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1. 发明授权

US3960875A Process for the preparation of 2,2,6,6-tetramethyl-4-oxopiperidine 失效
标题翻译：制备2,2,6,6-四甲基-4-氧代哌啶的方法
公开(公告)号：US3960875A
公开(公告)日：1976-06-01
申请号：US481935
申请日：1974-06-21
申请人： Ivan Orban , Hanns Lind , Heimo Brunetti , Jean Rody
发明人： Ivan Orban , Hanns Lind , Heimo Brunetti , Jean Rody
IPC分类号： C07D211/74
CPC分类号： C07D211/74
摘要： 2,2,6,6-Tetramethyl-4-oxopiperidine is prepared from 2,2,4,4,6-pentamethyl-2,3,4,5-tetramethylpyrimidine (acetonine) by heating in the presence of acetone, diacetone alcohol or water. These regents may be used in excess or an organic solvent is added. The preferred modification is the heating of acetonine hydrate in an excess of acetone or in an acetone-methanol mixture to about 40.degree. to 65.degree.C for several hours. The use of diacetone alcohol permits higher reaction temperatures leading to shorter reaction times.
摘要翻译： 2,2,6,6-四甲基-4-氧代哌啶由2,2,4,4,6-五甲基-2,3,4,5-四甲基嘧啶（丙酮）通过在丙酮存在下加热，双丙酮醇或水。这些试剂可以过量使用或添加有机溶剂。优选的修改是将丙酮水合物在过量丙酮中或在丙酮 - 甲醇混合物中加热至约40至65℃几个小时。使用双丙酮醇允许更高的反应温度导致更短的反应时间。

2. 发明授权

US3959295A Process for the preparation of 2,2,6,6-tetramethyl-4-oxopiperidine 失效
标题翻译：制备2,2,6,6-四甲基-4-氧代哌啶的方法
公开(公告)号：US3959295A
公开(公告)日：1976-05-25
申请号：US481922
申请日：1974-06-21
申请人： Ivan Orban , Hanns Lind , Heimo Brunetti , Jean Rody , Michael Rasberger
发明人： Ivan Orban , Hanns Lind , Heimo Brunetti , Jean Rody , Michael Rasberger
IPC分类号： C07D211/74
摘要： 2,2,6,6-Tetramethyl-4-oxopiperidine is prepared from acetone and ammonia in the presence of acidic catalysts. Suitable catalysts are Lewis acids, protionic acids and their salts with ammonia or with organic bases, as for example BF.sub.3, NH.sub.4 Cl or H.sub.2 SO.sub.4. The addition of an alcohol such as methanol as well as the use of a cocatalyst may promote the reaction. The process may be carried out in two steps, in the first of which the temperature is held below 35.degree.C. In the second step a further amount of acetone is added and the temperature is rised to about 40.degree. to 65.degree.C.
摘要翻译：在酸性催化剂存在下，由丙酮和氨制备2,2,6,6-四甲基-4-氧代哌啶。合适的催化剂是路易斯酸，丙酸及其与氨或有机碱的盐，例如BF 3，NH 4 Cl或H 2 SO 4。加入醇如甲醇以及助催化剂的使用可能促进反应。该方法可以在两个步骤中进行，其中第一步将温度保持在35℃以下。在第二步中，加入另外量的丙酮，将温度升至约40℃至65℃。

3. 发明授权

US3953459A Process for the preparation of 2,2,6,6-tetramethyl-4-oxopiperidine 失效
标题翻译：制备2,2,6,6-四甲基-4-氧代哌啶的方法
公开(公告)号：US3953459A
公开(公告)日：1976-04-27
申请号：US481921
申请日：1974-06-21
申请人： Ivan Orban , Hanns Lind , Heimo Brunetti , Jean Rody
发明人： Ivan Orban , Hanns Lind , Heimo Brunetti , Jean Rody
IPC分类号： C07D211/74
CPC分类号： C07D211/74
摘要： 2,2,6,6-Tetramethyl-4-oxopiperidine is prepared from 2,2,4,4,6-pentamethyl-2,3,4,5-tetrahydropyrimidine by treatment with an acidic catalyst. Suitable catalysts are Lewis acids, protonic acids and their salts with ammonia or organic bases. The reaction may be carried out in organic solvents, preferably in acetone, by gentle heating, for example at 40.degree. to 65.degree.C. Yields of 95% are obtainable after a reaction of several hours.
摘要翻译：通过用酸性催化剂处理由2,2,4,4,6-五甲基-2,3,4,5-四氢嘧啶制备2,2,6,6-四甲基-4-氧代哌啶。合适的催化剂是路易斯酸，质子酸及其与氨或有机碱的盐。反应可以在有机溶剂中，优选在丙酮中，通过温和加热，例如在40至65℃下进行。反应几小时后可获得95％的产率。

