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    • 1. 发明申请
    • Phase change inks containing curable isocyanate-derived compounds
    • 含有可固化异氰酸酯衍生化合物的相变油墨
    • US20070123642A1
    • 2007-05-31
    • US11289931
    • 2005-11-30
    • Jeffrey BanningJennifer BeleliePeter OdellRina CarliniJule ThomasDonald TitteringtonPaul SmithStephan DrappelChris Wagner
    • Jeffrey BanningJennifer BeleliePeter OdellRina CarliniJule ThomasDonald TitteringtonPaul SmithStephan DrappelChris Wagner
    • C08G18/08
    • C09D11/101C09D11/34
    • Disclosed is a phase change ink comprising a colorant, an initiator, and a phase change ink carrier, said carrier comprising (A) a urethane which is the reaction product of a mixture comprising (1) an isocyanate; and (2) an alcohol selected from the group consisting of 1,4 butanediol vinyl ether, 2-allyloxy ethanol, 1,4-cyclohexanedimethanol vinyl ether, ethylene glycol vinyl ether, di(ethylene glycol) vinyl ether, and mixtures thereof; (B) a compound which is the reaction product of a mixture comprising (1) an isocyanate; and (2) a component comprising (a) an amine having at least one ethylenic unsaturation; (b) an acid having at least one ethylenic unsaturation; (c) a mixture of an amine having at least one ethylenic unsaturation and an alcohol having at least one ethylenic unsaturation; (d) a mixture of an acid having at least one ethylenic unsaturation and an alcohol having at least one ethylenic unsaturation; or (e) mixtures thereof; or (C) a mixture of (A) and (B); said ink being curable upon exposure to ultraviolet radiation.
    • 公开了一种相变油墨,其包含着色剂,引发剂和相变油墨载体,所述载体包含(A)氨酯,其是包含(1)异氰酸酯的混合物的反应产物; 和(2)选自1,4-丁二醇乙烯基醚,2-烯丙氧基乙醇,1,4-环己烷二甲醇乙烯基醚,乙二醇乙烯基醚,二(乙二醇)乙烯基醚及其混合物的醇的醇; (B)化合物,其为包含(1)异氰酸酯的混合物的反应产物; 和(2)包含(a)具有至少一个烯属不饱和度的胺的组分; (b)具有至少一个烯属不饱和度的酸; (c)具有至少一个烯属不饱和度的胺和具有至少一个烯属不饱和度的醇的混合物; (d)具有至少一个烯属不饱和度的酸和至少一个烯属不饱和度的醇的混合物; 或(e)它们的混合物; 或(C)(A)和(B)的混合物; 所述油墨在暴露于紫外线辐射下是可固化的。
    • 3. 发明申请
    • Curable Trans-1,2-cyclohexane bis(urea-urethane) compounds
    • 可固化的反式1,2-环己烷双(脲 - 氨基甲酸酯)化合物
    • US20060122354A1
    • 2006-06-08
    • US11004761
    • 2004-12-04
    • Rina CarliniEniko TomaPeter OdellJeffrey Banning
    • Rina CarliniEniko TomaPeter OdellJeffrey Banning
    • C08G18/00
    • C08G18/8166C08G18/3234C08G18/8175C08L75/16C09D11/34
    • Curable trans-1,2-cyclohexane bis(urea-urethane) compounds of the formulae wherein R1 and R′1 each, independently of the other, are alkylene, arylene, arylalkylene, or alkylarylene groups, R2 and R′2 each, independently of the other, are alkyl, aryl, arylalkyl, or alkylaryl groups, R3 and R′3 each, independently of the other, are hydrogen atoms or alkyl groups, R4 and R′4 each, independently of the other, are hydrogen atoms, fluorine atoms, alkyl groups, or phenyl groups, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl, aryl, arylalkyl, or alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group, provided that at least one of R1, R′1, R2, R′2, R3, R′3, R4, R′4, or one or more of R5 is an alkyl, alkylene, arylalkyl, arylalkylene, alkylaryl, or alkylarylene group containing an ethylenic unsaturation rendering the compound curable upon exposure to heat and/or actinic radiation.
