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1. 发明申请

US20090023820A1 SURFACTANT MIXTURE CONTAINING SHORT-CHAIN AND ALSO LONG-CHAIN COMPONENTS 审中-公开
标题翻译：含短链和长链组分的表面活性剂混合物
公开(公告)号：US20090023820A1
公开(公告)日：2009-01-22
申请号：US12280114
申请日：2007-02-15
申请人： James S. Dailey , Ernst Lippert , Sridhar G. Iyer , Ulrich Steinbrenner , Christoffer Kieburg , Jurgen Tropsch , Richard Baur , Soeren Zimdahl
发明人： James S. Dailey , Ernst Lippert , Sridhar G. Iyer , Ulrich Steinbrenner , Christoffer Kieburg , Jurgen Tropsch , Richard Baur , Soeren Zimdahl
IPC分类号： B01F17/38
CPC分类号： C11D1/8255 , A01N25/30 , C11D1/29 , C11D1/345 , C11D1/37 , C11D1/72 , C11D1/8305 , C11D3/0026 , D06M13/17 , D06M15/53
摘要： The present invention relates to a surfactant mixture comprising (A) a short-chain component comprising the alkoxylation product of alkanols, where the alkanols have 8 to 12 carbon atoms and the average number of alkoxy groups per alkanol group in the alkoxylation product assumes a value from 3 to 30 and the alkoxy groups are chosen from the group consisting of ethoxy, propoxy, butoxy and pentoxy groups and the alkanols have an average degree of branching of at least 1; and (B) a long-chain component comprising the alkoxylation product of alkanols where the alkanols have 13 to 20 carbon atoms and the average number of alkoxy groups per alkanol group in the alkoxylation product assumes a value from 3 to 30 and the alkoxy groups are chosen from the group consisting of ethoxy, propoxy, butoxy and pentoxy groups and the alkanols have an average degree of branching of from 0.0 to 0.3; and phosphate esters, sulfate esters and ether carboxylates thereof. In addition, the present invention relates to a formulation comprising such surfactant mixtures, and to the use of these, for example for the cleaning of hard surfaces.
摘要翻译：本发明涉及一种表面活性剂混合物，其包含（A）包含烷醇的烷氧基化产物的短链组分，其中烷醇具有8至12个碳原子，并且烷氧基化产物中每个烷醇基团的烷氧基的平均数呈现值 3至30，并且烷氧基选自乙氧基，丙氧基，丁氧基和戊氧基，并且所述链烷醇具有至少1的平均支化度; 和（B）包含烷醇的烷氧基化产物的长链组分，其中链烷醇具有13-20个碳原子，烷氧基化产物中每个烷醇基团的烷氧基的平均数为3-30，烷氧基为选自乙氧基，丙氧基，丁氧基和戊氧基，并且所述链烷醇的平均支化度为0.0至0.3; 和磷酸酯，硫酸酯和醚羧酸盐。此外，本发明涉及包含这种表面活性剂混合物的制剂，以及这些用于清洁硬表面的用途。

2. 发明申请

US20070225189A1 Surfactant Composition And Method Of Forming 有权
标题翻译：表面活性剂组合物和形成方法
公开(公告)号：US20070225189A1
公开(公告)日：2007-09-27
申请号：US11677824
申请日：2007-02-22
申请人： James Dailey , Ernst Lippert , Sridhar Iyer , Ulrich Steinbrenner , Christoffer Kieburg , Jurgen Tropsch , Richard Baur , Soeren Zimdahl
发明人： James Dailey , Ernst Lippert , Sridhar Iyer , Ulrich Steinbrenner , Christoffer Kieburg , Jurgen Tropsch , Richard Baur , Soeren Zimdahl
IPC分类号： C11D3/00
CPC分类号： C11D1/8255 , A01N25/30 , C11D1/29 , C11D1/345 , C11D1/37 , C11D1/72 , C11D1/8305 , C11D3/0026 , D06M13/17 , D06M15/53
摘要： A surfactant composition includes a first surfactant, a second surfactant, and a polyalkylene glycol. The first surfactant is of the general formula R1—O-(A)mH, wherein R1 is an aliphatic hydrocarbon having 10 carbon atoms, A is an alkyleneoxy group having from 2 to 5 carbon atoms, and m is a positive number. The second surfactant is of the general formula R2—O—(B)nH, wherein R2 is an aliphatic hydrocarbon having from 12 to 14 carbon atoms, B is an alkyleneoxy group having from 2 to 5 carbon atoms, and n is a positive number. The polyalkylene glycol is present in the surfactant composition in an amount of from 3 to 20 parts by weight per 100 parts by weight of the surfactant composition.
摘要翻译：表面活性剂组合物包括第一表面活性剂，第二表面活性剂和聚亚烷基二醇。第一表面活性剂具有通式R 1 -O -O-（A）m H，其中R 1是具有10个碳原子的脂族烃原子，A是具有2至5个碳原子的亚烷氧基，m是正数。第二表面活性剂具有通式R 2 -O-（B）n H，其中R 2是具有12个碳原子的脂族烃，至14个碳原子，B为具有2至5个碳原子的亚烷基氧基，n为正数。表面活性剂组合物中存在的聚亚烷基二醇的量为每100重量份表面活性剂组合物3至20重量份。

