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1. 发明授权

US5981804A Catalyst for production of unsaturated aldehyde and unsaturated carboxylic acid and method for production of unsaturated aldehyde and unsaturated carboxylic acid by use of the catalyst 失效
标题翻译：用于生产不饱和醛和不饱和羧酸的催化剂以及通过使用催化剂生产不饱和醛和不饱和羧酸的方法
公开(公告)号：US5981804A
公开(公告)日：1999-11-09
申请号：US995642
申请日：1997-12-22
申请人： Ikuo Kurimoto , Tatsuya Kawajiri , Hideo Onodera , Michio Tanimoto , Yukio Aoki
发明人： Ikuo Kurimoto , Tatsuya Kawajiri , Hideo Onodera , Michio Tanimoto , Yukio Aoki
IPC分类号： B01J23/887 , B01J27/053 , B01J35/00 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/23 , C07C51/25 , C07C45/34 , B01J23/84
CPC分类号： C07C51/23 , B01J23/002 , B01J23/8876 , B01J27/053 , B01J35/0006 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/252 , B01J2523/00 , B01J35/002
摘要： A catalyst for the production of unsaturated aldehyde and unsaturated carboxylic acid by the vapor-phase catalytic oxidation of at least one compound selected from the group consisting of propylene, isobutylene, t-butanol and methyl-t-butyl ether and a method for the production of unsaturated aldehyde and unsaturated carboxylic acid by the use of this catalyst are provided. The catalyst of this invention comprises (A) a catalyst having Mo, Bi and Fe as essential components and used for the production of unsaturated aldehyde and unsaturated carboxylic acid by vapor-phase catalytic oxidation of propylene, isobutylene, t-butanol and/or methyl-t-butyl ether and (B) a solid acid having acid strength (Ho) of not more than -11.93. Since this catalyst excels in catalytic activity and service life, it allows unsaturated aldehyde and unsaturated carboxylic acid to be produced stably at a high yield for a long time.
摘要翻译：用于通过气相催化氧化至少一种选自丙烯，异丁烯，叔丁醇和甲基叔丁基醚的化合物来生产不饱和醛和不饱和羧酸的催化剂及其制备方法的不饱和醛和不饱和羧酸。本发明的催化剂包含（A）具有Mo，Bi和Fe作为必需组分的催化剂，用于通过丙烯，异丁烯，叔丁醇和/或甲基的气相催化氧化生产不饱和醛和不饱和羧酸叔丁基醚和（B）酸强度（Ho）不大于-11.93的固体酸。由于该催化剂在催化活性和使用寿命方面优异，因此可以长时间以高产率稳定地制备不饱和醛和不饱和羧酸。

2. 发明授权

US5700752A Catalyst for production of unsaturated aldehyde and unsaturated carboxylic acid and method for production of unsaturated aldehyde and unsaturated carboxylic acid by the use of the catalyst 失效
标题翻译：用于生产不饱和醛和不饱和羧酸的催化剂以及通过使用催化剂生产不饱和醛和不饱和羧酸的方法
公开(公告)号：US5700752A
公开(公告)日：1997-12-23
申请号：US456062
申请日：1995-05-31
申请人： Ikuo Kurimoto , Tatsuya Kawajiri , Hideo Onodera , Michio Tanimoto , Yukio Aoki
发明人： Ikuo Kurimoto , Tatsuya Kawajiri , Hideo Onodera , Michio Tanimoto , Yukio Aoki
IPC分类号： B01J23/887 , B01J27/053 , B01J35/00 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/23 , C07C51/25 , B01J23/25 , B01J23/30 , B01J23/31
CPC分类号： C07C51/23 , B01J23/002 , B01J23/8876 , B01J27/053 , B01J35/0006 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/252 , B01J2523/00 , B01J35/002
摘要： A catalyst for the production of unsaturated aldehyde and unsaturated carboxylic acid by the vapor-phase catalytic oxidation of at least one compound selected from the group consisting of propylene, isobutylene, t-butanol and methyl-t-butyl ether and a method for the production of unsaturated aldehyde and unsaturated carboxylic acid by the use of this catalyst are provided. The catalyst of this invention comprises (A) a catalyst having Mo, Bi and Fe as essential components and used for the production of unsaturated aldehyde and unsaturated carboxylic acid by vapor-phase catalytic oxidation of propylene, isobutylene, t-butanol and/or methyl-t-butyl ether and (B) a solid acid having acid strength (Ho) of not more than -11.93. Since this catalyst excels in catalytic activity and service life, it allows unsaturated aldehyde and unsaturated carboxylic acid to be produced stably at a high yield for a long time.
摘要翻译：用于通过气相催化氧化至少一种选自丙烯，异丁烯，叔丁醇和甲基叔丁基醚的化合物来生产不饱和醛和不饱和羧酸的催化剂及其制备方法的不饱和醛和不饱和羧酸。本发明的催化剂包含（A）具有Mo，Bi和Fe作为必需组分的催化剂，用于通过丙烯，异丁烯，叔丁醇和/或甲基的气相催化氧化生产不饱和醛和不饱和羧酸叔丁基醚和（B）酸强度（Ho）不大于-11.93的固体酸。由于该催化剂在催化活性和使用寿命方面优异，因此可以长时间以高产率稳定地制备不饱和醛和不饱和羧酸。

