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1. 发明申请

WO9842693A3 NEUTRAL COLOURING PHOTOCHROMIC 2H-NAPHTHO(1,2-B)PYRANS AND HETEROCYCLIC PYRANS 审中-公开
标题翻译：中性色光照相2H-NAPHTHO（1,2-B）PYRANS AND HEOCOCYCLIC PYRANS
公开(公告)号：WO9842693A3
公开(公告)日：1999-02-11
申请号：PCT/GB9800904
申请日：1998-03-25
申请人： JAMES ROBINSON LTD , CLARKE DAVID ALLAN , HERON BERNARD MARK , GABBUTT CHRISTOPHER DAVID , HEPWORTH JOHN DAVID , PARTINGTON STEVEN MICHAEL , CORNS STEPHEN NIGEL
发明人： CLARKE DAVID ALLAN , HERON BERNARD MARK , GABBUTT CHRISTOPHER DAVID , HEPWORTH JOHN DAVID , PARTINGTON STEVEN MICHAEL , CORNS STEPHEN NIGEL
IPC分类号： G02C7/10 , C07D311/92 , C07D491/04 , C07D491/052 , C07D493/04 , C07D495/04 , C09K9/02 , G02B5/23 , C07D311/00
CPC分类号： C07D491/04 , C07D311/92 , C07D495/04
摘要： A naphtho[1,2-b]pyran of general formula (I) wherein R?1 and R2¿ are each selected from unsubstituted, mono-, di- or polysubstituted aryl groups, phenyl and naphthyl and heteroaryl groups. R5 is selected from linear or branched C¿1?-C10 alkyl, C1-C20 cycloalkyl, C1-C20 bicycloalkyl, C1-C20 polycycloalkyl, linear or branched C1-C10 haloalkyl, linear or branched C1-C10 perhaloalkyl, linear or branched C1-C10 perhaloalkenyl, linear or branched C1-C10 alkenyl, C1-C10 alkynyl, linear or branched C1-C10 alkoxy, linear or branched C1-C10 alkylthio, linear or branched C1-C10 alkoxy (linear or branched C1-C10 alkyl), linear or branched C1-C10 hydroxyalkyl, linear or branched C1-C10 aminoalkyl, aryl, phenyl, heteroaryl, halogen, nitrile, nitro, amino, linear or branched C1-C20 alkoxycarbonyl, hydroxyl, formyl, acetyl, amido, C1-C5 alkyl amido, C1-C5 dialkylamido, aroyl, benzoyl, alkyl C1-C5 amino, dialkyl C1-C5 amino, arylamino, diarylamino, aryl C1-C5 alkylamino and cyclicamino groups, arylsulfinyl, arylsulfanyl, arylsulfonyl, linear or branched C1-C10 alkylsulfonyl, P(O)(O-C1-C10 alkyl)2 or is an alkenyl function of general formula (a) wherein R?11¿ and/or R12 and/or R13 is hydrogen or R?5, R3, R4, R6, R8 and R10¿ are each hydrogen, R?1, R2 or R5; and R7¿ and/or R9 is hydrogen or an amino group provided that R?7 and R9¿ are not both hydrogen. The compounds may be combined with a polymeric host material such as plastic or glass to make a sunglass lens, an ophthalmic lens or a window.
摘要翻译：包含式（I）的萘并[1,2-b]吡喃的组合物：其中R 7和/或R 9为氢或氨基，条件是R 7和R 9不同时为氢，其它取代基如本说明书中所定义。

2. 发明专利

ES2178462T3 未知
公开(公告)号：ES2178462T3
公开(公告)日：2002-12-16
申请号：ES99941744
申请日：1999-08-24
申请人： JAMES ROBINSON LTD
发明人： CLARKE DAVID ALLAN , HERON BERNARD MARK , GABBUTT CHRISTOPHER DAVID , HEPWORTH JOHN DAVID , PARTINGTON STEVEN MICHAEL , CORNS STEPHEN NIGEL
IPC分类号： G02C7/10 , C07D311/78 , C07D311/92 , C07D491/04 , C07D493/04 , C07D495/04 , C08K5/3437 , C08L101/00 , C09D11/00 , C09K9/02 , G02B1/04 , G02B5/23 , G03C1/73 , C08K5/15

