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    • 8. 发明授权
    • Photochromic glass
    • 光致变色玻璃
    • US4190451A
    • 1980-02-26
    • US14981
    • 1979-02-28
    • George B. HaresDavid L. MorseThomas P. Seward, IIIDennis W. Smith
    • George B. HaresDavid L. MorseThomas P. Seward, IIIDennis W. Smith
    • C03C3/064C03C3/11C03C4/06C03C21/00G02C7/10C03C3/08C03C3/26
    • C03C4/06Y10S501/903
    • The instant invention is concerned with transparent photochromic glass compositions which not only exhibit desirably rapid darkening and fading characteristics, but which also demonstrate the other physical and optical properties required for use in ophthalmic applications. Such glasses utilize the presence of silver chloride and/or silver bromide crystals to impart photochromic behavior in a narrowly-defined composition range within the alkali metal aluminoborosilicate base system. Copper ions are also included in the composition to perform as a sensitizing agent. The glasses have the capability of being either thermally tempered or chemically strengthened to comply with the United States Food and Drug Administration regulations for lenses used in ophthalmic applications. Improved independence of temperature effects upon the photochromic properties can be achieved where the copper level, expressed as CuO, is maintained between about 0.004-0.02% by weight, the chloride value, expressed as Cl, is held between about 0.1-0.25% by weight, the silver content, expressed as Ag, is included between about 0.15-0.3% by weight, and the quantity of bromide, expressed as Br, is varied between about 0.1-0.2% by weight. The fading rate of the glasses is enhanced by maintaining the molar ratio of alkali metal oxides to B.sub.2 O.sub.3 between about 0.55-0.85, the molar ratio of alkali metal oxides minus Al.sub.2 O.sub.3 to B.sub.2 O.sub.3 is about 0.25-0.4, and the weight ratio Ag:(Cl+Br) is about 0.65-0.95.
    • 本发明涉及透明光致变色玻璃组合物,其不仅表现出期望的快速变暗和褪色特性,而且还显示了用于眼科应用所需的其它物理和光学性质。 这种玻璃利用氯化银和/或溴化银晶体的存在,以在碱金属铝硼硅酸盐基体系内的窄范围的组成范围内赋予光致变色行为。 铜离子也包括在组合物中以用作敏化剂。 眼镜具有热回火或化学强化的能力,以符合美国食品和药物管理局对眼科应用中使用的镜片的规定。 可以实现温度对光致变色性能的独立性,其中以CuO表示的铜含量维持在约0.004-0.02重量%之间,氯化物值(以Cl表示)保持在约0.1-0.25重量% ,以Ag表示的银含量在约0.15-0.3重量%之间,以Br表示的溴的量在约0.1-0.2重量%之间变化。 通过将碱金属氧化物与B 2 O 3的摩尔比保持在约0.55-0.85之间,碱金属氧化物减去Al 2 O 3与B 2 O 3的摩尔比为约0.25-0.4,并且重量比Ag Cl + Br)为约0.65-0.95。