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    • 4. 发明授权
    • High tenacity polyethylene-2, 6-naphthalate fibers having excellent processability
    • 高韧性的聚2,6-萘二甲酸乙二醇酯纤维具有优异的加工性能
    • US06955854B2
    • 2005-10-18
    • US10763543
    • 2004-01-23
    • Ik-Hyeon KwonWoo-Sung KimYun-Hyuk BangYoung-Jo KimChan-Min Park
    • Ik-Hyeon KwonWoo-Sung KimYun-Hyuk BangYoung-Jo KimChan-Min Park
    • B60C9/00C08K3/36C08L67/02D01F1/10D01F6/62D01F6/92D02G3/48D01F6/00
    • B60C9/0042D01F1/10D01F6/62D02G3/48D10B2321/021Y10T428/2913Y10T428/2927Y10T428/2969
    • The present invention relates to a high tenacity polyethylene naphthalate fiber containing a silica compound. This fiber is produced by a method comprising the steps of: (A) melt-spinning a solid phase-polymerized polyethylene-2,6-naphthalate chip containing ethylene-2,6-naphthalate units at more than 85 mole % and a silica compound and having an intrinsic viscosity of 0.70-1.20, to produce a melt-spun yarn; (B) passing the melt-spun yarn through a retarded cooling zone and a cooling zone to solidify the yarn; (C) withdrawing the yarn at such a speed that the undrawn yarn has a birefringence of 0.001-0.1; and (D) subjecting the undrawn yarn to multi-stage drawing at a total draw ratio of at least 1.5 and a drawing temperature of 50-250° C. The polyethylene naphthalate fiber has improved physical properties, such as high tenacity, and a dipped cord produced from this fiber has excellent dimensional stability and tenacity such that it can be advantageously employed as a reinforcement material of rubber products.
    • 本发明涉及含有二氧化硅化合物的高韧性聚萘二甲酸乙二醇酯纤维。 该纤维通过包括以下步骤的方法制备:(A)将含有大于85摩尔%的乙烯-2,6-萘二甲酸酯单元的固相聚合的聚2,6-萘二甲酸乙二醇酯芯片熔融纺丝,以及二氧化硅化合物 并且具有0.70-1.20的特性粘度,以生产熔纺纱; (B)使熔纺纱通过延迟冷却区和冷却区使纱线固化; (C)以未拉伸纱线的双折射率为0.001-0.1的速度取出纱线; 和(D)使未拉伸丝以总拉伸比为至少1.5,拉伸温度为50-250℃的多段拉伸。聚萘二甲酸乙二醇酯纤维具有改善的物理性能,例如高强度,和浸渍 由该纤维制成的帘线具有优异的尺寸稳定性和韧性,使得其可以有利地用作橡胶制品的增强材料。