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1. 发明授权

US4873305A Tin monochelate catalysis of organopolysiloxane compositions 失效
标题翻译：锡单壳催化有机聚硅氧烷组合物
公开(公告)号：US4873305A
公开(公告)日：1989-10-10
申请号：US212184
申请日：1988-06-27
申请人： Jacques Cavezzan , Jean-Marc Frances , Claude Millet
发明人： Jacques Cavezzan , Jean-Marc Frances , Claude Millet
IPC分类号： C07F7/22 , C08K5/57 , C08L83/04
CPC分类号： C07F7/2244 , C08K5/57 , Y10S528/901
摘要： Organopolysiloxane compositions curable into elastomeric state, whether in single- or two-component form, comprise an .alpha.,.omega.-dihydroxypolydiorganopolysiloxane oil, a crosslinking agent therefor, optionally, inorganic fillers and an adhesion promoter, and a catalytically effective amount of a pentacoordinated tin monochelate produced by reacting a tin oxide with a .beta.-dicarbonyl compound and a carboxylic acid.
摘要翻译：固化到弹性体状态的有机聚硅氧烷组合物，无论是单组分还是双组分形式，均包含α，ω-二羟基聚二有机聚硅氧烷油，其交联剂，任选的无机填料和粘合促进剂，以及催化有效量的五配位锡单晶通过使氧化锡与β-二羰基化合物和羧酸反应而产生。

2. 发明授权

US4929702A Tin monochelate catalysis of organopolysiloxane compositions 失效
标题翻译：锡单壳催化有机聚硅氧烷组合物
公开(公告)号：US4929702A
公开(公告)日：1990-05-29
申请号：US211897
申请日：1988-06-27
申请人： Jacques Cavezzan , Jean-Marc Frances , Pierre Lancelin
发明人： Jacques Cavezzan , Jean-Marc Frances , Pierre Lancelin
IPC分类号： C08K5/09 , C08K5/54 , C08K5/56 , C08K5/57 , C08L83/04 , C08L83/06
CPC分类号： C08K5/57 , Y10S528/901
摘要： Organopolysiloxane compositions curable into elastomeric state, whether in single- or two-component form, comprise an .alpha., .omega.-dihydroxypolydiorganopolysiloxane oil, a crosslinking agent therefor, optionally, inorganic fillers and an adhesion promoter, and a catalytically effective amount of a pentacoordinated tin monochelate produced by reacting a tin bischelate with an organic carboxylic acid.
摘要翻译：固化到弹性体状态的有机聚硅氧烷组合物，无论是单组分还是双组分形式，均包含α，ω-二羟基聚二有机聚硅氧烷油，其交联剂，任选的无机填料和粘合促进剂，以及催化有效量的五配位锡单晶通过使二锡酸锡与有机羧酸反应制得。

3. 发明授权

US5502084A Organopolysiloxane composition containing a cyclopentenyl radical and crosslinkable in a thin layer under ultraviolet 失效
标题翻译：含有环戊烯基的有机聚硅氧烷组合物可在紫外线下在薄层中交联
公开(公告)号：US5502084A
公开(公告)日：1996-03-26
申请号：US616942
申请日：1990-11-21
申请人： Jacques Cavezzan , Jean-Marc Frances
发明人： Jacques Cavezzan , Jean-Marc Frances
IPC分类号： C08L83/07 , C08F2/50 , C08F290/00 , C08F299/08 , C08G77/20 , C08G77/38 , C08L83/04 , C09D183/04 , C08G77/12
CPC分类号： C08G77/38 , C08G77/20 , C09D183/04
摘要： The present invention relates to an organopolysiloxane composition containing a cyclopentenyl radical and crosslinkable in a thin layer by exposure to ultraviolet light, characterized in that it comprises:A. 100 parts of diorganopolysiloxane containing at least 3 cyclopentenyl radicals per molecule, each of these groups being directly linked, by an SiC bond, to a different silicon atom, andB. an effective amount of at least one photoinitiator.Application of the compositions to the production of coatings, especially for the production of non-stick coatings on paper, and for the encapsulation of printed circuits.
摘要翻译：本发明涉及一种含有环戊烯基的有机聚硅氧烷组合物，通过暴露于紫外线可在薄层中交联，其特征在于：它包括：A.每分子含有至少3个环戊烯基的二有机聚硅氧烷，这些基团分别为通过SiC键直接连接到不同的硅原子上，和B.有效量的至少一种光引发剂。组合物在涂料生产中的应用，特别是用于在纸上生产不粘涂层以及印刷电路封装。