4. 发明授权

US3943139A Process for the manufacture of triacetone-amine 失效
标题翻译：制备三丙酮胺的方法
公开(公告)号：US3943139A
公开(公告)日：1976-03-09
申请号：US403360
申请日：1973-10-04
申请人： Ivan Orban , Jean Rody
发明人： Ivan Orban , Jean Rody
IPC分类号： C07D211/74 , C07D211/02
CPC分类号： C07D211/74
摘要： A new process for producing triacetone-amine by reacting phoron and ammonia under pressure and higher temperature.
摘要翻译：一种在压力和较高温度下使佛波酮和氨反应生成三丙酮胺的新方法。

5. 发明授权

US4716244A Process for the preparation of sterically hindered hydroxyphenylcarboxylic acid esters 失效
标题翻译：空间位阻羟基苯基羧酸酯的制备方法
公开(公告)号：US4716244A
公开(公告)日：1987-12-29
申请号：US853839
申请日：1986-04-21
申请人： Ivan Orban
发明人： Ivan Orban
IPC分类号： C10M129/76 , C07C67/02 , C07C67/03 , C07C69/732 , C07C69/88 , C10N30/10 , C11B5/00
CPC分类号： C07C69/732 , C07C69/88 , Y10S203/06
摘要： If the transesterification of esters of formula II ##STR1## with alcohols of formula III A--OH).sub.m is catalysed by treatment with catalytic amounts of an organic or inorganic zinc salt and the resultant melt is subsequently distilled in a short-time distillation apparatus under specific conditions, then compounds of the formula ##STR2## are obtained in virtually quantitative yield, in which formulae I, II and III n is a number from 0 to 2, m is 1 or 2, A is a radical derived from an m-valent aliphatic alcohol, which radical contains 2 to 18 carbon atoms, B is methyl or tert-butyl and R is methyl or ethyl. The products thus obtained contain no troublesome by-products and do not have to be additionally purified.
摘要翻译：如果通过用催化量的有机或无机锌盐处理来催化式II酯与式IIIA-OH）m的醇的酯交换反应，随后在短时蒸馏装置中蒸馏所得的熔体，具体条件下，以实质上的定量产率获得式（I）化合物，其中式I，II和III n为0至2的数，m为1或2，A为衍生自一个含有2至18个碳原子的B价基的脂肪醇，B是甲基或叔丁基，R是甲基或乙基。由此获得的产品不含麻烦的副产物，不必另外纯化。

