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1. 发明申请

US20070191223A1 Alcohol Steam Reforming Catalysts and Methods of Alcohol Steam Reforming 失效
标题翻译：醇蒸汽重整催化剂和酒精蒸汽重整方法
公开(公告)号：US20070191223A1
公开(公告)日：2007-08-16
申请号：US11691400
申请日：2007-03-26
申请人： Jamelyn Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert Dagle , Guanguang Xia , Eddie Baker , Daniel Palo , Max Phelps , Heon Jung
发明人： Jamelyn Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert Dagle , Guanguang Xia , Eddie Baker , Daniel Palo , Max Phelps , Heon Jung
IPC分类号： B01J23/44 , B01J23/42
CPC分类号： C01B3/326 , B01J19/0093 , B01J21/04 , B01J23/60 , B01J35/002 , B01J37/0201 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00862 , B01J2219/00873 , B01J2219/00891 , B01J2219/00961 , B01J2219/00997 , C01B3/586 , C01B2203/0233 , C01B2203/0445 , C01B2203/047 , C01B2203/1041 , C01B2203/1064 , C01B2203/1223 , Y02P20/52
摘要： The present invention provides steam reforming catalyst compositions containing Pd and Zn, and methods of steam reforming alcohols over a catalyst. Surprisingly superior results and properties of the present invention, including low temperature activity and/or low carbon monoxide output, are also described. Methods of making a steam reforming catalyst are also provided.
摘要翻译：本发明提供含有Pd和Zn的蒸汽重整催化剂组合物，以及在催化剂上蒸汽重整醇的方法。还描述了包括低温活性和/或低一氧化碳输出的本发明的令人惊奇的优异结果和性质。还提供了制备蒸汽重整催化剂的方法。

2. 发明申请

US20070041893A1 ALCOHOL STEAM REFORMING CATALYSTS AND METHODS ALCOHOL STEAM REFORMING 有权
标题翻译：酒精蒸汽重整催化剂和方法酒精蒸汽重整
公开(公告)号：US20070041893A1
公开(公告)日：2007-02-22
申请号：US10440448
申请日：2003-05-16
申请人： Jamelyn Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert Dagle , Guanguang Xia , Eddie Baker , Daniel Palo , Max Phelps , Heon Jung
发明人： Jamelyn Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert Dagle , Guanguang Xia , Eddie Baker , Daniel Palo , Max Phelps , Heon Jung
IPC分类号： C01B3/02
CPC分类号： C01B3/326 , B01J19/0093 , B01J21/04 , B01J23/60 , B01J35/002 , B01J37/0201 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00862 , B01J2219/00873 , B01J2219/00891 , B01J2219/00961 , B01J2219/00997 , C01B3/586 , C01B2203/0233 , C01B2203/0445 , C01B2203/047 , C01B2203/1041 , C01B2203/1064 , C01B2203/1223 , Y02P20/52
摘要： The present invention provides steam reforming catalyst compositions containing Pd and Zn, and methods of steam reforming alcohols over a catalyst. Surprisingly superior results and properties of the present invention, including low temperature activity and/or low carbon monoxide output, are also described. Methods of making a steam reforming catalyst are also provided.
摘要翻译：本发明提供含有Pd和Zn的蒸汽重整催化剂组合物，以及在催化剂上蒸汽重整醇的方法。还描述了包括低温活性和/或低一氧化碳输出的本发明的令人惊奇的优异结果和性质。还提供了制备蒸汽重整催化剂的方法。

