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    • 3. 发明授权
    • Novel cyclopropane carboxylates
    • 新型环丙烷羧酸酯
    • US5030655A
    • 1991-07-09
    • US412081
    • 1989-09-25
    • Jean TessierJacques DemasseyJean-Pierre Demoute
    • Jean TessierJacques DemasseyJean-Pierre Demoute
    • C07D209/49A01N53/00A01N53/02A01N53/10C07C62/08C07C309/70C07D213/62C07D213/68C07D233/72C07D307/45
    • C07C62/08A01N53/00
    • A compound selected from the group consisting of all possible isomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms and cycloalkyl and cycloalkylalkyl of 3 to 8 carbon atoms, R.sub.2 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms, cycloalkyl of 3 to 8 carbon atoms and acyl of 1 to 9 carbon atoms, X.sub.1 and X.sub.2 are individually selected from the group consisting of fluorine, chlorine, bromine, iodine, --CF.sub.3, --CN, --COOR and ##STR2## R is alkyl of 1 to 8 carbon atoms, Hal is chlorine, bromine or fluorine and R.sub.3 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms and residue of an alcohol used in pyrethrinoid synthesis having excellent pesticidal properties.
    • 选自下列化合物的化合物的化合物的化合物的所有可能的异构体形式及其混合物,其中R 1选自氢,1至8个碳原子的烷基,2至2的烯基和炔基 8个碳原子和3至8个碳原子的环烷基和环烷基烷基,R2选自氢,1至8个碳原子的烷基,2至8个碳原子的烯基和炔基,3至8个碳原子的环烷基和 1至9个碳原子的酰基,X 1和X 2分别选自氟,氯,溴,碘,-CF 3,-CN,-COOR,R 1是具有1至8个碳原子的烷基,Hal 是氯,溴或氟,并且R 3选自氢,1至8个碳原子的烷基和用于除虫菊酯合成中具有优异杀虫性质的醇的残基。
    • 7. 发明授权
    • Vinylsulfone nor-pyrethric compounds
    • 乙烯基砜除虫菊酯化合物
    • US5329017A
    • 1994-07-12
    • US51177
    • 1993-04-22
    • Didier BabinJean-Pierre DemouteJean Tessier
    • Didier BabinJean-Pierre DemouteJean Tessier
    • C07C69/743C07D327/04
    • C07C69/743
    • Novel all possible stereoisomers and mixtures thereof of vinylsulfone nor-pyrethric compounds of the formula ##STR1## wherein R.sub.a is selected from the group consisting of alkyl of 1 to 18 carbon atoms, alkenyl and alkynyl of 2 to 18 carbon atoms, cycloalkyl of 3 to 18 carbon atoms, cycloalkylalkyl of 4 to 18 carbon atoms and aryl of 6 to 14 carbon atoms unsubstituted or substituted with at least one functional group, n is 0, 1 or 2, R.sub.b is selected from the group consisting of alkyl of 1 to 18 carbon atoms, alkenyl and alkynyl of 2 to 18 carbon atoms, cycloalkyl of 3 to 18 carbon atoms, cycloalkylalkyl of 4 to 18 carbon atoms and aryl of 6 to 14 carbon atoms, all unsubstituted or unsubstituted with at least one functional group or R.sub.a and R.sub.b together with the C-S-C to which they are attached form ##STR2##
    • 其中R a选自1至18个碳原子的烷基,2至18个碳原子的烯基和炔基,3个环烷基的全部可能的立体异构体及其混合物, 至18个碳原子,4至18个碳原子的环烷基烷基和未被取代或被至少一个官能团取代的6至14个碳原子的芳基,n为0,1或2,Rb选自1至 2至18个碳原子的烯基和炔基,3至18个碳原子的环烷基,4至18个碳原子的环烷基烷基和6至14个碳原子的芳基,全部未取代或未取代,至少有一个官能团或Ra 和Rb与它们所连接的CSC一起形成
    • 8. 发明授权
    • 3-(2-cyano-2-halo-ethenyl)-2,2-dimethyl-cyclopropanecarboxylates
    • 3-(2-氰基-2-甲基-2-戊烯)-2,2-二甲基 - 环丙烷氧基甲酸酯
    • US5135951A
    • 1992-08-04
    • US661383
    • 1991-02-26
    • Didier BabinMarc BenoitJean-Pierre DemouteJean Tessier
    • Didier BabinMarc BenoitJean-Pierre DemouteJean Tessier
    • C07F7/10A01N53/00A01N53/06A01N53/08A01N55/10C07C253/30C07C255/31C07C255/39C07C255/55C07C319/20C07C323/16C07F7/12
    • A01N53/00C07C255/31
    • All stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein the cyclopropane copula has (1R, cis) or (1R, trans) structure, the geometry of the double bond carried by the 3-carbon atom is (E) or (Z), X is halogen, Z is selected from the group consisting of hydrogen, methyl, --CN and --C.tbd.CH, n is an integer from 1 to 5, m represents the number 5-n, Y is selected from the group consisting of hydrogen, halogen, --CH.sub.2 --CN, --OH, optionally unsaturated alkyl of 1 to 8 carbon atoms unsubstituted or substituted with at least one halogen, --CN, --COOAlk, --COAlk, --(CH.sub.2).sub.m' OAlk, --(CH.sub.2).sub.m' --S--Alk, --(CH.sub.2).sub.m' --N(Alk).sub.2, --Si(Alk).sub.3, --OAr and (CH.sub.2).sub.m' --Ar, m' is 0, 1,2,3 or 4, Alk is optionally unsaturated alkyl of 1 to 8 carbon atom unsubstituted or substituted with at least one halogen and Ar is aryl of 6 to 14 carbon atoms and the Ys identical or different may be on any position of the phenyl having pesticidal properties.
    • 式(I)化合物的所有立体异构体形式及其混合物,其中环丙烷共聚物具有(1R,顺式)或(1R,反式)结构,由3-碳原子携带的双键的几何形状为(E )或(Z)中,X为卤素,Z选自氢,甲基,-CN和-C 3BOND CH,n为1〜5的整数,m为5〜n的数,Y为 由氢,卤素,-CH 2 -CN,-OH,未取代或被至少一个卤素,-CN,-COOAlk,-COAlk, - (CH 2)m'取代或被取代的碳原子数1〜 OAlk, - (CH 2)m'-S-Alk, - (CH 2)m'-N(Alk)2,-Si(Alk)3,-OAr和(CH 2)m'-Ar,m' ,2,3或4,Alk任选是未被取代或被至少一个卤素取代的1至8个碳原子的不饱和烷基,Ar是6至14个碳原子的芳基,并且Y相同或不同可以在苯基的任何位置 具有杀虫性。