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1. 发明授权

US4889577A Method for making an improved supported membrane/electrode structure combination wherein catalytically active particles are coated onto the membrane 失效
标题翻译：制备改进的支撑膜/电极结构组合的方法，其中将催化活性颗粒涂覆在膜上
公开(公告)号：US4889577A
公开(公告)日：1989-12-26
申请号：US944474
申请日：1986-12-19
申请人： James W. McMichael , Robert D. Door
发明人： James W. McMichael , Robert D. Door
IPC分类号： C25B9/10 , H01M4/90 , H01M4/92 , H01M8/10
CPC分类号： H01M4/9091 , C25B9/10 , H01M4/928 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1053 , Y02P70/56
摘要： The invention is a membrane/electrode combination having an electrically conductive screen which has a first and a second face. At least the first face of the screen is substantially flat. The screen has a plurality of openings passing therethrough and connecting the first and the second faces of the screen. The openings occupying up to about 75% of the surface area of each face of the electrically conductive screen. The first face of an ion exchange membrane film, which has a first and a second face, is attached to the first face of the electrically conductive screen, thereby leaving portions of the first face of the membrane film exposed through the openings in the electrically conductive screen. A plurality of catalytically active particles are disposed on the exposed portions of the first face of the membrane film in electrical and physical contact with the membrane and with the electrically conductive screen.
摘要翻译：本发明是具有导电屏的膜/电极组合，其具有第一和第二面。至少屏幕的第一面基本上是平的。屏幕具有穿过其中并且连接屏幕的第一和第二面的多个开口。这些开口占据导电屏的每个表面的表面积的多达约75％。具有第一和第二面的离子交换膜膜的第一面被附着到导电屏的第一面上，从而使膜膜的第一面的一部分通过开口暴露于导电屏幕。多个催化活性颗粒被布置在膜膜的第一面的暴露部分上，与膜和导电屏幕电接触和物理接触。

2. 发明授权

US4752370A Supported membrane/electrode structure combination wherein catalytically active particles are coated onto the membrane 失效
标题翻译：支持的膜/电极结构组合，其中将催化活性颗粒涂覆在膜上
公开(公告)号：US4752370A
公开(公告)日：1988-06-21
申请号：US944395
申请日：1986-12-19
申请人： James W. McMichael , Robert D. Door
发明人： James W. McMichael , Robert D. Door
IPC分类号： C25B9/10 , H01M4/88 , H01M4/90 , H01M4/92 , H01M8/10 , C25B11/20
CPC分类号： H01M4/9091 , C25B9/10 , H01M4/928 , H01M8/1023 , H01M8/1039
摘要： The invention is a membrane/electrode combination having an electrically conductive screen which has a first and a second face. The first face is substantially flat and the screen has a plurality of openings passing through it. The openings connect the first and the second faces of the screen and occupy up to about 75% of the surface area of each face of the electrically conductive screen. There is also an ion exchange membrane film having a first and a second face. The first face of the membrane film is attached to the first face of the electrically conductive screen, thereby leaving portions of the first face of the membrane film exposed through the openings in the electrically conductive screen. A plurality of catalytically active particles are disposed on the exposed portions of the first face of the membrane film and are in electrical and physical contact with the membrane and with the electrically conductive screen.
摘要翻译：本发明是具有导电屏的膜/电极组合，其具有第一和第二面。第一面基本上是平的，并且屏幕具有穿过它的多个开口。开口连接屏幕的第一面和第二面，占据导电屏的每个面的表面积的约75％。还有一种具有第一和第二面的离子交换膜膜。膜膜的第一面附着在导电屏的第一面上，从而使膜膜的第一面的一部分通过导电屏中的开口露出。多个催化活性颗粒设置在膜膜的第一面的暴露部分上，并与膜和导电屏幕电气和物理接触。

