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1. 发明授权

US5961805A Method and apparatus for producing deionized water 失效
标题翻译：用于生产去离子水的方法和设备
公开(公告)号：US5961805A
公开(公告)日：1999-10-05
申请号：US952218
申请日：1997-11-21
申请人： Ichiro Terada , Hiroshi Toda , Junjiro Iwamoto , Kazuo Umemura , Ken Komatsu , Tohru Hoshi , Mark Philip Huehnergard , David Florian Tessier , Ian Glenn Towe
发明人： Ichiro Terada , Hiroshi Toda , Junjiro Iwamoto , Kazuo Umemura , Ken Komatsu , Tohru Hoshi , Mark Philip Huehnergard , David Florian Tessier , Ian Glenn Towe
IPC分类号： B01D61/48 , B01J47/08 , C02F1/42 , C02F1/46 , C02F1/469
CPC分类号： C02F1/4695 , B01D61/48 , B01J47/08 , C02F1/42 , C02F1/4604 , C02F2201/46115
摘要： An apparatus for producing deionized water consisting essentially of an electrodialyzer having cation exchange membranes and anion exchange membranes alternately arranged between a cathode and an anode to form demineralizing compartments and concentrating compartments, and ion exchangers accommodated in the demineralizing compartments, wherein a pressure of from 0.1 to 20 kg/cm.sup.2 is exerted between the ion exchangers accommodated in the demineralizing compartments and the cation exchange membranes and anion exchange membranes defining the demineralizing compartments.
摘要翻译： PCT No.PCT / JP97 / 00896 Sec。 371日期：1997年11月21日 102（e）1997年11月21日PCT PCT 1997年3月19日PCT公布。公开号WO97 / 34696 日本1997年9月25日一种用于生产基本上由具有阳离子交换膜和交替布置在阴极和阳极之间的阴离子交换膜的电渗析器组成的去离子水的设备，以形成软化室和浓缩隔室，以及容纳在脱盐室中的离子交换器，其中在容纳在脱盐室中的离子交换膜和限定脱盐室的阳离子交换膜和阴离子交换膜之间施加0.1至20kg / cm2的压力。

2. 发明授权

US06338784B1 Apparatus for producing deionized water 失效
标题翻译：用于生产去离子水的设备
公开(公告)号：US06338784B1
公开(公告)日：2002-01-15
申请号：US09030943
申请日：1998-02-26
申请人： Ichiro Terada , Hiroshi Toda , Kazuo Umemura , Mark Philip Huehnergard , David Florian Tessier , Ian Glenn Towe
发明人： Ichiro Terada , Hiroshi Toda , Kazuo Umemura , Mark Philip Huehnergard , David Florian Tessier , Ian Glenn Towe
IPC分类号： B01D6148
CPC分类号： B01D61/48 , C02F1/4604 , C02F1/469
摘要： An apparatus for producing deionized water, comprising an electrodialyzer having cation exchange membranes and anion exchange membranes alternately arranged to form demineralizing compartments and concentrating compartments and having ion exchangers accommodated in the demineralizing compartments, and designed to conduct an electric current while supplying water to be treated to the demineralizing compartments, wherein a spacer is arranged in each concentrating compartment to maintain the thickness of the concentrating compartment, and the cation exchange membranes or the anion exchange membranes are incorporated in their dry state in the electrodialyzer, whereby water is supplied to the electrodialyzer, while each ion exchange membrane is brought in contact with the spacer by a pressure from the demineralizing compartment side.
摘要翻译：一种用于生产去离子水的设备，包括具有阳离子交换膜和阴离子交换膜的电渗析器，交替布置成形成脱盐室和浓缩室，并且具有容纳在脱盐室内的离子交换器，并设计成在供给被处理水的同时进行电流到脱盐室，其中在每个浓缩室中布置间隔物以保持浓缩室的厚度，并且阳离子交换膜或阴离子交换膜以其干燥状态并入电渗析器中，由此将水供应到电渗析器而每个离子交换膜通过来自脱盐处理室侧的压力与间隔物接触。