    • 具有下式的可固化的反式-1,2-环己烷双(脲 - 氨基甲酸酯)化合物其中R 1和R 1'各自独立地为亚烷基,亚芳基 ,芳基亚烷基或烷基亚芳基,R 2和R“2各自独立地是烷基,芳基,芳基烷基或烷基芳基,R 3 各自独立地为氢原子或烷基,R 4和R 4各自独立地为氢原子或烷基 独立地是氢原子,氟原子,烷基或苯基,n是0,1,2,3或4的整数,R 5是烷基, 芳基,芳烷基或烷基芳基,或除烷基,芳基,芳基烷基或烷基芳基以外的取代基,条件是R 1,R'1, R 2,R 3,R 3,R'3,R 4, R 5,R 4,或R 5中的一个或多个是烷基,亚烷基,芳基烷基,芳基亚烷基,烷基芳基或烷基 含有烯属不饱和键的化合物,使得化合物在暴露于热和/或光化辐射下可固化。
    • 4. 发明申请
    • Phase change inks containing curable trans-1,2-cyclohexane bis(urea-urethane) compounds
    • 含有可固化反式-1,2-环己烷双(脲 - 氨基甲酸酯)化合物的相变油墨
    • US20060117993A1
    • 2006-06-08
    • US11004451
    • 2004-12-04
    • Rina CarliniEniko TomaPeter OdellJeffrey Banning
    • Rina CarliniEniko TomaPeter OdellJeffrey Banning
    • C09D11/00
    • C09D11/34C09D11/101
    • Phase change inks comprising a phase change ink carrier and one or more curable trans-1,2-cyclohexane bis[urea-urethane] compounds of the formulae wherein R1 and R′1 are alkylene, arylene, arylalkylene, or alkylarylene groups, R2 and R′2 are alkyl, aryl, arylalkyl, or alkylaryl groups, R3 and R′3 are hydrogen atoms or alkyl groups, R4 and R′4 are hydrogen atoms, fluorine atoms, alkyl groups, or phenyl groups, n is an integer of 0, 1, 2, 3, or 4, and R5 is an alkyl, aryl, arylalkyl, or alkylaryl group, or a substituent other than an alkyl, aryl, arylalkyl, or alkylaryl group, provided that at least one of R1, R′1, R2, R′2, R3, R′3, R4, R′4, or one or more of R5 is an alkyl, alkylene, arylalkyl, arylalkylene, alkylaryl, or alkylarylene group containing an ethylenic unsaturation rendering the compound curable upon exposure to heat and/or actinic radiation.
    • 相变油墨,其包含相变油墨载体和一种或多种下式的可固化的反式-1,2-环己烷双[尿素 - 氨基甲酸酯]化合物,其中R 1和R 2 < R 2是亚烷基,亚芳基,芳基亚烷基或烷基亚芳基,R 2和R“2是烷基,芳基,芳基烷基或烷基芳基, R 3和R 3'是氢原子或烷基,R 4和R“4是氢原子,氟原子,烷基 或苯基,n是0,1,2,3或4的整数,并且R 5是烷基,芳基,芳基烷基或烷基芳基,或除烷基以外的取代基 ,芳基,芳基烷基或烷基芳基,条件是R 1,R'1,R 2,R 2,R',SUB中的至少一个 R 2,R 3,R 4,R 4,或者R 3,R 3, R 5中的一个或多个是含有烯属不饱和键的烷基,亚烷基,芳基烷基,芳基亚烷基,烷基芳基或烷基亚芳基,使得c 在暴露于热和/或光化辐射下可固化。
    • 6. 发明申请
    • Radiation curable inks containing curable gelator additives
    • 含可固化凝胶剂添加剂的可辐射固化油墨
    • US20060159850A1
    • 2006-07-20
    • US11034866
    • 2005-01-14
    • Marcel BretonPeter OdellChristy BedfordJennifer BelelieJeffrey Banning
    • Marcel BretonPeter OdellChristy BedfordJennifer BelelieJeffrey Banning
    • C09D11/00B05D5/00
    • C09D11/101
    • An ink preferably used in piezoelectric ink jet devices includes an ink vehicle that includes at least one curable monomer, at least one polymerizable organic gelator, at least one initiator, at least one colorant and optionally at least one low molecular mass non-reactive organic gelator and/or at least one thermal solvent. The use of the curable gelator enables the ink to form a gel state having a viscosity of at least 102.5 cps at very low temperatures of about 30° C. to about 50° C. The ink may thus be jetted at low temperatures of about 50° C. to about 90° C. The ink is heated to a first temperature above the gel point of the ink, jetted onto a surface maintained at a second temperature at which the ink forms a gel state, and when on the image receiving substrate, is exposed to radiation energy to polymerize the polymerizable components of the ink.
