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    • 1. 发明授权
    • Hybrid solar cells based on nanostructured semiconductors and organic materials
    • 基于纳米结构半导体和有机材料的混合太阳能电池
    • US07618838B2
    • 2009-11-17
    • US11410796
    • 2006-04-25
    • Igor A. LevitskyWilliam B. EulerNatalya A. TokranovaBai XuJames Castracane
    • Igor A. LevitskyWilliam B. EulerNatalya A. TokranovaBai XuJames Castracane
    • H01L51/48H01L31/00
    • H01L51/4213H01L51/0037H01L51/0078H01L51/4253Y02E10/549
    • A method for forming a photovoltaic cell which includes forming a nanostructured layer in a semiconductor material having a plurality of pores opening onto a surface, the plurality of pores having a depth greater than about 1 micron and a diameter between about 5 nanometers and about 1,200 nanometers, and disposing an organic charge-transfer material in the pores of the nanostructured layer. A first electrode is attached to the semiconductor material, and a second electrode is attached to the organic charge-transfer material. The semiconductor material has a thickness between about 5 microns and about 700 microns. Desirably, the nanostructured layer has a porosity of less than the porosity corresponding to the percolation threshold, and the organic charge-transfer material extends at least about 100 nm from the surface of the nanostructured layer. The organic charge-transfer material may partially cover the sides of the pores of the nanostructured layer thereby providing a generally cylindrical cavity therein.
    • 一种形成光伏电池的方法,包括在半导体材料中形成纳米结构层,所述半导体材料具有在表面上开口的多个孔,所述多个孔的深度大于约1微米,直径在约5纳米至约1,200纳米 并且在纳米结构层的孔中设置有机电荷转移材料。 第一电极附接到半导体材料,第二电极附着到有机电荷转移材料上。 半导体材料具有约5微米至约700微米的厚度。 期望地,纳米结构层具有小于对应于渗滤阈值的孔隙率的孔隙率,并且有机电荷转移材料从纳米结构层的表面延伸至少约100nm。 有机电荷转移材料可以部分地覆盖纳米结构层的孔的侧面,从而在其中提供大致圆柱形的空腔。