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    • 2. 发明申请
    • Synthesis of alkoxylated sucrose esters
    • 烷氧基化蔗糖酯的合成
    • US20060047110A1
    • 2006-03-02
    • US11158355
    • 2005-06-20
    • Jared Schaefer
    • Jared Schaefer
    • C08B31/00
    • C07H15/04C07H1/00C07H13/06C07H15/08
    • A process for the preparation of an alkoxylated sucrose ester including the steps of: forming an initial reaction mixture of a sucrose ester and from about 0.01% to about 5% of a catalyst; and forming an initial reaction product by reacting the initial reaction mixture with an epoxide for a period of time in the range of from about 30 minutes to about 6 hours and at a temperature in the range of from about 80° C. to about 120° C.; wherein the epoxide and the sucrose ester are selected such that a mole ratio of epoxide groups to sucrose hydroxyls is from about 1 to about 100. Useful catalysts include sodium metals, potassium metals, sodium/potassium alloys, and mixtures thereof
    • 一种制备烷氧基化蔗糖酯的方法,包括以下步骤:形成蔗糖酯和约0.01%至约5%催化剂的初始反应混合物; 并通过使初始反应混合物与环氧化物反应约30分钟至约6小时,并且在约80℃至约120℃的温度下反应形成初始反应产物 C。; 其中选择环氧化物和蔗糖酯使得环氧基团与蔗糖羟基的摩尔比为约1至约100.可用的催化剂包括钠金属,金属钾,钠/钾合金及其混合物
    • 7. 发明申请
    • Synthesis of purified, moderately esterified polyol polyester fatty acid compositions
    • 纯化的中等酯化多元醇多酯脂肪酸组合物的合成
    • US20050250941A1
    • 2005-11-10
    • US10841307
    • 2004-05-07
    • Jared Schaefer
    • Jared Schaefer
    • C07H13/02
    • C07H13/02
    • Processes for the preparation of a purified moderately esterified polyol fatty acid polyester composition including the steps of: (a) forming an initial reaction mixture, said initial reaction mixture containing: a polyol portion; a highly esterified polyol fatty acid polyester; a solvent; and, a catalyst, wherein the molar ratio of said polyol portion to said highly esterified polyol polyester is chosen such that the final ratio of total fatty acid esters to total polyol backbones is in the range from about 3.2:1 to about 6.4:1; wherein the molar ratio of said catalyst to said highly esterified polyol polyester is in the range of from about 0.01:1 to about 10:1, and wherein the weight ratio of said solvent to the combined weight of said polyol portion, said highly esterified polyol polyester, and said catalyst is in the range of from about 0.01:1 to about 2:1; and (b) forming an initial reaction product by reacting said initial reaction mixture in an inert atmosphere, in the presence of a sufficient amount of agitation, for a period of time in the range of from about 30 minutes to about 6 hours, and at a temperature in the range of from about 80° C. to about 140° C.