6. 发明授权

US06403680B1 Block oligomers containing 1-hydrocarbyloxy-2,2,6,6-tetramethyl-4-piperidyl groups as stabilizers for organic materials 有权
标题翻译：含有1-烃氧基-2,2,6,6-四甲基-4-哌啶基的嵌段低聚物作为有机材料的稳定剂
公开(公告)号：US06403680B1
公开(公告)日：2002-06-11
申请号：US09424138
申请日：1999-11-18
申请人： James Peter Galbo , Nicola Lelli , Valerio Borzatta , Jean-Pierre Wolf , Michael Ackerman , Piero Piccinelli , Ivan Orban
发明人： James Peter Galbo , Nicola Lelli , Valerio Borzatta , Jean-Pierre Wolf , Michael Ackerman , Piero Piccinelli , Ivan Orban
IPC分类号： C08K534
CPC分类号： C07D401/14 , C08K5/34926
摘要： A product obtained by 1) reacting a compound of the formula (&agr;) with a compound of the formula (&bgr;) in a stoichiometric ratio to obtain a compound of the formula (&ggr;) 2) reacting the compound of the formula (&bgr;) with the compound of the formula (&ggr;) in a molar ratio of 0.4:1 to 0.75:1; 3) reacting the end groups of the formula (&dgr;) being present in the product of the reaction 2) with e.g. dibutylamine in a molar ratio of 2:1.7 to 2:3; the reactions 1) to 3) being carried out in an organic solvent in the presence of an inorganic base; and 4) transferring the groups of the formula being present in the product of the reaction 3) to groups of the formula said transfer being carried out by reacting the product of the reaction 3) with a hydroperoxide in a hydrocarbon solvent in the presence of a peroxide decomposing catalyst; R1 is in particular a hydrocarbyl radical, B is e.g. N-(2,2,6,6-tetramethyl-4-piperdyl)-butylamino, R is e.g. 2,2,6,6-tetramethyl-4-piperidyl and R2 is e.g. hexamethylene.
摘要翻译：通过以下方式获得的产物：1）以化学计量比使式（α）化合物与式（β）化合物反应得到式（γ）化合物2）使式（β）化合物与式使摩尔比为0.4:1至0.75:1的式（γ）化合物; 3）使反应2）的产物中存在的式（delta）的端基与例如二丁胺摩尔比为2：1.7至2：3; 反应1）〜3）在无机碱存在下在有机溶剂中进行; 和4）将反应3）中存在的配方的基团转移到通过在过氧化物分解催化剂存在下在烃溶剂中使反应3）的产物与氢过氧化物反应来进行的公式转移的基团 ; R1特别是烃基，B是例如。 N-（2,2,6,6-四甲基-4-哌啶基） - 丁基氨基， 2,2,6,6-四甲基-4-哌啶基，R 2是例如。六亚甲基。

7. 发明授权

US5130429A Process for the methylation of triazine compounds containing 2,2,6,6-tetramethylpiperidine groups 失效
标题翻译：包含2,2,6,6-四甲基哌啶基组合物的三嗪化合物的甲基化方法
公开(公告)号：US5130429A
公开(公告)日：1992-07-14
申请号：US800871
申请日：1991-11-27
申请人： Piero Piccinelli , Ivan Orban , Martin Holer , Valerio Borzatta
发明人： Piero Piccinelli , Ivan Orban , Martin Holer , Valerio Borzatta
IPC分类号： C07D401/12 , C07D401/14
CPC分类号： C07D401/14
摘要： Process for the methylation of compounds at least one group of the formula (I) ##STR1## by means of a mixture of formaldehyde and formic acid in a reaction medium consisting of an aromatic hydrocarbon solvent.

8. 发明授权

US4536593A Process for the preparation of sterically hindered hydroxphenylcarboxylic acid esters 失效
标题翻译：空间位阻羟基羧酸酯的制备方法
公开(公告)号：US4536593A
公开(公告)日：1985-08-20
申请号：US510705
申请日：1983-07-05
申请人： Ivan Orban , Eduard Troxler
发明人： Ivan Orban , Eduard Troxler
IPC分类号： C07C67/03 , B01J21/16 , B01J29/00 , B01J31/12 , C07B61/00 , C07C67/00 , C07C69/003 , C07C69/732 , C07C69/88 , C07C313/00 , C07C323/12 , C07C69/76
CPC分类号： C07C69/732 , C07C69/88
摘要： If the transesterification of esters of the formula ##STR1## with alcohols of the formula III A--(OH).sub.m is catalyzed by successive treatment with catalytic amounts (a) of a tin compound of a metal of the fourth main group or the fourth sub-group of the periodic system and (b) of an acid earth, compounds of the formula I ##STR2## are obtained in virtually quantitative yield. The products thus obtained contain no troublesome by-products and do not have to be additionally purified.R is methyl or ethyl, A is a radical derived from an m-hydric aliphatic alcohol, n is 0 to 2, and m is 1 to 4.
摘要翻译：如果通过用催化量（a）第四主族的金属的锡化合物或第四主体的第四主体的连续处理来催化式II-（OH）m的醇的酯交换，周期性系统的亚组和（b）酸性土，以几乎定量的产率获得式I“IMAGE”的化合物。由此获得的产品不含麻烦的副产物，不必另外纯化。 R为甲基或乙基，A为衍生自间二羟基脂肪醇的基团，n为0〜2，m为1〜4。

