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    • 4. 发明授权
    • Organic recycling with metal addition
    • 有机回收与金属添加
    • US08057569B2
    • 2011-11-15
    • US12847630
    • 2010-07-30
    • Jeffrey C. BurnhamGary L. Dahms
    • Jeffrey C. BurnhamGary L. Dahms
    • C05F7/00C05F11/00C05D9/02
    • C05C3/00C05B7/00C05B17/00C05F3/00C05F5/008
    • The invention is directed to methods for producing a granular nitrogen fertilizer from an organic material comprising adding a metallic salt to said organic material to form a slurry. Preferably the organic material comprises dewatered biosolids and contains water from a scrubber. Metallic salts that can be used comprise a salt of iron, zinc, or a mixture thereof. Preferred iron salts comprises ferric sulfate or ferric oxide, and preferred zinc salts comprises zinc sulfate or zinc oxide. Preferably, the metallic salt is mixed with an acid such as sulfuric acid to form an acidified metal salt. Slurry pH ranges from approximately 2-2.5. The acidified metal salt is added to the organic material in sufficient quantity to lower viscosity of the slurry such that the resulting fluid does not hinder fluid flow during operation. When the metallic salt comprises acidified ferric sulfate or ferrous sulfate, sufficient iron can be present to produce a fertilizer product with 0.1 weight percent to 10 weight percent iron sulfate calculated on a dry weight basis. The invention is also directed to fertilizer products made by the methods of the invention. Preferred products are granules and the metallic salt increases product hardness. Fertilizer granules preferably contain metal that is bioavailable to a plant when used as a fertilizer. Solubility of the metal of the product in water is enhanced, and the product is low staining.
    • 本发明涉及从有机材料制备颗粒状氮肥的方法,包括向所述有机材料中加入金属盐以形成浆料。 优选地,有机材料包括脱水生物固体并含有来自洗涤器的水。 可以使用的金属盐包括铁,锌或其混合物的盐。 优选的铁盐包括硫酸铁或氧化铁,优选的锌盐包括硫酸锌或氧化锌。 优选地,金属盐与酸如硫酸混合以形成酸化的金属盐。 浆液pH范围约2-2.5。 将酸化的金属盐以足够的量加入到有机材料中以降低浆料的粘度,使得所得流体在操作期间不阻碍流体流动。 当金属盐包括酸化的硫酸铁或硫酸亚铁时,可以存在足够的铁以产生以干重计算的0.1重量%至10重量%的硫酸铁的肥料产品。 本发明还涉及通过本发明的方法制备的肥料产品。 优选的产品是颗粒剂,金属盐提高了产品的硬度。 当用作肥料时,肥料颗粒优选含有对植物生物可利用的金属。 产品的金属在水中的溶解度增强,产品染色浅。
    • 6. 发明申请
    • PROCESS FOR TREATING SLUDGE AND MANUFACTURING BIOORGANICALLY-AUGMENTED HIGH NITROGEN-CONTAINING INORGANIC FERTILIZER
    • 处理污泥和生产生物有机高含氮无机肥料的方法
    • US20080230484A1
    • 2008-09-25
    • US12033809
    • 2008-02-19
    • Jeffrey C. BurnhamJames P. CarrGary L. Dahms
    • Jeffrey C. BurnhamJames P. CarrGary L. Dahms
    • C02F1/52C02F1/68C05D11/00
    • C05F5/00C05F3/00C05F7/00Y02A40/205Y02A40/209Y02A40/213Y02P20/145Y02W10/40C05F9/00C05G1/00
    • The invention describes a new method for treating sludge, which can result in the production of high nitrogen organically-augmented inorganic fertilizer that incorporates municipal sludges or biosolids or organic sludges that can compete with traditional fertilizers such as ammonium phosphate, ammonium sulfate and urea on the commodity fertilizer marketplace. The method takes advantage of the thixotropic property of dewatered biosolids or organic sludge to create a pumpable paste-like material from the biosolids or organic sludge that is then treated with an oxidizer to reduce odorant effects and an acid. This mix is then interacted with concentrated sulfuric and or phosphoric acids and an ammonia source or alternatively a hot or molten melt or salt of ammonium sulfate/phosphate to form a fertilizer mix. The present invention controls the heat, atmospheric pressure and retention time of the fertilizer mix in the reaction vessel. When a fertilizer melt is formed ammoniation is subsequently completed by the specific use of vaporized ammonia. The invention can also be an add-on to commercial production of ammonium salts. The fertilizer produced by the present invention contains more than 8 wt. % nitrogen and preferably 15 wt. % nitrogen. The invention is oriented to be tailored to the biosolids production for individual municipal waste treatment plants in order to keep the fertilizer manufacturing plants of the present invention small with a minimization of logistics and liability.