3. 发明申请

US20090297435A1 Microcombustors, Microreformers, And Methods Involving Combusting Or Reforming Liquids 有权
标题翻译：微燃烧器，微型反应器和涉及燃烧或重整液体的方法
公开(公告)号：US20090297435A1
公开(公告)日：2009-12-03
申请号：US12538140
申请日：2009-08-09
申请人： Jamelyn D. Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert A. Dagle , Guanguang Xia , Eddie G. Baker , Daniel R. Palo , Max Phelps , Heon Jung
发明人： Jamelyn D. Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert A. Dagle , Guanguang Xia , Eddie G. Baker , Daniel R. Palo , Max Phelps , Heon Jung
IPC分类号： C01B3/26 , H01M8/18 , B01J8/04 , C01B3/02
CPC分类号： F23C13/00 , B01J19/0093 , B01J21/04 , B01J21/066 , B01J23/60 , B01J23/63 , B01J37/03 , B01J2219/00783 , B01J2219/00833 , B01J2219/00835 , B01J2219/00873 , B01J2219/00891 , C01B3/323 , C01B3/384 , C01B2203/00 , C01B2203/0233 , C01B2203/04 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/1011 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1217 , C01B2203/1223 , C01B2203/1288 , C01B2203/1619 , F23C2900/03001 , Y02P20/128 , Y02P20/52
摘要： The invention describes combustors and steam reformers and methods of combustion and steam reforming. For example, integrated combustion reactors are described in which heat from combustion is transferred to an endothermic reaction. Thermally efficient reactors and methods of alcohol steam reforming are also described. Also described is an integrated combustor/reformer containing a methanation catalyst.
摘要翻译：本发明描述了燃烧器和蒸汽重整器以及燃烧和蒸汽重整的方法。例如，描述了将来自燃烧的热转移到吸热反应的综合燃烧反应器。还描述了热效率的反应器和醇蒸汽重整的方法。还描述了含有甲烷化催化剂的一体化燃烧器/重整器。

4. 发明授权

US07585472B2 Microcombustors, microreformers, and methods involving combusting or reforming fluids 有权
标题翻译：微型燃烧器，微型重整器和涉及燃烧或重整流体的方法
公开(公告)号：US07585472B2
公开(公告)日：2009-09-08
申请号：US10434443
申请日：2003-05-07
申请人： Jamelyn D. Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert A. Dagle , Guanguang Xia , Eddie G. Baker , Daniel R. Palo , Max Phelps , Heon Jung
发明人： Jamelyn D. Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert A. Dagle , Guanguang Xia , Eddie G. Baker , Daniel R. Palo , Max Phelps , Heon Jung
IPC分类号： B01J8/04
CPC分类号： F23C13/00 , B01J19/0093 , B01J21/04 , B01J21/066 , B01J23/60 , B01J23/63 , B01J37/03 , B01J2219/00783 , B01J2219/00833 , B01J2219/00835 , B01J2219/00873 , B01J2219/00891 , C01B3/323 , C01B3/384 , C01B2203/00 , C01B2203/0233 , C01B2203/04 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0816 , C01B2203/0822 , C01B2203/0827 , C01B2203/1011 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1217 , C01B2203/1223 , C01B2203/1288 , C01B2203/1619 , F23C2900/03001 , Y02P20/128 , Y02P20/52
摘要： The invention describes combustors and steam reformers and methods of combustion and steam reforming. For example, integrated combustion reactors are described in which heat from combustion is transferred to an endothermic reaction. Thermally efficient reactors and methods of alcohol steam reforming are also described. Also described is an integrated combustor/reformer containing a methanation catalyst.
摘要翻译：本发明描述了燃烧器和蒸汽重整器以及燃烧和蒸汽重整的方法。例如，描述了将来自燃烧的热转移到吸热反应的综合燃烧反应器。还描述了热效率的反应器和醇蒸汽重整的方法。还描述了含有甲烷化催化剂的一体化燃烧器/重整器。