4. 发明授权

US4968824A Tin monochelate catalysis of organopolysiloxane compositions 失效
标题翻译：锡单壳催化有机聚硅氧烷组合物
公开(公告)号：US4968824A
公开(公告)日：1990-11-06
申请号：US340462
申请日：1989-04-19
申请人： Jacques Cavezzan , Jean-Marc Frances , Claude Millet
发明人： Jacques Cavezzan , Jean-Marc Frances , Claude Millet
IPC分类号： C07F7/22 , C08K5/57 , C08L83/04
CPC分类号： C07F7/2244 , C08K5/57 , Y10S528/901
摘要： Organopolysiloxane compositions curable into elastomeric state, whether in single- or two-component form, comprise an .alpha.,.omega.-dihydroxypolydiorganopolysiloxane oil, a crosslinking agent therefor, optionally, inorganic fillers and an adhesion promoter, and a catalytically effective amount of a pentacoordinated tin monochelate produced by reacting a tin oxide with a .beta.-dicarbonyl compound and a carboxylic acid.

5. 发明授权

US08436066B2 Compositions polymerizable/crosslinkable by cationic/radical irradiation 有权
标题翻译：通过阳离子/自由基照射可聚合/交联的组合物
公开(公告)号：US08436066B2
公开(公告)日：2013-05-07
申请号：US12309603
申请日：2007-07-23
申请人： Jean-Marc Frances , Philippe Barbeau , Jean-Marie Bernard , Damien Bourgeois
发明人： Jean-Marc Frances , Philippe Barbeau , Jean-Marie Bernard , Damien Bourgeois
IPC分类号： H05B6/68 , C08G18/67 , C08G65/18 , C08G2/10 , C08F20/22 , C07D303/40 , C03C25/10 , B29D22/00 , B29D23/00 , B32B1/08 , B32B27/08 , B32B9/00 , B32B33/00
CPC分类号： C08G18/792 , C08G18/003 , C08G59/22 , C08G65/18 , C08J7/18 , C09D175/04 , G03F7/038 , G03F7/0755 , G03F7/0757 , Y10T428/1352 , Y10T428/1457 , Y10T428/31515
摘要： Compositions that can be polymerized and/or crosslinked into coatings by cationic and/or radical irradiation contain at least one photoinitiator and at least one compound having at least one isocyanate function.
摘要翻译：可以通过阳离子和/或自由基照射聚合和/或交联成涂层的组合物含有至少一种光引发剂和至少一种具有至少一个异氰酸酯官能团的化合物。

6. 发明申请

US20070149636A1 Dental composition based on silicone crosslinkable by cation process 审中-公开
公开(公告)号：US20070149636A1
公开(公告)日：2007-06-28
申请号：US11604510
申请日：2006-11-27
申请人： Jean-Marc Frances
发明人： Jean-Marc Frances
IPC分类号： A61C13/00
CPC分类号： A61K6/093 , A61K6/0052 , A61K6/083 , Y10S522/908 , C08L51/08 , C08L83/12
摘要： The invention concerns dental compositions. Said composition comprises (1) a silicone crosslinkable and/or polymerizable by cation process; (2) an efficient amount of at least an initiator such as onium borate; (3) at least a photosensitizer ; and (4) a dental filler present in the composition in a proportion of at least 10 wt. % relative to the composition total weight. Said dental compositions are useful for making dental prostheses or for dental restoration.