9. 发明授权

US5688969A Process for the preparation of thiophene-2-5-dicarboxylic acid and the dichloride thereof 失效
标题翻译：噻吩-2,5-二羧酸及其二氯化物的制备方法
公开(公告)号：US5688969A
公开(公告)日：1997-11-18
申请号：US751566
申请日：1996-11-18
申请人： Ivan Orban
发明人： Ivan Orban
IPC分类号： C07D333/40 , B01J31/02 , C07B61/00 , C07D333/38
CPC分类号： C07D333/38
摘要： The invention relates to a process for the preparation of thiophene-2,5-dicarboxylic acid by reacting thionyl chloride and adipic acid, with pyridine as catalyst, which process comprises A) adding 1 part of adipic acid to 3 to 6 parts of thionyl chloride, mixed with a catalytic amount of pyridine, B) adding a further 4 to 7 parts of thionyl chloride in the temperature range from 85.degree. to 95.degree. C., C) removing excess thionyl chloride and volatile by-products under reduced pressure, and D) bringing the reaction to completion in the temperature range from 140.degree. to 160.degree. C., and E) preparing a salt of thiophene-2,5-dicarboxylic acid by hydrolysing the chloride obtained with an aqueous solution of an alkaline earth metal hydroxide or an alkali metal hydroxide, and F) obtaining the free acid from this salt with a mineral acid.
摘要翻译：本发明涉及通过亚硫酰氯和己二酸与吡啶反应制备噻吩-2,5-二羧酸的方法，该方法包括：A）将1份己二酸加入3至6份亚硫酰氯与催化量的吡啶混合，B）在85℃〜95℃的温度范围内再加入4〜7份亚硫酰氯，C）在减压下除去过量的亚硫酰氯和挥发性副产物， D）使反应在140℃至160℃的温度范围内完成，E）通过水解由碱土金属氢氧化物水溶液获得的氯化物制备噻吩-2,5-二羧酸的盐或碱金属氢氧化物，F）用无机酸从该盐得到游离酸。

10. 发明授权

US4492791A Process for the preparation of polyaminotriazines 失效
标题翻译：制备聚氨基三嗪的方法
公开(公告)号：US4492791A
公开(公告)日：1985-01-08
申请号：US488246
申请日：1983-04-25
申请人： Ivan Orban , Eduard Troxler
发明人： Ivan Orban , Eduard Troxler
IPC分类号： C08G73/00 , C07D401/14 , C08G73/06 , C08G73/08 , C08K5/3492 , C08L79/04 , C08L101/00
CPC分类号： C07D401/14 , C08G73/0644 , C08K5/34926
摘要： The known reaction of dichlorotriazines of the formula II ##STR1## in which Q is an ether or amino radical, with diamines of the formula IIIPip--NH--R--NH--Pip (III)in which Pip is a radical of the formula ##STR2## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.8 -alkenyl, C.sub.7 -C.sub.11 -phenylalkyl, C.sub.2 -C.sub.8 -alkanoyl or C.sub.3 -C.sub.5 -alkenoyl and R is a divalent organic radical leads to undesirable, sparingly soluble by-products. The formation of these by-products can be suppressed if the reaction is carried out in a water-immiscible organic solvent with the addition of an aqueous base--preferably NaOH or KOH--under pressure at 140.degree.-220.degree. C.
摘要翻译：其中Q是醚或氨基的式II（II）的二氯三嗪与式III的二胺Pip-NH-R-NH-Pip（III）的已知反应，其中Pip是其中R 1是氢，C 1 -C 12 - 烷基，C 3 -C 8 - 烯基，C 7 -C 11 - 苯基烷基，C 2 -C 8 - 烷酰基或C 3 -C 5 - 烯酰基和R是二价有机基团的式导致不期望的，微溶副产物。如果反应在水不混溶的有机溶剂中通过加入碱水溶液 - 优选NaOH或KOH-在140-220℃的压力下进行，则可以抑制这些副产物的形成。

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