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1. 发明授权

US4939065A UV-curable organopolysiloxane compositions and negative photoresists comprised thereof 失效
标题翻译：可UV固化的有机基聚硅氧烷组合物和由其组成的负性光致抗蚀剂
公开(公告)号：US4939065A
公开(公告)日：1990-07-03
申请号：US217498
申请日：1988-07-11
申请人： Jacques Cavezzan , Sylvianne Dumas , Louis Giral , Christian Prud'Homme , Francois Schue
发明人： Jacques Cavezzan , Sylvianne Dumas , Louis Giral , Christian Prud'Homme , Francois Schue
IPC分类号： C08K3/00 , C08K5/23 , C08L83/05 , C08L83/07 , G03F7/038 , G03F7/075
CPC分类号： G03F7/0757 , C08K5/23 , Y10S430/114 , Y10S430/118
摘要： Substrates, e.g., silicon wafers, coated with a UV-curable organopolysiloxane composition including a crosslinking catalyst therefor (e.g., a platinum group metal compound) and an amount of a crosslinking inhibitor (e.g., an azodicarboxylate) which is effective at ambient temperature, but ineffective to prevent crosslinking on exposure of the composition to ultraviolet radiation, are well adapted for the imaging of negative intelligence patterns thereon.
摘要翻译：衬底，例如硅晶片，其涂覆有包含其交联催化剂的可UV固化的有机聚硅氧烷组合物（例如，铂族金属化合物）和一定量的在环境温度下有效的交联抑制剂（例如，偶氮二羧酸酯），但是无法防止组合物暴露于紫外线辐射下的交联，很好地适用于其上的阴性情报模式的成像。

2. 发明授权

US4518758A Organopolysiloxane/polyurethane elastomeric block copolymers 失效
标题翻译：有机聚硅氧烷/聚氨酯弹性体嵌段共聚物
公开(公告)号：US4518758A
公开(公告)日：1985-05-21
申请号：US423259
申请日：1982-09-24
申请人： Jacques Cavezzan , Christian Prud'Homme
发明人： Jacques Cavezzan , Christian Prud'Homme
IPC分类号： C08G18/00 , C08G18/61 , C08G18/77 , C08G18/81 , C08G77/00 , C08G77/38 , C08G77/388 , C08G77/42 , C08G77/26
CPC分类号： C08G18/61 , C08G18/778 , C08G77/38 , C08G77/388 , C08G77/42
摘要： Novel organopolysiloxane/polyurethane block copolymers which are thermoplastic elastomers and which possess good thermomechanical properties, are comprised of the following recurring units (A) and (B): ##STR1## wherein Z is a divalent radical which comprises a polysiloxane block and has the formula: ##STR2## in which Y and Y' are each a divalent radical having one of the formulae: ##STR3## wherein T and T' comprise the divalent or trivalent residue having from 1 to 20 carbon atoms of an unsaturated isocyanate or alcohol having one of the formulae:OCN--T--CR.sub.1 .dbd.CR.sub.2 R.sub.3HO--T--CR.sub.1 .dbd.CR.sub.2 R.sub.3 ##STR4## or an oxygen, sulfur, silicon, nitrogen, ester or amide interrupted such T or T' residue, and further wherein R.sub.1, R.sub.2 and R.sub.3 are each hydrogen, alkyl or aryl, with the proviso that two of the radicals R.sub.1 and R.sub.2 may together form a single alkylene radical; each R is an alkyl or halogenoalkyl radical having from 1 to 5 carbon atoms and containing from 1 to 7 chlorine and/or fluorine substituents, cycloalkyl or halogenocycloalkyl radical having from 3 to 8 carbon atoms and containing from 1 to 4 chlorine and/or fluorine substituents, aryl, alkylaryl or halogenoaryl radical having from 6 to 8 carbon atoms and containing from 1 to 4 chlorine and/or fluorine substituents, or a cyanoalkyl radical having from 3 to 4 carbon atoms; n is a number of at least 10; G.sub.1 and G.sub.2 are each divalent hydrocarbon radicals having from 2 to 20 carbon atoms, or two such hydrocarbon radicals joined together by a direct valence bond or through an oxygen atom or alkylene or alkylidene bridge having from 1 to 4 carbon atoms; m is a number ranging from 1 to 20; and a is a number which is either zero or 1.
摘要翻译：作为热塑性弹性体并具有良好热机械性能的新型有机聚硅氧烷/聚氨酯嵌段共聚物由以下重复单元（A）和（B）组成：其中Z为二价基团其包含聚硅氧烷嵌段，并具有下式：其中Y和Y'各自为具有下式之一的二价基团：其中T和T'包含具有1或2的2价或3价残基具有下式之一的不饱和异氰酸酯或醇的至少20个碳原子：OCN-T-CR1 = CR2R3 HO-T-CR1 = CR2R3 或者氧，硫，硅，氮，酯或酰胺中断这样的T或T'残基，并且其中R 1，R 2和R 3各自为氢，烷基或芳基，条件是基团R 1和R 2中的两个可以一起形成单个亚烷基; 每个R是具有1至5个碳原子并含有1至7个氯和/或氟取代基的烷基或卤代烷基，具有3至8个碳原子并含有1至4个氯和/或氟的环烷基或卤代环烷基具有6至8个碳原子并含有1至4个氯和/或氟取代基的取代基，芳基，烷基芳基或卤代芳基，或具有3至4个碳原子的氰基烷基; n是至少10的数; G1和G2是具有2至20个碳原子的二价烃基，或两个这样的烃基通过直接键键或通过氧原子或具有1至4个碳原子的亚烷基桥连接在一起; m是从1到20的数字; a是0或1的数字。