7. 发明授权

US06929863B2 Surface treatment of plastic material with an organic polymerizable and/or crosslinkable composition having reactive functions 有权
标题翻译：用具有反应性功能的有机可聚合和/或可交联组合物对塑料材料进行表面处理
公开(公告)号：US06929863B2
公开(公告)日：2005-08-16
申请号：US10203983
申请日：2001-02-14
申请人： Jean-Marc Frances
发明人： Jean-Marc Frances
IPC分类号： C08J7/04 , C09D183/06 , B32B25/20
CPC分类号： C09D183/06 , C08J7/047 , C08J2483/06 , Y10T428/31511 , Y10T428/31663 , C08L83/00 , C08L2666/28 , C08L2666/44 , C08L2666/02
摘要： A process for surface treatment of a plastic is provided. The process includes applying to at least one surface of the plastic a composition with reactive functional groups which can be polymerized and/or crosslinked by irradiation. The process can be used to form a coating such as an ink, a non-stick coating, an adhesive coating or a varnish.
摘要翻译：提供了一种用于表面处理塑料的方法。该方法包括向组合物的至少一个表面施加具有可通过照射聚合和/或交联的反应性官能团的组合物。该方法可以用于形成诸如油墨，不粘涂层，粘合剂涂层或清漆的涂层。

8. 发明申请

US20050059752A1 Stable, cationically polymerizable/crosslinkable dental compositions having high filler contents 审中-公开
标题翻译：具有高填料含量的稳定的可阳离子聚合/可交联牙科组合物
公开(公告)号：US20050059752A1
公开(公告)日：2005-03-17
申请号：US10933537
申请日：2004-09-03
申请人： Jean-Marc Frances
发明人： Jean-Marc Frances
IPC分类号： A61K6/083 , A61K6/093 , A61K6/08
CPC分类号： A61K6/0052 , A61K6/093 , Y10S522/908 , C08L83/12
摘要： Stable, highly filled cationic dental compositions useful for the production of dental prostheses and dental restoration materials contain: (1) at least one compound which is reactive cationically when activated, advantageously at least one UV-and cationically reactive oxirane-functionalized silicone; (2) at least one dental filler, advantageously SiO2; (3) at least one organic polymer or copolymer dispersant having an amine index less than or equal to 100 mg of potassium hydroxide per gram of dispersant, advantageously a polyurethane/acrylate copolymer or alkylammonium salt thereof; (4) at least one cationic photoinitiator, advantageously iodonium borate; and (5) optionally, at least one photosensitizer.
摘要翻译：用于生产牙科假体和牙科修复材料的稳定，高度填充的阳离子牙科组合物包含：（1）至少一种当被活化时反应阳离子的化合物，有利的是至少一种UV-阳离子反应性环氧乙烷官能化硅酮; （2）至少一种牙科填料，有利地是SiO 2; （3）至少一种有机聚合物或共聚物分散剂，其胺指数小于或等于100mg氢氧化钾/克分散剂，有利地是聚氨酯/丙烯酸酯共聚物或其烷基铵盐; （4）至少一种阳离子光引发剂，优选硼酸铵; 和（5）任选的至少一种光敏剂。