    • 本发明描述了一种用于处理污泥的新方法,其可以产生高氮有机增强的无机肥料,其包含可与传统肥料如磷酸铵,硫酸铵和尿素竞争的市政污泥或生物固体或有机污泥 商品化肥市场。 该方法利用脱水生物固体或有机污泥的触变性质,从生物固体或有机污泥中产生可抽出的糊状材料,然后用氧化剂处理以减少气味效应和酸。 然后将该混合物与浓硫酸和/或磷酸和氨源或热或熔融的熔融物或硫酸铵/磷酸盐形成一种肥料混合物相互作用。 本发明控制肥料混合物在反应容器中的热,大气压力和保留时间。 当形成化肥熔体时,氨化随后通过具体使用蒸发的氨完成。 本发明也可以是商业生产铵盐的附加物。 本发明生产的肥料含有超过8wt。 %氮,优选15wt。 % 氮。 本发明的目标是针对各个城市废物处理厂的生物固体生产进行定制,以便使物流和责任最小化来保持本发明的肥料制造工厂的效果。
    • 8. 发明申请
    • Organic Recycling With Metal Addition
    • 有机回收与金属添加
    • US20100288003A1
    • 2010-11-18
    • US12847630
    • 2010-07-30
    • Jeffrey C. BurnhamGary L. Dahms
    • Jeffrey C. BurnhamGary L. Dahms
    • C05F3/00
    • C05C3/00C05B7/00C05B17/00C05F3/00C05F5/008
    • The invention is directed to methods for producing a granular nitrogen fertilizer from an organic material comprising adding a metallic salt to said organic material to form a slurry. Preferably the organic material comprises dewatered biosolids and contains water from a scrubber. Metallic salts that can be used comprise a salt of iron, zinc, or a mixture thereof. Preferred iron salts comprises ferric sulfate or ferric oxide, and preferred zinc salts comprises zinc sulfate or zinc oxide. Preferably, the metallic salt is mixed with an acid such as sulfuric acid to form an acidified metal salt. Slurry pH ranges from approximately 2-2.5. The acidified metal salt is added to the organic material in sufficient quantity to lower viscosity of the slurry such that the resulting fluid does not hinder fluid flow during operation. When the metallic salt comprises acidified ferric sulfate or ferrous sulfate, sufficient iron can be present to produce a fertilizer product with 0.1 weight percent to 10 weight percent iron sulfate calculated on a dry weight basis. The invention is also directed to fertilizer products made by the methods of the invention. Preferred products are granules and the metallic salt increases product hardness. Fertilizer granules preferably contain metal that is bioavailable to a plant when used as a fertilizer. Solubility of the metal of the product in water is enhanced, and the product is low staining.
    • 本发明涉及从有机材料制备颗粒状氮肥的方法,包括向所述有机材料中加入金属盐以形成浆料。 优选地,有机材料包括脱水生物固体并含有来自洗涤器的水。 可以使用的金属盐包括铁,锌或其混合物的盐。 优选的铁盐包括硫酸铁或氧化铁,优选的锌盐包括硫酸锌或氧化锌。 优选地,金属盐与酸如硫酸混合以形成酸化的金属盐。 浆液pH范围约2-2.5。 将酸化的金属盐以足够的量加入到有机材料中以降低浆料的粘度,使得所得流体在操作期间不阻碍流体流动。 当金属盐包括酸化的硫酸铁或硫酸亚铁时,可以存在足够的铁以产生以干重计算的0.1重量%至10重量%的硫酸铁的肥料产品。 本发明还涉及通过本发明的方法制备的肥料产品。 优选的产品是颗粒剂,金属盐提高了产品的硬度。 当用作肥料时,肥料颗粒优选含有对植物生物可利用的金属。 产品的金属在水中的溶解度增强,产品染色浅。
    • 10. 发明授权
    • Process for treating sludge and manufacturing bioorganically-augmented high nitrogen-containing inorganic fertilizer
    • 污泥处理工艺,生产有机增强高含氮无机肥料
    • US07947104B2
    • 2011-05-24
    • US12033809
    • 2008-02-19
    • Jeffrey C. BurnhamJames P. CarrGary L. Dahms
    • Jeffrey C. BurnhamJames P. CarrGary L. Dahms
    • C05F3/00C05F11/00C05C9/00C05C9/02C05B7/00C05D1/00C05D9/02
    • C05F5/00C05F3/00C05F7/00Y02A40/205Y02A40/209Y02A40/213Y02P20/145Y02W10/40C05F9/00C05G1/00
    • The invention describes a new method for treating sludge, which can result in the production of high nitrogen organically-augmented inorganic fertilizer that incorporates municipal sludges or biosolids or organic sludges that can compete with traditional fertilizers such as ammonium phosphate, ammonium sulfate and urea on the commodity fertilizer marketplace. The method takes advantage of the thixotropic property of dewatered biosolids or organic sludge to create a pumpable paste-like material from the biosolids or organic sludge that is then treated with an oxidizer to reduce odorant effects and an acid. This mix is then interacted with concentrated sulfuric and or phosphoric acids and an ammonia source or alternatively a hot or molten melt or salt of ammonium sulfate/phosphate to form a fertilizer mix. The present invention controls the heat, atmospheric pressure and retention time of the fertilizer mix in the reaction vessel. When a fertilizer melt is formed ammoniation is subsequently completed by the specific use of vaporized ammonia. The invention can also be an add-on to commercial production of ammonium salts. The fertilizer produced by the present invention contains more than 8 wt. % nitrogen and preferably 15 wt. % nitrogen. The invention is oriented to be tailored to the biosolids production for individual municipal waste treatment plants in order to keep the fertilizer manufacturing plants of the present invention small with a minimization of logistics and liability.
    • 本发明描述了一种用于处理污泥的新方法,其可以产生高氮有机增强的无机肥料,其包含可与传统肥料如磷酸铵,硫酸铵和尿素竞争的市政污泥或生物固体或有机污泥 商品化肥市场。 该方法利用脱水生物固体或有机污泥的触变性质,从生物固体或有机污泥中产生可抽出的糊状材料,然后用氧化剂处理以减少气味效应和酸。 然后将该混合物与浓硫酸和/或磷酸和氨源或热或熔融的熔融物或硫酸铵/磷酸盐形成一种肥料混合物相互作用。 本发明控制肥料混合物在反应容器中的热,大气压力和保留时间。 当形成化肥熔体时,氨化随后通过具体使用蒸发的氨完成。 本发明也可以是商业生产铵盐的附加物。 本发明生产的肥料含有超过8wt。 %氮,优选15wt。 % 氮。 本发明的目标是针对各个城市废物处理厂的生物固体生产进行定制,以便使物流和责任最小化来保持本发明的肥料制造工厂的效果。