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1. 发明授权

US08034978B2 Process for the preparation of an amine 有权
标题翻译：制备胺的方法
公开(公告)号：US08034978B2
公开(公告)日：2011-10-11
申请号：US12301811
申请日：2007-05-24
申请人： Jan Eberhardt , Harald Meiβner , Bram Willem Hoffer , Johann-Peter Melder , Ekkehard Schwab
发明人： Jan Eberhardt , Harald Meiβner , Bram Willem Hoffer , Johann-Peter Melder , Ekkehard Schwab
IPC分类号： C07C209/26 , C07D265/30
CPC分类号： C07C209/26 , C07C2601/14 , C07D295/023 , C07C211/07 , C07C211/08 , C07C211/35
摘要： Process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of primary and secondary amines in the presence of a heterogeneous catalyst, wherein the reaction is carried out using a suspended catalyst as heterogeneous catalyst and is carried out in the semibatch mode in which the nitrogen compound as one reactant is placed in the reaction vessel and the aldehyde and/or the ketone as the other reactant is added during the course of the reaction and the aldehyde and/or the ketone is added in portions or continuously to the reaction mixture during the course of the reaction as a function of the achieved conversion of the nitrogen compound until a conversion of the nitrogen compound of at least 95% results, and all or part of the catalyst remains in the reaction vessel after the reaction batch and is reused for the next reaction batch.
摘要翻译：在非均相催化剂存在下使醛和/或酮与氢和选自伯胺和仲胺的氮化合物反应制备胺的方法，其中反应使用悬浮催化剂作为非均相催化剂进行并且以半反应模式进行，其中作为一种反应物的氮化合物被放置在反应容器中，并且在反应过程中加入作为其它反应物的醛和/或酮，醛和/或酮在反应过程中以部分或连续的方式加入到反应混合物中，作为实现氮化合物转化的函数，直至氮化合物的转化率至少为95％，并且全部或部分催化剂保持在反应容器在反应批次后再次用于下一反应批次。

2. 发明授权

US08017808B2 Process for preparing an amine 有权
标题翻译：制备胺的方法
公开(公告)号：US08017808B2
公开(公告)日：2011-09-13
申请号：US12293609
申请日：2007-03-13
申请人： Jan Eberhardt , Bram Willem Hoffer , Frank Haese , Johann-Peter Melder , Bernd Stein , Michael Stang , Thomas Hill , Ekkehard Schwab
发明人： Jan Eberhardt , Bram Willem Hoffer , Frank Haese , Johann-Peter Melder , Bernd Stein , Michael Stang , Thomas Hill , Ekkehard Schwab
IPC分类号： C07C209/16
CPC分类号： C07C209/26 , C07C2601/14 , C07D295/023 , C07C211/35 , C07C211/08
摘要： A process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of primary and secondary amines in the presence of a heterogeneous catalyst, wherein the catalyst is a coated catalyst which comprises at least one metal of group VIII of the Periodic Table of the Elements as a hydrogenating metal and additionally a promoter on an oxidic support, at least 80% of the metal of group VIII of the Periodic Table of the Elements being present in a layer between the surface of the catalyst and a penetration depth which is not more than 80% of the radius of the catalyst, calculated from the surface of the catalyst.
摘要翻译：一种通过在多相催化剂存在下使醛和/或酮与氢和选自伯胺和仲胺的氮化合物反应制备胺的方法，其中催化剂是包含至少一种金属作为氢化金属的元素周期表第Ⅷ族，另外是氧化载体上的助催化剂，元素周期表第VIII族金属的至少80％存在于催化剂和渗透深度不超过催化剂半径的80％，由催化剂的表面计算。

3. 发明申请

US20090082562A1 PROCESS FOR PREPARING AN AMINE 有权
标题翻译：制备胺的方法
公开(公告)号：US20090082562A1
公开(公告)日：2009-03-26
申请号：US12293609
申请日：2007-03-13
申请人： Jan Eberhardt , Bram Willem Hoffer , Frank Haese , Johann-Peter Melder , Bernd Stein , Michael Stang , Thomas Hill , Ekkehard Schwab
发明人： Jan Eberhardt , Bram Willem Hoffer , Frank Haese , Johann-Peter Melder , Bernd Stein , Michael Stang , Thomas Hill , Ekkehard Schwab
IPC分类号： C07D295/033
CPC分类号： C07C209/26 , C07C2601/14 , C07D295/023 , C07C211/35 , C07C211/08
摘要： A process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group of primary and secondary amines in the presence of a heterogeneous catalyst, wherein the catalyst is a coated catalyst which comprises at least one metal of group VIII of the Periodic Table of the Elements as a hydrogenating metal and additionally a promoter on an oxidic support, at least 80% of the metal of group VIII of the Periodic Table of the Elements being present in a layer between the surface of the catalyst and a penetration depth which is not more than 80% of the radius of the catalyst, calculated from the surface of the catalyst.
摘要翻译：一种通过在多相催化剂存在下使醛和/或酮与氢和选自伯胺和仲胺的氮化合物反应制备胺的方法，其中催化剂是包含至少一种金属元素周期表第VIII族作为氢化金属，另外是氧化载体上的助催化剂，元素周期表第VIII族金属的至少80％存在于催化剂和渗透深度不超过催化剂半径的80％，由催化剂的表面计算。