4. 发明专利

GB2232680B AZOPHENYL COMPOUNDS 未知
公开(公告)号：GB2232680B
公开(公告)日：1992-12-16
申请号：GB8913933
申请日：1989-06-16
申请人： JAMES ROBINSON LTD
发明人： PARTINGTON STEVEN MICHAEL , CLARKE DAVID ALLAN
IPC分类号： C09B29/08 , C09B29/12
摘要： Azophenyl compounds of the formula: I wherein R1 is an o-, p-directing substituent; R2 is a substituted or unsubstituted beta -hydroxyalkyl group; R3 is an aromatic carbocyclic or heterocyclic group which is mono- or poly-cyclic and is substituted or unsubstituted; and wherein the benzene ring A may contain one or more further substituents. The compounds are useful as dyestuffs (if they are themselves colored) or as intermediates in the preparation of dyestuffs.

5. 发明专利

ES2275303T3 2H-NAFTO(1,2-B)PIRANOS HETEROCICLICOS FOTOCROMICOS DE COLORACION INTENSA. 未知
公开(公告)号：ES2275303T3
公开(公告)日：2007-06-01
申请号：ES98913903
申请日：1998-03-25
申请人： JAMES ROBINSON LTD
发明人： CLARKE DAVID ALLAN , HERON BERNARD MARK , GABBUTT CHRISTOPHER DAVID , HEPWORTH JOHN DAVID , PARTINGTON STEVEN MICHAEL , CORNS STEPHEN NIGEL
IPC分类号： C07D311/92 , G02C7/10 , C07D311/78 , C07D409/04 , C07D491/052 , C07D493/04 , C07D495/04 , C09K9/02 , G02B5/23 , G03C1/73
摘要： La presente invención se refiere a un nafto{[}1,2b{]}pirano de fórmula general (I) en la que uno o ambos de R{sup,1} y R{sup,2} es un grupo 4-aminoarilo; R{sup,5} se selecciona de entre grupos con cadena lineal o ramificada alquilo C{sub,1-10}, cicloalquilo C{sub,1-20}, bicicloalquilo C{sub,1-20}, policicloalquilo C{sub,1-20}, o haloalquilo C{sub,1-10} lineal o ramificado, un perhaloalquilo C{sub,1-10} lineal o ramificado, un perhaloalquilo C{sub,1-10} lineal o ramificado, un alquenilo C{sub,1-10} lineal o ramificado, un alquinilo C{sub,1-10} , un alcoxi C{sub,1-C10} lineal o ramificado, un alquiltio lineal o ramificado C{sub,1-10}, un alcoxilo C{sub,1-10} lineal o ramificado (alquilo C{sub,1-10} lineal o ramificado), un hidroxialquilo C{sub,1-10} lineal o ramificado, un aminoalquilo C{sub,1-10} lineal o ramificado, arilo, fenilo, heteroarilo, halógeno, nitrilo, nitroamino, alcoxicarbonilo C{sub,1-10} lineal o ramificado hidroxilo, formilo, acetilo, amido, alquilamido C{sub,1-5}, dialquilamido C{sub,1-5}, aroílo, benzoílo, alquilo C{sub,1-5} amino, dialquil C{sub,1-5}amino, arilamino, diarilamino, aril C{sub,1-5} alquilamino y ciclicamino.; arilsulfinilo, arilsulfanilo, arilsulfonilo, alquilsulfonilo C{sub,1-10} lineal o ramificado, P(O)(O- C{sub,1-10} alquilo) {sub,2} o es la función alquenilo (II) en la que R{sup,11} y R{sup,12} y/o R{sup,13}son H o como se definió para R{sup,5}, y R{sup,3}, R{sup,4} y R{sup,6}- R{sup,10}que son cada uno H o como se definió para R{sup,1}, R{sup,2} o R{sup,5}. Los compuestos se pueden combinar con material anfitrión tal como un plástico o un vidrio para hacer lentes de gafas de sol o gafas oftálmicas o ventanas.