3. 发明授权

US06852787B1 Free-flowing polymer composition 有权
标题翻译：自由流动的聚合物组成
公开(公告)号：US06852787B1
公开(公告)日：2005-02-08
申请号：US10049395
申请日：2000-08-16
申请人： James W. McMichael , Friedhelm Bunge , Jeffrey R. Montanye , Shrikant V. Dhodapkar
发明人： James W. McMichael , Friedhelm Bunge , Jeffrey R. Montanye , Shrikant V. Dhodapkar
IPC分类号： C08J3/12 , C08K3/26 , C08K3/34 , C08K5/09 , C08K5/10 , C08L25/04 , C08L27/06 , C08L53/02 , C08L3/34
CPC分类号： C08L23/0838 , C08J3/124 , C08J3/203 , C08J2323/08 , C08J2325/08 , C08K3/34 , C08L23/16 , C08L25/06 , C08L83/04 , Y10T428/2993 , C08L2666/02 , C08L2666/04 , C08L83/00
摘要： The present invention relates to substantially free-flowing polymer particles. The polymer particles are those which have a one millimeter penetration temperature of less than about 75° C. as determined by thermal mechanical analysis or an unconfined yield strength of greater than about 15 pounds per square foot (73 kilograms per square meter). The composition also comprises an effective amount of an anti-blocking agent in the presence or absence of a binding agent.
摘要翻译：本发明涉及基本上自由流动的聚合物颗粒。聚合物颗粒是通过热机械分析或大于约15磅/平方英尺（73千克每平方米）的无约束屈服强度确定的具有小于约75℃的1毫米渗透温度的聚合物颗粒。该组合物还包含有效量的防粘连剂，在存在或不存在粘合剂的情况下。

4. 发明授权

US4792386A Method and apparatus for installing a large, planar, delicate membrane in an electrolysis cell 失效
标题翻译：在电解池中安装大型，平面，细密膜的方法和装置
公开(公告)号：US4792386A
公开(公告)日：1988-12-20
申请号：US818465
申请日：1986-01-13
申请人： James W. McMichael
发明人： James W. McMichael
IPC分类号： C25B9/00
CPC分类号： C25B9/00
摘要： A method and apparatus for installing a sheet membrane in an electrolysis cell is disclosed. In the procedure, a rectangular sheet is first soaked in a selected wetting liquid preliminary to installation, one edge of the rectangular sheet is grasped in a lengthwise rigid releasable clamp, that edge is then positioned through a slot to extend the sheet member from a transport cylinder whereupon the sheet is rolled around the cylinder. This leaves an exposed marginal edge on the sheet which is clamped in a second and similar clamp. This then enables the sheet to be transported and positioned above a slot where the sheet is unrolled and positioned through the slot into an electrolysis cell. Suitable apparatus is also disclosed.
摘要翻译：公开了一种在电解槽中安装薄膜的方法和装置。在该过程中，首先将矩形片材浸入预先安装的选定的润湿液体中，将矩形片材的一个边缘沿纵向刚性可释放夹具夹持，然后将该边缘定位成穿过狭槽，以将片材部件从运输气缸，因此片材围绕气缸滚动。这样在片材上留下一个暴露的边缘，该边缘夹在第二个和类似的夹具中。这样就能使片材被传送和定位在片材被展开并通过狭槽定位成槽的插槽之上，进入电解槽。还公开了合适的装置。

5. 发明授权

US07101926B2 Free-flowing polymer composition 有权
公开(公告)号：US07101926B2
公开(公告)日：2006-09-05
申请号：US10961294
申请日：2004-10-08
申请人： James W. McMichael , Jeffrey Richard Montayne , Friedheim Bunge , Shirkant V. Dhodapkar
发明人： James W. McMichael , Jeffrey Richard Montayne , Friedheim Bunge , Shirkant V. Dhodapkar
IPC分类号： C08L3/34
CPC分类号： C08L23/0838 , C08J3/124 , C08J3/203 , C08J2323/08 , C08J2325/08 , C08K3/34 , C08L23/16 , C08L25/06 , C08L83/04 , Y10T428/2993 , C08L2666/02 , C08L2666/04 , C08L83/00
摘要： The present invention relates to substantially free-flowing polymer particles. The polymer particles are those which have a one millimeter penetration temperature of less than about 75° C. as determined by thermal mechanical analysis or an unconfined yield strength of greater than about 15 pounds per square foot (73 kilograms per square meter). The composition also comprises an effective amount of an anti-blocking agent in the presence or absence of a binding agent.

6. 发明授权

US5203978A Membrane-electrode structure for electrochemical cells 失效
标题翻译：电化学电池的膜 - 电极结构
公开(公告)号：US5203978A
公开(公告)日：1993-04-20
申请号：US792339
申请日：1991-11-14
申请人： Yu-Min Tsou , James W. McMichael , Richard N. Beaaver, deceased , Thomas J. Pisklak
发明人： Yu-Min Tsou , James W. McMichael , Richard N. Beaaver, deceased , Thomas J. Pisklak
IPC分类号： C25B9/10 , C25B9/00 , C25B9/08 , C25B13/08
CPC分类号： C25B9/10
摘要： A membrane-electrode structure for use in an electrochemical cell comprising an ion exchange membrane with a cathode layer and an intermediate layer between the cathode and the membrane. The intermediate layer comprises about 5 to 80% by weight of inorganic solid particles and about 95 to 20% by weight of an ionic conductive polymeric binder.
摘要翻译：一种用于电化学电池的膜电极结构，包括具有阴极层的离子交换膜和阴极和膜之间的中间层。中间层包含约5至80重量％的无机固体颗粒和约95至20重量％的离子导电聚合物粘合剂。

