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1. 发明授权

US5234962A Polyolefin foams having a homogeneous cell structure 失效
标题翻译：具有均质细胞结构的聚烯烃基团
公开(公告)号：US5234962A
公开(公告)日：1993-08-10
申请号：US2039
申请日：1993-01-08
申请人： Isidoor de Grave , Wolfram Koegel , Klaus Hahn
发明人： Isidoor de Grave , Wolfram Koegel , Klaus Hahn
IPC分类号： C08J9/14 , C08J9/16 , C08J9/18 , C08J9/232
CPC分类号： C08J9/232 , C08J9/18 , C08J2203/06 , C08J2323/02
摘要： Polyolefin foams having a density of from 0.01 to 0.1 g/cm.sup.3 and having 2 to 1000 cells/mm.sup.2 and containing a resin acid, a lower alkyl ester or a resin acid or (hydro) abietyl phthalate as organic foaming aid have a homogeneous cell structure.
摘要翻译：密度为0.01〜0.1g / cm 3，具有2〜1000个/ mm 2的含有树脂酸，低级烷基酯或树脂酸或邻苯二甲酸（氢化）邻苯二甲酸酯作为有机发泡助剂的聚烯烃泡沫具有均匀的电池结构。

2. 发明授权

US5262446A Polyolefin foams having a homogeneous cell structure 失效
标题翻译：具有均匀单元结构的聚烯烃泡沫
公开(公告)号：US5262446A
公开(公告)日：1993-11-16
申请号：US36855
申请日：1993-03-25
申请人： Isidoor de Grave , Wolfram Koegel , Klaus Hahn
发明人： Isidoor de Grave , Wolfram Koegel , Klaus Hahn
IPC分类号： C08J9/18 , C08J9/232 , C08J9/20 , C08J9/224
CPC分类号： C08J9/232 , C08J9/18 , C08J2203/06 , C08J2323/02
摘要： Polyolefin foams having a density of from 0.01 to 0.1 g/cm.sup.3 and having 2 to 1000 cells/mm.sup.2 and containing a resin acid, a lower alkyl ester of a resin acid or (hydro) abietyl phthalate as organic foaming aid have a homogeneous cell structure.
摘要翻译：密度为0.01〜0.1g / cm 3，2〜1000个/ mm 2，含有树脂酸，作为有机发泡助剂的树脂酸或（氢化）邻苯二甲酸酯的低级烷基酯的聚烯烃泡沫具有均匀的电池结构。

3. 发明授权

US5925686A Production of expanded polyolefin particles 失效
标题翻译：发泡聚烯烃颗粒的生产
公开(公告)号：US5925686A
公开(公告)日：1999-07-20
申请号：US952113
申请日：1997-11-24
申请人： Wolfram Kogel , Isidoor De Grave , Klaus Hahn , Joachim Fischer
发明人： Wolfram Kogel , Isidoor De Grave , Klaus Hahn , Joachim Fischer
IPC分类号： C08J9/18 , C08L23/02 , C08J9/10
CPC分类号： C08J9/18 , C08J2203/06 , C08J2323/02
摘要： Expanded polyolefin particles are produced by impregnation of polyolefin granules with a volatile blowing agent in suspension under pressure and subsequent decompression. The blowing agent used is ammonia.
摘要翻译： PCT No.PCT / EP96 / 02116 Sec。 371日期：1997年11月24日 102（e）1997年11月24日PCT PCT 1996年5月17日PCT公布。第WO96 / 37541号公报日期1996年11月28日扩展的聚烯烃颗粒通过在压力悬浮液中随后减压的挥发性发泡剂浸渍聚烯烃颗粒来制备。使用的发泡剂是氨。

4. 发明授权

US4369227A Particulate styrene polymers containing blowing agent 失效
标题翻译：含发泡剂的颗粒状苯乙烯聚合物
公开(公告)号：US4369227A
公开(公告)日：1983-01-18
申请号：US356308
申请日：1982-03-10
申请人： Klaus Hahn , Hans P. Rath , Heinz Krapf , Isidoor De Grave , Manfred Walter
发明人： Klaus Hahn , Hans P. Rath , Heinz Krapf , Isidoor De Grave , Manfred Walter
IPC分类号： C08J9/22 , C08J9/224 , C08J9/232
CPC分类号： C08J9/224 , C08J2325/04 , Y10T428/249987 , Y10T428/2998
摘要： Particulate styrene polymers which contain a blowing agent and are surface-coated with from 0.05 to 1% by weight of an ester. The coating agent is a hydroxycarboxylic acid ester, or an ester of a carboxylic acid with an oxyalkylated alcohol; tristearyl citrate is a preferred ester.The styrene polymers can be used to produce foam moldings, with short mold dwell times and good welding of the foam particles.
摘要翻译：含有发泡剂并用0.05-1％（重量）酯表面包覆的颗粒状苯乙烯聚合物。涂层剂是羟基羧酸酯，或羧酸与烷氧基化醇的酯; 柠檬酸三硬脂酸酯是优选的酯。苯乙烯聚合物可用于生产泡沫模制品，具有短的停留时间和良好的泡沫颗粒焊接。