6. 发明专利

GB2345910B Photochromic compounds 未知
公开(公告)号：GB2345910B
公开(公告)日：2002-04-10
申请号：GB0009378
申请日：1998-10-19
申请人： JAMES ROBINSON LTD
发明人： HERON BERNARD MARK , GABBUTT CHRISTOPHER DAVID , HEPWORTH JOHN DAVID , PARTINGTON STEVEN MICHAEL , CORNS STEPHEN NIGEL , CLARKE DAVID ALLAN
IPC分类号： C07C251/44 , C07D295/135 , C07D498/10 , G03C1/685 , C07C207/04 , C07C251/48
摘要： A photochromic compound has the formula (I) wherein R1 is selected from the group including substituted amino aryl moieties, substituted cyclic amino aryl moieties and substituted N-indolinoaryl or N-tetrahydroquinolino aryl groups, R3 is selected from the group including linear or branched C1-C20 alkyl, linear or branched C2-C20 alkenyl or polyalkenyl, C2-C20 alkynyl or polyalkynyl, aryl, heteroaryl, linear or branched C1-C20 alkyl aryl, linear or branched C1-C20 alkyl-cycloalkyl or -bicycloalkyl or -tricycloalkyl or substituted -cycloalkyl or -bicycloalkyl or -tricycloalkyl, linear or branched C1-C20 haloalkyl or perhaloalkyl, linear or branched C1-C20 alkoxyalkyl or peralkoxyalkyl, linear or branched C1-C20 alkylthioalkyl or peralkylthioalkyl, linear or branched C1-C20 amino alkyl or peraminoalkyl, C3-C20 cycloalkyl or substituted cycloalkyl, C4-C20 bicycloalkyl or substituted bicycloalkyl, C6-C20 tricycloalkyl or substituted tricycloalkl or linear or branched C1-C20 hydroxyalkyl or perhydroxyalkyl; R4 and R5 which may be the same or different are R3 or R4 and R5 are conjoined to form a spiro linked C3-C20 cyclic system or substituted cyclic system; and wherein R2 and R6 are each selected from R3 or hydrogen, halogen, nitro, nitroso, amino, acetamido, C2-C10 N-alkylamido, alkoxycarbonyl, nitrile, carboxy, hydroxy, aryloxy, C1-C10 alkoxy, a heteroatom which is O or N or S or P which in turn can be bonded either singly or multiply to carbon, oxygen, sulphur or nitrogen, C1-C5 alkoxy or alkylthio or aryl or aryloxy or multiples thereof.

7. 发明专利

AT129001T 未知
公开(公告)号：AT129001T
公开(公告)日：1995-10-15
申请号：AT90909154
申请日：1990-06-07
申请人： JAMES ROBINSON LTD
发明人： PARTINGTON STEVEN MICHAEL WOOD , CLARKE DAVID ALLAN
IPC分类号： C09B29/08 , C09B29/12
摘要： Azophenyl compounds of the formula: I wherein R1 is an o-, p-directing substituent; R2 is a substituted or unsubstituted beta -hydroxyalkyl group; R3 is an aromatic carbocyclic or heterocyclic group which is mono- or poly-cyclic and is substituted or unsubstituted; and wherein the benzene ring A may contain one or more further substituents. The compounds are useful as dyestuffs (if they are themselves colored) or as intermediates in the preparation of dyestuffs.

8. 发明专利

DK1025107T3 未知
公开(公告)号：DK1025107T3
公开(公告)日：2002-11-04
申请号：DK98947700
申请日：1998-10-19
申请人： JAMES ROBINSON LTD
发明人： CLARKE DAVID ALLAN , HERON BERNARD MARK , GABBUTT CHRISTOPHER DAVID , HEPWORTH JOHN DAVID , PARTINGTON STEVEN MICHAEL , CORNS STEPHEN NIGEL
IPC分类号： C07C251/44 , C07D295/135 , C07D498/10 , G03C1/685
摘要： A photochromic compound has the formula (I) wherein R1 is selected from the group including substituted amino aryl moieties, substituted cyclic amino aryl moieties and substituted N-indolinoaryl or N-tetrahydroquinolino aryl groups, R3 is selected from the group including linear or branched C1-C20 alkyl, linear or branched C2-C20 alkenyl or polyalkenyl, C2-C20 alkynyl or polyalkynyl, aryl, heteroaryl, linear or branched C1-C20 alkyl aryl, linear or branched C1-C20 alkyl-cycloalkyl or -bicycloalkyl or -tricycloalkyl or substituted -cycloalkyl or -bicycloalkyl or -tricycloalkyl, linear or branched C1-C20 haloalkyl or perhaloalkyl, linear or branched C1-C20 alkoxyalkyl or peralkoxyalkyl, linear or branched C1-C20 alkylthioalkyl or peralkylthioalkyl, linear or branched C1-C20 amino alkyl or peraminoalkyl, C3-C20 cycloalkyl or substituted cycloalkyl, C4-C20 bicycloalkyl or substituted bicycloalkyl, C6-C20 tricycloalkyl or substituted tricycloalkl or linear or branched C1-C20 hydroxyalkyl or perhydroxyalkyl; R4 and R5 which may be the same or different are R3 or R4 and R5 are conjoined to form a spiro linked C3-C20 cyclic system or substituted cyclic system; and wherein R2 and R6 are each selected from R3 or hydrogen, halogen, nitro, nitroso, amino, acetamido, C2-C10 N-alkylamido, alkoxycarbonyl, nitrile, carboxy, hydroxy, aryloxy, C1-C10 alkoxy, a heteroatom which is O or N or S or P which in turn can be bonded either singly or multiply to carbon, oxygen, sulphur or nitrogen, C1-C5 alkoxy or alkylthio or aryl or aryloxy or multiples thereof.