3. 发明授权

US5618974A Catalyst for production of methacrylic acid and method for production of methacrylic acid by the use of the catalyst 失效
标题翻译：用于生产甲基丙烯酸的催化剂和通过使用催化剂生产甲基丙烯酸的方法
公开(公告)号：US5618974A
公开(公告)日：1997-04-08
申请号：US456061
申请日：1995-05-31
申请人： Ikuo Kurimoto , Hideo Onodera , Yukio Aoki
发明人： Ikuo Kurimoto , Hideo Onodera , Yukio Aoki
IPC分类号： B01J27/053 , B01J27/199 , B01J35/00 , C07C57/055 , B01J27/16
CPC分类号： B01J27/199 , B01J23/002 , B01J27/053 , B01J35/0006 , B01J2523/00
摘要： A catalyst for the production of methacrylic acid by the vapor-phase catalyst oxidation and/or oxidative dehydrogenation of at least one compound selected rom the group consisting of methacrolein, isobutyl aldehyde, and isobutyric acid and a method for the production of methacrylic acid by the use of this catalyst are provided. The catalyst of this invention comprises (A) a composite oxide having Mo and P as essential components and used for the production of methacrylic acid by vapor-phase catalytic oxidation and/or oxidative dehydrogenation of methacrolein, isobutyl aldehyde, and/or isobutyric acid and (B) a solid acid having acid strength (Ho) of not more than -11.93. Since this catalyst excels in catalytic activity and service life, it allows methacrylic acid to be produced stably at a high yield for a long time.
摘要翻译：用于通过气相催化剂氧化和/或氧化脱氢至少一种选自甲基丙烯醛，异丁醛和异丁酸的化合物生产甲基丙烯酸的催化剂，以及由甲基丙烯酸生产甲基丙烯酸的方法提供了该催化剂的使用。本发明的催化剂包含（A）具有Mo和P作为必要组分并用于通过气相催化氧化和/或氧化脱氢甲基丙烯醛，异丁醛和/或异丁酸生产甲基丙烯酸的复合氧化物，和（B）酸强度（Ho）为-11.93以下的固体酸。由于该催化剂在催化活性和使用寿命方面优异，因此能够以高产率长时间稳定地生产甲基丙烯酸。

4. 发明授权

US5276178A Process for producing methacrolein and methacrylic acid 失效
标题翻译：甲基丙烯醛和甲基丙烯酸的制备方法
公开(公告)号：US5276178A
公开(公告)日：1994-01-04
申请号：US721574
申请日：1991-08-02
申请人： Hideo Onodera , Shigeru Ohno , Ikuo Kurimoto , Yukio Aoki
发明人： Hideo Onodera , Shigeru Ohno , Ikuo Kurimoto , Yukio Aoki
IPC分类号： B01J8/06 , B01J23/88 , B01J23/887 , B01J23/888 , B01J27/057 , B01J27/186 , B01J27/192 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/23 , C07C51/235 , C07C51/25 , C07C57/05 , C07C51/16 , C07C51/00
CPC分类号： B01J23/8873 , B01J23/002 , B01J23/88 , B01J23/887 , B01J23/8872 , B01J23/8875 , B01J23/8876 , B01J23/8885 , B01J27/0576 , B01J27/186 , B01J27/192 , B01J8/06 , C07C45/32 , C07C45/35 , C07C45/37 , C07C51/23 , C07C51/235 , C07C51/252 , B01J2208/025 , B01J2523/00
摘要： The present invention provides a process for producing methacrolein and methacrylic acid by subjecting at least one material selected from isobutylene, t-butanol and methyl t-butyl ether to gas phase catalytic oxidation with molecular oxygen or a molecular oxygen-containing gas using a fixed bed multi-tubular reactor.
摘要翻译： PCT No.PCT / JP90 / 01594 Sec。 371日期1991年8月2日 102（e）1991年8月2日PCT PCT 1990年12月6日PCT公布。出版物WO91 / 08185 日本6月13日，1991年。本发明提供了通过使选自异丁烯，叔丁醇和甲基叔丁基醚中的至少一种的材料用分子氧或分子氧进行气相催化氧化来制备异丁烯醛和甲基丙烯酸的方法使用固定床多管式反应器。