    • 用于制备纯化的中等酯化多元醇脂肪酸聚酯组合物的方法,包括以下步骤:(a)形成初始反应混合物,所述初始反应混合物含有:多元醇部分; 高度酯化的多元醇脂肪酸聚酯; 溶剂; 以及催化剂,其中所述多元醇部分与所述高度酯化的多元醇多酯的摩尔比选择为使得总脂肪酸酯与总多元醇主链的最终比例在约3.2:1至约6.4:1的范围内; 其中所述催化剂与所述高度酯化的多元醇多酯的摩尔比在约0.01:1至约10:1的范围内,并且其中所述溶剂与所述多元醇部分,所述高度酯化的多元醇的总重量的重量比 聚酯,所述催化剂在约0.01:1至约2:1的范围内; 和(b)通过使所述初始反应混合物在惰性气氛中,在足够量的搅拌下,在约30分钟至约6小时的时间内和在 温度范围为约80℃至约140℃。
    • 9. 发明申请
    • Purified, moderately esterified polyol polyester fatty acid compositions
    • 纯化的中等酯化的多元醇多酯脂肪酸组合物
    • US20050250732A1
    • 2005-11-10
    • US10840955
    • 2004-05-07
    • Jared Schaefer
    • Jared Schaefer
    • A61K31/7024
    • C11D3/3757A23L33/26A61K8/498A61Q19/00C11D3/2079
    • Processes for the production of purified, moderately esterified polyol fatty acid polyesters and the compositions derived from those processes. The purified, moderately esterified polyol fatty acid polyesters are particularly well suited for use in a variety of cosmetic, laundry, and industrial lubrication applications. The purified, moderately esterified polyol fatty acid polyester compositions contain: a moderately esterified polyol fatty acid polyester; less than about 5% polyol; less than about 5 ppm of residual solvent; less than about 700 ppm of lower alkyl esters; less than about 2% of a soap and free fatty acid mixture; and less than about 1% of ash; wherein the polyester composition has an acid value of less than about 2; and wherein the polyester composition has a Lovibond Red color of less than about 10.
    • 用于生产纯化的中等酯化的多元醇脂肪酸聚酯的方法和由这些方法衍生的组合物。 纯化的中等酯化的多元醇脂肪酸聚酯特别适用于各种化妆品,洗衣和工业润滑应用。 纯化的中等酯化的多元醇脂肪酸聚酯组合物含有:中等酯化的多元醇脂肪酸聚酯; 少于约5%的多元醇; 小于约5ppm的残留溶剂; 低于约700ppm的低级烷基酯; 少于约2%的皂和游离脂肪酸混合物; 和小于约1%的灰分; 其中所述聚酯组合物的酸值小于约2; 并且其中所述聚酯组合物具有小于约10的Lovibond Red颜色。
    • 10. 发明申请
    • Synthesis of purified, moderately esterified polyol polyester fatty acid compositions
    • 纯化的中等酯化多元醇多酯脂肪酸组合物的合成
    • US20050250731A1
    • 2005-11-10
    • US10840804
    • 2004-05-07
    • Jared Schaefer
    • Jared Schaefer
    • A61K31/7024C07H13/02
    • C07H13/02
    • Processes for the preparation of a purified moderately esterified polyol fatty acid polyester composition including the steps of: forming an initial reaction mixture containing a polyol portion, a highly esterified polyol fatty acid polyester, a moderately esterified polyol fatty acid polyester; and a catalyst; wherein the molar ratio of the polyol portion, highly esterified polyol polyester portion, and moderately esterified polyol polyester portion should be chosen such that the final ratio of total fatty acid esters to total polyol backbones is in the range from about 3.2:1 to about 6.4:1; wherein the molar ratio of said catalyst to said highly esterified polyol polyester is in the range of from about 0.01:1 to about 10:1; and then forming an initial reaction product by reacting the initial reaction mixture in an inert atmosphere, in the presence of a sufficient amount of agitation, for a period of time in the range of from about 30 minutes to about 6 hours, and at a temperature in the range of from about 80° C. to about 140° C.
    • 用于制备纯化的中等酯化多元醇脂肪酸聚酯组合物的方法,包括以下步骤:形成含有多元醇部分,高度酯化的多元醇脂肪酸聚酯,中等酯化的多元醇脂肪酸聚酯的初始反应混合物; 和催化剂; 其中多元醇部分,高度酯化的多元醇酯部分和中等酯化的多元醇多酯部分的摩尔比应当选择为使总脂肪酸酯与总多元醇主链的最终比例在约3.2:1至约6.4的范围内 :1; 其中所述催化剂与所述高度酯化的多元醇多酯的摩尔比在约0.01:1至约10:1的范围内; 然后通过在惰性气氛中,在足够量的搅拌下,将初始反应混合物在约30分钟至约6小时的时间内,在温度下反应形成初始反应产物 在约80℃至约140℃的范围内。