9. 发明专利

GB2338233B Red colouring hyperchromic 3 H-Naphtho[2,1-b]Pyrans 未知
公开(公告)号：GB2338233B
公开(公告)日：2001-09-05
申请号：GB9922328
申请日：1998-04-03
申请人： JAMES ROBINSON LTD
发明人： CLARKE DAVID ALLAN , HERON BERNARD MARK , GABBUTT CHRISTOPHER DAVID , HEPWORTH JOHN DAVID , PARTINGTON STEVEN MICHAEL , CORNS STEPHEN NIGEL
IPC分类号： C07D311/92 , C07D405/10 , C07D413/10 , C07D417/10 , C09B57/02 , C09D7/12 , C09D11/02 , C09D201/00 , C09K9/02 , C07D409/04 , G02B5/23 , G03C1/00

10. 发明专利

GB2338480A Intense colouring photochromic 2H-Naphtho[1,2-b]pyrans and heterocyclic pyrans 未知
公开(公告)号：GB2338480A
公开(公告)日：1999-12-22
申请号：GB9922331
申请日：1998-03-25
申请人： JAMES ROBINSON LTD
发明人： CLARKE DAVID ALLAN , HERON BERNARD MARK , GABBUTT CHRISTOPHER DAVID , HEPWORTH JOHN DAVID , PARTINGTON STEVEN MICHAEL , CORNS STEPHEN NIGEL
IPC分类号： G02C7/10 , C07D311/78 , C07D311/92 , C07D409/04 , C07D491/052 , C07D493/04 , C07D495/04 , C09K9/02 , G02B5/23 , G03C1/73
摘要： A naphtho [1,2-b] pyran of general formula (1), wherein one or both of R 1 and R 2 is a 4-aminoaryl group; R 5 is selected from linear or branched C 1 -C 10 alkyl, C 1 -C 20 cycloalkyl, C 1 -C 20 bicycloalkyl, C 1 -C 20 polycycloalkyl, linear or branched C 1 -C 10 haloalkyl, linear or branched C 1 -C 10 perhaloalkyl, linear or branched C 1 -C 10 perhaloalkenyl, linear or branched C 1 -C 10 alkenyl, C 1 -C 10 alkynyl, linear or branched C 1 -C 10 alkoxy, linear or branched C 1 -C 10 alkylthio, linear or branched C 1 -C 10 alkoxy (linear or branched C 1 -C 10 alkyl), linear or branched C 1 -C 10 hydroxyalkyl, linear or branched C 1 -C 10 aminoalkyl, aryl, phenyl, heteroaryl, halogen, nitrile, nitro, amino, linear or branched C 1 -C 20 alkoxycarbonyl, hydroxyl, formyl, acetyl, amido, C 1 -C 5 alkylamido, C 1 -C 5 dialkylamido aroyl, benzoyl, alkyl C 1 -C 5 amino, dialkyl C 1 -C 5 amino, arylamino, diarylamino, aryl C 1 -C 5 alkylamino and cyclicamino groups; arylsulfinyl, arylsulfanyl, arylsulfonyl, linear or branched C 1 -C 10 alkylsulfonyl, P(O)(O-C 1 -C 10 alkyl) 2 or is the alkenyl function (II), wherein R 11 and/or R 12 and/or R 13 is hydrogen or is as defined for R 5 , and R 3 , R 4 and R 6 -R 10 are each hydrogen or as defined R 1 , R 2 or R 5 . The compounds may be combined with a polymeric host material such as a plastic or a glass to make a sunglass lens, an ophthalmic lens or a window.

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