3. 发明申请

US20050107628A1 Modified method for producing surfactant alcohols and surfactant alcohol ethers, the products of said method and use of the same 审中-公开
标题翻译：用于生产表面活性剂醇和表面活性剂醇醚的改性方法，所述方法的用途和使用方法相同
公开(公告)号：US20050107628A1
公开(公告)日：2005-05-19
申请号：US10503213
申请日：2003-02-19
申请人： Michael Roper , Jurgen Stephan , Gotz-Peter Schindler , Jurgen Tropsch , Thomas Heidemann , Martina Prinz , Soeren Zimdahl
发明人： Michael Roper , Jurgen Stephan , Gotz-Peter Schindler , Jurgen Tropsch , Thomas Heidemann , Martina Prinz , Soeren Zimdahl
IPC分类号： C07B61/00 , C07C2/00 , C07C2/06 , C07C2/10 , C07C6/04 , C07C11/02 , C07C11/107 , C07C29/141 , C07C29/16 , C07C31/125 , C07C41/03 , C07C45/50 , C07C47/21 , C07C9/00 , C07C27/12 , C07F9/02 , C07H13/02
CPC分类号： C07C29/141 , C07C2/06 , C07C6/04 , C07C29/16 , C07C45/50 , C07C31/125 , C07C47/02
摘要： A process for preparing surfactant alcohols and surfactant alcohol ethers by derivatization of olefins having about 10 to 20 carbon atoms or of mixtures of such olefins and optional subsequent alkoxylation is described. As features, the process involves (a) subjecting a C4-olefin mixture with a 1-butene/2-butene ratio of ≧1.2 to a metathesis, (b) separating off olefins having 5 to 8 carbon atoms from the metathesis mixture, (c) subjecting the separated-off olefins individually or in a mixture to a dimerization to give olefin mixtures having 10 to 16 carbon atoms, (d) subjecting the resulting olefin mixture, optionally after a fractionation, to derivatization to give a mixture of surfactant alcohols and (e) optionally alkoxylating the surfactant alcohols. The olefin mixture obtained in the dimerization comprises a high content of branched components and less than 10% by weight of compounds which contain a vinylidene group. Also described is the use of surfactant alcohols and surfactant alcohol ethers to give surfactans by glycosidation or polyglycosidation, sulfation or phosphation.
摘要翻译：描述了通过衍生具有约10至20个碳原子的烯烃或这种烯烃的混合物和任选的随后的烷氧基化来制备表面活性剂醇和表面活性剂醇醚的方法。作为特征，该方法包括（a）使具有> = 1.2的1-丁烯/ 2-丁烯比的C 4 - 4 - 烯烃混合物复分解，（b）将具有5至（c）将单独或混合物中的分离的烯烃进行二聚，得到具有10至16个碳原子的烯烃混合物，（d）任选地在分馏之后对所得烯烃混合物进行处理，衍生化得到表面活性剂醇的混合物和（e）任选地使表面活性剂醇烷氧基化。在二聚中获得的烯烃混合物包含高含量的支链组分和小于10重量％的含有亚乙烯基的化合物。还描述了表面活性剂醇和表面活性剂醇醚通过糖基化或多糖苷化，硫酸化或磷酸化来提供表面活性剂的用途。

