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1. 发明授权

US5463082A Fluorous multiphase systems 失效
标题翻译：氟多相体系
公开(公告)号：US5463082A
公开(公告)日：1995-10-31
申请号：US88706
申请日：1993-07-08
申请人： Istvan T. Horvath , Jozsef Rabai
发明人： Istvan T. Horvath , Jozsef Rabai
IPC分类号： B01J31/02 , B01J31/20 , B01J31/22 , B01J31/24 , B01J31/40 , C07C17/38 , C07C45/50 , C07C315/02 , C07C317/14 , C07D303/32 , C07D333/76 , C07F9/09 , C07F9/141 , C07F9/50 , C07C37/58 , C07C45/62
CPC分类号： C07F9/1411 , B01J31/183 , B01J31/185 , B01J31/20 , B01J31/24 , B01J31/4046 , C07C17/38 , C07C315/02 , C07C45/50 , C07D303/32 , C07D333/76 , C07F9/091 , C07F9/5004 , B01J2231/321 , B01J2231/70 , B01J2531/025 , B01J2531/822 , B01J2531/842 , B01J2531/845 , B01J2531/847 , B01J2531/94 , B01J2531/98 , B01J2540/225 , B01J2540/64 , B01J31/2234 , Y02P20/582 , Y02P20/584
摘要： Stoichiometric and catalytic chemical transformations may be carried out in solution using novel fluorous multiphase systems (FMS). The term "fluorous" is defined as a carbon-fluorine bond rich organic molecule. The FMS consists of a fluorous phase containing a fluorous solvent, typically a fluorocarbon or a fluorohydrocarbon and a reagent or a catalyst containing a sufficient number of fluorous moieties to render it preferentially soluble in the fluorous solvent without impairing the ability of the catalyst or reagent to be effective in the reaction and while maintaining the reaction in a liquid or fluid phase. The nonfluorous solvent may be any suitable organic or nonorganic solvent(s) with limited or no solubility in the fluorous solvent that is effective for dissolving the reactant(s) and most desirably, for separating the resulting product(s). Typically, such solvents have a Hildebrand solubility parameter of at least about 18.0 MPa1/2. Appropriate fluorous moieties are linear, branched and carbocyclic fluorocarbon alkyl chains with high carbon numbers. FMS reagents and catalysts can be prepared by (1) fluorination (i.e., replacement of C--H bonds with fluorine); (2) fluorofunctionalization, e.g., the attachment of fluorous moieties to the reagents or catalysts; or (3) by total synthesis. The invention is useful in separations technology and in catalyst design and synthesis.
摘要翻译：化学计量和催化化学转化可以在溶液中使用新的氟多相体系（FMS）进行。术语“氟”被定义为富含氟 - 氟的有机分子。 FMS由含氟溶剂（通常为碳氟化合物或氟代烃）的氟相和含有足够数量的氟部分的试剂或催化剂组成，使其优先溶于氟溶剂中而不损害催化剂或试剂的能力在反应中有效并且在液体或流体相中保持反应。非氟溶剂可以是在氟溶剂中溶解有限或不溶性的任何合适的有机溶剂或非有机溶剂，其有效溶解反应物，最理想的是用于分离所得产物。通常，这样的溶剂具有至少约18.0MPa1 / 2的希尔德布兰德溶解度参数。合适的氟部分是具有高碳数的直链，支链和碳环碳氟烷基链。 FMS试剂和催化剂可以通过（1）氟化（即用氟取代C-H键）来制备; （2）氟官能化，例如将氟部分连接到试剂或催化剂上; 或（3）通过总合成。本发明在分离技术和催化剂设计和合成中是有用的。

2. 发明授权

US5981422A Fluorous multiphase system 失效
标题翻译：氟多相系统
公开(公告)号：US5981422A
公开(公告)日：1999-11-09
申请号：US918828
申请日：1997-08-26
申请人： Istvan Tamas Horvath , Jozsef Rabai
发明人： Istvan Tamas Horvath , Jozsef Rabai
IPC分类号： B01J31/18 , C07C17/38 , C07C315/02 , C07C317/14 , C07D303/32 , C07D333/76 , C07B47/00
CPC分类号： C07D333/76 , B01J31/183 , C07C17/38 , C07C315/02 , C07D303/32 , B01J2531/025 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , B01J2531/847 , Y02P20/582
摘要： Stoichiometric and catalytic chemical transformations may be carried out in solution using novel fluorous multiphase systems (FMS). The term "fluorous" is defined as a carbon-fluorine bond rich organic molecule which is generated by replacing hydrogen atoms bonded to carbon atoms with fluorine. The novel complexes suitable for use as fluorous catalysts and reagents in the present invention contain sufficient number of fluorous moieties to render them preferentially soluble in the appropriate fluorous solvent without impairing the ability of the catalyst or reagent to be effective or participate in the corresponding reaction. Thus, a variety of fluorous compositions may be prepared according to the present invention, included among them are complexes selected from the group consisting of perfluoroalkylphthalocyaninato metal complexes wherein the metal is selected from ruthenium, iron, cobalt, osmium, rhodium and iridium; (perfluoro-alkyl) 5, 10, 15, 20-tetrakis-pentafluorophenyl porphyrin metal complexes selected from ClM{P[(CH.sub.2).sub.n (CF.sub.2) CF.sub.3 ].sub.3 }.sub.3, ClM{P[O(CH.sub.2).sub.n (CF.sub.2).sub.m CF.sub.3 ].sub.3 }.sub.3, HM(CO).sub.x {P[(CH.sub.2).sub.n (CF.sub.2) .sub.m CF.sub.3 ].sub.3 }.sub.4-x, and HM(CO).sub.x {P[O(CH.sub.2).sub.n (CF.sub.2).sub.m CF.sub.3 ].sub.3 }.sub.4-x, wherein in each occurrence M is selected from cobalt, rhodium, iron, osmium, and iridium, x ranges from 1-3, (CH.sub.2).sub.n may be present or absent and when present n ranges from 1-5, and m ranges from 4-20.
摘要翻译：化学计量和催化化学转化可以在溶液中使用新的氟多相体系（FMS）进行。术语“氟”被定义为通过用氟取代与碳原子键合的氢原子而产生的富含碳 - 氟的有机分子。适用于本发明的氟代催化剂和试剂的新型配合物含有足够数量的氟部分，使其优先溶于合适的氟溶剂中，而不会损害催化剂或试剂有效或参与相应反应的能力。因此，可以根据本发明制备各种氟组合物，其中包括选自全氟烷基酞菁金属络合物的络合物，其中金属选自钌，铁，钴，锇，铑和铱; （CF 2）CF 3] 3，ClM（P（O（CH 2）n（CF 2））的5,10,15,20-四五氟苯基卟啉金属络合物， mCF3] 3} 3，HM（CO）x {P [（CH2）n（CF2）mCF3] 3} 4-x和HM（CO）x {P [O（CH2）n（CF2）mCF3] 3} 4-x，其中在每次出现的情况下，M选自钴，铑，铁，锇和铱，x的范围为1-3，（CH 2）n可以存在或不存在，并且当存在n的范围为1-5时，和 m范围从4-20。

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