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    • 3. 发明授权
    • 3-(Phosphoryloxy) and (phosphonyloxy)-thiophenes
    • 3-(磷酰氧基)和(膦酰氧基) - 噻吩
    • US4155996A
    • 1979-05-22
    • US944809
    • 1978-09-22
    • Jacques PerronnetLaurent Taliani
    • Jacques PerronnetLaurent Taliani
    • C07F9/6553A01N9/36C07F9/09C07F9/165
    • C07F9/655345
    • Novel 3-(phosphoryloxy) or (phosphonyloxy)-thiophenes of the formula ##STR1## wherein R is alkyl of 1 to 4 carbon atoms, R.sub.1 is selected from the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms and ##STR2## wherein R' and R" are individually selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms, R.sub.2 is selected from the group consisting of cyano, alkoxy carbonyl of 2 to 4 carbon atoms and ##STR3## wherein Z is selected from the group consisting of phenyl and alkyl of 1 to 4 carbon atoms, R.sub.3 is selected from the group consisting of alkyl of 1 to 6 carbon atoms, alkoxy of 1 to 6 carbon atoms, alkylthio of 1 to 6 carbon atoms, phenyl, morpholino, piperidinyl and alkoxy carbonyl of 2 to 4 carbon atoms and X is selected from the group consisting of oxygen and sulfur having pesticidal properties and their preparation.
    • 新颖的3-(磷酰氧基)或(膦酰基氧基) - 噻吩类化合物其中R是1至4个碳原子的烷基,R 1选自1至4个碳原子的烷基,1至 4个碳原子和其中R'和R“分别选自氢和1至4个碳原子的烷基,R 2选自氰基,2至4个碳原子的烷氧基羰基 和其中Z选自苯基和1至4个碳原子的烷基,R 3选自1至6个碳原子的烷基,1至6个碳原子的烷氧基,1至6个碳原子的烷硫基, 2个碳原子的苯基,吗啉代,哌啶基和烷氧基羰基,X选自具有杀虫特性的氧和硫及其制备。
    • 4. 发明授权
    • Novel 3-(phosphoryloxy) and (phosphonyloxy)-thiophenes
    • 新的3-(磷酰氧基)和(膦酰氧基) - 噻吩
    • US4128562A
    • 1978-12-05
    • US850922
    • 1977-11-14
    • Jacques PerronnetLaurent Taliani
    • Jacques PerronnetLaurent Taliani
    • C07F9/6553C07D333/16A01N9/36C07D333/00
    • C07F9/655345
    • Novel 3-(phosphoryloxy) or (phosphonyloxy)-thiophenes of the formula ##STR1## wherein R is alkyl of 1 to 4 carbon atoms, R.sub.1 is selected from the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms and ##STR2## wherein R' and R" are individually selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms, R.sub.2 is selected from the group consisting of cyano, alkoxy carbonyl of 2 to 4 carbon atoms and ##STR3## wherein Z is selected from the group consisting of phenyl and alkyl of 1 to 4 carbon atoms, R.sub.3 is selected from the group consisting of alkyl of 1 to 6 carbon atoms, alkoxy of 1 to 6 carbon atoms, alkylthio of 1 to 6 carbon atoms, phenyl, morpholino, piperidinyl and alkoxy carbonyl of 2 to 4 carbon atoms and X is selected from the group consisting of oxygen and sulfur having pesticidal properties and their preparation.