5. 发明授权

US5153162A Catalyst for the production of methacrylic acid 失效
标题翻译：催化剂生产甲基丙烯酸
公开(公告)号：US5153162A
公开(公告)日：1992-10-06
申请号：US574139
申请日：1990-08-29
申请人： Ikuo Kurimoto , Hideto Hashiba , Hideo Onodera , Yukio Aoki
发明人： Ikuo Kurimoto , Hideto Hashiba , Hideo Onodera , Yukio Aoki
IPC分类号： B01J27/19 , B01J27/192 , B01J27/199 , C07C51/235 , C07C51/25 , C07C51/377 , C07C57/055
CPC分类号： B01J23/002 , B01J27/19 , B01J27/192 , B01J27/199 , C07C51/235 , C07C51/252 , C07C51/377 , B01J2523/00
摘要： A catalyst for the production of methacrylic acid composed of an inert carrier and a catalytically active substance. The catalytically active substance layer being composed of oxides represented by the following formula (I)Mo.sub.a P.sub.b a.sub.c B.sub.d C.sub.e D.sub.f O.sub.x (I)where Mo represents molybdenum, P represents phosphorus, A represents at least one element selected from arsenic, antimony, germanium, bismuth, zirconium, cerium and selenium, B is at least one element selected from copper, iron, chromium, nickel, maganese, cobalt, tin, silver, zinc, palladium, rhodium and tellurium, C represents at least one element selected from vanadium, tungsten and niobium, D represents at least one element selected from alkali metals, alkaline earth metals and thallium, and O represents oxygen, a, b, c, d, e, f and x respectively represent the atomic ratios of Mo, P, A, B, C, D and O, and when a=12, b=0.5-4, c=0-5, d=0-3, e=0-4, and f=0.01-4, and x is a numerical value determined by the oxidation states of these elements. The catalytically active substance layers are formed by mixing compounds of the elemental components of the oxides of formula (I), as required, heating them to prepare a slurry or a solution, spraying the slurry or solution onto the inert carrier, and calcining the inert carrier so sprayed.

6. 发明授权

US5264627A Method for production of methacrylic acid 失效
标题翻译：甲基丙烯酸生产方法
公开(公告)号：US5264627A
公开(公告)日：1993-11-23
申请号：US909649
申请日：1992-07-07
申请人： Hiroyuki Tazaki , Ikuo Kurimoto , Hiroyuki Uhara , Yukio Aoki
发明人： Hiroyuki Tazaki , Ikuo Kurimoto , Hiroyuki Uhara , Yukio Aoki
IPC分类号： B01J23/88 , B01J27/188 , C07B61/00 , C07C51/235 , C07C51/25 , C07C57/05 , C07C57/055 , C07C51/00
CPC分类号： C07C51/25 , C07C51/235 , C07C51/252
摘要： A method for the production of methacrylic acid comprising the steps of simultaneously introducing at least one compound selected from the group consisting of methacrolein and isobutyl aldehyde and a molecular oxygen-containing gas into a heat exchanger type shell-and-tube reaction vessel packed with an oxide catalyst containing molybdenum and phosphorus thereby effecting catalytic vapor-phase oxidation reaction and/or catalytic vapor-phase oxidative dehydrogenation reaction and consequently forming methacrylic acid, which method is characterized by having the empty space in the gas outlet part of said reaction vessel with a solid filler.
摘要翻译：一种生产甲基丙烯酸的方法，包括以下步骤：将同时引入至少一种选自甲基丙烯醛和异丁醛的化合物和含分子氧的气体引入到热交换器型管壳式反应容器中含有钼和磷的氧化物催化剂，从而进行催化气相氧化反应和/或催化气相氧化脱氢反应，从而形成甲基丙烯酸，该方法的特征在于在反应容器的气体出口部分具有空的空间，固体填料。