4. 发明申请

US20070203050A1 Synergistic Surfactant Mixtures With Higher Dynamic Properties And Lower Cmc 审中-公开
标题翻译：具有较高动态特性和较低Cmc的协同表面活性剂混合物
公开(公告)号：US20070203050A1
公开(公告)日：2007-08-30
申请号：US11578140
申请日：2005-04-28
申请人： Gunter Oetter , Stephan Hess , Ulrich Steinbrenner , Jurgen Tropsch
发明人： Gunter Oetter , Stephan Hess , Ulrich Steinbrenner , Jurgen Tropsch
IPC分类号： C11D17/00
CPC分类号： C11D1/83 , C11D1/123 , C11D1/72 , C11D1/75 , C11D1/825 , C11D1/94
摘要： The present invention relates to a surfactant mixture of at least one anionic surfactant and at least one amphoteric surfactant, to a solution consisting of 0.01-40% by weight of such a surfactant mixture, 60-99.99% by weight of water and 0-5% by weight of additives, to the use of surfactant mixtures of at least one anionic surfactant and at least one amphoteric surfactant or of at least one nonionic surfactant and at least one amphoteric surfactant for reducing the critical micelle formation concentration, increasing the rate of wetting and improving the adsorption at interfaces in detergents, cleaning compositions, dishwashing compositions, coatings, humectants, emulsions, suspensions, leveling assistants or formulations for the treatment of leather and/or textiles, and to cleaning compositions comprising surfactant mixtures of the Na salt of di-2-ethylhexyl sulfosuccinate and myristyl- and/or lauryldimethylamine oxide or isotridecanol which is ethoxylated with 3 to 7 equivalents of ethylene oxide, and myristyl- and/or lauryidimethylamine oxide.
摘要翻译：本发明涉及至少一种阴离子表面活性剂和至少一种两性表面活性剂的表面活性剂混合物与由0.01-40重量％的这种表面活性剂混合物，60-99.99重量％的水和0-5 使用至少一种阴离子表面活性剂和至少一种两性表面活性剂或至少一种非离子表面活性剂和至少一种两性表面活性剂的表面活性剂混合物用于降低临界胶束形成浓度，增加润湿速率并且改善洗涤剂，清洁组合物，餐具洗涤组合物，涂层，保湿剂，乳液，悬浮液，流平助剂或用于处理皮革和/或纺织品的制剂中的界面处的吸附，以及清洁组合物，其包含二 -2-乙基己基磺基琥珀酸酯和肉豆蔻基 - 和/或月桂基二甲基胺氧化物或异三癸醇，其用3至7当量的环氧乙烷和肉豆蔻基 - 和/或月桂基二甲基胺氧化物。

5. 发明申请

US20080214683A1 Rapid Low-Foam Wetting Agents for Hydrophobic Surfaces 失效
标题翻译：用于疏水表面的快速低泡沫润湿剂
公开(公告)号：US20080214683A1
公开(公告)日：2008-09-04
申请号：US11578417
申请日：2005-04-26
申请人： Ulrich Steinbrenner , Paul Klingelhoefer , Jurgen Tropsch
发明人： Ulrich Steinbrenner , Paul Klingelhoefer , Jurgen Tropsch
IPC分类号： C07C43/15 , B01D12/00
CPC分类号： B01F17/0028 , B01F17/0021 , B01F17/0092 , C11D1/72 , C11D1/722 , C11D1/8255
摘要： The present invention relates to the use of surfactants of the general formula (I) R—O-(A)n-(B)m—H (I) where R is a C8-alkyl radical, A is propylenoxy, B is ethylenoxy, n is an average value of from 0.8 to 2.0 and m is an average value of from 2.0 to 5.0 as a wetting agent for hydrophobic polymer surfaces, and to a wetting agent comprising a) from 0.5 to 50% by weight of at least one surfactant of the general formula (I) according to claim 1, b) from 1.0 to 10% by weight of a C8-alcohol and c) from 0.5 to 30% by weight of a compound of the general formula (IV) R—O-(A)n-H (IV) where R is a C8-alkyl radical, A is propylenoxy and n is an average value of from 0.8 to 2.0.
摘要翻译：本发明涉及通式（I）的表面活性剂的用途<？in-line-formula description =“In-line Formulas”end =“lead”→> RO-（A） - （B） -H（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R是C < /亚烷基，A为丙烯氧基，B为乙烯氧基，n为0.8〜2.0的平均值，m为疏水性聚合物表面的润湿剂的平均值为2.0〜5.0，润湿剂包含a）0.5至50重量％的至少一种根据权利要求1所述的通式（I）的表面活性剂，b）1.0-10重量％的C 8 - 醇和 c）0.5至30重量％的通式（IV）的化合物<？in-line-formula description =“In-line Formulas”end =“lead”→> RO-（A） -H（IV）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R是C 8 - 烷基，A是丙烯氧基，n为0.8〜2.0的平均值。