3. 发明授权

US06228240B1 Method and apparatus for producing deionized water 有权
标题翻译：用于生产去离子水的方法和设备
公开(公告)号：US06228240B1
公开(公告)日：2001-05-08
申请号：US09338570
申请日：1999-06-23
申请人： Ichiro Terada , Hiroshi Toda , Junjiro Iwamoto , Kazuo Umemura , Ken Komatsu , Tohru Hoshi , Mark Philip Huehnergard , David Florian Tessier , Ian Glenn Towe
发明人： Ichiro Terada , Hiroshi Toda , Junjiro Iwamoto , Kazuo Umemura , Ken Komatsu , Tohru Hoshi , Mark Philip Huehnergard , David Florian Tessier , Ian Glenn Towe
IPC分类号： B01D6148
CPC分类号： C02F1/4695 , B01D61/48 , B01J47/08 , C02F1/42 , C02F1/4604 , C02F2201/46115
摘要： An apparatus for producing deionized water consisting essentially of an electrodialyzer having cation exchange membranes and anion exchange membranes alternately arranged between a cathode and an anode to form demineralizing compartments and concentrating compartments, and ion exchangers accommodated in the demineralizing compartments, wherein a pressure of from 0.1 to 20 kg/cm2 is exerted between the ion exchangers accommodated in the demineralizing compartments and the cation exchange membranes and anion exchange membranes defining the demineralizing compartments.
摘要翻译：一种用于生产基本上由具有阳离子交换膜和交替布置在阴极和阳极之间的阴离子交换膜的电渗析器组成的去离子水的设备，用于形成脱盐室和浓缩室，以及容纳在脱盐室中的离子交换器，其中压力为0.1 在容纳在脱盐室中的离子交换剂和限定脱矿质隔室的阳离子交换膜和阴离子交换膜之间施加至20kg / cm 2。

4. 发明授权

US06193869B1 Modular apparatus for the demineralization of liquids 有权
标题翻译：用于液体软化的模块化设备
公开(公告)号：US06193869B1
公开(公告)日：2001-02-27
申请号：US09117775
申请日：1998-08-06
申请人： Ian Glenn Towe , David Florian Tessier , Mark Philip Huehnergard
发明人： Ian Glenn Towe , David Florian Tessier , Mark Philip Huehnergard
IPC分类号： B01D6148
CPC分类号： B01D61/52 , B01D61/48 , B01D61/50 , B01J47/08
摘要： A modular sysTem for the demineralization of aqueous liquids comprising a plurality of modular units, each of the modular units being encapsulated and having a cathode proximate a first end of the modular unit and an anode proximate the opposite end of said modular, a plurality of alternating diluting compartments and concentrating compartments positioned between the cathode and the anode, and ion exchange material positioned within the diluting compartments. Each of the diluting compartments has a compartment spacer with an elongated central cavity and a plurality of fine slit openings at each end adjacent the cavity. The ion exchange means comprise a porous and permeable continuous phase of cation or anion exchange resin particles and a porous and permeable dispersed phase of clusters of the other of the cation or anion exchange resin particles. Releasable connecting means are provided to interconnect the modular units in the system to allow for facile substitution of modular units for servicing and to permit modification of flow capacity requirements by increasing or decreasing the total number of modular units in the system.
摘要翻译：一种用于包含多个模块单元的水性液体脱矿质的模块化系统，每个模块单元被封装并且具有靠近模块化单元的第一端的阴极和靠近所述模块的相对端的阳极，多个交替位于阴极和阳极之间的稀释室和浓缩室以及位于稀释室内的离子交换材料。每个稀释隔室具有隔室间隔件，其具有细长的中心空腔和在与空腔相邻的每个端部处的多个细缝隙开口。离子交换装置包括阳离子或阴离子交换树脂颗粒的多孔且可渗透的连续相以及阳离子或阴离子交换树脂颗粒中另一个的簇的多孔且可渗透的分散相。提供可释放的连接装置以将系统中的模块化单元互连，以便容易地代替模块化单元进行维修，并允许通过增加或减少系统中模块化单元的总数来修改流量容量要求。