5. 发明授权

US06458858B1 Biodegradable polyester material particles 有权
标题翻译：可生物降解的聚酯材料颗粒
公开(公告)号：US06458858B1
公开(公告)日：2002-10-01
申请号：US09926509
申请日：2001-11-13
申请人： Frank Braun , Guiscard Glück , Klaus Hahn , Uwe Witt , Isidoor de Grave
发明人： Frank Braun , Guiscard Glück , Klaus Hahn , Uwe Witt , Isidoor de Grave
IPC分类号： C08J918
CPC分类号： C08J9/18 , C08J2203/06 , C08J2203/14 , C08J2367/02
摘要： In a process for preparing expanded or expandable polymer beads based on biodegradable saturated polyesters made from at least one diol and from at least one dicarboxylic acid, A. polymer pellets are dispersed in a liquid, B. a volatile blowing agent is injected into the dispersion and made to impregnate the pellets at an elevated temperature, C. the pressure on the dispersion is reduced at an elevated temperature, whereupon the pellets comprising blowing agent expand to give foam, and, respectively, D. the pellets are isolated from the liquid.
摘要翻译：在基于由至少一种二醇和至少一种二羧酸A制备的可生物降解的饱和聚酯制备膨胀或可膨胀聚合物珠粒的方法中。聚合物颗粒分散在液体B中。将挥发性发泡剂注入到分散体中并使其在升高的温度C下浸渍。分散体的压力在升高的温度下降低，于是包含发泡剂的颗粒膨胀以产生泡沫，并分别为D。颗粒与液体分离。

6. 发明授权

US5773481A Polyolefin particle foam 失效
标题翻译：聚烯烃颗粒泡沫
公开(公告)号：US5773481A
公开(公告)日：1998-06-30
申请号：US760406
申请日：1996-12-04
申请人： Joachim Fischer , Jens Rieger , Klaus Hahn , Isidoor De Grave , Wolfram Kogel
发明人： Joachim Fischer , Jens Rieger , Klaus Hahn , Isidoor De Grave , Wolfram Kogel
IPC分类号： C08J9/16 , C08J9/22 , C08J9/228 , C08L23/14
CPC分类号： C08J9/228 , B29C44/3461 , C08J9/16 , C08J2323/02 , C08L23/14
摘要： In a process for producing polyolefin foam particles, partially foamed particles are produced in a first stage by extrusion of a polyolefin containing solid blowing agents, and these are then further foamed in the second stage using steam.
摘要翻译：在制造聚烯烃泡沫颗粒的方法中，通过挤出含有固体发泡剂的聚烯烃，在第一阶段中制备部分发泡的颗粒，然后在第二阶段使用蒸汽进一步发泡。

7. 发明授权

US4459373A Pre-expanded plastic beads based on poly-para-methylstyrene 失效
标题翻译：基于聚对甲基苯乙烯的预膨胀塑料珠
公开(公告)号：US4459373A
公开(公告)日：1984-07-10
申请号：US531823
申请日：1983-09-13
申请人： Klaus Hahn , Isidoor De Grave , Rupert Schick
发明人： Klaus Hahn , Isidoor De Grave , Rupert Schick
IPC分类号： C08F2/18 , C08F2/38 , C08F2/44 , C08F12/12 , C08J9/20 , C08J9/18
CPC分类号： C08J9/20 , C08F12/12 , C08J2325/00
摘要： The invention relates to pre-expanded plastic beads based on poly-para-methylstyrene with the following properties:(a) the bead size lies between 0.2 and 3 cm,(b) the thermal stability, measured in accordance with DIN 53,424 is above 110.degree. C., and(c) the bulk density is below 35 g/l.The corresponding expandable plastic beads are prepared through the polymerization of para-methylstyrene in an aqueous suspension with the addition of volatile organic blowing agents during or after polymerization, whereby polymerization occurs in the presence of molecular-weight-regulating substances. Typical molecular-weight-regulating substances are organic chain transfer agents with a transfer constant K between 0.1 and 50, said agents being added in amounts ranging from 0.1 percent by weight to 1 percent by weight when a yield ranging from 20 to 95 percent is reached. Oligomers of the styrene or para-methylstyrene in quantities from 0.1 percent by weight to 10 percent by weight may also be employed.
摘要翻译：本发明涉及基于聚对甲基苯乙烯的预发泡塑料珠，具有以下特性：（a）珠粒尺寸在0.2和3厘米之间，（b）根据DIN 53,424测量的热稳定性高于110 ℃，（c）体积密度低于35g / l。通过在水性悬浮液中聚合对甲基苯乙烯来制备相应的可膨胀塑料珠，在聚合期间或之后加入挥发性有机发泡剂，由此在分子量调节物质存在下进行聚合。典型的分子量调节物质是转移常数K为0.1至50的有机链转移剂，当达到20至95％的产率时，所述试剂的加入量为0.1重量％至1重量％。也可以使用0.1重量％至10重量％的量的苯乙烯或对甲基苯乙烯的低聚物。