6. 发明申请

US20070142258A1 Method for producing alkylaryl compounds 审中-公开
标题翻译：烷基芳基化合物的制备方法
公开(公告)号：US20070142258A1
公开(公告)日：2007-06-21
申请号：US10583140
申请日：2004-12-17
申请人： Ulrich Steinbrenner , Thomas Heidemann , Michael Roper , Jurgen Stephan , Thomas Narbeshuber , Jurgen Tropsch , Nils Bottke , Regina Benfer
发明人： Ulrich Steinbrenner , Thomas Heidemann , Michael Roper , Jurgen Stephan , Thomas Narbeshuber , Jurgen Tropsch , Nils Bottke , Regina Benfer
IPC分类号： C09D9/00
CPC分类号： C07C6/04 , C07C2/08 , C07C2/66 , C07C5/2506 , C07C303/06 , C11D1/22 , C11D11/04 , C07C309/31 , C07C11/02 , C07C11/10 , C07C15/107
摘要： The preparation of alkylaryl compounds takes place by a) reaction of a C4/C5-olefin mixture over a metathesis catalyst to prepare a C4-8-olefin mixture comprising 2-pentene, and optional removal of the C4-8-olefin mixture, b) removal of from 5 to 100% of the 2-pentene present in stage a) and subsequent reaction over an isomerization catalyst to give a mixture of 2-pentene and 1-pentene which is returned to stage a), c) dimerization of the C4-8-olefin mixture obtained in stage b) following removal in the presence of a dimerization catalyst to give a mixture containing C8-16-olefins, removal of these C8-16-olefins and optional removal of a partial stream thereof, d) reaction of the c8-16-olefin mixtures obtained in stage c) or of the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds where, prior to the reaction, 0 to 60% by weight, based on the c8-16-olefin mixtures obtained in stage c), of linear olefins may additionally be added, e) optional sulfonation of the alkyl aromatic compounds obtained in stage d) and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, 0 to 60% by weight, based on the alkyl aromatic compounds obtained in stage d), of linear alkylbenzenes may additionally be added if no admixing has taken place in stage d), f) optional mixing of the alkylarylsulfonates obtained in stage e) with 0 to 60% by weight, based on the alkylarylsulfonates obtained in stage e), of linear alkylarylsulfonate, if no admixing has taken place in stages d) and e).
摘要翻译：烷基芳基化合物的制备通过以下步骤进行：a）在复分解催化剂上使C 4-14 C 5 -C 5 - 烯烃混合物反应以制备C 4-8 - 其包含2-戊烯，任选地除去C 4-18α-烯烃混合物，b）除去在步骤a）中存在的5-100％的2-戊烯，并随后在异构化催化剂上反应，得到2-戊烯和1-戊烯的混合物，将其返回到a）步骤，c）在步骤b中获得的C 4-18α-烯烃混合物的二聚反应），在二聚催化剂存在下除去，得到含有C 8-16 - 烯烃的混合物，除去这些C 8-16 - 烯烃并任选地除去其部分流，d）在烷基化催化剂存在下，将阶段c）或部分流中获得的C 8-16 - α-烯烃混合物与芳族烃反应，形成烷基芳族化合物，其中在反应之前，0至60重量％，b 在阶段c）中得到的C 8-16α-烯烃混合物中，可以另外加入线性烯烃，e）任选的在步骤d）中获得的烷基芳族化合物磺化，中和得到烷基芳基磺酸盐，其中在磺化之前，如果在步骤d）中没有混合，则可以另外加入基于直链烷基苯中得到的直链烷基苯0至60重量％，f）任选混合如果在阶段d）和e）中没有混合，则在阶段e）中获得的烷基芳基磺酸盐以0至60重量％的量计，基于阶段e）中得到的烷基芳基磺酸盐，为直链烷基芳基磺酸盐。