5. 发明授权

US6156180A Electrodeionization apparatus having geometric arrangement of ion exchange material 失效
标题翻译：具有离子交换材料几何排列的电离离子装置
公开(公告)号：US6156180A
公开(公告)日：2000-12-05
申请号：US142242
申请日：1998-07-13
申请人： David Florian Tessier , Joseph Denis Robert Toupin , Ian Glenn Towe
发明人： David Florian Tessier , Joseph Denis Robert Toupin , Ian Glenn Towe
IPC分类号： B01D43/00 , B01D61/48 , B01J47/00 , B01J47/08 , C02F1/469
CPC分类号： B01D43/00 , B01D61/48 , B01J47/007 , B01J47/08 , C02F1/4695
摘要： An electrodeionization apparatus adapted to remove ions from a liquid, the apparatus having a cathode proximate a first end of the apparatus and an anode proximate the opposite end of the apparatus and having a plurality of alternating diluting compartments and concentrating compartments positioned between the cathode and the anode, the diluting and concentrating compartments defined by anion and cation permeable membranes, and ion exchange material positioned within the diluting compartments, the diluting compartments having therein a continuous phase of a first ion exchange material containing a dispersed phase of clusters of a second ion exchange material. The method of removing ions from a liquid in such an electrodeionization apparatus comprises passing an aqueous liquid to be purified through the diluting compartments in which the diluting compartments have the continuous phase of a first ion exchange material with the dispersed phase of a second ion exchange material.
摘要翻译： PCT No.PCT / CA97 / 00018 Sec。 371日期1998年8月21日 102（e）1998年8月21日PCT PCT 1997年1月13日PCT公布。公开号WO97 / 25147 日期1997年7月17日一种用于从液体中去除离子的电去离子装置，该装置具有靠近装置的第一端的阴极和靠近装置的相对端的阳极，并且具有多个交替的稀释隔室和集中隔室在阴极和阳极之间，由阴离子和阳离子可渗透膜定义的稀释和浓缩隔室以及位于稀释隔室内的离子交换材料，其中具有连续相的第一离子交换材料含有分散相的簇的第二离子交换材料。在这种电去离子装置中从液体中除去离子的方法包括将要净化的水性液体通过稀释室，其中稀释室具有第一离子交换材料的连续相，其中第二离子交换材料的分散相。

6. 发明授权

US06056878A Method and apparatus for reducing scaling in electrodeionization systems and for improving efficiency thereof 有权
标题翻译：用于减少电去离子系统中的结垢并提高其效率的方法和装置
公开(公告)号：US06056878A
公开(公告)日：2000-05-02
申请号：US127975
申请日：1998-08-03
申请人： David Florian Tessier , Tom Kosir , Steve Siverns , Mark Philip Huehnergard , Robert Glegg
发明人： David Florian Tessier , Tom Kosir , Steve Siverns , Mark Philip Huehnergard , Robert Glegg
IPC分类号： B01D61/48 , B01D61/52 , B01D61/58 , C02F1/42 , C02F1/44 , C02F1/46 , C02F1/469 , C02F5/00 , C02F9/00 , B01D15/04 , B01D61/02 , B03D3/06
CPC分类号： B01D61/58 , B01D61/48 , B01D61/52 , C02F1/4695 , B01D61/025 , C02F1/42 , C02F1/441 , C02F1/4602 , C02F1/4604 , C02F2201/46115 , C02F5/00
摘要： A method and apparatus for inhibiting scaling in an electrodeionization system or in a combined reverse osmosis/electrodeionization system for water treatment and, more particularly, for increasing tolerance to hardness in the feed water to an electrodeionization unit to inhibit precipitation of metal cations contained in the feed water and for increasing efficiency of the electrodeionization system. Water to be purified is passed through a electrodeionization unit in which a concentrate stream recycling through concentrating compartments and anode and cathode compartments contains effective amounts of an antiscalant to inhibit precipitation of scale. One or more preliminary reverse osmosis units in series with the electrodeionization unit preferably receives a portion of the antiscalants in the concentrate stream. The antiscalant in the water fed to the reverse osmosis unit can be supplemented and adjusted. Electrolyte can be provided to the concentrate stream of the electrodeionization unit from products of the reverse osmosis.
摘要翻译：一种用于抑制电去离子系统或用于水处理的组合反渗透/电去离子系统中的结垢的方法和装置，更具体地，用于增加供给到电去离子单元的进料中的硬度的耐受性，以抑制包含在给水和提高电去离子系统的效率。待净化的水通过电去离子单元，其中通过浓缩室和阳极和阴极室再循环的浓缩物流含有有效量的防垢剂以抑制垢的沉淀。与电去离子单元串联的一个或多个初步反渗透单元优选地接收浓缩物流中的一部分防垢剂。供给反渗透装置的水中的防垢剂可以进行补充和调整。可以从反渗透产物向电去离子单元的浓缩物流提供电解质。

