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    • 6. 发明授权
    • Aqueous polyurethane emulsions
    • 水性聚氨酯乳液
    • US06521702B1
    • 2003-02-18
    • US09716741
    • 2000-11-20
    • Jan WeikardErhard LühmannDieter ErdmannWolfgang FischerWolfgang Kremer
    • Jan WeikardErhard LühmannDieter ErdmannWolfgang FischerWolfgang Kremer
    • C08J303
    • C08G18/673C08G18/0823C08G18/6725C08G18/68C09D175/16Y10T428/31551Y10T428/31591
    • The present invention relates to a radiation-curable, aqueous polyurethane emulsion which is prepared by I) reacting A) 40 to 90 wt. % of an isocyanate-reactive component that contains a polyester acrylate containing hydroxyl groups and having an OH content of 40 to 200 mg KOH/g and optionally other isocyanate-reactive compounds other than B) and B) 0.5 to 20 wt. % of one or more monofunctional and/or difunctional isocyanate-reactive compounds that contain cationic or anionic groups, potential cationic or anionic or hydrophilic ether groups, with C) 10 to 50 wt. % of one or more diisocyanates and/or polyisocyanates, II) optionally converting any potential cationic or anionic groups into cationic or anionic groups by salt formation and III) forming a dispersion of the reaction product of A), B) and C) in water and reacting it with D) 0.1 to 10 wt. % of one or more diamines and/or polyamines, wherein the wt. % percentages of (A) to (D) add up to 100%, and the equivalent ratio of the sum of the isocyanate-reactive groups in (A) and (B) to the isocyanate groups in (C) is 0.8:1 to 1.25:1 and the reaction of components (A) and (B) with (C) is carried out such that 65 to 95% of the isocyanate groups in (C) react with the isocyanate-reactive groups of (A) and (B). The present invention also relates to a process of making these polyurethane emulsions and to substrates coated with the polyurethane emulsions.
    • 本发明涉及可辐射固化的水性聚氨酯乳液,其通过以下方法制备:I)将40至90重量% %的异氰酸酯反应性组分,其含有含羟基并且OH含量为40至200mg KOH / g的聚酯丙烯酸酯和任选的除B)和B)外的其它异氰酸酯反应性化合物,和B)0.5至20wt。 含有阳离子或阴离子基团的潜在阳离子或阴离子或亲水醚基团的一种或多种单官能和/或二官能异氰酸酯反应性化合物的%,C)10至50wt。 %的一种或多种二异氰酸酯和/或多异氰酸酯,II)任选地通过盐形成将任何潜在的阳离子或阴离子基团转化为阳离子或阴离子基团; III)在水中形成A),B)和C)的反应产物的分散体,以及 与D)反应0.1〜10重量% %的一种或多种二胺和/或多胺,其中wt。 (A)至(D)的百分比百分比加起来为100%,(A)和(B)中异氰酸酯反应性基团与(C)中异氰酸酯基团之和的当量比为0.8:1至 (A)和(B)与(C)的反应进行,使得(C)中的异氰酸酯基中的65〜95%与(A)和(B)的异氰酸酯反应性基团反应 )。 本发明还涉及制备这些聚氨酯乳液和用聚氨酯乳液涂覆的基材的方法。
    • 10. 发明授权
    • Process for preparing allophanate-containing actinically curable polyurethane prepolymers with increased resistance
    • 制备具有增加电阻的含有脲基甲酸酯的光固化型聚氨酯预聚物的方法
    • US07700662B2
    • 2010-04-20
    • US11731592
    • 2007-03-30
    • Michael LudewigJan WeikardNicolas StoeckelWolfgang Fischer
    • Michael LudewigJan WeikardNicolas StoeckelWolfgang Fischer
    • C07C275/60C07C269/00C07C271/62C07C273/00C08L75/14C08L75/16C08G18/42C08G18/44C08G18/48C08G18/67
    • C08G18/672C08G18/6633C08G18/7837C08G18/8175C09D175/16
    • The present invention relates to a process for preparing low-viscosity, allophanate-containing and NCO-free polyurethane prepolymers curable by actinic radiation, and to the products obtainable by this process. The prepolymers have residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, and are prepared by a process in which A) diisocyanates, B) hydroxy-functional compounds containing groups which react with ethylenically unsaturated compounds on exposure to actinic radiation, and C) polyester, polyether or polycarbonate polyols having a functionality of at least 1.9 and a number-average molecular weight (Mn) of at least 1000 g/mol, D) optionally in the presence of a catalyst, are reacted to form NCO-group-containing prepolymers having radiation-curing groups, which are subsequently reacted E) optionally after addition of monofunctional isocyanates in the presence F) of an allophanatization catalyst to give allophanate-containing prepolymers, the ratio of NCO groups of the compounds from A) to the OH groups of the compounds from B) and C) being 1.45:1.0 to 1.1:1.0 and the ratio of the OH groups from B) to the OH groups from C) being 8.0:1 to 1.5:1.
    • 本发明涉及一种制备可通过光化辐射固化的低粘度,含有脲基甲酸酯和不含NCO的聚氨酯预聚物和通过该方法获得的产品的方法。 预聚物的残留单体含量小于0.5重量%,NCO含量小于1重量%,并且通过以下方法制备:A)二异氰酸酯,B)含有与烯属不饱和基团反应的基团的羟基官能化合物 化合物暴露于光化辐射,以及C)官能度为至少1.9,数均分子量(Mn)至少为1000g / mol的聚酯,聚醚或聚碳酸酯多元醇,D)任选地在催化剂存在下 反应形成具有放射线固化基团的含有NCO基团的预聚物,其随后反应E)任选地在加入单官能异氰酸酯的情况下,在脲基化催化剂存在下,得到含脲基甲酸酯的预聚物,NCO基团 的来自A)的化合物与来自B)和C)的化合物的OH基团的摩尔比为C:1.45:1.0至1.1:1.0,并且B)中的OH基与C)中的OH基团的比例为8.0:1至1.5 :1。