9. 发明授权

US5767216A Process for the preparation of optionally alkoxylated polyorganosiloxane resin by non-hydrolytic condensation 失效
标题翻译：通过非水解缩合制备任选烷氧基化聚有机硅氧烷树脂的方法
公开(公告)号：US5767216A
公开(公告)日：1998-06-16
申请号：US594398
申请日：1996-01-31
申请人： Jean-Marc Frances , Hubert Pierre Mutin , Laurence Bourget , Dominique LeClercq , Andre Vioux
发明人： Jean-Marc Frances , Hubert Pierre Mutin , Laurence Bourget , Dominique LeClercq , Andre Vioux
IPC分类号： C08G77/06 , C08G77/08 , C08G77/18 , C08G77/22 , C08G77/48 , C08G77/60
CPC分类号： C08G77/18 , C08G77/06 , C08G77/08
摘要： The present invention relates to the synthesis of optionally alkoxylated polyorganosiloxane (POS) resins by non-hydrolytic condensation. The object is to provide a process which offers the possibility of controlling the crosslinking. This object, inter alia, is achieved by the process according to the invention, which makes provision for carrying out a non-hydrolytic condensation reaction between alkoxysilyl units (Mo1) and halogenosilyl units (Mo2), both of which are carried by identical or different silanes, in the presence of a catalyst of the Lewis acid type, said condensation reaction generating essentially .tbd.Si--O--Si.tbd. linkages and coproducts XR (X=halogen). In this process, the target POS comprise siloxy units D, T and/or Q, or perhaps M, the catalyst is selected from metal compounds or mixtures thereof based on at least one metal belonging to group IIIB, IVB or VB of the periodic table, and the reaction temperature and the initial ratio OR/X are adjusted so that condensation takes place substantially exclusively between the units Mo1 and Mo2, with extreme minimization of secondary condensation between two alkoxy units OR to give the by-product R.sub.2 O.
摘要翻译：本发明涉及通过非水解缩合合成任选的烷氧基化聚有机硅氧烷（POS）树脂。目的是提供一种提供控制交联的可能性的方法。该目的尤其通过根据本发明的方法实现，其提供了在烷氧基甲硅烷基单元（Mo1）和卤代甲硅烷基单元（Mo2）之间进行非水解缩合反应，两者均由相同或不同的载体硅烷，在路易斯酸型催化剂存在下，所述缩合反应产生基本上为3BOND Si-O-Si 3BOND键和副产物XR（X =卤素）。在该方法中，目标POS包含基于至少一种属于元素周期表IIIB，IVB或VB族金属的金属化合物或其混合物的甲硅烷氧基单元D，T和/或Q，或者也许M ，并且调节反应温度和初始比例OR / X，使得冷凝仅在单元Mo1和Mo2之间发生，极端地最小化两个烷氧基单元之间的二次缩合或得到副产物R2O。

10. 发明授权

US07893129B2 Stable, cationically polymerizable/crosslinkable dental compositions 有权
标题翻译：稳定的阳离子聚合/交联牙科组合物
公开(公告)号：US07893129B2
公开(公告)日：2011-02-22
申请号：US12400314
申请日：2009-03-09
申请人： Jean-Marc Frances
发明人： Jean-Marc Frances
IPC分类号： A61K6/087 , A61F2/01 , C07D303/02 , C08G59/20 , C08G59/68 , C08F2/50 , G03F7/029 , A61L27/34 , A61C5/00
CPC分类号： A61K6/0052 , A61K6/093 , Y10S522/908 , C08L83/12
摘要： Stable, highly filled cationic dental compositions useful for the production of dental prostheses and dental restoration materials contain: (1) at least one compound which is reactive cationically when activated, advantageously at least one UV- and cationically reactive oxirane-functionalized silicone; (2) at least one dental filler, advantageously SiO2; (3) at least one organic polymer or copolymer dispersant having an amine index less than or equal to 100 mg of potassium hydroxide per gram of dispersant, advantageously a polyurethane/acrylate copolymer or alkylammonium salt thereof; (4) at least one cationic photoinitiator, advantageously iodonium borate; and (5) optionally, at least one photosensitizer.
摘要翻译：用于生产牙科假体和牙齿修复材料的稳定，高度填充的阳离子牙科组合物包含：（1）至少一种当被活化时反应阳离子的化合物，有利的是至少一种UV-和阳离子反应性环氧乙烷官能化的硅氧烷; （2）至少一种牙科填料，有利地是SiO 2; （3）至少一种有机聚合物或共聚物分散剂，其胺指数小于或等于100mg氢氧化钾/克分散剂，有利地是聚氨酯/丙烯酸酯共聚物或其烷基铵盐; （4）至少一种阳离子光引发剂，优选硼酸铵; 和（5）任选的至少一种光敏剂。

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