7. 发明申请

US20050170991A1 Alkoxylate mixtures and detergents containing the same 有权
标题翻译：烷氧基化物混合物和含有它们的洗涤剂
公开(公告)号：US20050170991A1
公开(公告)日：2005-08-04
申请号：US10511445
申请日：2003-04-25
申请人： Alfred Ruland , Martin Scholtissek , Jurgen Tropsch , Richard Baur
发明人： Alfred Ruland , Martin Scholtissek , Jurgen Tropsch , Richard Baur
IPC分类号： C07C41/03 , C07C43/11 , C08G65/26 , C11D1/72 , C11D1/722 , C11D1/825 , C11D17/00
CPC分类号： C07C43/11 , C07C41/03 , C08G65/2663 , C11D1/72 , C11D1/722 , C11D1/825 , C11D1/8255
摘要： The alkoxylate mixture comprises 0.1 to 99.9% by weight of at least one alkoxylate of the formula (I) CnH2n+1O(A)x(B)yH (I) where A is ethyleneoxy, B is C3-C10-alkyleneoxy or mixtures thereof, where groups A and B may be present randomly distributed, alternately or in the form of two or more blocks in any order, n is an integer in the range from 8 to 11, x is a number in the range from 1 to 20, y is a number in the range from 0 to 10, and 0.1 to 99.9% by weight of at least one alkoxylate of the formula (II) CmH2m+1O(A)v(B)wH (II) where A is ethyleneoxy, B is C3-C10-alkyleneoxy or mixtures thereof, where groups A and B may be present randomly distributed, alternately or in the form of two or more blocks in any order, m is an integer in the range from 12 to 24, v is a number in the range from 1 to 50, w is a number in the range from 0 to 10.
摘要翻译：所述烷氧基化物混合物包含0.1至99.9重量％的至少一种式（I）的烷氧基化物，其中所述烷氧基化物混合物包含0.1至99.9重量％的至少一种式（I）的烷氧基化物，（A）x（B）H（I）＆lt;＆lt;直线公式描述=“ 其中A是亚乙基氧基，B是C 3 -C 10 - 亚烷基氧基或其混合物，其中基团A和B可以以任何顺序交替地或以两个或多个块的形式随机分布，n为8至11的整数，x为1至20的数，y为范围内的数字 0至10，和0.1至99.9重量％的至少一种式（II）的烷氧基化物<？在线公式描述=“在线公式”末端=“铅”→> C （B）H（II）<β在线公式描述中，H（II）

8. 发明申请

US20080167215A1 Esterified Alkylalkoxylates Used as Low-Foam Surfactants 有权
标题翻译：用作低泡沫表面活性剂的酯化烷基烷氧基化物
公开(公告)号：US20080167215A1
公开(公告)日：2008-07-10
申请号：US11908432
申请日：2006-03-10
申请人： Christian Bittner , Jurgen Tropsch , Ralf Norenberg
发明人： Christian Bittner , Jurgen Tropsch , Ralf Norenberg
IPC分类号： C11D1/74 , C07C69/22
CPC分类号： C07C41/03 , C07C67/03 , C07C67/08 , C07C69/24 , C11D1/74 , C11D3/0026 , C07C43/11
摘要： The present invention relates to low-foam surfactant mixtures of the general formula (I) where R, Ra, R1 and R2, l, n and m have the meaning given in the description and the claims, and to the production thereof. For example, R=C13-alkyl, Ra=H, l=5, m=22, n=1, R1=methyl and R2=C6-C14-alkyl. The surfactants are suitable for detergent and cleaner formulations.
摘要翻译：本发明涉及通式（I）的低泡表面活性剂混合物，其中R 1，R 2，R 1，R 2和R 2， l，n和m具有在说明书和权利要求书中给出的含义及其生产。例如，R = C 13 - 烷基，R a = H，l = 5，m = 22，n = 1，R 1， =甲基，R 2是C 6 -C 14 - 烷基。表面活性剂适用于洗涤剂和清洁剂配方。