4. 发明申请

US20100267948A1 PROCESS FOR THE PREPARATION OF AN AMINE 有权
标题翻译：制备胺的方法
公开(公告)号：US20100267948A1
公开(公告)日：2010-10-21
申请号：US12301811
申请日：2007-05-24
申请人： Jan Eberhardt , Harald Meissner , Bram Willem Hoffer , Johann-Peter Melder , Ekkehard Schwab
发明人： Jan Eberhardt , Harald Meissner , Bram Willem Hoffer , Johann-Peter Melder , Ekkehard Schwab
IPC分类号： C07D265/30 , C07C209/02
CPC分类号： C07C209/26 , C07C2601/14 , C07D295/023 , C07C211/07 , C07C211/08 , C07C211/35
摘要： Process for preparing an amine by reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound selected from the group consisting of primary and secondary amines in the presence of a heterogeneous catalyst, wherein the reaction is carried out using a suspended catalyst as heterogeneous catalyst and is carried out in the semibatch mode in which the nitrogen compound as one reactant is placed in the reaction vessel and the aldehyde and/or the ketone as the other reactant is added during the course of the reaction and the aldehyde and/or the ketone is added in portions or continuously to the reaction mixture during the course of the reaction as a function of the achieved conversion of the nitrogen compound until a conversion of the nitrogen compound of at least 95% results, and all or part of the catalyst remains in the reaction vessel after the reaction batch and is reused for the next reaction batch.
摘要翻译：在非均相催化剂存在下使醛和/或酮与氢和选自伯胺和仲胺的氮化合物反应制备胺的方法，其中反应使用悬浮催化剂作为非均相催化剂进行并且以半反应模式进行，其中作为一种反应物的氮化合物被放置在反应容器中，并且在反应过程中加入作为其它反应物的醛和/或酮，醛和/或酮在反应过程中以部分或连续的方式加入到反应混合物中，作为实现氮化合物转化的函数，直至氮化合物的转化率至少为95％，并且全部或部分催化剂保持在反应容器在反应批次后再次用于下一反应批次。

5. 发明申请

US20080200727A1 Method for Producing an Amine 审中-公开
标题翻译：生产胺的方法
公开(公告)号：US20080200727A1
公开(公告)日：2008-08-21
申请号：US11912981
申请日：2006-04-26
申请人： Jan Eberhardt , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder , Udo Rheude
发明人： Jan Eberhardt , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder , Udo Rheude
IPC分类号： C07C209/00
CPC分类号： C07D295/023 , C07C209/26 , C07C2601/14 , C07C211/35
摘要： Processes for preparing amines comprising reacting an aldehyde and/or ketone with hydrogen and a nitrogen compound in the presence of a heterogeneous catalyst, wherein the heterogeneous catalyst comprises a catalyst packing prepared by applying at least one compound selected from the group consisting of catalytically active metals, compounds of catalytically active metals, and mixtures thereof to a support material selected from the group consisting of woven fabrics, knitted fabrics, foils, and combinations thereof.
摘要翻译：制备胺的方法，包括在非均相催化剂存在下使醛和/或酮与氢和氮化合物反应，其中非均相催化剂包括通过将至少一种选自催化活性金属的化合物，催化活性金属的化合物及其混合物与选自机织织物，针织物，箔及其组合的支撑材料组合。