7. 发明授权

US5206431A Process for producing methacrylic acid 失效
标题翻译：生产甲基丙烯酸的方法
公开(公告)号：US5206431A
公开(公告)日：1993-04-27
申请号：US928184
申请日：1992-08-14
申请人： Hideto Hashiba , Shigeru Ohno , Ikuo Kurimoto , Yukio Aoki
发明人： Hideto Hashiba , Shigeru Ohno , Ikuo Kurimoto , Yukio Aoki
IPC分类号： B01J27/19 , B01J27/199 , B01J35/00 , C07C51/25 , C07C51/377
CPC分类号： C07C51/377 , B01J23/002 , B01J27/19 , B01J27/199 , B01J35/0006 , C07C51/252 , B01J2523/00
摘要： A process for producing methacrylic acid, which comprisesfilling a plurality of catalysts of different activities into a plurality of reaction zones which have been formed in each of the reaction tubes of a fixed bed multi-tubular reactor by dividing said reaction tube into two or more portions in the direction of tubular axis, so that the activity of catalyst is higher as the reaction zone is closer to the outlet of the reaction tube, andintroducing into the reaction zones containing the catalysts at least one compound selected from methacrolein, isobutyl aldehyde and isobutyric acid to oxidize the at least one compound with molecular oxygen or a molecular oxygen-containing gas.
摘要翻译：一种生产甲基丙烯酸的方法，其包括将多种不同活性的催化剂填充到通过将所述反应管分成两个或更多个而在固定床多管式反应器的每个反应管中形成的多个反应区中使得催化剂的活性随着反应区域更靠近反应管的出口而更高，并且在含有催化剂的反应区中引入至少一种选自甲基丙烯醛，异丁醛和异丁酸，以用分子氧或含分子氧的气体氧化至少一种化合物。

8. 发明授权

US4760153A Process for producing maleic anhydride 失效
标题翻译：马来酸酐生产工艺
公开(公告)号：US4760153A
公开(公告)日：1988-07-26
申请号：US842934
申请日：1986-03-24
申请人： Youjirou Takahashi , Junichi Toyoda , Toshimasa Kushihara , Ikuo Kurimoto , Shigemi Osaka , Yoshiyuki Nakanishi
发明人： Youjirou Takahashi , Junichi Toyoda , Toshimasa Kushihara , Ikuo Kurimoto , Shigemi Osaka , Yoshiyuki Nakanishi
IPC分类号： B01J27/199 , B01J35/00 , C07C51/31 , C07D307/60
CPC分类号： B01J23/002 , B01J27/199 , B01J35/0006 , C07C51/313 , B01J2523/00
摘要： An improved process for producing maleic anhydride which comprises catalytically oxidizing benzene with a molecular oxygen-containing gas in the vapor phase in a multitubular heat-exchanger-type reactor. The process is characterized in thata catalyst-packed layer of the reactor is divided into a gas inlet side layer and a gas outlet side layer,the activity of the gas inlet side layer is controlled by adding at least one component selected from the group consisting of potassium, cesium, thallium and rubidium as a promoter or by decreasing the amount of phosphorus pentoxide (P.sub.2 O.sub.5) to be added in the catalytically active substance containing vanadium pentoxide, molybdenum trioxide and sodium oxide, andthe activity of the gas outlet side layer is increased by decreasing the amount of at least one component selected from the group consisting of potassium, cesium, thallium, rubidium, magnesium, calcium, strontium and barium or by not adding such a component from that in the catalyst, or by increasing the amount of phosphorus pentoxide (P.sub.2 O.sub.5) from the gas inlet side catalyst.
摘要翻译：一种生产马来酸酐的改进方法，其包括在多管式热交换器型反应器中在气相中用分子氧气体催化氧化苯。该方法的特征在于将反应器的催化剂填充层分成气体入口侧层和气体出口侧层，通过加入至少一种选自以下的组分来控制气体入口侧层的活性：钾，铯，铊和铷作为助催化剂或通过减少含有五氧化二钒，三氧化钼和氧化钠的催化活性物质中添加的五氧化二磷（P 2 O 5）的量，气体出口侧层的活性为通过减少选自钾，铯，铊，铷，镁，钙，锶和钡中的至少一种成分的量来增加，或者不将这样的成分从催化剂中添加，或者通过增加来自气体入口侧催化剂的五氧化二磷（P 2 O 5）。