5. 发明授权

US07208136B2 Alcohol steam reforming catalysts and methods of alcohol steam reforming 有权
标题翻译：醇蒸汽重整催化剂和醇蒸汽重整方法
公开(公告)号：US07208136B2
公开(公告)日：2007-04-24
申请号：US10440448
申请日：2003-05-16
申请人： Jamelyn D. Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert A. Dagle , Guanguang Xia , Eddie G. Baker , Daniel R. Palo , Max R. Phelps , Heon Jung
发明人： Jamelyn D. Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert A. Dagle , Guanguang Xia , Eddie G. Baker , Daniel R. Palo , Max R. Phelps , Heon Jung
IPC分类号： C01B3/26 , B01J23/60 , B01J23/44 , B01J23/42 , B01J23/00
CPC分类号： C01B3/326 , B01J19/0093 , B01J21/04 , B01J23/60 , B01J35/002 , B01J37/0201 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00862 , B01J2219/00873 , B01J2219/00891 , B01J2219/00961 , B01J2219/00997 , C01B3/586 , C01B2203/0233 , C01B2203/0445 , C01B2203/047 , C01B2203/1041 , C01B2203/1064 , C01B2203/1223 , Y02P20/52
摘要： The present invention provides steam reforming catalyst compositions containing Pd and Zn, and methods of steam reforming alcohols over a catalyst. Surprisingly superior results and properties of the present invention, including low temperature activity and/or low carbon monoxide output, are also described. Methods of making a steam reforming catalyst are also provided.
摘要翻译：本发明提供含有Pd和Zn的蒸汽重整催化剂组合物，以及在催化剂上蒸汽重整醇的方法。还描述了包括低温活性和/或低一氧化碳输出的本发明的令人惊奇的优异结果和性质。还提供了制备蒸汽重整催化剂的方法。

6. 发明授权

US07563390B2 Alcohol steam reforming catalysts and methods of alcohol steam reforming 失效
标题翻译：醇蒸汽重整催化剂和醇蒸汽重整方法
公开(公告)号：US07563390B2
公开(公告)日：2009-07-21
申请号：US11691400
申请日：2007-03-26
申请人： Jamelyn D. Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert A. Dagle , Guanguang Xia , Eddie G. Baker , Daniel R. Palo , Max R. Phelps , Heon Jung
发明人： Jamelyn D. Holladay , Yong Wang , Jianli Hu , Ya-Huei Chin , Robert A. Dagle , Guanguang Xia , Eddie G. Baker , Daniel R. Palo , Max R. Phelps , Heon Jung
IPC分类号： B01J23/42 , B01J23/44 , C01B3/26 , C01B3/38 , C07C1/02
CPC分类号： C01B3/326 , B01J19/0093 , B01J21/04 , B01J23/60 , B01J35/002 , B01J37/0201 , B01J2219/00783 , B01J2219/00788 , B01J2219/00822 , B01J2219/00824 , B01J2219/00835 , B01J2219/00862 , B01J2219/00873 , B01J2219/00891 , B01J2219/00961 , B01J2219/00997 , C01B3/586 , C01B2203/0233 , C01B2203/0445 , C01B2203/047 , C01B2203/1041 , C01B2203/1064 , C01B2203/1223 , Y02P20/52
摘要： The present invention provides steam reforming catalyst compositions containing Pd and Zn, and methods of steam reforming alcohols over a catalyst. Surprisingly superior results and properties of the present invention, including low temperature activity and/or low carbon monoxide output, are also described. Methods of making a steam reforming catalyst are also provided.
摘要翻译：本发明提供含有Pd和Zn的蒸汽重整催化剂组合物，以及在催化剂上蒸汽重整醇的方法。还描述了包括低温活性和/或低一氧化碳输出的本发明的令人惊奇的优异结果和性质。还提供了制备蒸汽重整催化剂的方法。