    • 新颖的3-(磷酰氧基)或(膦酰基氧基) - 噻吩类化合物其中R是1至4个碳原子的烷基,R 1选自1至4个碳原子的烷基,1至 4个碳原子和其中R'和R“分别选自氢和1至4个碳原子的烷基,R 2选自氰基,2至4个碳原子的烷氧基羰基 和其中Z选自苯基和1至4个碳原子的烷基,R 3选自1至6个碳原子的烷基,1至6个碳原子的烷氧基,1至6个碳原子的烷硫基, 2个碳原子的苯基,吗啉代,哌啶基和烷氧基羰基,X选自具有杀虫特性的氧和硫及其制备。
    • 6. 发明授权
    • Novel thiazole derivatives
    • 新型噻唑衍生物
    • US3948925A
    • 1976-04-06
    • US515479
    • 1974-10-17
    • Jacques PerronnetLaurent Taliani
    • Jacques PerronnetLaurent Taliani
    • A01N57/08A01N57/16A01P7/02A01P7/04C07D277/34C07D277/56C07F9/6539
    • C07F9/6539C07D277/34C07D277/56
    • Novel compounds of the formula ##EQU1## wherein X is selected from the group consisting of oxygen and sulfur, X.sub.1 is selected from the group consisting of alkyl of 1 to 6 carbon atoms, cyano and ##EQU2## Y.sub.1 is selected from the group consisting of alkyl of 1 to 6 carbon atoms, alkoxy of 1 to 6 carbon atoms and amino, n is 0, 1 or 2, X.sub.2 is selected from the group consisting of hydrogen, chlorine, bromine, alkyl of 1 to 6 carbon atoms, cyano and ##EQU3## R is alkyl of 1 to 6 carbon atoms, R.sub.1 is selected from the group consisting of alkyl of 1 to 6 carbon atoms, alkoxy of 1 to 6 carbon atoms and ##EQU4## and R.sub.2 and R.sub.3 are selected from the group consisting of hydrogen and alkyl of 1 to 6 carbon atoms with the proviso that X.sub.1 is other than alkyl when X.sub.2 is alkyl or hydrogen, having insecticidal, nematocidal and acaricidal properties.
    • 新的式X 1化合物:其中X选自氧和硫,X 1选自由以下组成的组:1〜 (CH 2)n C-Y 1,Y 1选自1至6个碳原子的烷基,1至6个碳原子的烷氧基和氨基,n是0,1或2, X 2选自氢,氯,溴,1至6个碳原子的烷基,氰基和O平行 - (CH 2)n C-Y 1,R是1至6个碳原子的烷基,R 1选自 由1至6个碳原子的烷基,1至6个碳原子的烷氧基和R2-ANGLE R3组成的组,R2和R3选自氢和1至6个碳原子的烷基,条件是X1是其他 当X2是烷基或氢时,具有烷基,具有杀虫,杀线虫和杀螨性质。
    • 7. 发明授权
    • Novel pyrrole derivatives
    • 新型吡咯衍生物
    • US4798901A
    • 1989-01-17
    • US127922
    • 1987-12-02
    • Jean TessierJean-Pierre DemouteLaurent Taliani
    • Jean TessierJean-Pierre DemouteLaurent Taliani
    • A01N43/36A01N53/00A01N53/04A01N53/06A23K1/16C07D207/32C07D207/333C07D207/337C07D207/34C07D207/42C07D207/325
    • C07D207/333A01N43/36A01N53/00A23K20/132C07D207/337C07D207/34C07D207/42
    • Novel pyrrole derivatives of the formula ##STR1## wherein one of R.sub.2 and R.sub.3 is ##STR2## and the other of R.sub.2 and R.sub.3 as well as R.sub.4 and R.sub.5 are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 18 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 7 to 18 carbon atoms, --CN, --CF.sub.3, --NO.sub.2, --COOAlk and Alk is alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms, ##STR3## n is 0, 1 or 2, R', R.sub.1 ' and R.sub.2 ' are alkyl of 1 to 8 carbon atoms and R.sub.4 and R.sub.5 taken together with the carbon atoms to which they are attached may form an optionally further unsaturated carbon homocycle of up to 8 carbon atoms, Z is selected from the group consisting of hydrogen, --CN, --C.tbd.CH, --CF.sub.3 and alkyl of 1 to 3 carbon atoms, A is the residue of a pyrethrinoid acid, R.sub.1 is selected from the group consisting of ##STR4## X', X, Y, Y' and Y" are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms and aryl of 6 to 14 carbon atoms, the dotted line indicating an optional double bond, r' is selected from the group consisting of hydrogen, alkyl of 1 to 18 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 7 to 18 carbon atoms, --CF.sub.3, --COOAlk and alkoxy of 1 to 8 carbon atoms and Alk has the above definition, R" and R"' are individually selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 6 to 18 carbon atoms, --CF.sub.3, --COOAlk' and alkoxy of 1 to 8 carbon atoms and Alk' is alkyl of 1 to 8 carbon atoms having pesticidal properties and novel intermediates.