9. 发明授权

US4665200A Method for preparing pyromellitic acid and/or pyromellitic anhydride 失效
标题翻译：制备均苯四酸和/或均苯四酸酐的方法
公开(公告)号：US4665200A
公开(公告)日：1987-05-12
申请号：US841833
申请日：1986-03-20
申请人： Yoshiyuki Nakanishi , Yoji Akazawa , Ikuo Kurimoto , Youjirou Takahashi , Shinichi Uchida , Hisashi Yoshikawa
发明人： Yoshiyuki Nakanishi , Yoji Akazawa , Ikuo Kurimoto , Youjirou Takahashi , Shinichi Uchida , Hisashi Yoshikawa
IPC分类号： B01J23/00 , B01J23/20 , B01J35/02 , B01J37/02 , C07C51/265 , C07D307/89
CPC分类号： C07C51/265 , B01J23/002 , B01J23/20 , B01J2523/00 , B01J35/026 , B01J37/0223
摘要： In a method for the preparation of pyromellitic acid or its anhydride by catalytic vapor phase oxidation of a tetra-C.sub.1 -C.sub.4 -alkylbenzene using a catalyst comprising catalytically active material composed of 1 to 20 parts by weight of V.sub.2 O.sub.5, 99 to 80 parts by weight of TiO.sub.2 and/or SnO.sub.2 and/or ZrO.sub.2, and per one hundred parts by weight of V.sub.2 O.sub.5, TiO.sub.2 and/or SnO.sub.2 and/or ZrO.sub.2 0.02 to 10 parts by weight, calculated as P.sub.2 O.sub.5, of a phosphorus compound, 0.01 to 5 parts by weight, calculated as Nb.sub.2 O.sub.5, of a niobium compound, 0 to 1.2 parts by weight, calculated as oxide, of at least one metal selected from the group consisting of potassium, cesium, rubidium and thallium, and 0 to 10 parts by weight, calculated as Sb.sub.2 O.sub.3, of an antimony compound, and an inert carrier supporting said catalytically active material thereon, the improvement in which said catalyst is divided into at least two layers, a layer on the gas inlet side and a layer on the gas outlet side, and (i) the content of potassium, cesium, rubidium or thallium is higher in the catalyst layer on the gas inlet side than in the catalyst layer on the gas outlet side, or (ii) the content of the phosphorus compound is lower in the catalyst layer on the gas inlet side than in the catalyst layer on the gas outlet side, or (iii) the surface area of TiO.sub.2 and/or SnO.sub.2 and/or ZrO.sub.2 is lower in the catalyst layer on the gas inlet side than in the catalyst layer on the gas outlet side.
摘要翻译：在通过使用包含由1-20重量份V 2 O 5组成的催化活性材料的催化剂四丁基-C1-烷基苯的催化气相氧化制备1,2,4,5-苯四酸或其酸酐的方法中，99至80重量份的TiO 2和/或SnO 2和/或ZrO 2，并且每100重量份的V 2 O 5，TiO 2和/或SnO 2和/或ZrO 2为0.02至10重量份，以P2O5计，磷化合物为0.01至5重量份以Nb 2 O 5计，铌化合物，0〜1.2重量份（以氧化物计）为至少一种选自钾，铯，铷和铊的金属，0〜10重量份，以锑化合物计，锑化合物和负载其上的催化活性物质的惰性载体，其中所述催化剂分为至少两层，气体入口侧的层和气体出口侧的层的改进，和（i）钾，铯，r的含量氦或铊在气体入口侧的催化剂层中高于气体出口侧的催化剂层，或者（ⅱ）在气体入口侧的催化剂层中的含量比在催化剂中低或（iii）在气体导入侧的催化剂层中，与气体出口侧的催化剂层相比，TiO 2和/或SnO 2和/或ZrO 2的表面积较低。

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