8. 发明授权

US06239185B1 Method for producing expanded polyolefin particles 有权
标题翻译：聚烯烃发泡粒子的制造方法
公开(公告)号：US06239185B1
公开(公告)日：2001-05-29
申请号：US09485686
申请日：2000-02-25
申请人： Frank Braun , Klaus Hahn , Manfred Leibach , Wolfram Kögel , Isidoor De Grave
发明人： Frank Braun , Klaus Hahn , Manfred Leibach , Wolfram Kögel , Isidoor De Grave
IPC分类号： C08J918
CPC分类号： C08J9/18 , C08J2203/06 , C08J2203/12 , C08J2323/10
摘要： A process comprises producing expanded polyolefin particles by impregnating polyolefin granules with a volatile blowing agent in suspension under pressure, and then releasing the pressure. The suspension medium has a lower density than the polyolefin granules and the suspension is practically free from suspension agents.
摘要翻译：一种方法包括通过在压力下用悬浮液中的挥发性发泡剂浸渍聚烯烃颗粒，然后释放压力来生产发泡聚烯烃颗粒。悬浮介质的密度低于聚烯烃颗粒，悬浮液实际上不含悬浮剂。

9. 发明授权

US4520135A Particulate polystyrene containing blowing agent and having improved expandability 失效
标题翻译：含有发泡剂的颗粒状聚苯乙烯并具有改善的膨胀性
公开(公告)号：US4520135A
公开(公告)日：1985-05-28
申请号：US531658
申请日：1983-09-13
申请人： Klaus Hahn , Paul Wittmer , Isidoor De Grave , Rupert Schick , Adolf Echte
发明人： Klaus Hahn , Paul Wittmer , Isidoor De Grave , Rupert Schick , Adolf Echte
IPC分类号： C08F12/08 , C08J9/16 , C08J9/18 , C08J9/20
CPC分类号： C08J9/16 , C08F12/08 , C08J2325/06
摘要： Particulate polystyrene containing blowing agent and having improved expandability is based on polystyrene having a weight-average mean molecular weight of not more than from 130,000 to 180,000 and a molecular weight distribution curve in which the high molecular weight flank drops steeply. The expandable polystyrene particles are produced by polymerizing styrene in aqueous suspension in the presence of blowing agents and of chain transfer agents or styrene oligomers.
摘要翻译：含有聚苯乙烯的发泡剂并具有改善的膨胀性是基于重均分子量不大于130,000至180,000的聚苯乙烯和高分子量侧面急剧下降的分子量分布曲线。可发性聚苯乙烯颗粒通过在发泡剂和链转移剂或苯乙烯低聚物的存在下在水悬浮液中聚合苯乙烯来制备。

10. 发明授权

US4513105A Particulate polystyrene containing blowing agent and having improved expandability 失效
公开(公告)号：US4513105A
公开(公告)日：1985-04-23
申请号：US623211
申请日：1984-06-21
申请人： Klaus Hahn , Paul Wittmer , Isidoor De Grave , Rupert Schick , Adolf Echte
发明人： Klaus Hahn , Paul Wittmer , Isidoor De Grave , Rupert Schick , Adolf Echte
IPC分类号： C08J9/16 , C08F2/38 , C08F12/08 , C08J9/20 , C08J9/18
CPC分类号： C08J9/20 , C08F12/08 , C08J2325/00
摘要： Particulate polystyrene containing blowing agent and having improved expandability is based on polystyrene having a weight-average mean molecular weight of not more than from 130,000 to 180,000 and a molecular weight distribution curve in which the high molecular weight flank drops steeply. The expandable polystyrene particles are produced by polymerizing styrene in aqueous suspension in the presence of blowing agents and of chain transfer agents or styrene oligomers.

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