    • 优选用于压电喷墨装置的油墨包括油墨载体,其包含至少一种可固化单体,至少一种可聚合有机胶凝剂,至少一种引发剂,至少一种着色剂和任选的至少一种低分子量非反应性有机胶凝剂 和/或至少一种热溶剂。 使用可固化胶凝剂使油墨能够在约30℃至约50℃的非常低的温度下形成粘度至少为10-2.5psps的凝胶状态。因此,油墨可以 在约50℃至约90℃的低温下喷射。将油墨加热至高于油墨凝胶点的第一温度,喷射到保持在油墨形成凝胶状态的第二温度的表面上 并且当在图像接收基板上暴露于辐射能量以聚合墨水的可聚合组分时。
    • 7. 发明申请
    • Guanidinopyrimidinone compounds and phase change inks containing same
    • 胍基嘧啶酮化合物和含有它们的相变油墨
    • US20060149063A1
    • 2006-07-06
    • US10794930
    • 2004-03-05
    • Danielle Boils-BoissierMarcel BretonJule ThomasDonald TitteringtonJeffrey BanningH. GoodbrandJames WuestMarie-Eve PerronHugues Duval
    • Danielle Boils-BoissierMarcel BretonJule ThomasDonald TitteringtonJeffrey BanningH. GoodbrandJames WuestMarie-Eve PerronHugues Duval
    • C07D403/02C07D239/47
    • C07D239/47C09D11/34
    • Compounds of the formulae wherein, provided that at least one of R1, R2, and R3 is not a hydrogen atom, R1, R2, and R3 each, independently of the other, is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, and wherein R1 and R2 can also be alkoxy aryloxy, arylalkyloxy, alkylaryloxy, polyalkyleneoxy, polyaryleneoxy, polyarylalkyleneoxy, polyalkylaryleneoxy, silyl, siloxane, polysilylene, polysiloxane, or a group of the formula wherein r and s are integers representing a number of repeat —CH2— groups, and wherein X is a direct bond, oxygen, sulfur, —NR40— wherein R40 is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, or —CR50R60— wherein R50 and R60 each, independently of the other, is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, and R10 and R11 each, independently of the other, is alkylene, arylene, arylalkylene, or alkylarylene, and wherein R10 can also be alkyleneoxy, polyaryleneoxy, polyarylalkyleneoxy, polyalkylaryleneoxy, silylene, siloxane, polysilylene, or polysiloxane.
    • 下式的化合物其中,只要R 1,R 2和R 3 3中的至少一个不是氢原子, 各自独立地为氢,烷基,芳基,芳基烷基或烷基芳基,其中R 1,R 2,R 3和R 3各自独立地为氢,烷基,芳基, R 1和R 2也可以是烷氧基芳氧基,芳基烷氧基,烷芳基氧基,聚亚烷氧基,聚亚芳基氧基,聚芳基亚烷基氧基,聚烷基亚芳基氧基,甲硅烷基,硅氧烷,聚亚芳基,聚硅氧烷或式 其中r和s是代表多个重复-CH 2 - 基团的整数,并且其中X是直接键,氧,硫,-NR 40 - ,其中R' 其中R 50是氢,烷基,芳基,芳基烷基或烷基芳基,或-CR 50 R 60 - ,其中R 50是氢, 和R 60各自独立地为氢,烷基,芳基,芳烷基或烷芳基,R 10和R 11各自独立地为 独立地是亚烷基,亚芳基,芳基 亚烷基或烷基亚芳基,其中R 10也可以是亚烷基氧基,聚亚芳基氧基,聚芳基亚烷氧基,聚烷基亚芳基氧基,亚甲硅烷基,硅氧烷,聚亚芳基或聚硅氧烷。
    • 10. 发明申请
    • Processes for preparing phase change inks
    • 制备相变油墨的方法
    • US20060021546A1
    • 2006-02-02
    • US10898724
    • 2004-07-23
    • Bo WuJeffrey BanningRandall BridgemanDonald Titterington
    • Bo WuJeffrey BanningRandall BridgemanDonald Titterington
    • C09D11/00
    • C09D11/34
    • Processes for preparing phase change inks comprising admixing (a) a phase change ink carrier; (b) a colorant of the formula or mixtures thereof, wherein M1, z, A1, R1, R2, R3, R4, R5, R6, R7, a, b, c, d, Y, Q, Q−, A1, and CA are as defined herein; and (c) a metal salt of the formula (M2v+)w(A2w−)v of which the metal portion M2 is either a metal ion having positive charge +v, a metal-containing moiety, or a mixture thereof, and A2 is an anion having negative charge −w, wherein M1 and M2 can be the same as or different from each other, wherein A1 and A2 can be the same as or different from each other, said admixing occurring at a temperature at which the ink carrier is a liquid.
    • 制备相变油墨的方法,包括混合(a)相变油墨载体; (b)下式的着色剂或其混合物,其中M 1,z,A 1,R 1,R 2 R 3,R 4,R 5,R 6,R 7, a,b,c,d,Y,Q,Q 1,A 1和CA如本文所定义; 和(c)式(M 2)的金属盐(M 2 H 2 O) 其中金属部分M 2 2是具有正电荷的金属离子+ v,含金属的部分或其混合物 ,并且A 2是具有负电荷-w的阴离子,其中M 1和M 2 2可以彼此相同或不同 其中A 1和A 2可以彼此相同或不同,所述混合在墨载体为液体的温度下发生。