6. 发明授权

US08063252B2 Process for preparing amines and zirconium dioxide- and nickel-containing catalysts for use therein 有权
标题翻译：制备用于其中的胺和二氧化锆和含镍催化剂的方法
公开(公告)号：US08063252B2
公开(公告)日：2011-11-22
申请号：US12373825
申请日：2007-07-04
申请人： Petr Kubanek , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder , Holger Evers , Till Gerlach
发明人： Petr Kubanek , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder , Holger Evers , Till Gerlach
IPC分类号： C07C209/00
CPC分类号： C07C209/16 , B01J23/002 , B01J23/825 , B01J23/835 , B01J23/8435 , B01J23/8437 , B01J37/0009 , B01J37/0045 , B01J37/03 , B01J37/18 , B01J2523/00 , C07C209/26 , C07C213/02 , C07D295/023 , Y02P20/582 , B01J2523/17 , B01J2523/48 , B01J2523/54 , B01J2523/845 , B01J2523/847 , B01J2523/43 , B01J2523/53 , B01J2523/33 , C07C211/10 , C07C215/08 , C07C217/08
摘要： Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, nickel and cobalt, and one or more oxygen compounds of one or more metals selected from the group consisting of Pb, Bi, Sn, Sb and In.
摘要翻译：方法包括：（i）提供选自伯醇，仲醇，醛，酮及其混合物的反应物; 和（ii）在包含二氧化锆和含镍的催化活性组合物的催化剂存在下，使反应物与氢气和选自氨，伯胺，仲胺及其混合物的氮化合物反应，形成胺; 其中所述催化活性组合物在用氢还原之前包括锆，铜，镍和钴的氧化合物，以及一种或多种选自Pb，Bi，Sn，Sb和In中的一种或多种金属的氧化合物。

7. 发明申请

US20090275781A1 METHOD FOR PRODUCING AN AMINE 失效
标题翻译：生产氨的方法
公开(公告)号：US20090275781A1
公开(公告)日：2009-11-05
申请号：US12373793
申请日：2007-07-04
申请人： Petr Kubanek , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder , Holger Evers , Till Gerlach
发明人： Petr Kubanek , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder , Holger Evers , Till Gerlach
IPC分类号： C07C209/68 , B01J23/28
CPC分类号： C07C213/02 , B01J23/002 , B01J23/885 , B01J37/0009 , B01J37/0045 , B01J37/03 , B01J37/18 , B01J2523/00 , C07C209/16 , C07C209/26 , C07D295/023 , C07C211/10 , C07C215/08 , C07C217/08
摘要： Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof, and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, nickel and cobalt, and one or more oxygen compounds of molybdenum in an amount of 5.5 to 12% by weight, calculated as MoO3.
摘要翻译：方法包括：（i）提供选自伯醇，仲醇，醛，酮及其混合物的反应物，和（ii）使反应物与氢和氮化合物反应，所述氮和化合物选自氨，伯胺，仲胺及其混合物，在含有二氧化锆和镍的催化活性组合物的催化剂存在下，形成胺; 其中所述催化活性组合物在用氢还原之前包括锆，铜，镍和钴的氧化合物，以及以MoO 3计算的一种或多种重量百分比为5.5至12％的钼的氧化合物。

8. 发明申请

US20080255360A1 Process for Producing Ethyleneamines 有权
标题翻译：生产乙烯胺的方法
公开(公告)号：US20080255360A1
公开(公告)日：2008-10-16
申请号：US12088715
申请日：2006-09-25
申请人： Gunther van Cauwenberge , Johann-Peter Melder , Holger Evers , Till Gerlach , Frank Kiesslich , Ekkehard Schwab , Bram Willem Hoffer
发明人： Gunther van Cauwenberge , Johann-Peter Melder , Holger Evers , Till Gerlach , Frank Kiesslich , Ekkehard Schwab , Bram Willem Hoffer
IPC分类号： C07C209/14 , C07D295/023 , C07D241/04
CPC分类号： C07C209/16 , B01J21/04 , B01J23/755 , B01J35/023 , B01J37/0201 , B01J37/18 , C07D295/02 , C07D295/13 , C07C211/10 , C07C211/14
摘要： Processes comprising: providing a starting material comprising monoethanolamine; and reacting the starting material with ammonia in the presence of a heterogeneous transition metal catalyst to form a reaction product comprising one or more ethylene amines; wherein the catalyst comprises a catalytically active composition, which prior to treatment with hydrogen, comprises a mixture of oxygen-containing compounds of aluminum, copper, nickel and cobalt; and wherein the catalyst is present as one or more shaped catalyst particles selected from spheres, extrudates, pellets and other geometries, wherein the sphere or extrudate has a diameter of
摘要翻译：方法包括：提供包含单乙醇胺的原料; 并在非均相过渡金属催化剂的存在下使原料与氨反应形成包含一种或多种亚乙基胺的反应产物; 其中所述催化剂包含催化活性组合物，其在用氢处理之前包括铝，铜，镍和钴的含氧化合物的混合物; 并且其中所述催化剂作为选自球体，挤出物，丸粒和其它几何形状的一种或多种成型催化剂颗粒存在，其中所述球体或挤出物的直径<3mm，所述颗粒具有<3mm的高度，而另一种几何形状具有等效直径L = 1 / a'<0.70mm，其中a'是每单位体积的外表面积（mm×s×2 / 由 ${定义的}^{3 MI> a =A/ MSUB>Vp其中A < SUB>是催化剂颗粒的外表面积（mm 2），V p是催化剂颗粒的体积（mm 3） 3＆lt; 3＆gt; 3＆lt; 3＆gt;）。}$

