%的(甲基)丙烯酸,c。 约20至约40重量%的丙烯腈,以及d。 0至约15重量%的乙烯基单体,除了丙烯腈,其中a。 通过d。 等于100%; 和C.0至约94.9重量%的增量聚合物,其中A.,B.和C.的总和为100%,wt%基于组合物中固体的总量。