3. 发明授权

US5340898A Cationically crosslinkable polyorganosiloxanes and antiadhesive coatings produced therefrom 失效
标题翻译：阳离子交联的聚有机硅氧烷和由其制备的防粘涂层
公开(公告)号：US5340898A
公开(公告)日：1994-08-23
申请号：US35603
申请日：1993-03-23
申请人： Jacques Cavezzan , Christian Priou
发明人： Jacques Cavezzan , Christian Priou
IPC分类号： C08J3/28 , C07F5/02 , C08K5/55 , C08L83/04 , C09D183/04 , C09D183/06 , C08G77/06
CPC分类号： C08K5/55 , C07F5/027 , C09D183/06 , Y10T428/31663
摘要： Cationically crosslinkable polyorganosiloxane compositions, well suited for providing antiadhesive coatings on a wide variety of shaped substrates via the photochemical/electron beam crosslinking thereof, include a catalytically effective amount of an onium borate of an element of Groups 15 to 17 of the Periodic Table, the anionic borate moiety of which onium borate having the formula:[BX.sub.a R.sub.b ].sup.-in which a and b are integers ranging from 0 to 4 and a+b=4; the symbols X are each a halogen atom when a ranges up to 3 and an OH functional group when a ranges up to 2; and the symbols R, which may be identical or different, are each a phenyl radical substituted by at least one electron-withdrawing substituent or by at least two halogen atoms, or an aryl radical containing at least two aromatic ring members, or such aryl radical bearing at least one electron-withdrawing substituent.
摘要翻译：非常适合通过其光化学/电子束交联在各种成形基材上提供抗粘附涂层的阳离子交联性聚有机硅氧烷组合物包括催化有效量的元素周期表第15-17族元素的硼酸镧，其中硼和硼酸盐的阴离子硼酸盐部分具有下式：[BXaRb] - 其中a和b是0-4和a + b = 4的整数; 当范围高达3时，符号X各自为卤素原子，当范围达到2时，符号X为OH官能团; 并且可以相同或不同的符号R各自为被至少一个吸电子取代基或至少两个卤素原子取代的苯基，或含有至少两个芳族环成员的芳基或这样的芳基带有至少一个吸电子取代基。