9. 发明申请

US20100010264A1 METHOD FOR PRODUCING AN AMINE 失效
标题翻译：生产氨的方法
公开(公告)号：US20100010264A1
公开(公告)日：2010-01-14
申请号：US12373849
申请日：2007-07-04
申请人： Petr Kubanek , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder , Holger Evers , Till Gerlach
发明人： Petr Kubanek , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder , Holger Evers , Till Gerlach
IPC分类号： C07C209/00 , B01J23/72 , B01J23/755
CPC分类号： C07C209/16 , B01J23/825 , B01J23/835 , B01J23/8435 , B01J23/8437 , B01J37/0009 , B01J37/03 , B01J37/14 , B01J37/18 , C07C209/26 , C07C213/02 , C07D295/02 , C07D295/023 , C07C211/10 , C07C215/08 , C07C217/08
摘要： Processes comprising: (i) providing a reactant selected from the group consisting of primary alcohols, secondary alcohols, aldehydes, ketones and mixtures thereof; and (ii) reacting the reactant with hydrogen and a nitrogen compound selected from the group consisting of ammonia, primary amines, secondary amines and mixtures thereof, in the presence of a catalyst comprising a zirconium dioxide- and nickel-containing catalytically active composition, to form an amine; wherein the catalytically active composition, prior to reduction with hydrogen, comprises oxygen compounds of zirconium, copper, and nickel, and one or more oxygen compounds of one or more metals selected from the group consisting of Sb, Pb, Bi, and In.
摘要翻译：方法包括：（i）提供选自伯醇，仲醇，醛，酮及其混合物的反应物; 和（ii）在包含二氧化锆和含镍的催化活性组合物的催化剂存在下，使反应物与氢气和选自氨，伯胺，仲胺及其混合物的氮化合物反应，形成胺; 其中所述催化活性组合物在用氢还原之前包含锆，铜和镍的氧化合物和一种或多种选自Sb，Pb，Bi和In的一种或多种金属的氧化合物。

10. 发明申请

US20090030237A1 METHOD FOR PRODUCING ETHYLENE AMINES AND ETHANOL AMINES BY THE HYDROGENATING AMINATION OF MONOETHYLENE GLYCOL AND AMMONIA IN THE PRESENCE OF A CATALYST 有权
标题翻译：通过催化剂存在下单乙基甘氨酸和氨基甲酸的加氢胺化生产乙烯胺和乙醇胺的方法
公开(公告)号：US20090030237A1
公开(公告)日：2009-01-29
申请号：US12279215
申请日：2007-02-08
申请人： Gunther van Cauwenberge , Johann-Peter Melder , Bram Willem Hoffer , Thomas Krug , Karin Pickenaecker , Frank-Friedrich Pape , Ekkehard Schwab
发明人： Gunther van Cauwenberge , Johann-Peter Melder , Bram Willem Hoffer , Thomas Krug , Karin Pickenaecker , Frank-Friedrich Pape , Ekkehard Schwab
IPC分类号： C07C209/14
CPC分类号： C07C209/16 , C07C211/10 , C07C211/14
摘要： A process for preparing ethylene amines and ethanolamines by hydrogenative amination of monoethylene glycol and ammonia in the presence of a catalyst, wherein a catalyst having an active composition comprising ruthenium and cobalt and no further additional metal of group VIII and also no metal of group IB is used in the form of shaped catalyst bodies which in the case of a spherical shape or rod shape in each case have a diameter of
摘要翻译：一种在催化剂存在下通过单乙酰胺和氨的氢化胺化制备乙烯胺和乙醇胺的方法，其中具有包含钌和钴的活性组合物以及没有另外的另外的第VIII族金属以及也没有IB族金属的催化剂是使用成形催化剂体的形式，在球形或棒状的情况下，每种情况具有<3mm的直径，在颗粒形状的情况下具有<3mm的高度，并且在全部情况下每种情况下的其他几何形状具有等效直径L = 1 / a'<0.70mm，其中a'是每单位体积的外表面积（mms2 / mmp3），并且： $a'=\frac{其中Ap是成形催化剂体的外表面面积（mms2），Vp是（mms2），其中Ap是成形催化剂体的外表面积（mms2），Vp是}{提出了成形催化剂体的体积（mmp3）。}$

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