    • 式(I)的新颖的吡咯衍生物,其中R 2和R 3之一是R 1和R 2之一,以及R 4和R 5中的另一个分别选自氢,卤素,1至18的烷基 碳原子数为6〜14的芳基,碳原子数为7〜18的芳烷基,-CN,-CF 3,-NO 2,-COOAlk,Alk为碳原子数为1〜8的烷基,碳原子数为1〜8的烷氧基, 图像> n是0,1或2,R',R 1'和R 2'是1至8个碳原子的烷基,R 4和R 5与它们所连接的碳原子一起可以形成任选的另外的不饱和碳均质碳 Z最多为8个碳原子,Z选自氢,-CN,-C3BCH,-CF3和1至3个碳原子的烷基,A是除虫烯酸的残基,R1选自 由X,Y,Y'分别选自氢,卤素,碳原子数1〜8的烷基,碳原子数为6〜14的芳基组成的组合 n个原子,表示任选的双键的虚线,r'选自氢,1至18个碳原子的烷基,6至14个碳原子的芳基,7至18个碳原子的芳烷基,-CF 3, -COOAlk和1-8个碳原子的烷氧基,Alk具有上述定义,R“和R”'分别选自氢,1至8个碳原子的烷基,6至14个碳原子的芳基 6〜18个碳原子的芳烷基,-CF 3,-COOAlk'和1〜8个碳原子的烷氧基,Alk'是具有杀虫性的1〜8个碳原子的烷基和新的中间体。
    • 8. 发明授权
    • Novel pyrrole derivatives
    • 新型吡咯衍生物
    • US4737513A
    • 1988-04-12
    • US765317
    • 1985-08-13
    • Jean TessierJean-Pierre DemouteLaurent Taliani
    • Jean TessierJean-Pierre DemouteLaurent Taliani
    • A01N43/36A01N53/00A01N53/04A01N53/06A23K1/16C07D207/32C07D207/333C07D207/337C07D207/34C07D207/42A61K31/40C07D207/325
    • C07D207/333A01N43/36A01N53/00A23K20/132C07D207/337C07D207/34C07D207/42
    • Novel pyrrole derivatives of the formula ##STR1## wherein one of R.sub.2 and R.sub.3 is ##STR2## and the other of R.sub.2 and R.sub.3 as well as R.sub.4 and R.sub.5 are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 18 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 7 to 18 carbon atoms, --CN, --CF.sub.3, --NO.sub.2, --COOAlk and Alk is alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms, ##STR3## n is 0, 1 or 2, R', R.sub.1 ' and R.sub.2 ' are alkyl of 1 to 8 carbon atoms and R.sub.4 and R.sub.5 taken together with the carbon atoms to which they are attached may form an optionally further unsaturated carbon homocycle of up to 8 carbon atoms, Z is selected from the group consisting of hydrogen, --CN, --C.tbd.CH, --CF.sub.3 and alkyl of 1 to 3 carbon atoms, A is the residue of a pyrethrinoid acid, R.sub.1 is selected from the group consisting of ##STR4## X', X, Y, Y' and Y" are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms and aryl of 6 to 14 carbon atoms, the dotted line indicating an optional double bond, r' is selected from the group consisting of hydrogen, alkyl of 1 to 18 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 7 to 18 carbon atoms, --CF.sub.3, --COOAlk and alkoxy of 1 to 8 carbon atoms and Alk has the above definition, R" and R'" are individually selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 6 to 18 carbon atoms, --CF.sub.3 ' --COOAlk' and alkoxy of 1 to 8 carbon atoms and Alk' is alkyl of 1 to 8 carbon atoms having pesticidal properties and novel intermediates.
