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    • 7. 发明授权
    • Process for cracking an olefin-rich hydrocarbon feedstock
    • 裂化烯烃富烃原料的方法
    • US07375257B2
    • 2008-05-20
    • US10398603
    • 2001-10-03
    • Jean-Pierre DathWalter Vermeiren
    • Jean-Pierre DathWalter Vermeiren
    • C07C4/02C10G11/02
    • C10G11/16C10G2400/20
    • A process for cracking an olefin containing hydrocarbon feedstock which is selective towards light olefins in the effluent, the process comprising passing a hydrocarbon feedstock containing one or more olefins through a moving bed reactor containing a crystalline silicate catalyst selected from an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminium atomic ration of from 150 to 800 which has been subjected to a steaming step, at an inlet temperature of from 500 to 600° C., at an olefin partial pressure of from 0.1 to 2 bars and the feedstock being passed over the catalyst at an LHSV of from 5 to 30 h−1 to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, intermittently removing a first fraction of the catalyst from the moving bed reactor, regenerating the first fraction of the catalyst in a regenerator and intermittently feeding into the moving bed reactor a second fraction of the catalyst which has been regenerated in the regenerator, the catalyst regeneration rate being controlled whereby the propylene purity is maintained constant at a value corresponding to the average value observed in a fixed bed reactor using the same feedstock, catalyst and cracking conditions, for example at least 94 wt. %.
    • 一种用于裂解对流出物中的轻质烯烃具有选择性的含烯烃的原料的方法,该方法包括使含有一种或多种烯烃的烃原料通过含有结晶硅酸盐催化剂的移动床反应器,该结晶硅酸盐催化剂选自MFI型结晶硅酸盐, 入口温度为500-600℃的硅/铝原子比至少为180的硅/铝原子比为150〜800的MEL型结晶硅酸盐,其进行了蒸汽工序。 ,烯烃分压为0.1至2巴,原料以5至30小时-1的LHSV通过催化剂以产生具有较低分子量的烯烃含量的流出物 比原料间歇地从移动床反应器中除去催化剂的第一部分,在再生器中再生催化剂的第一馏分并间歇地进料 在移动床反应器中,在再生器中再生的催化剂的第二部分,控制催化剂再生速率,由此丙烯纯度保持恒定在与使用相同原料的固定床反应器中观察到的平均值的值 ,催化剂和裂化条件,例如至少94wt。 %。