4. 发明授权

US4873305A Tin monochelate catalysis of organopolysiloxane compositions 失效
标题翻译：锡单壳催化有机聚硅氧烷组合物
公开(公告)号：US4873305A
公开(公告)日：1989-10-10
申请号：US212184
申请日：1988-06-27
申请人： Jacques Cavezzan , Jean-Marc Frances , Claude Millet
发明人： Jacques Cavezzan , Jean-Marc Frances , Claude Millet
IPC分类号： C07F7/22 , C08K5/57 , C08L83/04
CPC分类号： C07F7/2244 , C08K5/57 , Y10S528/901
摘要： Organopolysiloxane compositions curable into elastomeric state, whether in single- or two-component form, comprise an .alpha.,.omega.-dihydroxypolydiorganopolysiloxane oil, a crosslinking agent therefor, optionally, inorganic fillers and an adhesion promoter, and a catalytically effective amount of a pentacoordinated tin monochelate produced by reacting a tin oxide with a .beta.-dicarbonyl compound and a carboxylic acid.
摘要翻译：固化到弹性体状态的有机聚硅氧烷组合物，无论是单组分还是双组分形式，均包含α，ω-二羟基聚二有机聚硅氧烷油，其交联剂，任选的无机填料和粘合促进剂，以及催化有效量的五配位锡单晶通过使氧化锡与β-二羰基化合物和羧酸反应而产生。

5. 发明授权

US06153661A Onium borates/borates of organometallic complexes and cationic initiation of polymerization therewith 失效
公开(公告)号：US06153661A
公开(公告)日：2000-11-28
申请号：US851713
申请日：1997-05-06
申请人： Frederic Castellanos , Jacques Cavezzan , Jean-Pierre Fouassier , Christian Priou
发明人： Frederic Castellanos , Jacques Cavezzan , Jean-Pierre Fouassier , Christian Priou
IPC分类号： C07F5/02 , C07F9/50 , C07F19/00 , C08F2/46 , C08F2/50 , C08F4/00 , C08F4/52 , C08G59/24 , C08G59/68 , C08G59/72 , G03F7/004 , G03F7/029 , G03F7/038
CPC分类号： C08G59/72 , C07F5/022 , C08F2/50 , C08F4/52 , C08G59/24 , C08G59/68 , G03F7/0042 , G03F7/0045 , G03F7/029 , G03F7/038
摘要： Novel onium borates of an element of Groups 15 to 17 of the Periodic Table, or borates of an organometallic complex of an element of Groups 4 to 10 of the Periodic Table, well suited for the photochemical/electron beam cationic initiation of polymerization/crosslinking, the anionic borate moiety of which having the formula:[BX.sub.a R.sub.b ].sup.-in which a and b are integers ranging from 0 to 4 and a+b=4; the symbols X are each a halogen atom when a ranges up to 3 and an OH functional group when a ranges up to 2; and the symbols R, which may be identical or different, are each a phenyl radical substituted by at least one element or electron-withdrawing substituent or by at least two halogen atoms, or an aryl radical containing at least two aromatic ring members, or such aryl radical bearing at least one electron-withdrawing substituent.