7. 发明授权

US4738741A Method for forming an improved membrane/electrode combination having interconnected roadways of catalytically active particles 失效
标题翻译：用于形成具有相互连接的催化活性颗粒的道路的改进的膜/电极组合的方法
公开(公告)号：US4738741A
公开(公告)日：1988-04-19
申请号：US944279
申请日：1986-12-19
申请人： James W. McMichael
发明人： James W. McMichael
IPC分类号： C25B9/10 , H01M4/90 , H01M4/92 , H01M8/10 , B44C3/00
CPC分类号： H01M4/9091 , C25B9/10 , H01M4/926 , H01M4/928 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1053 , Y02P70/56
摘要： The invention is a method for making an improved membrane/electrode combination by at least partially coating at least a portion of a first face of a screen template with a plurality of catalytically active particles, where the substantially flat screen has the first face, a second face, and a plurality of openings passing therethrough which connect the first and the second faces of the screen. The openings occupy up to about 75% of the surface area of each face of the screen template. The coated face of the screen template is contacted with an ion exchange membrane. The catalytically active particles are transferred from the screen template to the membrane and the particles are bonded to the membrane.
摘要翻译：本发明是通过用多个催化活性颗粒至少部分地涂覆筛网模板的第一面的至少一部分来制备改进的膜/电极组合的方法，其中基本上平的屏幕具有第一面，第二面面和穿过其中的多个开口连接屏幕的第一和第二面。开口占据屏幕模板每个面的表面积的约75％。屏幕模板的涂覆面与离子交换膜接触。催化活性颗粒从筛网模板转移到膜上，并且颗粒结合到膜上。

8. 发明授权

US08975341B2 Process for attaching a modifying agent to a substrate 有权
标题翻译：将改性剂附着于基材的方法
公开(公告)号：US08975341B2
公开(公告)日：2015-03-10
申请号：US13121313
申请日：2009-08-31
申请人： James W. McMichael , Jorg Theuerkauf , Bruce D. Hook , Malcolm F. Finlayson
发明人： James W. McMichael , Jorg Theuerkauf , Bruce D. Hook , Malcolm F. Finlayson
IPC分类号： C08F8/00 , B05D3/04 , C08J3/22 , C08J3/205 , C08K5/43
CPC分类号： C08J3/226 , C08J3/2053 , C08J2400/14 , C08J2423/00 , C08K5/43 , C08L23/02
摘要： Modifying agents, e.g., a poly(sulfonyl) azide, are attached to a substrate surface, e.g., the surface of a polyolefin particle, by a process comprising the steps of: A. Contacting in an open contact zone and under a flow of inert gas a substrate with a modifying agent, binding agent, e.g., a phenolic-based antioxidant, and a liquid mixing agent, e.g., methylene chloride, to form a substrate mixture; B. Closing the contact zone and stopping the flow of inert gas to the contact zone; C. Agitating the substrate mixture under the inert gas in the closed contact zone to commence evaporation of the liquid mixing agent; D. Reducing the temperature and pressure of the closed contact zone while continuing to agitate the substrate mixture; and E. Completing the substantial evaporation of the mixing agent from the substrate mixture by opening the contact zone and initiating an inert gas flow while continuing agitation of the substrate mixture and maintaining a reduced pressure.
摘要翻译：通过包括以下步骤的方法将改性剂例如聚（磺酰基）叠氮化物连接到基材表面，例如聚烯烃颗粒的表面上：A.在开放接触区域和惰性气流下接触用改性剂，粘合剂（例如酚类抗氧化剂）和液体混合剂（例如二氯甲烷）气化基质以形成底物混合物; B.关闭接触区并阻止惰性气体流向接触区; C.在密闭接触区域内将惰性气体下的底物混合物搅拌以开始液体混合剂的蒸发; D.减少封闭接触区的温度和压力，同时继续搅拌底物混合物; E.通过打开接触区并引发惰性气体流，同时继续搅拌基底混合物并保持减压，完成混合剂从基质混合物的充分蒸发。