7. 发明授权

US5944972A Method for producing deionized water 失效
标题翻译：去离子水的生产方法
公开(公告)号：US5944972A
公开(公告)日：1999-08-31
申请号：US47409
申请日：1998-03-25
申请人： Hiroshi Toda , Tohru Hoshi , David Florian Tessier
发明人： Hiroshi Toda , Tohru Hoshi , David Florian Tessier
IPC分类号： B01D61/48 , B01J47/08 , C02F1/42 , C02F1/46 , C02F1/469
CPC分类号： B01J47/08 , B01D61/48 , C02F1/4695 , C02F1/4604 , C02F2201/46115
摘要： A method for producing deionized water by self-regenerating type electrodialysis deionization, which comprises (i) using a deionized water-producing apparatus containing an electrodialyzer comprising cation exchange membranes and anion exchange membranes alternately arranged between an anode compartment provided with an anode and a cathode compartment provided with a cathode, demineralizing compartments compartmentalized with anion exchange membranes on the anode side and compartmentalized with cation exchange membranes on the cathode side, and concentrating compartments compartmentalized with cation exchange membranes on the anode side and compartmentalized with anion exchange membranes on the cathode side, the electrodialyzer having ion exchangers accommodated in the demineralizing compartments, and (ii) applying a voltage while supplying water to be treated to the demineralizing compartments to remove impurity ions in the water to be treated, wherein at least a part of the untreated water or already treated water is withdrawn to be added to a concentrating water for recycle, a flow amount of untreated water to be introduced into the demineralizing compartments being from 2 to 5.5 to a flow amount of a concentrating water to be introduced into the concentrating compartments, a linear velocity of untreated water in the demineralizing compartments being from 0.5 to 7.0 cm/sec, and a linear velocity of a concentrating water in the concentrating compartments being from 1.2 to 20 times to the linear velocity in the demineralizing compartments.
摘要翻译：一种通过自再生型电渗析去离子体制造去离子水的方法，其包括：（i）使用含有阳离子交换膜和阴离子交换膜的电渗析器的去离子水生产装置，所述阴离子交换膜交替布置在设置有阳极和阴极的阳极室之间隔室设有阴极，在阳极侧隔着阴离子交换膜分隔并在阳极侧隔开阳离子交换膜的脱盐室，以及在阳极侧与阴离子交换膜分隔的浓缩室，并在阴极侧隔着阴离子交换膜所述电渗析器具有容纳在所述软化室中的离子交换器，以及（ii）在将待处理的水供应到所述去矿质隔间以施加电压以除去待处理水中的杂质离子，其中至少一部分未处理将水或已经处理的水取出以加入到浓缩水中进行再循环，待引入脱盐室的未处理水的流量为2至5.5，以引入浓缩室中的浓缩水的流量软化室中的未处理水的线速度为0.5-7.0cm / sec，浓缩室中浓缩水的线速度为脱盐室中的线速度的1.2〜20倍。

8. 发明授权

US6149788A Method and apparatus for preventing scaling in electrodeionization units 有权
标题翻译：用于防止电去电离单元中的结垢的方法和装置
公开(公告)号：US6149788A
公开(公告)日：2000-11-21
申请号：US174248
申请日：1998-10-16
申请人： David Florian Tessier , Robert Glegg , John H. Barber
发明人： David Florian Tessier , Robert Glegg , John H. Barber
IPC分类号： B01D61/48 , B01D61/52 , B01D61/54 , C02F1/42 , C02F1/44 , C02F1/46 , C02F1/469 , C02F9/00
CPC分类号： C02F1/4602 , B01D61/48 , B01D61/52 , C02F1/4695 , C02F1/42 , C02F1/441 , C02F2201/4611 , C02F2201/46115
摘要： A method and apparatus is provided for inhibiting scaling in an electrodeionization system and, more particularly, for increasing tolerance to hardness in the feed water to an electrodeionization unit by inhibiting precipitation of scale-forming metallic cations contained in the feed water and thereby increasing efficiencies of the electrodeionization system. Water to be purified is passed through an electrodeionization unit in which the flow in the diluting compartment is countercurrent to the flow in the concentrating compartment. This is to impede the migration of scale-forming metallic cations from the diluting compartment, through the cation exchange membrane, into the concentrating compartment and towards the concentrating compartment side of the anion exchange membrane, thereby preventing scale formation on the anion exchange membrane. The electrodeionization unit may be further modified by dividing the concentrating compartments into first and second compartments by a porous diaphragm or ion-conducting membrane. The porous diaphragm or ion-conducting membrane effectively eliminates convective transport of scale-forming metallic cations from the cation exchange membrane side of the concentrating compartment to the anion exchange membrane side of the concentrating compartment, thereby inhibiting scale formation on the anion exchange membrane.
摘要翻译：提供了一种用于抑制电去离子系统中的结垢的方法和装置，更具体地，通过抑制进料水中包含的形成规模的金属阳离子的沉淀，增加对去电单元的给水中的硬度的耐受性，从而提高电去离子系统。待净化的水通过电去离子单元，其中稀释室中的流动与浓缩室中的流动逆流。这是为了阻止鳞片形成金属阳离子从稀释室通过阳离子交换膜迁移到浓缩室中并朝向阴离子交换膜的浓缩室侧迁移，从而防止阴离子交换膜上的结垢形成。可以通过多孔隔膜或离子传导膜将浓缩室分成第一和第二隔室来进一步修改电去离子单元。多孔隔膜或离子导电膜有效地消除了形成规模的金属阳离子从浓缩室的阳离子交换膜侧到浓缩室的阴离子交换膜侧的对流传输，从而抑制阴离子交换膜上的结垢。