7. 发明申请

US20070253893A1 Selective CO methanation catalysis 有权
标题翻译：选择性CO甲烷化催化
公开(公告)号：US20070253893A1
公开(公告)日：2007-11-01
申请号：US11413129
申请日：2006-04-26
申请人： Robert Dagle , Yong Wang , Guanguang Xia
发明人： Robert Dagle , Yong Wang , Guanguang Xia
IPC分类号： C01B3/02
CPC分类号： C01B3/586 , B01J21/04 , B01J23/462 , B01J35/002 , B01J35/006 , B01J35/1019 , B01J2219/00781 , C01B2203/0445 , C01B2203/047
摘要： Carbon monoxide (CO) is selectively reacted with hydrogen (H2) over a ruthenium (Ru) on alumina catalyst at a temperature of about 210 to about 290° C. To be a viable option for micro catalytic fuel processing devices, highly active, selective, and stable catalysts must be demonstrated with as large a temperature window for feasible operation as possible. We have studied the effects of metal loading, preparation method, pretreatment conditions, and choice of support on the performance of Ru-based catalysts for such applications. Catalyst testing results and catalyst characterization using XRD and BET are discussed. In one example, operating at a gas hourly space velocity (GHSV) of 13,500 hr−1, a 3% Ru/Al2O3 catalyst yielded CO outputs less than 100 ppm in a temperature range from 240° C. to 285° C., while not exceeding a hydrogen consumption of 10%. This catalyst was further successfully demonstrated in a microchannel device.
摘要翻译：在约210至约290℃的温度下，一氧化碳（CO）在氧化钌催化剂上的钌（Ru）上选择性地与氢（H 2 O 2）反应。作为微催化剂的可行选择燃料处理装置，高活性，选择性和稳定的催化剂必须用尽可能大的温度窗口进行演示，以实现可行的操作。我们研究了金属负载的影响，制备方法，预处理条件以及对这种应用中Ru基催化剂性能的支持选择。讨论了使用XRD和BET的催化剂测试结果和催化剂表征。在一个实施例中，以13,500小时-1的气时空速（GHSV）操作3％Ru / Al 2 O 3 催化剂在240℃至285℃的温度范围内产生小于100ppm的CO输出，而不超过10％的氢消耗。该催化剂在微通道装置中进一步成功地证明。

8. 发明授权

US08877674B2 Selective CO methanation catalysis 有权
标题翻译：选择性CO甲烷化催化
公开(公告)号：US08877674B2
公开(公告)日：2014-11-04
申请号：US11413129
申请日：2006-04-26
申请人： Robert A. Dagle , Yong Wang , Guanguang Xia
发明人： Robert A. Dagle , Yong Wang , Guanguang Xia
IPC分类号： B01J23/00 , B01J23/02 , B01J23/08 , B01J23/40 , B01J23/42 , B01J23/56 , B01J21/04 , B01J20/00 , C01B3/58 , B01J35/00 , B01J23/46 , B01J35/10
CPC分类号： C01B3/586 , B01J21/04 , B01J23/462 , B01J35/002 , B01J35/006 , B01J35/1019 , B01J2219/00781 , C01B2203/0445 , C01B2203/047
摘要： Carbon monoxide (CO) is selectively reacted with hydrogen (H2) over a ruthenium (Ru) on alumina catalyst at a temperature of about 210 to about 290° C. To be a viable option for micro catalytic fuel processing devices, highly active, selective, and stable catalysts must be demonstrated with as large a temperature window for feasible operation as possible. We have studied the effects of metal loading, preparation method, pretreatment conditions, and choice of support on the performance of Ru-based catalysts for such applications. Catalyst testing results and catalyst characterization using XRD and BET are discussed. In one example, operating at a gas hourly space velocity (GHSV) of 13,500 hr−1, a 3% Ru/Al2O3 catalyst yielded CO outputs less than 100 ppm in a temperature range from 240° C. to 285° C., while not exceeding a hydrogen consumption of 10%. This catalyst was further successfully demonstrated in a microchannel device.
摘要翻译：在约210至约290℃的温度下，一氧化碳（CO）与氧化钌（Ru）在钌（Ru）上选择性地与氢（H 2）反应。作为微催化燃料处理装置的可行选择，高活性，选择性必须用尽可能高的操作温度窗来证明稳定的催化剂。我们研究了金属负载的影响，制备方法，预处理条件以及对这种应用中Ru基催化剂性能的支持选择。讨论了使用XRD和BET的催化剂测试结果和催化剂表征。在一个实例中，以13,500hr-1的气时空速（GHSV）操作，3％Ru / Al 2 O 3催化剂在240℃至285℃的温度范围内产生小于100ppm的CO，而不超过10％的氢消耗。该催化剂在微通道装置中进一步成功地证明。