9. 发明申请

US20110178243A1 Process for Attaching a Modifying Agent to a Substrate 有权
标题翻译：将改性剂附着到基材上的方法
公开(公告)号：US20110178243A1
公开(公告)日：2011-07-21
申请号：US13121313
申请日：2009-08-31
申请人： James W. McMichael , Jorg Theuerkauf , Bruce D. Hook , Malcolm F. Ginlayson
发明人： James W. McMichael , Jorg Theuerkauf , Bruce D. Hook , Malcolm F. Ginlayson
IPC分类号： C08F8/00 , B05D3/04
CPC分类号： C08J3/226 , C08J3/2053 , C08J2400/14 , C08J2423/00 , C08K5/43 , C08L23/02
摘要： Modifying agents, e.g., a poly(sulfonyl) azide, are attached to a substrate surface, e.g., the surface of a polyolefin particle, by a process comprising the steps of: A. Contacting in an open contact zone and under a flow of inert gas a substrate with a modifying agent, binding agent, e.g., a phenolic-based antioxidant, and a liquid mixing agent, e.g., methylene chloride, to form a substrate mixture; B. Closing the contact zone and stopping the flow of inert gas to the contact zone; C. Agitating the substrate mixture under the inert gas in the closed contact zone to commence evaporation of the liquid mixing agent; D. Reducing the temperature and pressure of the closed contact zone while continuing to agitate the substrate mixture; and E. Completing the substantial evaporation of the mixing agent from the substrate mixture by opening the contact zone and initiating an inert gas flow while continuing agitation of the substrate mixture and maintaining a reduced pressure.
摘要翻译：通过包括以下步骤的方法将改性剂例如聚（磺酰基）叠氮化物连接到基材表面，例如聚烯烃颗粒的表面上：A.在开放接触区域和惰性气流下接触用改性剂，粘合剂（例如酚类抗氧化剂）和液体混合剂（例如二氯甲烷）气化基质以形成底物混合物; B.关闭接触区并阻止惰性气体流向接触区; C.在密闭接触区域内将惰性气体下的底物混合物搅拌以开始液体混合剂的蒸发; D.减少封闭接触区的温度和压力，同时继续搅拌底物混合物; E.通过打开接触区并引发惰性气体流，同时继续搅拌基底混合物并保持减压，完成混合剂从基质混合物的充分蒸发。

10. 发明申请

US20110008623A1 COAT POLYMERIC PARTICULATE, AND A PROCESS FOR COATING A POLYMERIC PARTICULATE 审中-公开
标题翻译：涂层聚合物颗粒，以及涂覆聚合物颗粒的方法
公开(公告)号：US20110008623A1
公开(公告)日：2011-01-13
申请号：US12677215
申请日：2008-09-02
申请人： Shrikant V. Dhodapkar , James W. McMichael
发明人： Shrikant V. Dhodapkar , James W. McMichael
IPC分类号： B32B1/00 , B05D7/02
CPC分类号： B29B9/16 , B29B2009/163 , Y10T428/2998
摘要： The instant invention is a coated polymeric particulate, and a process for coating a polymeric particulate. The coated polymeric particulate includes a polymeric particulate; and a coating composition present on at least a portion of at least one surface of the polymeric particulate. The coating includes an interconnected media; and at least one discrete island at least partially embedded in the interconnected media. The process for coating a polymeric particulate includes the following steps: (1) selecting a polymeric particulate; (2) selecting an aqueous dispersion comprising (a) a small particle component, wherein the small particle component comprises a polyolefin polymer having an average particle size in the range of 0.02 to 0.15 μm; (b) a large particle component, wherein the large particle component comprises a polyolefin polymer having an average particle size in the range of 0.3 to 0.8 μm; and (c) water; (3) applying the aqueous dispersion to the polymeric particulate; (4) thereby coating the polymeric particulate.
摘要翻译：本发明是涂覆的聚合物颗粒，以及用于涂覆聚合物颗粒的方法。涂覆的聚合物颗粒包括聚合物颗粒; 以及存在于聚合物颗粒的至少一个表面的至少一部分上的涂料组合物。涂层包括互连的介质; 以及至少部分地嵌入在所述互连的介质中的至少一个离散的岛。涂覆聚合物颗粒的方法包括以下步骤：（1）选择聚合物颗粒; （2）选择含有（a）小颗粒成分的水分散体，其中所述小颗粒组分包含平均粒径在0.02至0.15μm范围内的聚烯烃聚合物; （b）大颗粒组分，其中大颗粒组分包含平均粒度在0.3至0.8μm范围内的聚烯烃聚合物; 和（c）水; （3）将水分散体施加到聚合物颗粒上; （4），从而涂覆聚合物颗粒。

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