9. 发明授权

US08168055B2 Arrangement of ion exchange material within an electrodeionization apparatus 有权
公开(公告)号：US08168055B2
公开(公告)日：2012-05-01
申请号：US12923227
申请日：2010-09-10
申请人： John H. Barber , David Florian Tessier
发明人： John H. Barber , David Florian Tessier
IPC分类号： B01D61/48
CPC分类号： B01D61/48 , B01D2313/28 , B01D2321/22 , C02F1/4695 , C02F2201/46115
摘要： An electrodeionization apparatus is provided comprising an ion-concentrating compartment partially bounded by an anion permeable membrane and also partially bounded by a cation permeable membrane, and a first ion exchange material domain disposed within the ion-concentrating compartment, wherein the first ion exchange material domain is contiguous with at least a portion of an ion-concentrating compartment side surface of one of the anion permeable membrane and the cation permeable membrane, and is spaced apart from the other one of the one of the anion permeable membrane and the cation permeable membrane. In the case where the one of the anion permeable membrane and the cation permeable membrane, having the at least a portion of an ion-concentrating compartment side surface with which the first ion exchange material domain is contiguous, is an anion permeable membrane, the first ion exchange material domain is an anion exchange material predominant domain. In the case where the one of the anion permeable membrane and the cation permeable membrane, having the at least a portion of an ion-concentrating compartment side surface with which the first ion exchange material domain is contiguous, is a cation permeable membrane, the first ion exchange material domain is a cation exchange material predominant domain.

10. 发明授权

US08066860B2 Arrangement of ion exchange material within an electrodeionization apparatus 有权
标题翻译：离子交换材料在电去电离装置内的布置
公开(公告)号：US08066860B2
公开(公告)日：2011-11-29
申请号：US11525211
申请日：2006-09-22
申请人： John H. Barber , David Florian Tessier
发明人： John H. Barber , David Florian Tessier
IPC分类号： B01D61/48
CPC分类号： B01D61/48 , B01D2313/28 , B01D2321/22 , C02F1/4695 , C02F2201/46115
摘要： An electrodeionization apparatus is provided comprising an ion-concentrating compartment partially bounded by an anion permeable membrane and also partially bounded by a cation permeable membrane, and a first ion exchange material domain disposed within the ion-concentrating compartment, wherein the first ion exchange material domain is contiguous with at least a portion of an ion-concentrating compartment side surface of one of the anion permeable membrane and the cation permeable membrane, and is spaced apart from the other one of the one of the anion permeable membrane and the cation permeable membrane. In the case where the one of the anion permeable membrane and the cation permeable membrane, having the at least a portion of an ion-concentrating compartment side surface with which the first ion exchange material domain is contiguous, is an anion permeable membrane, the first ion exchange material domain is an anion exchange material predominant domain. In the case where the one of the anion permeable membrane and the cation permeable membrane, having the at least a portion of an ion-concentrating compartment side surface with which the first ion exchange material domain is contiguous, is a cation permeable membrane, the first ion exchange material domain is a cation exchange material predominant domain.
摘要翻译：提供了一种电去离子装置，其包括部分地由阴离子可渗透膜界定并且部分地由阳离子可渗透膜界定的离子浓缩室和设置在离子浓缩室内的第一离子交换材料区域，其中第一离子交换材料区域与阴离子可渗透膜和阳离子可渗透膜之一的离子浓缩室侧表面的至少一部分相邻，并且与阴离子可渗透膜和阳离子可渗透膜中的另一个间隔开。在具有离子浓缩室侧表面的至少一部分与第一离子交换材料区域相邻的阴离子可渗透膜和阳离子透过膜中的一个是阴离子可渗透膜的情况下，第一离子交换材料域是阴离子交换材料主导域。在具有离子浓缩室侧表面的至少一部分与第一离子交换材料区域相邻的阴离子可渗透膜和阳离子可渗透膜之一是阳离子可渗透膜的情况下，第一离子交换材料域是阳离子交换材料的主导域。

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