6. 发明授权

US5550265A Onium borates/borates of organometallic complexes and cationic initiation of polymerization therewith 失效
标题翻译：有机金属络合物的硼酸钡/硼酸盐和与其聚合的阳离子引发
公开(公告)号：US5550265A
公开(公告)日：1996-08-27
申请号：US400970
申请日：1995-03-08
申请人： Frederic Castellanos , Jacques Cavezzan , Jean-Pierre Fouassier , Christian Priou
发明人： Frederic Castellanos , Jacques Cavezzan , Jean-Pierre Fouassier , Christian Priou
IPC分类号： C07F5/02 , C07F9/50 , C07F19/00 , C08F2/46 , C08F2/50 , C08F4/00 , C08F4/52 , C08G59/24 , C08G59/68 , C08G59/72 , G03F7/004 , G03F7/029 , G03F7/038 , C07F9/00 , C07F13/00
CPC分类号： C08G59/72 , C07F5/022 , C08F2/50 , C08F4/52 , C08G59/24 , C08G59/68 , G03F7/0042 , G03F7/0045 , G03F7/029 , G03F7/038
摘要： Novel onium borates of an element of Groups 15 to 17 of the Periodic Table, or borates of an organometallic complex of an element of Groups 4 to 10 of the Periodic Table, well suited for the photochemical/electron beam cationic initiation of polymerization/crosslinking, the anionic borate moiety of which having the formula:[BX.sub.a R.sub.b ].sup.-which a and b are integers ranging from 0 to 4 and a+b=4; the symbols X are each a halogen atom when ranges up to 3 and an OH functional group when a ranges up to 2; and the symbols R, which may be identical or different, are each a phenyl radical substituted by at least one element or electron-withdrawing substituent or by at least two halogen atoms, or an aryl radical containing at least two aromatic ring members, or such aryl radical bearing at least one electron-withdrawing substituent.
摘要翻译：元素周期表第15至17族元素的新型硼酸盐或元素周期表第4至10族元素的有机金属络合物的硼酸盐，非常适合光化学/电子束阳离子引发聚合/交联，其具有下式的阴离子硼酸盐部分：[BXaRb] - 其中a和b为0-4和a + b = 4的整数; 当范围高达3时，符号X各自为卤素原子，当范围高达2时，符号X为OH官能团; 并且可以相同或不同的符号R各自为被至少一个元素或吸电子取代基或至少两个卤素原子取代的苯基或含有至少两个芳族环成员的芳基等具有至少一个吸电子取代基的芳基。

7. 发明授权

US4954539A Aqueous silicone emulsions containing tin monochelate crosslinking catalysts 失效
标题翻译：含有单氯苯乙烯交联催化剂的水性硅氧烷乳液
公开(公告)号：US4954539A
公开(公告)日：1990-09-04
申请号：US370782
申请日：1989-06-23
申请人： Jacques Cavezzan , Michel Peignier
发明人： Jacques Cavezzan , Michel Peignier
IPC分类号： C08K5/57 , C08L5/00 , C08L29/04 , C08L31/04 , C08L83/04 , C08L83/06 , C09D5/02 , C09D183/04 , C09D183/06 , C09K3/18
CPC分类号： C08K5/57 , C08L83/04 , C08G77/045 , C08G77/12 , C08G77/16 , C08G77/20 , C08G77/24 , Y10T428/31663
摘要： Aqueous silicone emulsions, especially useful for rendering a wide variety of substrates nonadhesive/water-repellent by polycondensation crosslinking, contain (a) an .alpha.,.omega.-dihydroxydiorganopolysiloxane, (b) an organohydropolysiloxane containing at least 3 hydrogen atoms bonded to silicon atoms per molecule, (c) a polyvinyl alcohol, (d) a nonionic emulsifying agent, and (e) a crosslinking catalytically effective amount of a monochelate of pentacoordinated tin of valency IV.
摘要翻译：水性硅氧烷乳液，特别适用于通过缩聚交联使各种不粘附/拒水性的底物含有（a）α，ω-二羟基二羟基聚硅氧烷，（b）每分子含有至少3个与硅原子键合的氢原子的有机氢聚硅氧烷，（c）聚乙烯醇，（d）非离子乳化剂，和（e）交联催化有效量的四价五价锡化合物四价铁。

8. 发明授权

US4929702A Tin monochelate catalysis of organopolysiloxane compositions 失效
标题翻译：锡单壳催化有机聚硅氧烷组合物
公开(公告)号：US4929702A
公开(公告)日：1990-05-29
申请号：US211897
申请日：1988-06-27
申请人： Jacques Cavezzan , Jean-Marc Frances , Pierre Lancelin
发明人： Jacques Cavezzan , Jean-Marc Frances , Pierre Lancelin
IPC分类号： C08K5/09 , C08K5/54 , C08K5/56 , C08K5/57 , C08L83/04 , C08L83/06
CPC分类号： C08K5/57 , Y10S528/901
摘要： Organopolysiloxane compositions curable into elastomeric state, whether in single- or two-component form, comprise an .alpha., .omega.-dihydroxypolydiorganopolysiloxane oil, a crosslinking agent therefor, optionally, inorganic fillers and an adhesion promoter, and a catalytically effective amount of a pentacoordinated tin monochelate produced by reacting a tin bischelate with an organic carboxylic acid.
摘要翻译：固化到弹性体状态的有机聚硅氧烷组合物，无论是单组分还是双组分形式，均包含α，ω-二羟基聚二有机聚硅氧烷油，其交联剂，任选的无机填料和粘合促进剂，以及催化有效量的五配位锡单晶通过使二锡酸锡与有机羧酸反应制得。