9. 发明授权

US08628880B2 Redox flow batteries based on supporting solutions containing chloride 有权
标题翻译：基于含有氯化物的支持溶液的氧化还原液流电池
公开(公告)号：US08628880B2
公开(公告)日：2014-01-14
申请号：US12892693
申请日：2010-09-28
申请人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
发明人： Liyu Li , Soowhan Kim , Zhenguo Yang , Wei Wang , Jianlu Zhang , Baowei Chen , Zimin Nie , Guanguang Xia
IPC分类号： H01M6/04
CPC分类号： H01M8/08 , H01M8/18 , H01M8/188 , H01M8/20 , H01M2300/0002 , H01M2300/0005 , H01M2300/0011 , Y02E60/528
摘要： Redox flow battery systems having a supporting solution that contains Cl− ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO42− and Cl− ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V2+ and V3+ in a supporting solution and a catholyte having V4+ and V5+ in a supporting solution. The supporting solution can contain Cl− ions or a mixture of SO42− and Cl− ions.
摘要翻译：具有包含Cl-离子的支持溶液的氧化还原液流电池系统可以表现出改进的性能和特性。此外，具有混合的SO42-和Cl-离子的支持溶液可以提供增加的能量密度并提高一种或多种离子物质在阴极电解液和/或阳极电解液中的稳定性和溶解度。根据一个示例，钒基氧化还原液流电池系统的特征在于在支撑溶液中具有V2 +和V3 +的阳极电解液，以及在支持溶液中具有V4 +和V5 +的阴极电解液。支持溶液可以含有Cl-离子或SO42-和Cl-离子的混合物。

10. 发明申请

US20100202952A1 NANOWIRE SYNTHESIS FROM VAPOR AND SOLID SOURCES 有权
标题翻译：从蒸气和固体源合成NANOWIRE
公开(公告)号：US20100202952A1
公开(公告)日：2010-08-12
申请号：US12368711
申请日：2009-02-10
申请人： Jiguang Zhang , Jun Liu , Zhenguo Yang , Guanguang Xia , Leonard S. Fifield , Donghai Wang , Daiwon Choi , Gordon L. Graff , Larry R. Pederson
发明人： Jiguang Zhang , Jun Liu , Zhenguo Yang , Guanguang Xia , Leonard S. Fifield , Donghai Wang , Daiwon Choi , Gordon L. Graff , Larry R. Pederson
IPC分类号： C01B31/36 , C01B21/068 , C01B33/02 , C01B15/14
CPC分类号： H01M4/134 , B82Y30/00 , B82Y40/00 , C01B33/02 , C01B33/113 , H01M4/386 , H01M4/485 , H01M4/58 , H01M10/052 , H01M2004/021 , Y10S977/721 , Y10S977/722 , Y10S977/762 , Y10S977/775 , Y10S977/843
摘要： Methods of the present invention can be used to synthesize nanowires with controllable compositions and/or with multiple elements. The methods can include coating solid powder granules, which comprise a first element, with a catalyst. The catalyst and the first element should form when heated a liquid, mixed phase having a eutectic or peritectic point. The granules, which have been coated with the catalyst, can then be heated to a temperature greater than or equal to the eutectic or peritectic point. During heating, a vapor source comprising the second element is introduced. The vapor source chemically interacts with the liquid, mixed phase to consume the first element and to induce condensation of a product that comprises the first and second elements in the form of a nanowire.
摘要翻译：本发明的方法可用于合成具有可控组合物和/或具有多种元素的纳米线。所述方法可以包括用催化剂涂覆包含第一元素的固体粉末颗粒。当加热液体，具有共晶或包晶点的混合相时，催化剂和第一元素应形成。已经涂覆有催化剂的颗粒然后可以被加热到大于或等于共晶或包晶点的温度。在加热期间，引入包括第二元件的蒸气源。蒸汽源与液体，混合相化学相互作用以消耗第一元素并诱导包含纳米线形式的第一和第二元素的产物的冷凝。

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