9. 发明申请

US20060009368A1 Alkylglycidol carbonates as cosurfactants 审中-公开
标题翻译：烷基甘氨醇碳酸酯作为辅助表面活性剂
公开(公告)号：US20060009368A1
公开(公告)日：2006-01-12
申请号：US10528700
申请日：2003-09-30
申请人： Ralf Noerenberg , Michael Kluge , Christian Wulff , Jurgen Tropsch , Martin Scholtissek
发明人： Ralf Noerenberg , Michael Kluge , Christian Wulff , Jurgen Tropsch , Martin Scholtissek
IPC分类号： C11D17/00
CPC分类号： C07D317/38 , C11D1/42 , C11D1/528 , C11D1/66 , C11D1/667 , C11D3/2096 , C11D3/32 , C11D3/3427
摘要： The present invention relates to novel alkylglycidol carbonates and to their use as cosurfactants. The cosurfactants are suitable for use in household detergents, household cleaners, body-cleansing compositions and body care compositions.
摘要翻译：本发明涉及新的烷基缩水甘油碳酸酯及其作为辅助表面活性剂的用途。辅助表面活性剂适用于家用洗涤剂，家用清洁剂，身体清洁组合物和身体护理组合物。

10. 发明授权

US6136873A Water-absorbing, expanded, crosslinked polymers, the production and use thereof 失效
标题翻译：吸水膨胀交联聚合物的生产和使用
公开(公告)号：US6136873A
公开(公告)日：2000-10-24
申请号：US68023
申请日：1998-05-04
申请人： Hans-Joachim Hahnle , Manfred Walter , Jurgen Tropsch , Gunnar Schornick , Thomas Anstock
发明人： Hans-Joachim Hahnle , Manfred Walter , Jurgen Tropsch , Gunnar Schornick , Thomas Anstock
IPC分类号： A61L15/00 , A61L15/42 , A61L15/60 , C08F2/16 , C08F220/06 , C08J9/30 , C08L33/02 , C08J9/28
CPC分类号： C08F220/06 , A61L15/425 , A61L15/60
摘要： Water-absorbing, expanded, crosslinked polymers obtainable by(I) foaming a polymerizable aqueous mixture which comprises(a) monoethylenically unsaturated monomers which contain acidic groups and are at least 50 mol % neutralized,(b) with or without other monoethylenically unsaturated monomers,(c) crosslinkers,(d) initiators,(e) 0.1-20% by weight of at least one surfactant,(f) with or without at least one solubilizer and(g) with or without thickeners, foam stabilizers, polymerization regulators, fillers and/or cell nucleating agents,where the foaming takes place by dispersing fine bubbles of a gas which is inert to free radicals, and(II) polymerizing the foamed mixture to form an expanded hydrogel and adjusting the water content of the expanded polymer to 1-45% by weight, a process for their production and their use in hygiene articles employed to absorb body fluids and in dressing material for covering wounds.
摘要翻译： PCT No.PCT / EP96 / 04644 Sec。 371日期：1998年5月4日 102（e）日期1998年5月4日PCT 1996年10月25日PCT公布。公开号WO97 / 17397 日期1997年5月15日可通过（I）发泡可聚合水性混合物得到的吸水膨胀交联聚合物，其包含（a）含有酸性基团并且至少50摩尔％中和的单烯属不饱和单体，（b）有或没有其它单烯属不饱和单体，（c）交联剂，（d）引发剂，（e）0.1-20重量％的至少一种表面活性剂，（f）有或没有至少一种增溶剂，和（g）有或没有增稠剂，泡沫稳定剂，聚合调节剂，填料和/或细胞成核剂，其中通过分散对自由基惰性的气体的细小气泡进行发泡，和（II）将发泡混合物聚合以形成膨胀的水凝胶并调节水分含量膨胀聚合物为1-45重量％，其生产方法及其在用于吸收体液的卫生制品中的用途以及用于覆盖伤口的敷料材料。

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