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    • 9. 发明授权
    • Universal grignard metathesis polymerization
    • 通用格氏复分解聚合
    • US08288508B2
    • 2012-10-16
    • US11849229
    • 2007-08-31
    • Richard D. McCulloughMihaela C. IovuItaru Osaka
    • Richard D. McCulloughMihaela C. IovuItaru Osaka
    • C08G61/00
    • C08G61/00C07B49/00
    • Universal Grignard Metathesis (GRIM) reactions which provide access to conjugated polymers by GRIM methods. A method comprising: providing an unsaturated ring compound comprising at least two halogen ring substituents, providing an organomagnesium reagent comprising an organomagnesium component and a metal activation agent, combining the unsaturated ring compound with the reagent to form a second compound by metal-halogen exchange, wherein the metal activation agent activates the metal-halogen exchange, coupling the second compound to itself in an oligomerization or polymerization reaction. Metal activation agent can be lithium chloride. The process is commercially attractive and can be executed in good yields. Polyfluorenes, polypyrroles, and polythiophenes can be prepared for use in OLED, PLED, photovoltaic, transistor, antistatic coatings, and sensor applications.
    • 通用Grignard复分解(GRIM)反应,通过GRIM方法提供对共轭聚合物的接触。 一种方法,包括:提供包含至少两个卤素环取代基的不饱和环化合物,提供包含有机镁组分和金属活化剂的有机镁试剂,将不饱和环化合物与试剂结合以通过金属 - 卤素交换形成第二化合物, 其中所述金属活化剂活化所述金属 - 卤素交换,在低聚反应或聚合反应中将所述第二化合物偶联至其自身。 金属活化剂可以是氯化锂。 该方法具有商业上的吸引力,可以以良好的产率进行。 聚芴,聚吡咯和聚噻吩可以制备用于OLED,PLED,光伏,晶体管,抗静电涂层和传感器应用。
    • 10. 发明申请
    • UNIVERSAL GIRNARD METATHESIS POLYMERIZATION
    • 通用GIRNARD METATHESIS聚合
    • US20080146754A1
    • 2008-06-19
    • US11849229
    • 2007-08-31
    • Richard D. MCCULLOUGHMihaela C. IovuItaru Osaka
    • Richard D. MCCULLOUGHMihaela C. IovuItaru Osaka
    • C08F2/00
    • C08G61/00C07B49/00
    • Universal Grignard Metathesis (GRIM) reactions which provide access to conjugated polymers by GRIM methods. A method comprising: providing an unsaturated ring compound comprising at least two halogen ring substituents, providing an organomagnesium reagent comprising an organomagnesium component and a metal activation agent, combining the unsaturated ring compound with the reagent to form a second compound by metal-halogen exchange, wherein the metal activation agent activates the metal-halogen exchange, coupling the second compound to itself in an oligomerization or polymerization reaction. Metal activation agent can be lithium chloride. The process is commercially attractive and can be executed in good yields. Polyfluorenes, polypyrroles, and polythiophenes can be prepared for use in OLED, PLED, photovoltaic, transistor, antistatic coatings, and sensor applications.
    • 通用Grignard复分解(GRIM)反应,通过GRIM方法提供对共轭聚合物的接触。 一种方法,包括:提供包含至少两个卤素取代基的不饱和环化合物,提供包含有机镁组分和金属活化剂的有机镁试剂,将不饱和环化合物与试剂结合以通过金属 - 卤素交换形成第二化合物, 其中所述金属活化剂活化所述金属 - 卤素交换,在低聚反应或聚合反应中将所述第二化合物偶联至其自身。 金属活化剂可以是氯化锂。 该方法具有商业上的吸引力,可以以良好的产率进行。 聚芴,聚吡咯和聚噻吩可以制备用于OLED,PLED,光伏,晶体管,抗静电涂层和传感器应用。