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    • 6. 发明授权
    • Thermal barrier coatings with high fracture toughness underlayer for improved impact resistance
    • 具有高断裂韧性底层的隔热涂层,以提高耐冲击性
    • US07255940B2
    • 2007-08-14
    • US10898776
    • 2004-07-26
    • Irene SpitsbergBrett Allen BoutwellRobert William Bruce
    • Irene SpitsbergBrett Allen BoutwellRobert William Bruce
    • B32B15/04F03B3/12
    • C23C14/08C23C28/321C23C28/3215C23C28/325C23C28/345C23C28/3455C23C28/42Y10T428/12611Y10T428/265
    • A reduced thermal conductivity thermal barrier coating having improved impact resistance for an underlying substrate of articles that operate at, or are exposed to, high temperatures. This coating comprises an inner high fracture toughness layer nearest to the underlying substrate and having a thickness up to about 5 mils (127 microns) sufficient to impart impact resistance to the thermal barrier coating, and comprises a zirconia-containing ceramic composition having a c/a ratio of the zirconia lattice in the range of from about 1.011 to about 1.016 and stabilized in the tetragonal phase by a stabilizing amount of a stabilizing metal oxide selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india, lanthana, gadolinia, neodymia, samaria, dysprosia, erbia, ytterbia, europia, praseodymia, and mixtures thereof. The thermal barrier coating further includes an outer thermal insulating layer adjacent to and overlaying the inner layer and comprising a ceramic thermal barrier coating material. The thermal barrier can be used to provide a thermally protected article having a substrate (e.g., metal substrate) and optionally a bond coat layer adjacent to and overlaying the substrate. The thermal barrier coating can be prepared by forming the inner high fracture toughness layer, followed by forming on the inner layer the outer thermal insulating layer.
    • 对于在高温下操作或暴露于高温的制品的下层基底,具有改善的抗冲击性的降低的导热性热障涂层。 该涂层包括最接近下面的基底的内部高断裂韧性层,其厚度至多约5密耳(127微米),足以赋予热障涂层耐冲击性,并且包含含有氧化锆的陶瓷组合物,其具有ac / a 氧化锆晶格的比例在约1.011至约1.016范围内,并通过稳定金属氧化物稳定化在四方相中,稳定金属氧化物选自氧化钇,氧化钙,二氧化铈,钪,氧化镁,印度,镧, 钆,痣,aria虫,恶臭,er虫,bia虫,欧罗巴,脯氨酸及其混合物。 隔热涂层还包括与内层相邻并覆盖内层的外部绝热层,并且包括陶瓷热障涂层材料。 热障可用于提供具有基底(例如,金属基底)和任选的邻近和覆盖基底的粘合涂层的热保护制品。 可以通过形成内部高断裂韧性层,然后在内层上形成外部绝热层来制备热障涂层。