    • 式(I)的新颖的吡咯衍生物,其中R 2和R 3之一是R 1和R 2之一,以及R 4和R 5中的另一个分别选自氢,卤素,1至18的烷基 碳原子数为6〜14的芳基,碳原子数为7〜18的芳烷基,-CN,-CF 3,-NO 2,-COOAlk,Alk为碳原子数为1〜8的烷基,碳原子数为1〜8的烷氧基, 图像> n是0,1或2,R',R 1'和R 2'是1至8个碳原子的烷基,R 4和R 5与它们所连接的碳原子一起可以形成任选的另外的不饱和碳均质碳 Z最多为8个碳原子,Z选自氢,-CN,-C3BCH,-CF3和1至3个碳原子的烷基,A是除虫烯酸的残基,R1选自 由X,Y,Y'分别选自氢,卤素,碳原子数为1〜8的烷基,碳原子数为6〜14的芳基, 表示任选的双键的虚线,r'选自氢,1至18个碳原子的烷基,6至14个碳原子的芳基,7至18个碳原子的芳烷基,-CF 3,-COOAlk和烷氧基 1〜8个碳原子,Alk具有上述定义,R“和R”'分别选自氢,1〜8个碳原子的烷基,6〜14个碳原子的芳基,6个芳烷基 至18个碳原子,-CF 3'-COOAlk'和1至8个碳原子的烷氧基,Alk'是具有杀虫特性的1至8个碳原子的烷基和新的中间体。
    • 10. 发明授权
    • Acylated amine compounds which are useful fungicigal agents
    • 有用的真菌药剂的胺化合物
    • US5064861A
    • 1991-11-12
    • US454685
    • 1989-12-21
    • Jean-Louis BrayerLaurent TalianiJean Tessier
    • Jean-Louis BrayerLaurent TalianiJean Tessier
    • A01N37/18A01N37/20A01N39/04A01N43/16A01N43/38A01N47/44C07C53/21C07C57/72C07C59/70C07C233/39C07C235/20C07C279/12C07C279/24C07D209/08C07D209/10C07D209/12C07D311/16
    • C07D209/08A01N37/20A01N39/04A01N43/16A01N43/38A01N47/44C07C233/39C07C235/20C07C279/12C07C53/21C07C57/72C07C59/70C07D209/10C07D209/12C07D311/16
    • A compound selected from the group consisting of a compound of the formula ##STR1## wherein R.sub.1 is selected from the group consisting of Ar-O- and aryl, polyaryl and condensed polyaryl unsubstituted or substituted and heterocycle unsubstituted or substituted, Ar is aryl of 6 to 14 carbon atoms unsubstituted or substituted, heteroaryl unsubstituted or substituted and heterocyclic unsubstituted or substituted, W is selected from the group comsisting of --(CH.sub.2).sub.n.sbsb.1 --or --(CH.sub.2).sub.n.sbsb.2 --NY--(CH.sub.2).sub.n.sbsb.3, n.sub.1, n.sub.2 and n.sub.3 are individually integers from 2 to 6, Y is selected from the group consisting of hydrogen, alkyl of 1 to 12 carbon atoms, aryl of 6 to 12 carbon atoms and aralkyl of 7 to 14 carbon atoms unsubstituted or substituted, --COOAlk and --COR.sub.2, Alk is alkyl of 1 to 12 carbon atoms, R.sub.2 is selected from the group consisting of alkyl of 1 to 12 carbon atoms, alkenyl and alkynyl of 2 to 12 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 7 to 18 carbon atoms unsubstituted or substituted and heterocyclic unsubstituted or substituted, Z is selected from the group consisting of hydrogen, ##STR2## R.sub.2 is alkyl of 1 to 12 carbon atoms or aralkyl of 7 to 18 carbon atoms, Alk' is alkyl of 1 to 12 carbon atoms, ArAlk is aralkyl of 7 to 18 carbon atoms, R.sub.2 ' is R.sub.2, R.sub.3 and R.sub.3 ' are selected from the group consisting of aryl substituted or unsubstituted, heteroaryl substituted or unsubstituted, heterocyclic unsubstituted or substituted and R.sub.1 with the proviso that Z is not hydrogen when W is --(CH.sub.2).sub.3 --and R.sub.1 is 2,4-dichlorophenoxy and their non-toxic, pharmaceutically acceptable acid addition salts having fungicidal activity.
    • 选自下式的化合物的化合物其中R 1选自Ar-O-和芳基,聚芳基和未取代或取代的缩合聚芳基,未取代或取代的杂环,Ar是 未取代或未取代的未取代或未取代的杂芳基,未取代或取代的杂芳基,W选自 - (CH 2)n1 - 或 - (CH 2)n 2 -YH-(CH 2)n3,n1,n2 和n3各自为2至6的整数,Y选自氢,1至12个碳原子的烷基,6至12个碳原子的芳基和未被取代或取代的7-14个碳原子的芳烷基,-COOAlk和 -COR 2,Alk为1〜12个碳原子的烷基,R2选自1〜12个碳原子的烷基,2〜12个碳原子的烯基和炔基,6〜14个碳原子的芳基,7个芳烷基 至18个碳原子未被取代或取代和杂合 Z取代或未取代的Z选自氢,-COCH 2 R 3,R 2是1至12个碳原子的烷基或7至18个碳原子的芳烷基,Alk'是1至12个碳的烷基 原子,ArAlk是7至18个碳原子的芳烷基,R2'是R2,R3和R3'选自芳基取代或未取代的杂芳基取代或未取代的杂环,未取代或取代的杂环,R1是条件是Z是 当W是 - (CH 2)3 - 且R 1是2,4-二氯苯氧基时,它们不是氢,它们是具有杀真菌活性的无毒的药学上可接受的酸加成盐。