9. 发明授权

US4687870A Platinum/triene complexes useful for hydrosilylation catalysis 失效
标题翻译：用于氢化硅烷化催化的铂/三烯配合物
公开(公告)号：US4687870A
公开(公告)日：1987-08-18
申请号：US811393
申请日：1985-12-20
申请人： Jacques Cavezzan
发明人： Jacques Cavezzan
IPC分类号： C08L83/00 , B01J31/22 , C08K5/56 , C08L83/04 , C08L83/05 , C08L83/07 , C07F15/00
CPC分类号： C08K5/56 , B01J31/2291 , C08L83/04 , B01J2231/14 , B01J2231/323 , B01J2531/828 , C08G77/12 , C08G77/20 , Y10T428/2995 , Y10T428/31663
摘要： Novel platinum/olefin complexes, useful for the hydrosilylation curing catalysis of hardenable organopolysiloxane compositions, are facilely prepared by reacting a platinum halide with at least one alkali or alkaline earth metal carbonate or bicarbonate in the presence of an aliphatic triene ligand having the general formula: ##STR1## wherein R.sub.1 is a linear or branched chain alkyl radical having from 1 to 6 carbon atoms, and R.sub.2 is R.sub.1 or a linear or branched chain alkenyl radical having from 2 to 16 carbon atoms and at least one site of ethylenic unsaturation, and said complex having a ratio, in gram-atoms of halogen to gram-atoms of platinum, ranging from virtually 0 to 4.
摘要翻译：通过使铂卤化物与至少一种碱金属或碱土金属碳酸盐或碳酸氢盐在具有以下通式的脂族三烯配体的存在下反应来容易地制备用于可硬化有机聚硅氧烷组合物的氢化硅烷化固化催化的新型铂/烯烃络合物：（I）其中R 1是具有1至6个碳原子的直链或支链烷基，R 2是R 1或具有2至16个碳原子的直链或支链烯基和至少一个烯属的位点不饱和度，并且所述络合物在卤素的克原子与铂的克原子之间具有几乎为0至4的比率。

10. 发明授权

US4595739A .alpha.-Ketone acetylenic inhibited platinum group metal catalyzed organopolysiloxane compositions 失效
标题翻译：乙炔酮抑制铂族金属催化的有机聚硅氧烷组合物
公开(公告)号：US4595739A
公开(公告)日：1986-06-17
申请号：US665448
申请日：1984-10-26
申请人： Jacques Cavezzan
发明人： Jacques Cavezzan
IPC分类号： C08K5/07 , C08L83/00 , C08L83/04 , C08L83/05 , C08L83/07 , C09D5/00 , C09D183/04
CPC分类号： C08K5/07 , C08L83/04 , C08G77/12 , C08G77/20 , C08G77/24 , C08G77/26 , C08G77/44 , C08G77/70 , Y10T428/31663
摘要： Curable organopolysiloxane compositions useful, e.g., for the production of anti-stick coatings, comprise (1) an organopolysiloxane, (2) an organohydropolysiloxane, (3) a platinum group metal hardening catalyst, and (4) a platinum catalysis inhibitor comprising an acetylenic .alpha.-ketone in an amount which inhibits gelation at ambient temperatures but does not prevent cross-linking at temperatures in excess thereof.
摘要翻译：可用于制备防粘涂层的可固化的有机聚硅氧烷组合物包括（1）有机聚硅氧烷，（2）有机氢聚硅氧烷，（3）铂族金属硬化催化剂，和（4）铂催化抑制剂，其包含炔属 α-酮，其量在环境温度下抑制凝胶化，但不能防止在其过量的温度下的交联。

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